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1
ENERGY FROM WASTE
(AEE551)
IARE-R16 B.Tech VII SEM
COMMON FOR ALL
Prepared by
Mr. Ch. Bala Krishna, Assistant Professor
Ms. B.Bhavani, Assistant Professor
2
COURSE OUTLINE
5
• S. K. Agarwal, “Industrial Environment Assessment and Strategy”, APH
Publishing Corporation, New Delhi, 1996.
• Sofer, Samir S. (ed.), Zaborsky, R. (ed.), “Biomass Conversion Processes
for Energy and Fuels”, New York, Plenum Press, 1981.
• Hagerty, D.Joseph; Pavoni, Joseph L; Heer, John E., “Solid Waste
Management‖, New York, Van Nostrand, 1973.
• George Tchobanoglous, Hilary Theisen and Samuel Vigil Prsl:
Tchobanoglous, George Theisen, Hillary Vigil, Samuel, “Integrated Solid
Waste management: Engineering Principles and Management issues”,
New York, McGraw Hill, 1993.
6
REFERENCE BOOKS
7
COURSE OBJECTIVES
8
UNIT 1
INTRODUCTION TO WASTE
AND WASTE PROCESSING
9
CONTENTS
10
INTRODUCTION TO SOLID WASTE
• Definition- Any
useless, discarded,
unwanted material
that is not a liquid or
gas is referred as solid
waste or refuse.
12
CLASSIFICATION OF SOLID WASTE
15
TYPE BASED CLASSIFICATION
16
TYPE BASED CLASSIFICATION
17
TYPE BASED CLASSIFICATION
18
TYPE BASED CLASSIFICATION
19
TYPE BASED CLASSIFICATION
11. E waste– these are the electronic products nearing the end
of their useful life. It include discarded computers,
televisions, fax machines, copiers, cell phones, batteries.
20
COMPOSITION OF SOLID WASTE
22
COMPOSITION OF SOLID WASTE
1. Greenhouse gases:
Greenhouse gases cause the greenhouse effect. The primary
greenhouse gases in Earth's atmosphere are water vapor,
carbon dioxide, methane, nitrous oxide and ozone.
2. Burning fossil fuels:
When we burn fossil fuels like coal, and gas to create electricity
or power our cars, we release CO2 pollution into the
atmosphere.
3. Deforestation & Tree-Clearing:
Plants and trees play an important role in regulating the climate
because they absorb carbon dioxide from the air and release
oxygen back into it. Forests and bush land act as carbon sinks
and are a valuable means of keeping global warming to 1.5°C.
24
CAUSES OF GLOBAL WARMING
25
EFFECTS OF GLOBAL WARMING
26
WASTE CHARACTERISTICS
CHARACTERISTICS OF WASTE:
1. Physical
2. Chemical
3. Biological
27
PHYSICAL CHARACTERISTICS
30
PARTICLE SIZE
31
OTHER PROPERTIES
32
CHEMICAL CHARACTERISTICS
33
CHEMICAL PROPERTIES INCLUDES…
LIPIDS CARBOHYDRATES
1. This class of compounds 1. These are found primarily in
includes fats, oils and grease food and yard wastes, which
encompass sugar and polymer
2. principal sources of garbage,
of sugars (e.g., Starch,
cooking oils and fats.
cellulose, etc.) With general
3. Lipids have high heating formula (CH2O)X.
values, about 38,000 KJ/Kg,
2. Carbohydrates are readily
which makes them suitable
biodegraded to products such
for energy recovery.
as carbon dioxide, water and
4. Since lipids become liquid at methane.
temperatures slightly
3. Decomposting carbohydrates
ambient, they add to the
content during attract flies and rats and
decomposition. therfore should not be left
exposed for long time. 34
CHEMICAL PROPERTIES INCLUDES…
37
CHEMICAL PROPERTIES
38
BIOLOGICAL PROPERTIES
It includes:
39
COLLECTION OF SOLID WASTE
40
CLASSIFICATION
• Classified based on
availability of collection services,
the mode of operation and
the types of waste materials collected
• Primary Collection of solid waste from the source of generation
and transportation of waste to the final disposal site, but more
often it involves transportation to communal collection bins or
points, processing or transfer station
• Secondary Collection of waste from communal bins, storage
points or transfer station, and transportation to the final
disposal
41
COMMUNAL SCHEME OF COLLECTION
43
KERBSIDE/ALLEY
44
DOOR TO DOOR COLLECTION
45
BASED ON MODES OF OPERATION
Hauled containers:
• An empty storage container (known as a drop-off box) is
hauled to the storage site to replace the container that is full
of waste, which is then hauled to the processing point,
transfer station or disposal site
• The time required per trip Thcs = (PThcs + q + m + nx)
Where,
T = time per trip for hauled-container system, h/trip hcs .
PThcs= pick-up time per trip for hauled-container system,
h/trip q = at-site time per trip,
h/trip m = empirical haul constant, h/km
n = empirical haul constant, h/km
x = round-trip haul distance, km/trip 46
HAULED CONTAINER
47
HAULED CONTAINER
48
STATIONARY CONTAINERS
49
STATIONARY CONTAINERS
50
STATIONARY CONTAINERS
51
FREQUENCY OF COLLECTION
• Quantity of waste
• rate of generation
• characteristics of waste
• Climate
• density and type of housing
• availability of space within the premises
• size and type of storage facilities (small, large, individual or
communal)
• attitude of generators
52
TRANSFER STATION
56
BIOMEDICAL WASTE MANAGMENT
Hospitals
Nursing homes
Clinics
Medical laboratories
Blood banks
Mortuaries
Medical research & training centers
Biotechnology institution/production units
Animal houses etc.
Such a waste can also be generated at home if health care is
being provided there to a patient (e.g. injection, dressing material
etc.)
58
STORAGE
59
TRANSPORT
61
DISPOSAL OF BIOMEDICAL WASTE
INCINERATORS:
• A high temperature dry oxidation process, which reduces
organic and combustible waste to inorganic incombustible
matter.
• Usually used for the waste that can not be reused, recycled
or disposed of in landfill site
• The incinerator should be installed and made operational as
per specification under the BMW rules 1998
• Certificate may be taken from Central pollution control
board(CPCB)/State Pollution Control Board.
63
AUTOCLAVE AND MICROWAVE TREATMENT
64
CHEMICAL DISINFECTING AND SHREDDING
• In chemical disinfecting
components are placed in chemical
solution and removed for
sterilization.
• In shredding the plastic (I.V. bottles,
I.V. sets, syringes, catheters etc.)
sharps (needles, blades, glass etc)
should be shredded but only after
chemical treatment/microwaving/
autoclaving.
• Needle destroyers can be used for
disposal of needles directly without
chemical treatment.
65
INCINEARTION
66
INCINEARTION
67
COMPONENTS OF INCINERATOR PLANT
Furnace :
• The furnace consists of a rectangular steel box lined with fire-
brick on the inside and insulated on the outer shell. Oil/gas
burners/registers of normal boiler furnace design are fitted,
and these project the flames towards the floor of the furnace.
• Running along the floor of the furnace is a steel-link fire grate
that is mechanically driven, picking up the waste at one end
from under the loading hopper and, through providing a
combustion bed, burning the waste as it moves along the
floor.
• At the end of the grate, the waste that has by now turned to
ash falls off the grate into a quench tank. From here it passes
under a magnet to remove any ferrous metals before passing
into a storage hopper. This residue is known as bottom ash.
68
COMPONENTS OF INCINERATOR PLANT
• Gas Cooler – The gases are still at a high temperature; exiting the
furnace after the waste heat boiler at around 200°C. So, before
passing to the treatment plant proper they are cooled using a
normal water tube cooler.
71
UNIT II
INTRODUCTION TO WASTE
AND WASTE PROCESSING
72
CONTENTS
• What is LANDFILL
• Components of landfill
• Site selection for sanitary land fill
• Control of landfill gas
• Leachate formation and migration
• Environmental impact of landfill
73
LANDFILL
Land fill:
An engineered method for land disposal of solid or hazardous
wastes in a manner that protects the environment.
74
ESSENTIAL COMPONENTS OF LANDFILL
75
TYPES OF LANDFILLS
• Sanitary landfills
• MSW landfills
• Construction and demolition landfill
• Industrial waste landfills
• Secure landfills
• Class I-HAZARDOUS
• Class II-NON- HAZARDOUS
• Class III-INERT WASTE
76
METHODS OF LANDFILING
78
OPERATING REQUIRMENTS FOR SOLID WASTE LANDFILL
81
SINGLE LINER
Single liner:
Single liners consist of a clay liner, a geosynthetic clay liner or a
geomembrane. Single liners are sometimes used in landfills
containing construction debris. Clay liner is easily available and
is durable. Synthetic geo-membranes are composed of polymers
such as: Thermoplastics(PVC);crystalline thermoplastics
(HDPE,LDPE); thermoplastic elastomers (chlorinated
polyethylene, chloryl sulphonated polyethylene);
(elastomersneoprene, ethylene propene diene monomer).
82
DOUBLE LINER
Double liner :
A double liner consists of either two single liners, two composite
liners, or a single and a composite liner. The upper (primary) liner
collects the leachate, while the lower (secondary) liner acts as a leak
detection system. Double liners are to be used in MSW landfills, and
especially in hazardous waste landfills. A double liner is more
resistant to stress cracking and increased strain due to tensile yield.
83
COMPOSITE LINER
Composite liner :
A composite liner consists of a geomembrane in combination with a
clay liner. These are more effective at limiting leachate migration
into the subsoil.
84
BASIC DEFINITIONS
85
LANDFILL GAS COMPOSITION
87
HAZARDS
• Landfill gas consists of a mixture of flammable, asphyxiating and
noxious gases and may be hazardous to health and safety, and
hence the need for precautions.
• Some of the major hazards are listed below:
1. Explosion and fire: Methane is flammable in air within the range
of 5 – 15% by volume, while hydrogen is flammable within the
range of 4.1 – 7.5% (in the presence of oxygen) and potentially
explosive. Fire, occurring within the waste, can be difficult to
extinguish and can lead to unpredictable and uncontrolled
subsidence as well as production of smoke and toxic fumes.
2. Trace components: These comprise mostly alkanes and alkenes,
and their oxidation products such as aldehydes, alcohols and
esters. Many of them are recognised as toxicants, when present
in air at concentrations above occupational exposure standards.
3. Global warming: Known also as greenhouse effect, it is the
warming of the earth‟s atmosphere by the accumulation of
gases (methane, carbon dioxide and chlorofluorocarbons) that
absorbs reflected solar radiation. 88
HAZARDS
91
LEACHATE FORMATION
92
LEACHATE MIGRATION
93
LEACHATE CONTROL
100
CONTENTS
101
BIOCHEMICAL CONVERSION
102
WHAT IS COMPOSTING
103
MATERIALS FOR COMPOSTING
104
MAIN COMPOSTING AGENTS
Psychrophiles 0 - 30
Mesophiles 30 – 45
Thermophiles 45 – 50
105
MAIN COMPOSTING AGENTS
106
MAIN COMPOSTING AGENTS
• Bacteria:
strong ability of growth in moist medium
large spectrum of activity
active in a large range of pH values
difficult to adapt in acid medium
• Fungi:
ability to live in medium with low moisture;
competitors of heterotrophic bacteria
active in a large range of pH: 2 – 9;
low requirements considering the nitrogen content
107
MAIN COMPOSTING AGENTS
• Actinomycetes:
1. Aerobic and thermophilic;
2. They are assimilated by bacteria and fungi;
3. Use organic nitrogen;
4. Active in neutral and slightly alkaline media;
5. Act in the ending phase of the composting process.
• Other agents:
1. Duckweeds (algae)
2. Cyanophytes
3. Prothozoe
4. Enzymes
108
STEPS TO PERFORM BIOCHEMICAL CONVERSION
110
111
CONTROL PARAMETERS
• Quantity of oxygen
C6H12O6 + 6O2 →6CO2 + 6H2O + 2 800 KJ/mol
Oxygen requirement
O2 could be supplied by means of: during the composting
process:
• Mechanical mixing;
• First stage – 5 - 15%
• Forced ventilation (aeration)
• Second stage – 1 - 5%
• Air: 10 – 100 N.m3/h
113
CONTROL PARAMETERS
116
SLUDGE FORMATION
118
SLUDGE TREATMENT
Sludge thickener:
In sludge thickeners, greater amount of water is removed from the
sludge than what could obtain from sedimentation tank. This
reduces overall volume of the sludge considerably. The thickening of
the sludge can be achieved either by gravity thickening, application
of air floatation or by centrifugation.
119
SLUDGE TREATMENT
1. Gravity thickening:
Gravity thickening is accomplished in a tank similar in design to a
sedimentation tank. This is most commonly used for concentrating
the sludge for achieving saving in the digester volume and sludge
handing cost. This is used for primary sludge and for combine
primary and secondary sludge, and it is not suitable for ASP sludge
alone.
2. Air floatation:
By applying air under pressure or vacuum the thickening of the
sludge can be achieved. This is normally preferred for ASP sludge.
This requires additional equipment, power for operation, skilled
supervision for operation and maintenance, hence it is costly.
120
SLUDGE TREATMENT
The floatation units can be of two types (i) pressure type and (ii)
vacuum type.
i. Pressure type floatation unit: In pressure type floatation unit,
a portion of the subnatant is pressurized from 3 to 5 kg/cm2
and then saturated with air in the pressure tank. The effluent
from the pressure tank is mixed with influent sludge
immediately before it is released into flotation tank (Figure
22.3). Once the pressure is released, excess dissolve air rises
up in the form of extremely small air bubbles, attaching
themselves to the sludge particles.
ii. Vacuum type floatation: The vacuum type floatation unit
employs the addition of air to saturation and applying vacuum
to the unit to release the air bubbles which float the solids to
the surface. The solids concentrated at the surface are skimmed
off.
121
SLUDGE TREATMENT
i. Centrifugation
Thickening by centrifugation is used only when the land available is
limited and sludge characteristics will not permit adoption of other
methods. This will require high maintenance and operational cost.
A centrifuge acts both ways to thicken and to dewater sludge. The
centrifuge process separates liquid and solid by the influence of
centrifugal force which is typically 50 to 300 times that of gravity
122
ANAROBIC DIGESTION
123
TYPES OF DIGESTERS
125
TYPES OF DIGESTERS
126
TYPES OF DIGESTERS
127
TYPES OF DIGESTERS
128
UNIT IV
THERMO -CHEMICAL
CONVERSION
129
CONTENTS
130
THERMOCHEMICAL CONVERSION
131
TYPES OF THERMOCHEMICAL CONVERSION
132
COMBUSTION
133
COMBUSTION
134
GASSIFICATION
136
GASSIFICATION PROCESS
137
GASSIFICATION PROCESS
139
REACTIONS INVOLVED IN GASSIFICATION
140
CLASSIFICATION OF GASSIFIERS
141
CLASSIFICATION OF GASSIFIERS
b. DOWNDRAFT GASSIFIER:
145
CROSS DRAFT GASSIFIER
147
FLUIDIZED BED GASSIFIER
• Fluidized bed (FB) gasification has been used extensively for coal
gasification from many years, its advantage over fixed bed
gasifiers being the uniform temperature distribution achieved in
the gasification zone.
• In this type of gasifier, air is blown through a bed of solid particles
at a sufficient velocity to keep these in a state of suspension.
• The bed is externally heated and the feedstock is introduced as
soon as a sufficiently high temperature is reached.
• The fuel particles are introduced at the bottom of the reactor,
very quickly mixed with the bed material and almost
instantaneously heated up to the bed temperature.
• As a result of this treatment relatively large amount of gaseous
materials produced. Further gasification and tar-conversion
reactions occur in the gas phase.
148
• Ash particles are also carried over the top of the reactor .
FLUIDIZED BED GASSIFIER
149
ADVANTAGES OF GASSIFICATION
151
BIOMASS BRIQUITTING
153
PROCESS OF BIOMASS BRIQUITTING
• In briquetting process the materials are first crushed into small size
so that they can be compressed properly and burn easily. Special
crushing machine is available in the market to crush the raw
materials.
• The briquette are highly preferred in the locations where fuel is
hard to find and is costly. Thus at such places briquetting can
become the best option for getting fuel at cheap price and easy
way. The main advantage in briquetting plant is that it does not
require any binder to bind the materials together to form a
briquette. Thus it is also known as binder-less technology.
• The briquettes are chosen over coal and other non renewable fuel
that are hard to obtain and generate. The advantage of briquetting
is the high calorific valve useful in easy ignition. Also other key
factors for briquetting are low production cost, waste material
management and conversion of waste to revenue. 154
ADVANTAGES AND DISADVANTAGES
ADVANTAGES DISADVANTAGES
• High calorific fraction • Potentially higher price
• Moisture content, conditioned by the
density and constant manufacturing
and homogeneous (compaction) process
granulometry and the availability of
• Lower ash content other cheaper biofuels
• International closer to the customer
marketing with premises
standardized
composition
155
BENEFITS OF BRIQUITTING
ENVIRONMENTAL:
• Using renewable energies can contribute to sustainable forest
management.
• Neutral CO2 emissions balance.
• Low sulphur emissions (which usually causes acid rain).
• If it has a forest origin under a proper management scheme, it
contributes to forest regeneration and prevention of forest fires.
• If it is sourced from agricultural or industrial waste, it enables a
residue with a second life.
• Ash from briquettes burning can be used as fertilizer.
156
BENEFITS OF BRIQUITTING
SOCIAL:
• Creates jobs throughout the supply chain, especially in rural
areas, thus preventing rural migration to urban areas.
• If it has a forest origin, it will promote its sustainable
management, improving the state of forests: - With direct
incidence to the decreased risk of fire and the corresponding
damages to human health and properties. - With indirect
incidence in perception of the forest as a source of jobs and
wealth creation (e.g. tourism).
• It promotes confidence in renewable energy at local and rural
levels.
157
BENEFITS OF BRIQUITTING
ECONOMIC:
• Positive life cycle economic balance, cost €/kWh lower
than fossil fuels.
• Decreases the dependence on energy imports, thus
favoring greater energy price stability by not depending on
international markets volatility.
• Local added value, fostering local or regional businesses
along the supply chain (forest operators, transportation
and warehousing, briquette manufacturers, dealers,
installers and maintenance services providers, etc.)
• Enables the valorization of sub-products and even waste.
158
UNIT V
E-WASTE
MANAGEMENT
159
CONTENTS
• What is E- Waste
• E- Waste generation in India
• Recycling
• Impact of hazardous E-Waste in India
• E-Waste legislation.
• Safeguards and environmental protection laws
160
WHAT IS E-WASTE
161
COMPOSITION OF E-WASTE
164
E-WASTE IN GLOBAL CONTEXT
165
GROWTH OF E-WASTE IN INDIA
167
ENVIRONMENTAL HEALTH HAZARD OF E-WASTE
168
ENVIRONMENTAL HEALTH HAZARD OF E-WASTE
169
RECYCLING OF E-WASTE
172
E-WASTE LEGISLATIONS
173
E-WASTE MANAGEMENT RULES
174
SALIENT POINTS ON E-WASTE RULES
175
SALIENT POINTS ON E-WASTE RULES
176
177