CSIR 2019 15 December Shift 2 Chemical Sciences

National Testing Agency
Question Paper Name: Chemical Sciences 15th December 2019 Shift 2

Subject Name: Chemical Sciences
Creation Date: 2019-12-15 19:00:21
Duration: 180
Total Marks: 200
Display Marks: Yes
Chemical Sciences
Group Number : 1
Group Id : 18798014
Group Maximum Duration : 0
Group Minimum Duration : 180
Revisit allowed for view? : No
Revisit allowed for edit? : No
Break time: 0
Group Marks: 200
Part A Chemical Sciences

Section Id : 18798040
Section Number : 1
Section type : Online
Mandatory or Optional: Mandatory
Number of Questions: 20
Number of Questions to be attempted: 15
Section Marks: 30
Display Number Panel: Yes
Group All Questions: No
Sub-Section Number: 1
Sub-Section Id: 18798040
Question Shuffling Allowed : Yes
Question Number : 1 Question Id : 1879801621 Question Type : MSQ Option Shuffling : No Display Question Number : Yes Single
Line Question Option : No Option Orientation : Vertical
Correct Marks : 2 Wrong Marks : 0.5
Examrace www.examrace.com
There are nine identical balls, one of which is heavier than tl1e other eight. \Vhat is the least
munber of weighings, using a two-pan balance, needed for defwitely identifying the heavier
ball?
(1) One
(2 ) Two
(3 ) Three
(4 ) Four
Options :
1879806481. 1
1879806482. 2
1879806483. 3
1879806484. 4
ｾ＠ｾ＠ .fr ｾ＠ｾ＠ｾ＠ 'R 3R! Wal ii 1ffit ｾ＠ I 1ffiT 'R c!iJ ｾ＠ qi;,-:w, J; ｾ＠ｾ＠ｾ＠

c!ffit ~ <ITT ~ ffl ｾ＠ •1 'i ci '1 ｾ＠ filffi c!iJ ¢l iq t .Qcfici l irfi7
(1)
(2 )
(3 )
(4 )
Options :
1879806481. 1
1879806482. 2
1879806483. 3
1879806484. 4
The number of triangles in the figure is
(1) 9
(2 ) 10
(3 ) 11
(4 ) 12
Options :
1879806485. 1
1879806486. 2
1879806487. 3
1879806488. 4
(1) 9
(2 ) 10
(3 ) 11
(4 ) 12
Options :
1879806485. 1
1879806486. 2
1879806487. 3
1879806488. 4
The difference, the ~'t11n and the product of two integers are in the propo,tion 1:3: 10. The two
integers are:
(1) 3, 9
(2 ) 2, S
(3 ) s, 10
(4 ) 3, 10
Options :
1879806489. 1
1879806490. 2
1879806491. 3
1879806492. 4
(1) 3, 9
(2 ) 2, S
(3 ) s, 10
(4 ) 3, 10
Options :
1879806489. 1
1879806490. 2
1879806491. 3
1879806492. 4
In a population of 900, the number of ma1ried couples is as much as the number of singles.
There are 100 twins ofwhid1 SO twins are singles. The population has 400 females in all. What
is the number of married persons?
(1) 325
(2 ) 600
(3 ) 250
(4 ) 300
Options :
1879806493. 1
1879806494. 2
1879806495. 3
1879806496. 4
900 <ITT ｾ＠ｾ＠ f<lq 1f%a \Jl'IRi;ll'i <15T ｾ＠ <llf<l q l ~ a' i c#i ｾ＠ <r; oRJoR %I 100 qr-sq'f ｾ＠
R;r,,-<i 'ft 50 31 f<lq 1f%a ｾ＠ I i3'R ｾ＠ｾ＠ <g<:>I 400 "l ~(>J I~ ｾ＠ I f<l q 1f%a Ul f<la ll'i <ITT ｾ＠
fclIB.fr %?
(1) 325
(2 ) 600
(3 ) 250
(4 ) 300
Options :
1879806493. 1
1879806494. 2
1879806495. 3
1879806496. 4
In a ce1iain cipher language ' BIKE' is coded as ' YFHB' and ' CAR' is coded as ' ZXO' then
' SCOOTER' can be coded as
(1) TAPPIYB
(2 ) PYVVAHJ
(3 ) PZLLQBO
(4 ) JZKKMCO
Options :
1879806497. 1
1879806498. 2
1870806400. 3
1879806500. 4
(1) TAPPIYB
(2 ) PYVVAHJ
(3 ) PZLLQBO
(4 ) JZKKMCO
Options :
1879806497. 1
1879806498. 2
1879806499. 3
1879806500. 4
Year
The trend5 of hvo quantities over five years are shown in the graph. \Vhich of the following are
valid inferences?
A. The mean values of the quantities are nearly equal
B. The variations in the two quantities are nearly equal
C. Quantity 1 varies less over the given period as compared to Quantity 2
(1) Only A is true
(2 ) Only B is true
(3 ) A and Care true
(4 ) and B are h11e

AExamrace www.examrace.com
Options :
1879806501. 1
1879806502. 2
1879806503. 3
1879806504. 4
ｾ＠
*
i:i'R! qqf GRR ｾ＠ "fP-fl3Il
<liR ii~?
* ｾ＠ -3q4i:f<1 ｾ＠ｾ＠ｾ＠ 1T11 ｾ＠ 1 f.,...,f& f&ti ｾ＠ ii ｾ＠
(3) A 3ITT C ｾ＠ tI
Options :
1879806501. 1
1879806502. 2
1879806503. 3
1879806504. 4
Which among the following diagran15 can represent the relationships bel:\veen hotl5es, offices
and buildings?
(1)
CD
(2 )
0
(3 )
(4 )
Options :
1879806505. 1
1879806506. 2
1879806507. 3
1879806508. 4
(1)
CD
(2 )
0
(3 )
(4 )
Options :
1879806505. 1
1879806506. 2
1879806507. 3
1879806508. 4
Con5ider a location on the Earth where the Sun is overhead at noon. Compared to it5 shadow at
10.00 AM, the shadow of a tower at 4.00 PM would be
(1) twice longer
(2 ) three times longer
(3 ) four times longer
(4 ) eight times longer

Options :
Examrace
1879806509. 1 www.examrace.com
1879806510. 2
1879806511. 3
1879806512. 4
ITTffi
<ITT ｾ＠
* it
\TT-I ｾ＠
Wf 4
*<NI<ITT it f<rnR
fcnm
ｾ＠
cl<R <ITT ｾ＠
'1161 ｾ＠ *
iflft :
ｾ＠ｾ＠ Im * i3){R ｾ＠ I m<a: 10 <NI
(1) ｾｾ＠
(2 ) fcrTfr ｾ＠
(3 ) ｾ＠
(4 ) 3lTo :r.fr ｾ＠
Options :
1879806509. 1
1879806510. 2
1879806511. 3
1879806512. 4
A girl is mnning at constant speed to catch a bus which is stationary. Before she reaches the
bus, the bus leaves and moves with a constant acceleration. \Vhich one of these graphs
describes the situation co1Tectly?
-- bus - - - gir1
"O
QJ
(1) QJ
a.
Vl
Time
"O
QJ
(2 ) QJ
Vl
Time
"O
.,
QJ
QJ
(3 ) a.
Vl ., ., .,
., .,
Time
.,
"O .,
., .,
QJ ;
QJ
(4 ) a. ;
Vl ., ;
., ;
Time
Options :
1879806513. 1
1879806514. 2
1879806515. 3
1879806516. 4
ｾ＠ｾ＠ fcR-fi ｾ＠ <ITT 4ct>,$'4 <5 ｾ＠
<f'R ｾ＠ 'fl"fR ｾ＠ ,i 41-$ ｾ＠ｾ＠ I ｾ＠ <f'R G<P
ｾ＠ "'H ~. <f'R '<m ｾ＠ｾ＠ 3ITT ｾ＠ 'fl"fR ＠ｾ "'H 3!Tll ｾ＠ WIBT ｾ＠ I f.i 9 f<-1f& a ｾ＠ "'H
ffl 'ffi ｾ＠ｾ＠ Gffl <ITT ｾ＠ q"O"R <ITTaT ~7
- i,if - - - c-1.i-Jl
(1) ｾ＠
(2 ) i --------- --------
,
,
,,
(3 ) ,,
,,
,,
,
,
,,
(4 ) ,,
, ;
,,
Options :
1879806513. 1
1879806514. 2
1879806515. 3
1879806516. 4
Question Number : 10 Question Id : 1879801630 Question Type : MSQ Option Shuffling : No Display Question Number : Yes
Single Line Question Option : No Option Orientation : Vertical
A dart is randomly thrown at a circular board on which l:\vo concentric rings of radii Rand 2R
having the same width (width much less than R) are marked. The probability of the dait hitting
the smaller ring is
(1) twice the probability that it hits the larger ring.
(2) half of the probability that it hits the larger ring.
(S) four tin1es the probability that it hits the larger ring.
(4) one-fotuth the probability that it hits the larger ring.

Options :
1879806517. 1
1879806518. 2
1879806519. 3
1879806520. 4
1;<l> m ｾ＠ cfRfr Gl" ~ 3ll- R ｾ＠ 2R (il1-si~ R <lil ｾ＠ "<i c1s<f <1511 ~) * Gl"
'fi<b•ifl cR>ITIT <ITT'T fcITTfr ~'ctl<bN oi'fi -q. 1;<l> "-sl~ {1.ti'if1'1c!i ｾ＠ if ｾ＠ iJ!@T ｾ＠ I ;git aTTT
ｾ＠ cRTTI <bl ffl <liT ｾ＠ <fflT ~ 7
Options :
1879806517. 1
1879806518. 2
1879806519. 3
1879806520. 4
The length of a rod is meas1ired repeatedly by two persons. Person A reports the length to be
1002 ± 1 cm while person B repo1is the length to be 1001 ± 2 cm. It is known from a more
reliable method that the leagth is 1000.1 ± 0.5 cm. \Vhich one of the following statements is
correct?
(1) Measurements made by B are less acctirate, but more precise, compared to those by A.
(2) MeasTirements made by A are less acctirate, but more precise, compared to those by B.
(3) MeasTirements made by Bare more precise and more accurate, compared to those by A.
( 4) Measurements made by A are more precise and more accurate, compared to those by B.
Options :
1879806521. 1
1879806522. 2
1879806523. 3
1879806524. 4
GT ai fua4'i aRT ｾ＠ｾ＠ (,/1-s) <15'1 ｾ＠ <TR- o!R iflifr '1ITTfr ｾ＠ I UlfcRr A ｾ＠ <15'1 do11£
1002 ± 1 {~e'i4k~ oR'!ffiT t ｾ＠ UlTTRf B * ｾ＠ｾ＠ <15'1 ｾ＠ 1001 ± 2 {~e'i4k~ ｾ＠ I
ｾ＠ｾ＠ Fclta,w,ht4 fclfu i-r ｾ＠ <15'1 ｾ＠ 1000.1 ± 0.!> fie'l~c~ ｾ＠ m<ft ｾ＠ 1 P11-,~fula
11' 'ft ffl 'ffi cl,~ ｾ＠ i -
Options :
1879806521. 1
1879806522. 2
1879806523. 3
1879806524. 4
Seven chairs numbered 1 to 7 are placed around a round table. Staiiing from chair munber 5, a
person keeps going around the table anticlodC\vise. After crossing 41 chairs, the person will
reach the chair number
(1) 1
(2 ) 3
(3 ) 5
(4 ) 7
Options :
1879806525. 1
1879806526. 2
1879806527. 3
1879806528. 4
ｾ＠ •i'k ll<bN ｾ＠ <r; <Im dR -, cgffilll ｾ＠ lTT1T ｾ＠ Ri·N~ 1 if 7 <!ft ｾ＠ｾ＠ｾ＠ I ｾ＠

ｾ＠ s i-r ＠ｾｾ＠ｾ＠ <!ft W <!ft ｾ＠ mrr .?i ｾ＠ uffcffi ｾ＠ <t; ｾ＠ 3rR tfldT ｾ＠
ｾ＠ I 4 1 cgff1<1'i <ITT 'lR ffl er; o[]c[ ｾ＠ «lT<R! f<ITT:! ~ ~ \fl q ~i1 •117
(1) 1
(2 ) 3
(3 ) 5
(4 ) 7
Options :
1879806525. 1
1879806526. 2
1879806527. 3
1879806528. 4
A, B, C and Dare four consecutive points on a circle such that chords AB=BC=CD=l0.0 cm
and DA = 20.0 cm. The radius of the circle (in cm) is
(1) 10.0
(2 ) 10.fi,
(3 ) 10./3
(4 ) 20.0
Options :
1879806529. 1
1879806530. 2
1879806531. 3
107900GSJ2. 4
A,B,C am
D f<ITTfr '[cl ＠ｾ <ITT .it> 'l l' lci ｾ＠ｾ＠ fui {1<51 ｾ＠ AB=BC=CD=l0.0 fie'ilflc'<
am DA=20.0 fie'ilflc'< ｾ＠ I '[cl "<51" ffi'm (f iellflc'< 'IJ <f'IT m-rft?
(1) 10.0
(2 ) 10.fi,
(3 ) 10./3
(4 ) 20.0
Options :
1879806529. 1
1879806530. 2
1879806531. 3
1879806532. 4
A tells B, "I could be visiting you on any day in the next two months and you must give me
gold coins of as much total weight in grams as the number of days that would elapse from
today". If gold coins are available in integer gram weights, what is the least number of coit15
with which B can meet A 's demand on any day?
(1) 31
(2) 7
(3 ) 6
(4 ) 13
Options :
1879806533. 1
1879806534. 2
1879806535. 3
1879806536. 4
A, B -ff %fil t ··i?f 3i7m G't ｾ＠ ii fcITTfr -ifr ITT ｾ＠ tfR:r 3TT 'Hc!mT { ｾ＠ｾ＠ <t; clR
ii ｾ＠ ITT oITTf'T ｾ＠ 1JT'l' 1ITT <f; <Rm ffl <f; ｾ＠ ~ - ｾ＠ｾ＠ ITT I" ｾ＠ ffl <f;
ｾ＠ｾ＠ mi:r 1ITT -q ｾ＠ i;'f cfT fcITTfr -ifr ITT fuffi q;]° •{'id"I ｾ＠ｾ＠ -ff B, A
<ITT i:ff.r <ITT ｾ＠ c!5x 'fl<lffiT t?
(1) 31
(2) 7
(3 ) 6
(4 ) 13
Options :
1879806533. 1
1879806534. 2
1879806535. 3
1879806536. 4
A move of a coin is defined as crossing any munber of points in a straight line on the 4 x 4 grid
(horizontally, ve,iically or diagonally). What is the least munber of moves in which a coin,
starting from the indicated position, can cover all nine points within the marked square?
...............................
1· • • •
jk • • •
l• .........ｾ＠ ..........ｾ＠ •
• • • •
(1) four
(2 ) five
(3 ) SIX
(4 ) seven
Options :
1879806537. 1
1879806538. 2
1879806539. 3
1879806540. 4
f<lffir ｾ＠ <ITT ｾ＠
cn'r 4 ｾ＠ 4 m ｾ＠ｾ＠ -mm wr ｾ＠ fcmr-r 'lfr ~w cn'r "ll"R m (IMwi,
ｾ＠ｾｾＱ＠ Rlc!iu'n) <t; ｾ＠ｾ＠ｾ＠ f<nm islIBT ｾ＠ 1 Pi"'lif<ha CfTf <t; '11fr .ft ~ ;if ci'"c!i
ｾ＠ '<i f.lRfi:e ~ ii ~ ffl ｾ＠ fcl;m ｾ＠ <ITT •{ 'i ci 'l ｾ＠ 'ifR'T ｾ＠ tjrl't?
...............................
* ...
ie • • •
ｾ＠
l• .........ｾ＠ ..........ｾ＠ •
• • • •
(1)
(2) ｾ＠
(3 )
(4 )
Options :
1879806537. 1
1879806538. 2
1879806539. 3
1879806540. 4
The graph below shows the rainfall and temperature at a place over one week. Which day of the
week would feel the most lnuuid?
30°c 100mm
--
0
.........::,
GI --- X
!11 ｾ＠
GI C
a. n,
c:,:
E
ｾ＠
20°c 10mm
M T w T F 5 5
(1) Monday
(2) \Vednesday
(3 ) Thursday
(4) Saturday
Options :
1879806541. 1
1879806542. 2
1879806543. 3
1879806544. 4
f.p:-, iRl,a ｾ＠ Ti fcITT:fi ~.rr-, fctmr # ｾ＠ｾ＠ Ti ｾ＠ •N<tt la ｾ＠ a 1q'11'i cir 4~1hl1 1TT1T ｾ＠
'3cffi ｾ＠ * fcR-1 wr ｾ＠ {1 a \~ ct, irft?
30°c 100mm
-
0 --
X
20°c 10mm
(1)
(2)
(4) ~1f.'l a 1~
Options :
1879806541. 1
1879806542. 2
1879806543. 3
1879806544. 4
The difference between tbe squares of two con5ecutive integers is 40823 5. The stun of the
munbers is
(1) 16324
(2) 27061
(3) 180235
(4) 408235
Options :
1879806545. 1
1879806546. 2
1879806547. 3
1879806548. 4
(1) 16324
(2) 27061
(3) 180235
(4) 408235
Options :
1879806545. 1
1879806546. 2
1879806547. 3
1879806548. 4
Find out the next figure in following sequence?
t>~ a
(1)
c 7_);?d
a~ d
(2 )
b~ c
a~ d
(3 )
b~ c
(4 )
Options :
1879806549. 1
1879806550. 2
1879806551. 3
1879806552. 4
?
(1)
c~ :
a~ d
(2 )
b~ c
ｾｾ､＠
(3 )
b~ c
(4 )
Options :
1879806549. 1
1879806550. 2
1879806551. 3
1879806552. 4
A partially filled hour glass has water falling from the upper bowl to the lower bowl. \Vhich of
the following statements is co1Tect?
(1) The level of water rises in the lower bowl at the same rate as the fall in the upper bowl
(2 ) The level of water rises in the lower bowl at the half rate as the fall in the upper bowl
The rate of increase in the vohune of water in the lower bowl is the same as the rate of
(3 )
decrease in the upper bowl
(4 ) The area of top surface of the water column is the same in both bowls at all tin1es
Options :
1879806553. 1
1879806554. 2
1879806555. 3
1879806556. 4
ｾ＠ ~ : 1Rf ｾ＠ｾ＠ utr ,?j ｾ＠ <1>cRT ii ｾ＠ <1>cRT ,?j qr.fr frR m ｾ＠ 1 f.'11-,f2.1fula ｾ＠

il <!iR'ITTc!>2R~ ~ :
(1)
(2 )
f.'iil<-'il <1?cR1 11 '11<'1 ｾ＠ｾ＠ｾ＠ <ITT <r< v,tR'1 <1>cRT 11ｾ＠ｾ＠ <f; ｾ＠ <ITT <r< <ITT
ｾｉ＠
f.'lilR! <l>cNt ,?j iJlc'T <f; q fQ'l lOI ,?j ol<t' l<'l '{i <i5'r <R ｾ＠ <l>cRT <f; qfQIJ IOI ,?j q;-,fl <ITT <R
(3 )
<r;~WIPl t l
Options :
1879806553. 1
1879806554. 2
1879806555. 3
1879806556. 4
Examine the following statements:
a. Fat cells nonnally produce hormone A in proportion to the amount of fat. Obese
individuals, however, have lower than normal levels of honnone A.
b. Honnone A reduces food intake
Which among the following is a valid inference based on the above statements?
(1) Impaired production ofhom1one A causes obesity
(2) Impaired action of honnone A causes obesity
(3) Obesity results into low levels of hom1one A
(4) Excess food intake cau5es depletion ofhom1one A

Options :
1879806557. 1
1879806558. 2
1879806559. 3
1879806560. 4
a. <f'fll ct,' l~ lcfi lq {1 I<w.!k : cfffi <15'1 "IT?!T c5 'tt 'l l j41ffi ｾ＠ A '3c'Cf9 c!5x<ft %' <1 ($\!!;Si<:>I, 1-lIB
ffi1IT -q ｾ＠ A <1iT ｾ＠ 'tt I 'll~U -H c1>l-! i@r ｾ＠ I
Options :
1879806557. 1
1879806558. 2
1879806559. 3
1879806560. 4
Part B Chemical Sciences

Section Number : 2
Section Marks: 70
Group All Questions: No
Correct o:rder of mow extincb'.o n coefficient values of the visible absorption bands for the
following species is.
i( 2 Chlorophyilll > [NmCl4] 2- > [Cr(lli:0)6]2+ > [Mn(lli:0)6]2+
i( 3 [NiCfil4] 2- > Chlo:mphyll > [Cr(H20)6]- > [l\lfu.(Hi0)6]-
Options :
1879806561. 1
1879806562. 2
1879806563. 3
1879806564. 4
Pt""'l~fuia ,p:fl!/i't'Jl Cfi ｾ＠ -6lc1 ~nt1 01 ｾ＠ cf5 ｾ＠ i:nffi fclc'11q1 101icb'i Cfi l!R <ITT 'fl6f
:mi=I tI
Options :
1879806561. 1
1879806562. 2
107900GSGJ. J
1879806564. 4
The expected number of Vco bands in the IR spectra of/ac-[Mo(PPh3)3(C0)3] and

trans-[Mo(PPh3)2(C0)4] are, respectively
(1) one and one
(2 ) hvo and two
(3 ) hvo and one
(4 ) three and one

Options :
1879806565. 1
1879806566. 2
1879806567. 3
1879806568. 4
/ac-[Mo(PPh3)3(C0)3) o2TT tra ns -[Mo(PPh3)2(C0)4) cf5 Th. f'1cf?;1il 1l Vco ｾ＠ cBJ J,klll~ lt,
«@1.q 'g_ ｾ＠
Options :
1879806565. 1
1879806566. 2
1879806567. 3
1879806568. 4
Pair of lanthanide io115 which show significant deviation between the experimental and
calculated magnetic moments, considering contribution from the ground state only
(given Jl•ff= g[J(J + 1)]112 , is
(1) Gd3+ and Lu3+
(2 ) Sm3+ and Tb3+
(3 ) Eu3+ and Tb3+
(4 ) Sm3+ and Eu3+

Options :
1 R7'lR0f\Sf\ 'l 1
1879806570. 2
1879806571. 3
1879806572. 4
CITTlc'f P11---1 a1-1 ~..rr <fi 411 1<:11 <ITT , i ~ 1-111 cB'-! 4'-!cb~ a am J.l1,M'l'1cB iJRtc6't<1 ｾ＠
Cfi llUI ｾ＠ ftlil cl'i .jj'r c'I""~ 3ITTRf <ITT~ c;~ lld l %.cfQ %
(j'qm %J4fr = g[J(J+l )]ll2)
(1) Gd3+ "t1m Lu3+
(2) Sm3+ -am Tb3+
Options :
1879806569. 1
1879806570. 2
187980657 L 3
1879806572. 4
In common glass electrode, alkaline eiTor caused at pH > 10 is least for
(1) 0.01M NaCl
(2) L O MNaCl
(3) L O M LiCl
(4 ) L O MKCI
Options :
1879806573. 1
1879806574. 2
1R7'lROf\S7S :l
1879806576. 4
(1) 0.0lM NaCl
(2) 1.0 M NaCl
(3 ) 1.0 M LiCl
(4 ) 1.0MKCl
Options :
1879806573. 1
1879806574. 2
1879806575. 3
1879806576. 4
Con5ider four species A, B, C, and D .

A + B Kl, H+ C
Oxidation of A with C in an ac.idic medium gives D . A, B, C and D are, respectively
Options :
1879806577. 1
1879806578. 2
1879806579. 3
1879806580. 4
'cfR -l4i~ft\JI A, B, C ('f2TT D "CR rcmR c6't 8i(!
A + B Kl, H+ C
ｾ＠ Rtcl ll'i ii A <ITT C 'f-1 6llfficf>~UI D ｾ＠ｾ＠ I A, B, C ('f2TT D ~, ~ •
Options :
1879806577. 1
1879806578. 2
1879806579. 3
1879806580. 4
For an octahedral Cu2+ complex depicting axial EPR spectrum (g 11> gi), the geometry of Cu2+
and the orbital containing the unpaired electron are, respectively
(1) Tetragonally elongated, dx2-y2
(2) Tetragonally compressed, dz'
(3 ) Tetragonally elongated, dl
(4 ) Tetragonally compressed, d.2-i

Options :
1879806581. 1
1879806582. 2
1879806583. 3
1879806584. 4
<llafm EPl<. ftl cfs?-l (g 11 > g0 ｾ＠ <!ffi 6l l!c,l/fflcf5't ll Cu2+~ ii cu2+ctr \Jll l~RI am
61 '!!"-l~ct !'k (>l cf~l"I CITT ｾ＠ｾ＠ <lTffi 6l tf.1c cl 6, wrn'.
Options :
1879806581. 1
1879806582. 2
107900GSOJ. J
1879806584. 4
The common heptacity observed for coordination of C60 to a metal center is
(1) 2
(2 ) 4
(3 ) 5
(4 ) 6
Options :
1879806585. 1
1879806586. 2
1879806587. 3
1879806588. 4
(1) 2
(2 ) 4
(3 ) 5
(4 ) 6
Options :
1879806585. 1
1879806586. 2
1879806587. 3
1879806588. 4
The pair of light source and atomizer resulting highest sensitivity to atomic absorption
spectrometric measurement is:
(1) Hg lamp; nitric oxide flan1e
(2) Hg lamp; graphite furnace
(3) Hollow cathode lamp; graphite furnace
( 4) Hollow cathode lamp; acetylene-nitric oxide flame

Options :
1879806589. 1
1879806590. 2
1879806591. 3
187D80G5D2. 4
qcpm 'f-3l1G a 2TT cl5fu@ c!>J ｾ＠ "(Jff q,u11u<flll 6J q~i)l:l o1 f(lcf~ 1fqRf 'TTtR Cnl" ｾ＠
'\!lll ~d l @ ~, ｾ＠ｾ＠
(1)
(2 )
(3 )
(4 )
Options :
1879806589. 1
1879806590. 2
1879806591. 3
1879806592. 4
The magnitude of bond angles in gaseous NF3, SbF3 and SbCh follow the order
(1) NF3 > SbF3 > SbCh
(2) SbCh > SbF3 > NF3
(3 ) Sbf3 > SbCh> Nf3
( 4) NF3 > SbCh > SbF3

Options :
1879806593. 1
1879806594. 2
1879806595. 3
1879806596. 4
(1) NF3 > SbF3 > SbCh
(2 ) SbCh > SbF3 > NF3
(3 ) SbF3 > SbCh> NF3
(4 ) NF3 > SbCh > SbF3

Options :
1879806593. 1
1879806594. 2
1879806595. 3
1879806596. 4
The most stable vanadium species in aqueous meditun is
(1) [V(H20 )s(OH))2+
(2 ) [VO(H20 )s)2+
Options :
1879806597. 1
1879806598. 2
1879806599. 3
1879806600. 4
(1) [V(H20 )s(OH))2+
(2 ) [VO(H20 )s)2+
(3 ) [VO(H20 )s]+
Options :
1879806597. 1
1879806598. 2
1879806599. 3
1879806600. 4
For the complex shown beiow in non-fluxional state, the expected 31P{1H} NMR resonance(s)
is/are [3 1P: J = ½]
(1) one singlet
(2 ) one doublet
(3 ) two singlets
(4 ) two doublets
Options :
1879806601. 1
1879806602. 2
1879806603. 3
1879806604. 4
(1) ｾ＠ｾ＠
(2 ) ｾ＠ fa<!,
(3 ) Gl" ~
(4 ) Gl" fa<!,
Options :
1879806601. 1
1879806602. 2
1879806603. 3
1879806604. 4
Identify from following, the product5 ofK-electron capture by the nucleus:
A. neutron
B . neutrino
C. positron
An5wer is
(1) A only
(2 ) AandB
(3) Conly
(4 ) BandC
Options :
1879806605. 1
1879806606. 2
1879806607. 3
1879806608. 4
A . .:qtl "I
B. ~ "11
C. q'ff\Jl~l"I
(1) cf;tlc'f A
(2) A 112TT B
(3 ) cf;tlc'f C
(4 ) B~-TTC
Options :
1879806605. 1
1879806606. 2
1879806607. 3
1879806608. 4
Choose the correct statements for oxymyoglobin and cytochrome P4so (resting state) from the
following:
A. Both contain dianion ofprotoporphyrin-IX
B. They have same fifth-ligand bonded to metal centre from the protein backbone
C. They contain single active site
D. They contain metal ion in +3 oxidation state
Answer is
(1) A, B andC
(2) A, Cand D
(3 ) A, B andD
(4) Band Conly

Options :
1879806609. 1
1879806610. 2
1879806611. 3
1879806612. 4
P11-11flfula ii ~ <A lcffil l-l ll1'1,~1f.H G°2TT ~i l~~l slill-l P4so(fcml1 ~ ) cf> ｾ＠ 00 cl52l'TT CITT
'cl<F[ ctlRnq
A. !.t'1e'1q1fcllR1-IX CITT fil?fl.Dllll'i G'A'i ii mm %I

B. ｾ＠ mt'r,=[ cf> ~'(t)c;o,s CITT, mg ｾ＠ｾ＠ ~ . 1:ffl1'I ~ ' 1"5 'fl1'IR mm% I
C. ｾ＠ｾ＠ ~-TT'f ｾ＠ mTT %I
(1) A, B G°2TT C
(2) A, C G°2TT D
(3) A, B G°2TT D
(4 ) cf;tR'f B G2TTC
Options :
1879806609. 1
1879806610. 2
1879806611. 3
1879806612. 4
The major product fonned in the following reaction is
0 s
NBS
(PhCOO)i
C6H6, h ea t
(1) OBr
s
(2 ) ,.----/
/(
5
;>--Br
(4 ) ,.----/
Br-1!.__s';>
Options :
1879806613. 1
1879806614. 2
1879806615. 3
1879806616. 4
ds
NBS
(PhC0Oh
C 6 H6 , heat
(1) OBr
s
(2 ) ,.----/
lzs:>--Br
(4 ) ,.----/
Br-1!.__s';>
Options :
1879806613. 1
1879806614. 2
1879806615. 3
1879806616. 4
The correct match of 13C N\1R chemical shift values (o ppm) for pyridine is
03
4
2
N
(1) C2: 136; C3 124; C4: 150
(2 ) C2: 124; C3 150; C4: 136
(3 ) C2: 150; C3 124; C4: 136
(4 ) C2: 150; C3 136; C4: 124

Options : Examrace www.examrace.com
1879806617. 1
1879806618. 2
1879806619. 3
1879806620. 4
03
4
2
N
(1) C2: 136; C3 124; C4: 150
(2 ) C2: 124; C3 150; C4: 136
(3 ) C2: 150; C3 124; C4: 136
(4 ) C2: 150; C3 136; C4: 124

Options :
1879806617. 1
1879806618. 2
1879806619. 3
1879806620. 4
H2 (3 a im)
Ra ney Ni, rt
Options :
1879806621. 1
1879806622. 2
1879806623. 3
1879806624. 4
H2 (3 atm)
0 2N - O - C 02H
Raney Ni, rt
Options :
1879806621. 1
1879806622. 2
1879806623. 3
1879806624. 4
The correct order for the rate of thennal decarboxylation of the following compounds is
O" A B
~C02H
(1) C>B>A
(2 ) C>A>B
(3 ) A > C> B
(4 ) B > C> A
Options :
1879806625. 1
1879806626. 2
1879806627. 3
1879806628. 4
P11-1ff1Rsla 4'1fl'1cB'i cf5 ｾ＠ FclcB1is1'1FcNkF1 ｾ＠ｾ＠ cITT ｾ＠ wi:i %
O" A B
~ C 02H
(1) C > B> A
(2 ) C > A> B
(3) A> C> B
(4 ) B> C> A
Options :
Examrace
1879806626. 2
1879806627. 3
1879806628. 4
The correct order of basicity of the following anions is
e e o,N
fy N
CH2N02
o, 6oe
y CH2CN
N0 2 N0 2
A B C D
(1) B> A> C>D
(2 ) D >B> C> A
(3 ) C>D >B> A
(4 ) B> A>D> C
Options :
1879806629. 1
1879806630. 2
1879806631. 3
1879806632. 4
0
e
y
02NAN02
N0 2
A B C
( 1) B> A> C> D
(2 ) D> B> C> A
(3 ) C> D> B> A
(4 ) B> A> D> C

Options :
1879806629. 1
1879806630. 2
1879806631. 3
1879806632. 4
Elcb mechanism is followed in the reaction of
(1) 2-bromopentane with t-BuOK to give pent-2-ene
(2) nitromethane with benzaldehyde in the presence of KOH to give ,8-nitrostyrene
(3) bromobenzene with NaNH2to give aniline
(4) p -chloronitrobenzene with NaOMe to give p -nitroanisole

Options :
1879806633. 1
1879806634. 2
1879806635. 3
1879806636. 4
(1)
(2)
"11$s;,'142Ff ctr KOH ctr ~-ITT'f if ~..Jf'&s61~,s 'fl" ｾ＠ 1l '3ff ,8-"ll~~'l-l-c1$-l'H
~ti
(3 )
(4 )
Options :
1879806633. 1
1879806634. 2
107900GGJS. J
1879806636. 4
The maj or product fonned ill the following reaction is
PhSNa
DMF
S Ph
(1)
N0 2
,,SPh
(2 )
N0 2
OTs
S Ph
(3 )
N02
OTs
(4 )
SPh
Options :
1879806637. 1
1879806638. 2
1879806639. 3
1879806640. 4
PhSNa
DM F
N0 2
(1)
.,,SPh
(2 )
OTs
S Ph
(3 )
(4 )
SPh
Options :
1879806637. 1
1879806638. 2
1879806639. 3
1879806640. 4
In IR spectrum, recorded neat, a compound shows a strong and broad band at 3300 cm- 1. The
band becomes shrup and shifts to 3600 cm- 1 when the spectnun is recorded in CC14 at high
dilution. This proves that the compound has
(1 ) OH group, which is involved in intramolecular H-bonding
(2 ) OH group, which is involved in intennolecular H-bonding
(3 ) ｾ＠ tP.nnin~l ~lkyt1P. gronp
(4 ) OH group, present in severely sterically hindered environment
Options :
1879806641. 1
1879806642. 2
1879806643. 3
1879806644. 4
"C!<B 4'1 fi'1i:ri <ITT ｾ＠ 3TT!xm ii ｾ＠ fcnm 'Tm IR ¥tc!'s ?l 3300 cm- 1 q;r ｾ＠ｾ＠ c-rm
Fcl'tqa ｾ＠ 'tClcfs;'.1-1 <ITT CC4 ii ｾ＠
<Hlia1 %I ~ i c'fJffi q;r ｾ＠ cl5'FI 'T'{ <ffi ｾ＠ 00T
ｾ＠ 3600 cm- 1 q;r fcR~ 15T '1l@T %I <ffi ｾ＠ Q)'(('TT %fcn 41fi"li:ri ti
Options :
1879806641. 1
1879806642. 2
1879806643. 3
1879806644. 4
TRUE statement for the following transformation is
0 +
(1) t.H0 and t.S0 are positive
(2 ) t.H0 and t.S0 are negative
(3 ) t.H0 is positive and t.S0 is negative
(4 ) t.H0 is negative and t.S 0 is positive
Options :
1879806645. 1
1879806646. 2
1879806647. 3
1879806648. 4
0 +
(1)
(2 )
(3 )
(4 )
Options :
1879806645. 1
1879806646. 2
1879806647. 3
1879806648. 4
Single Line Question
ExamraceOption : No Option Orientation : Vertical www.examrace.com

N2
1/
Meo
(1) ｾ＠ 0
Meo~
(2 )
Meo
(3 )
(4 ) O
0
Options :
1879806649. 1
1879806650. 2
1879806651. 3
1879806652. 4
0
Meo
(1) ｾ＠ 0
Meo~
(2 )
Meo
(3 )
(4 ) O
0
Options :
1879806649. 1
1879806650. 2
1879806651. 3
1879806652. 4
t-Bu0 2C
j='\ • >-NHCbz
Meo~
0
Cbz = /'--- ｾ＠
Ph O ｾ＠
(1)
t-Bu0 2C
(2 ) j='\ • >-NHCbz
HO ~
(3 )
H0 2 C\
(4 ) ____F\_______J NHCbz
Meo~
Options :
1879806653. 1
1879806654. 2
1879806655. 3
1879806656. 4
t-BuO2C
; = \ . )-NHCbz
Me O ~
0
Cbz = /'-- ｾ＠
Ph O ;,<'
(1)
t-BuO 2 C
(2 ) ; = \ . )-NHCbz
HO ~
HO2C
\
(3 ) /\ rNH2
Meo~
HO 2 C\
(4 ) __F\_______j NHCbz
Meo~
Options :
1879806653. 1
1879806654. 2
1879806655. 3
1879806656. 4
hv
(1) bo
(2) ｾ＠
(3 ) &-
(4 )
Options :
1879806657. 1
1879806658. 2
1879806659. 3
1879806660. 4
hv
(1) bo
(2) ｾ＠
(3 ) &-
(4 )
Options :
1879806657. 1
1879806658. 2
1879806659. 3
1879806660. 4
o : Br t-BuOK
' Br
(1)
(2 )
0
(3 )
0,
(4 )
0: 0
t-Bu
,,t-Bu
Options :
1879806661. 1
1879806662. 2
1879806663. 3
1879806664. 4
t-BuOK
(1)
(2 )
0
(3 )
(4 )
Options :
a o,
0
t-Bu
,,t-Bu
1879806661. 1
1879806662. 2
1879806663. 3
1879806664. 4
The ion having the highest bond order is
(1) NO+
(2 ) 02 +
(4) C2 +
Options :
1879806665. 1
1879806666. 2
1879806667. 3
1879806668. 4
Question Number : 47 Question Id : 1879801667 Question Type : MSQ Option Shuffling : No Display Question
Examrace Number : Yes
www.examrace.com
(1) NO+
(2 ) 02 +
(3) N2 +
(4) C2 +
Options :
1879806665. 1
1879806666. 2
1879806667. 3
1879806668. 4
The frequency of 0 - H stretch occurs at ~3600 cm- 1 . The 0 - D stretch frequency (in cm- 1 )
would be closest to
(1) 3000
(2 ) 2600
(3 ) 1800
(4 ) 900
Options :
1879806669. 1
1879806670. 2
1879806671. 3
1879806672. 4
0 - HG"'R ctr 3TT<Jfii" ~ 3600cm- 1 ｾ＠ WTc mcfr t i 0 - D ctf G"'R 3TT<Jfii" (cm- 1 ii)
Rs! 'fi J, Rcbcd 1-1 N'ft. <T6" ｾ＠
(1) 3000
(2 ) 2600
(3 ) 1800
(4 ) 900
Options :
1879806669. 1
1879806670. 2
1879806671. 3
1879806672. 4
The value of a physic.al variable was found to be 196, 198, 194, 199 and 198 in a set of five
independent measurements. The average value and the standard deviation would be dosest,
respectively, to
(1) 198 and 2
(2 ) 197 and 4
(3 ) 197 and2
(4 ) 198 and 4
Options :
1879806673. 1
1879806674. 2
1879806675. 3
1879806676. 4
"C!<l5 'lffidCf1 qfQc1df cf5 Qffl ｾ＠ ll"N'TT cf5 ｾ＠ ii mi-0 llA 196, 198, 194, 199 c,m 198 ｾ＠ I
3ftw llA c,m i:rF[q) Rlili:'1 "1 Ptct>ca1-1 mi't, wrn:
(1) 198 c,m 2 cfi
(2) 197 c,m 4 en

'
(3) 197 c,m 2 cf5
(4) 198 c,m 4 en

'
Options :
1879806673. 1
1879806674. 2
1879806675. 3
1879806676. 4
The titration of 4.4 g of a polymer having carboxylic acid end group requires 11 mL of
0.02M NaOH . The average molar mass (in kgmol·1) of the polymer is
(1) 40
(2) 20
(3) 15
(4) 10
Options :
1879806677. 1
1879806678. 2
18708OGG70. 3
1879806680. 4
"C!<l5 4.4 g isi§~c!5 ｾ＠ c!51isllfcN:I ~ ｾ＠ 3R'U ｾ＠ %. cf5 6l jl-ll4'1 q 0.02M NaOH Cfi 11 mL
c5l' ,!,J lcl~llc!5al Neff %I isl§~ c!5 c5l' 3Timf 1'ITffi ｾ＠ (kg moJ- 1 if) %I
(1) 40
(2 ) 20
(3 ) 15
(4 ) 10
Options :
1879806677. 1
1879806678. 2
1879806679. 3
1870806680. 4
A liquid of density 1.1 g cm- 3 climbs to a height of 5.0 cm when a capillaiy with inte111al radius
of 0.2 mm is dipped into it. The surface ten5ion (in Nm- 1 ) of the liquid is closest to
(1) 0.05
(2 ) 0.108
(3 ) 0.018
(4 ) 0.005
Options :
1879806681. 1
1879806682. 2
1879806683. 3
1879806684. 4
"C!<l5 1. 1 g cm-3 ~ cf> ~ ii 0.2 nun '1ll"'dRc!5 ｾ＠ cJ51 cfi~ lc!51 en'r ｾ＠ 1N ｾ＠ 5.0 cm
c5l" ｾ＠ dCl5 01 'c!G \l!IBT %I 01 <ITT ｾ＠ ('P[jq (Nm - 1 ii) ltifl cf> Ac!5cdll %_ cffi %
(1) 0.05
(2 ) 0.108
(3 ) 0.018
(4 ) 0.005
Options :
1879806681. 1
1879806682. 2
1879806683. 3
1879806684. 4
Con5ider a two-level system in which the excited state, separated from the ground state by
energy e, is doubly degenerate. The fraction of the molecules in the excited state, as T ＠ oo,
lS
(1) -1
3
(2 ) -1
2
(3 ) -2
3
(4 ) 1
Options :
1879806685. 1
1879806686. 2
1879806687. 3
1879806688. 4
"C!<l5 fGo: ｾ＠ filx-ct4'l ll Ptct>lll ftril:lii i3tal\Jla ｾ＠ CITT ｾ＠＠ｾｾ＠ -g~ e i3,(J!T
CITT %_ LR ｾ＠ ct\'11\Ji ｾ＠ I '3 ct1 !\JI a 3m~ ii, ~3TT CITT 3ffl '11<1 T ＠ oo, %
(1) -1
3
(2 ) -1
2
(3 ) -1.
3
(4 ) 1
Options :
1879806685. 1
187D80GG8G. 2
1879806687. 3
1879806688. 4
The cell potential (in V) ofa Ag/AgCI/KCI electrode connected to the standard hydrogen
electrode at 298 K is dosest to (Given E(AgCI/ Ag,cl- ) = 0.222 V and asstune that the activity of
KC! is 0.01)
(1) 0.197
(2 ) 0.297
(3 ) 0.340
(4 ) 0.440
Options :
1879806689. 1
1879806690. 2
1879806691. 3
1879806692. 4
lfAcfJ 01~'.>'?1\J1 '1, s~ct~'i-s 3lN Ag/AgCl/KCl $clct~'1-s cf> ~441011 'ff <ifl 'ff<1 cf)l ｾ＠
(V if) ltiflcri f.lcnccil-l ~- ｾ＠ｾ＠ ( ~ ｾ＠ E(AgCI/ Ag,CI- ) = 0.222 V; ｾ＠ KCI cITT fl Rislldl
0.0 l llFf C"l~tfti t.:)
(1) 0.197
(2) 0.2 97
(3) 0.340
(4) 0.440
Options :
1879806689. 1
1879806690. 2
187980669 1. 3
1879806692. 4
If the rate constant for a base catalyzed ester hydJolysis reaction is 0.20 L mol-1 s-1, half-life
(in s) of the ester (Given [ester]0 = [base]0 = 0.05 1nol. L-1) would be closest to
(1) 40
(2 ) 100
(3 ) 140
(4 ) 200
Options :
1879806693. 1
1879806694. 2
1879806695. 3
1879806696. 4
am 0d1Ra ｾ＠ c5\ '1lc'f 314tlc'i ｾ＠ Cfi ｾ＠ ufq ｾ＠ｾ＠ 0.20 L mo1- 1 s-1 %, m
ｾ＠ c5\ 3ltl ｾ＠ (s ii ) ~i/i c/i Flcricd "l ~ . <ffi %
(~ %[ester]o = [base]o = 0.05 mo!. L- 1)
(1) 40
(2) 100
(3 ) 140
(4 ) 200
Options :
1879806693. 1
1879806694. 2
1879806695. 3
1879806696. 4
The hydrogen atomic orbital given by Nr 2 e - r/ 3 ao(3 cos 2 0 - 1) represents
(1) 2p orbital
(2) 3p orbital
(3) 3d orbital
(4) 4d orbital
Options :
1879806697. 1
1879806698. 2
1870806600. 3
1879806700. 4
(1) 2p c!>!ITT!> <ITT
(2 ) 3p c!>!ITT!> <ITT
( 3) 3 d c!>!ITT!> <ITT
(4 ) 4d cn!Hcn <b l
Options :
1879806697. 1
1879806698. 2
1879806699. 3
1879806700. 4
Molar composition of a mixture of P and Q at equilibrium is 3: 1 (P Q) A small disturbance in

composition results in change of chemical potential of P by 10 J mo1- 1 . The chemical potential
of Q will change (in J moJ- 1 ) by:
(1) 30
(2 ) 3.3
(3 ) - 30
(4 ) - 3.3
Options :
1879806701. 1
1879806702. 2
1879806703. 3
1879806704. 4
P am cf5 f4JWJT <ITT ｾ＠
Q ~..rr ii lfR'R x4t1c'i 3 1 (P Q) %1 fit1 c 'i ii "C!'<P mt'r "ilfr
132@ 1J2IB P cf5 xlfl lllf.tcli fcmcr ii 10 J n101- 1 <ITT q Rc1cl1 <ITT ｾ＠ %I Q Cfi xlfl l<l f.tcb fc:Mcl
ii ltia'il qRcJcl'i (J mo1- 1 ii) 311 '111(! ' 11, i:ffi %
(1) 30
(2 ) 3.3
(3 ) - 30
(4 ) - 3.3
Options :
1879806701. 1
1879806702. 2
1879806703. 3
1879806704. 4
Con5ider the entropy changes in a system undergoing transfonnation, as depicted in the

diagram, below
LlS LlS
1
2s c ---=---+
0 so c ----=--
2
75° c 0
~s j
The c01Tect statement among the following is
Options :
1879806705. 1
1879806706. 2
1879806707. 3
1879806708. 4
"C!<f; Flc!51ll J; q,t1cfl qfQc1cl1 <Ix fcmR ct!Rnq, ~i/i c/i Xi>4itwo1 Cnl" f.rc1 h si1R1?1 ii <:~llll l
t
~s, ~s,
25° C -------+ SO"C Ｍ＠ 7s c 0
~s j
Options :
1879806705. 1
1879806706. 2
1879806707. 3
1879806708. 4
• • • • • b
• • • •
L,
• • • •
• • • •
The Miller index for the plane as shown in the figure and parallel to the c-axis, is
(1) 110
(2 ) 120
(3 ) 210
(4 ) 220
Options : Examrace www.examrace.com
1879806709. 1
1879806710. 2
1879806711. 3
1879806712. 4
• • • • • b
• • • • L.
• • • •
• • • •
(1) 110
(2) 120
(3 ) 210
(4 ) 220
Options :
1879806709. 1
1879806710. 2
1879806711. 3
1879806712. 4
A cube does not have the symmetiy element
Options :
1879806713. 1
1879806714. 2
1879806715. 3
1879806716. 4
Options :
1879806713. 1
1879806714. 2
1879806715. 3
1879806716. 4
The c01Tect match for the drug molecules in the Cohullll A with their medicinal use in Cohullll
B is
Cohullll A Column B
p I. Anaesthetic
Procaine
Q II. Anticoagulant
0
Warfari n
NH2 H
Ph ~ N l:is
R
oo)=t~ 111. Antibiotic
CO2H
Cephalexin
(1) P- i· Q - ii· R- iii

' '
(2 ) P- ii·' Q-i·' R- iii
(3 ) P- iii Q - i· R-ii
> '
(4 ) P- i· Q - iii· R-ii
' '
Options :
1879806717. 1
1879806718. 2
1879806719. 3
1879806720. 4
p L
Pr-ocaine
0
0
Warfarin
R um_
002H
Cephale·x in
P-i- Q• ·- ii"> R. - iii
P-u; Q-i- R - iu
P-iii-, Q. - i-, R - u
P - i- Q - iu; R - u
Options :
1879806717. 1
1879806718. 2
1879806719. 3
1879806720. 4
Part C Chemical Sciences

Section Number : 3
Section Marks: 100
Group All Questions:
Examrace No www.examrace.com
Correct Marks : 4 Wrong Marks : 1
The rate-detennining step in the catalytic synthesis of acetic acid by Mon5anto process is
(1) oxidative addition of CH3I to [Rhh(C0)2J-
(2 ) migration of CH3 group to CO of [RhI3(C0)2(CH3)r
( 4) coordination of CO to [RhI3CO(COCH3)J-
Options :
1879806721. 1
1879806722. 2
1879806723. 3
1879806724. 4
Options :
1879806721. 1
1879806722. 2
1879806723. 3
1879806724. 4
The cluster types of [Fe;(C0)1.iNJ- and [Co6(CO)13N] - are, respectively,
(1) nido-, nido-
(2) nido-, closo-
(3 ) c/oso-, nido-
(4 ) c/oso-, closo-
Options :
1879806725. 1
1879806726. 2
1879806727. 3
1879806728. 4
(1) nido-, nido-
(2) nido-, closo-
(3 ) c/oso-, nido-
(4 ) c/oso-, closo-
Options :
1879806725. 1
1879806726. 2
1879806727. 3
1879806728. 4
In the electronic spectrum of [IrBr6]2-, the number of charge tran5fer band(s) and their origin
are, respectively
(1) Two, ｬｩｧ｡ｮ､＠ metal (o ＠ t2g and o ＠ a1g*)
(2 ) One, ｬｩｧ｡ｮ､＠ metal (o ＠ e,)
(3 ) Two, ｬｩｧ｡ｮ､＠ metal (o ＠ t2g and o ＠ e;J
(4 ) One, ｬｩｧ｡ｮ､＠ metal (o ＠ t2J
Options :
1879806729. 1
1879806730. 2
1879806731. 3
1879806732. 4
Options :
1879806729. 1
1879806730. 2
1879806731. 3
1879806732. 4
The main product of nucleophillic attack of H- on the complex ion given below is
ｾ＠
v ~
., ~ Mo'-l:
ｾ＠
(1)
' ~Mo'-l:
T
V ｾ＠
(2 )
(3 )
(4 )
Options :
1879806733. l
1879806734. 2
1879806735. 3
1879806736. 4
(1)
q:1 -
~ M
o'L.. -
(2)
ｾ＠
!3"''L
ｾ＠
(3)
~ Mou
ｾ＠
(4)
~ Mo'<(
Options :
1879806733. 1
1879806734. 2
1879806735. 3
1879806736. 4
Choose the equilibria from the following that are NOT favoured to go to right:
(A) As2S; + S HgO ｾ＠ As20 s + S HgS
(B) La2(C03)3 + Bi2S3 .....,..~ La2S3 + Bi2(C03)3
(C) CdS04 + CaS ---=~ CdS + CaS04
(D) BeF2 + Hgl2 -=~ BeI2 + HgF2
(1) AandB
(2 ) A and C
(3 ) Band C
(4 ) BandD
Options :
1879806737. 1
1879806738. 2
1879806739. 3
1879806740. 4
P11-1ffi fuia ii ｾ＠ \3""f 'flTl'm CITT ｾ＠ c51 Ril ｾ＠ Ril.:i c!51 GIf6.fl .3ITT '1IAT ｾ＠ｾ＠ %I
(A) As2S; + S HgO -=~ As20 s + S HgS
(B) La2(C03)3 + Bi2S3 -=~ La2S3 + Bii(C03)3
(C) CdS04 + CaS -=~ CdS + CaS04
(D) BeF2 + Hgh ｾ＠ Beh + HgF2
(1) A (f2lf B
(2 ) A (f2lf C
(3) B ~ -IT C
(4 ) B~-TT D
Options :
1879806737. 1
1879806738. 2
1879806739. 3
1879806740. 4
The correct statements for dithionite and dithionate anions from the following are
(A) both have S- S bond
(B) both are dianionic
(C) oxidation state of sulphur is +3 and +5, respectively
(D) ~11lphur in dithionate has Jone pair of electron5
(1) A, B andC
(2 ) A, B andD
(3 ) B, Cand D
(4 ) A and B only
Options :
1879806741. 1
1879806742. 2
1879806743. 3
1879806744. 4
~ :a1,i' 11 1~c ('Im ;gr.'i>lJllll-1c ?fL011<i1'i cf5 fuC! Pl1--Jfc:iftrn q ｾ＠ｾ＠ cl52.R ｾ＠

(A) ｾ＠ ii S- S 3ITTl"".£l I t
(B) ｾ＠ f&- '51!.0llll.fl ｾ＠ I
(C) fl (>Q5'l, 3l1cF«icf5'l01 -3TTIT~ m"l'm• +3 om +5 ii t1
(D) ｾ＠ Cfi ili (>Q5'l ｾ＠ ~cb lc51 ~&i crs';11 gl1'f t I
(1) A, B o m C
(2) A, B o m D
(3 ) B, Com D
(4 ) CfitR'f A om B
Options :
1879806741. 1
1879806742. 2
1879806743. 3
1879806744. 4
Correct MarksExamrace
: 4 Wrong Marks : 1 www.examrace.com
The species for which the shapes (geomehy) can be predicted by VSEPR theory is/are
(A) [PtC14)2-
(B) [TeCl6]2-
(C) PF3 and SF6
An5wer is
(1) AandC
(2 ) R an<l C:
(3 ) Conly
(4 ) AandB
Options :
1879806745. 1
1879806746. 2
1879806747. 3
1879806748. 4
VSEPR lii<i'(l"fl -H ftR tCt~~~ cf> ｾ＠ (" lll~ Ri) <ITT ｾ＠ 6l jl-11Pid ｾ＠ 'ffCITT) ~, <lQ %/ t
(A) [PtCJ4)2-
(B) [TeCl6)2-
(C) PF3 am SF6
i3m i
(1) A a2TT C
(2 ) B cf.>-TT C
(3 ) cITTR'f C
(4 ) A a 2TT B
Options :
1879806745. 1
1879806746. 2
1879806747. 3
1879806748. 4
Examrace
Single Line Question Option : No Option Orientation : Vertical www.examrace.com
Among SOi(OH)F, CH3CQiH, LiF and H20 , the compound(s) which behave(s) as a base in
liquid HF is/are
(2 ) LiF only
(3 ) S02(0H)F and LiF only
Options :
1879806749. 1
1879806750. 2
1879806751. 3
1879806752. 4
S02(0H)F, CH3C02H, LiFc'PITTH20 if 'H ｾ＠ 4if.'lct> / m 4if.'lct>'i <ITT~ HFB a1R ｾ＠

cllQ61~ mm ~- ql$ ~/ ~ I
(2 ) cf;tlc'fLiF
(3 ) cf;tR'f S02(0H)F am LiF
Options :
1879806749. 1
1879806750. 2
1879806751. 3
1879806752. 4
Complex(es) which has/have unpaired electron(s) that is equal to that of iron center in
oxymyoglobin is/are
A. [Fe(ox)3J3-
B. [Fe(CN)6]3-
C. [NiCJ4)2-
D. [Cu(NH3)4)2+
(Given: ox = oxalato)
Correct answer is
(1) AandB
(2 ) B andD
(3 ) Conly
(4 ) CandD
Options :
1879806753. 1
1879806754. 2
1879806755. 3
1879806756. 4
ｾ＠ ~ / ~-icgc'l'i ftRii 61,afl'1-1a ~c'ict~11'i ctr 'f-mm 6ll cfffP-ll<ll •c'l'1f.H Cfi 3ITTIFI ctR Cfi
Sf-f4R ｾ＠ t cfQ ti t
A. [Fe(ox)3]3
B. [Fe(CN)6]3-
C. [NiCJ4)2-
D. [Cu(NH3)4)2+
ｾ＠ t: ox = 6llcN~c'i c'I)
(1) A o2TT B
(2 ) B o2TTD
(3 ) cITTm C
(4 ) Co2TTD
Options :
1879806753. 1
1879806754. 2
1879806755. 3
1879806756. 4
In spectrofluorimetric detennination in solution

A. absorbance of analyte solution is kept near to 0.05
B. oxygen is eradicated from solution
C. pH of solution is controlled
D. wavelength of incident light is always above 400 nm
Co1Tect from the above is
(1) A, B andD
(2 ) B, CandD
(3 ) A, B andC
(4 ) A, CandD
Options :
1879806757. 1
1879806758. 2
1879806759. 3
1879806760. 4
fcl cl ll'i 1l '(-lj at 4\ J.l RI G"Ifi'<l 1-11q) f.itITTur cf5 fmr
A . fcl!tc'IISQ cfi fclclll'i cl)f 6Jq!trli:1Ulicb 0 05 cf5 Jl lfl 4l'li ｾ＠ %I
B . fclcl ll'i ~ f ~ lcMl'Jl 'i cfl] 04fc1a ｾ＠ｾ＠ %I
C. fclcl ll'i cBJ pH cl5'r A48ia cb'[ff %I
D . -6114Rl d Wnm fcmur <ITT a'M ~u\ 400 nm 'ff 'f-lGT ｾ＠ｾ＠ %I
(1) A, B cr.ITTD
(2 ) B, Ccr.ITTD
(3 ) A, B er.ITT C
(4 ) A, Ccr.ITTD
Options :
1879806757. 1
1879806758. 2
1879806759. 3
1879806760. 4
Match the items in Column I with those of Column IL
Cohunn I (species) Column II (structure/properties)
a Nall 1 polymeric chain
b BeH2 11 interstitial hydride
C HfH2.10 ill tricapped trigonal prismatic
d [TcH9)2- IV saline hydride
The co1Tect match is
(1) a-iv, b-ii, c-iii, d-i
(2) a-i, b-iv, c-ii, d-iii
(3 ) a-iv, b-i, c-ii, d-iii
(4 ) a-iv, b-i, c-iii, d-ii

Options :
1879806761. 1
1879806762. 2
1879806763. 3
1879806764. 4
ｾ＠ I ('Bli~ft isl) cn1W{ II ('ti'l'<FII / :!• 1w1J

a NaH I .Jg(9<5l ｾ＠
b BeH2 11 3:io'{ Icl'i l~ft 61~*1~~
C HfH2.10 lll 1?1 c 1... ,"l" ~ x~i:i;n9 1a:r fi:i~ <i
d [TcH9]2- IV (9 qoft l:l 61~*1~~
(1) a-iv, b-ii, c-iii, d-i
(2) a-i, b-iv, c-ii, d-iii
(3) a-iv, b-i, c-ii, d-iii
(4) a-iv, b-i, c-iii, d-ii

Options :
1879806761. 1
1879806762. 2
1879806763. 3
1879806764. 4
In Mossbauer spectnun of a sample containing iron recorded in the presence of a static
magnetic field, the munber of possible allowed transition(s) is
(1) Two
(2) Four
(3 ) Six
(4 ) Eight
Options :
1879806765. 1
1879806766. 2
1879806767. 3
1879806768. 4
ｾ＠＠ｾ
"fl!:TT 3ITTR', %. <ITT ll'fxHi'i~ f(icftl-l ｾ＠ 1...ic61,i Ph c5\ ~ i i ~
fcnm 11m l ｾ＠ｾ＠ '(itli"lOli c5\ ｾ＠ %1
(1)
(2 )
(3 ) ty:
(4) 3lIB
Options :
1879806765. 1
1879806766. 2
1879806767. 3
1879806768. 4
FeCn04 and NiGa204bave nonual and inverse spine! structures, respectively. The co1Tect
statement is
(1) Fe(II) and Ni(II) occupy octahedral sites
(2 ) Fe(II) and Ni(II) occupy tetrahedral and octahedral sites, respectively
(3 ) Cr(III) and Ga(III) occupy only octahedral sites
(4 ) Cr(III) and Ga(III) occupy tetrahedral and octal1edral sites, respectively

Options :
1879806769. 1
1879806770. 2
1879806771. 3
1879806772. 4
Options :
1879806769. 1
1879806770. 2
1879806771. 3
1879806772. 4
The correct order of metal- carbon distance is
(4 ) Ni(1]' -Cp)2 > Co(11'-Cp)2 > Fe(1]' -Cp)2
Options :
1879806773. 1
1879806774. 2
1879806775. 3
1879806776. 4
Options :
1879806773. 1
1879806774. 2
1879806775. 3
1879806776. 4
The major product of the following reaction is
(1)
(2 )
(3 )
(4 )
Options :
1879806777. 1
1879806778. 2
1879806779. 3
1879806780. 4
..
(1)
(2 )
(3 )
(4 )
Options :
1879806777. 1
1879806778. 2
1879806779. 3
1879806780. 4
The correct match of ~pin-only magnetic moment for the complexes cis-[Fe(phen)2(NCS-N)2]
(A) and [Fe(phen)3]Ch (B) at 300 K is (phen = 1,10-phenanthroline)
(1) 4.89BMfor bothAand B
(2 ) 0 BM for both A and B
(3 ) 4.89 BM for A and 0 BM for B
(4 ) 0 BM for A and 4.89 BM for B

Options :
1879806781. 1
1879806782. 2
1879806783. 3
1879806784. 4
300 K 1:1'( ~-i<kd'i c:is-[Fte(IJ!1te11)2(NCS-N)2] (A) -rm [Fte(phe11)3)Cli (B) <fi ｾ＠ ftq,, g¼m'I ll
~,'i'.'if <ITT 'ff6f ftic'l 11 ｾ＠ (phen = 1, 10 - ~~
(1) A a m B, G'Rf cf> ｾ＠ 4.89 BM
(2) A a m B, G'Rf cf> ｾ＠ 0 BM
(3 ) A cf> ｾ＠ 4 .89 BM a m B cf> ｾ＠ 0 BM
(4 ) A cf>~ 0 BMam B cf>~ 4 .89 BM

Options :
1879806781. 1
1879806782. 2
1879806783. 3
1879806784. 4
Match Column I, II and ill

Cohuun I (metal) Column II (enzyme) Column ill (end product)
A Ni I Carbonic anhydrase X uric acid
B Zn 11 Xanthine oxidase y methane
C Mo Ill Coenzyme f 430 z carbonic acid
The co1Tect match is
(1) A-iii-Y; B-i-Z; C-ii-X
(2) A-iii-Y; B-ii-X; C-i-Z
(3) A-ii-X; B-i-Y; C-iii-Z
( 4) A-i-X; B-iii-Z; C-ii-Y

Options :
1879806785. 1
1879806786. 2
1879806787. 3
1879806788. 4
~ I (mTI) CITTW n ( ~;.;jj l~"l) ｾ＠ ill (3lc'<I '3ctl lc:)
A Ni I ~, . , .. ' '" ~ ""l ci l~>?\Jl X ｾ＠
B Zn 11 ｾｾ＠ ,!,jj cNfl ,g(jj y ir2R

...
C Mo lll ~ - ~'\J1 l~"l Eno z « 11 "1 11 ""1 «1 ｾ＠
(1) A-iii-Y; B-i-Z; C-ii-X
(2) A-iii-Y; B-ii-X; C-i-Z
(3) A-ii-X; B-i-Y; C-iii-Z
(4) A-i-X; B-iii-Z; C-ii-Y

Options :
1879806785. 1
1879806786. 2
1879806787. 3
1879806788. 4
Match the items in column I with tl1ose of cohu1111 II
Cohu1111 I Collllllll II
a. Conductometric titration i. Voltage
b. Amperometric titrations ii. Resistance
c. pH metric tiration iii. M
d. Differential pulse polarography iv. I.i
Correct match is
(1) a-ii; b-iv; c-i; d-iii
(2 ) a-iii; b-i; c-ii; d-iv
(3 ) a-iii; b-ii; c-iv; d-i
(4 ) a-i; b-iii; c-iv; d-ii

Options :
1879806789. 1
1879806790. 2
1879806791. 3
1879806792. 4
cnlWII cnlWI II
a. 'cl l ~crii9 1fi1a'l <l 31:J:l=ll q'l I. LI i '"'--'!'
b. ~ lxlfi1a'l <l 31:J;i'l lq"I 11. >t 1GX 1e<
c. pH-~ 3:i j Jllq "I iii. Af
d. ｾ＠ ffl ｾ＠ <'l lt<Bi iv Li
(1) a-ii; b-iv; c-i; d-iii
(2) a-iii; b-i; c-ii; d-iv
(3) a-iii; b-ii; c-iv; d-i
(4 ) a-i; b-iii; c-iv; d-ii

Options :
1879806789. 1
1879806790. 2
1879806791. 3
1879806792. 4
The correct statement about base hydrolysis of [Co(py)4Chr (py = pyridine) is
(1) rate expression is, Rate = k[Co(py)4Ch]+[oH-J
(2) reaction does not depend on hydroxide ion concentration
(3) reaction proceeds through SN1CB mechanism
(4 ) intennediate involved in this reaction is [Co(py)4Ch(OH)]

Options :
1879806793. 1
1879806794. 2
1879806795. 3
1879806796. 4
Options :
1879806793. 1
1879806794. 2
1879806795. 3
1879806796. 4
Con5ider the following statements:

(A) The highest oxidation state of Group 8 elements is more readily shown in their oxides than
in fluorides.
(B) Fe can exist in - 2 fomllli oxidation state also.
(C) Mn, Tc and Re easily fom1 M(II) compounds.
The co1Tect statement(s) is/are
(1) AandB
(2 ) A and C
(3 ) Band C
(4 ) Conly
Options :
1879806797. 1
1879806798. 2
1879806799. 3
1879806800. 4
Question Number : 80 Question Id : 1879801700 Question Type : MSQ Option Shuffling : No Display Question
Examrace Number : Yes
www.examrace.com
P11-1ffl fula c52Rl "Q'/" ftmN c6l Ril <:

(A) ~ 8 Cfi ITT'cTT &I'll f! q'j.,-,i j -6l lcNfl cfi~UI ｾ＠ tf<:F,1'1~1~,g'j clfr ~ . -6l li:N-ll~-s'i '{ 3lMcn
3ITT'{,.fi ｾ＠ C:~114'1 vmf %
(B) Fe, - 21:ITT"lm -6l lfflc!5'101 ~-TT ii 'lfr fcttt"l l"I i5'f ~i ct>al %
(C) Mn, Tc am Re 3ITT'{,.fi ｾ＠ M (II) <llr'l c!i ERIB ｾ＠
ｾ＠ cp2Ff % / ｾ＠
(1) A am B
(2) A amc
(3) B ~-ITC
(4 ) cITTR'f C
Options :
1879806797. 1
1879806798. 2
1879806799. 3
1879806800. 4
The intennediate A and the maj or product B fom1ed in the following reaction are
Bn KE!:) ~ _,, Me
I
(1) [A)= Me~ N tC0 2 Me B= _.. _yC02Me
HNI ' Me
Me Bn
Bn
(2 ) [A] = Me~ ~ ~ C0 2Me B=
Me 0
~ .,,Me
(3 ) B= ',.,~C02Me
HN Me
I
Bn
Bn
(4 ) [A)= Me~ ~ ~ C0 2 Me B=
Me 0
Options :
1879806801. 1
1879806802. 2
1879806803. 3
1879806804. 4
Ef)
Bn K ~Me
I C02Me
(1) [A)= Me ~ N tC0 2 Me B=
HN ' Me
1
Me Bn
Bn ~Me
(2 ) [A] = Me ~ ~ ~ C0 2Me B=
Me N C02Me
Me 0 I
Bn
Ef)
K Bn ~Me
I C02Me
(3 ) [A) = Me ~ NtC02Me B=
HN Me
I
Me Bn
~ , ,Me
Bn
(4 ) B=
[A) = Me ~ ~~ C0 2 Me Me N ··,co2Me
Me 0 I
Bn
Options :
1879806801. 1
1879806802. 2
1879806803. 3
1879806804. 4
1. PhCH=CH2
ｾｯｾ＠
PdCl2(PPh3lz
Et3N , DM F
2. Grubbs' 2 nd
MeOJlA I ge neration
catalyst, C6Hs
(2 )
MeO
Ph
0
0
(3 ) ;)
MeO
Ph
(4)
Options :
1879806805. 1
1879806806. 2
1879806807. 3
1879806808. 4
P11-1ffl ful a ｾ＠ ii FcHfil a ｾ＠ \3l(l[G ｾ＠
1. PhCH=CH2
ｾｯｾ＠
PdCl2(PPh3)2
El3N, DMF
2. Grubbs' 2nd
MeOJLAI generation
catalyst, CsHs
0
(1)
MeO fX: >
0
0
(2 )
MeO -->
Ph
0
0
(3 ) ;)
MeO
Ph
(4 )
MeO
)CCｾ＠
Options :
1879806805. 1
1879806806. 2
1879806807. 3
1879806808. 4
The maj or products A and B fonned in the following reactions are
0
1. y < J 0
Cl 1.Br~
A
Buli, -78 °c
2. HgCl2
r'l
s- s
Buli, -78 °C
2. HgCl2
B
0 0
(1) A= B=
~ H H~
(2 ) A= y<? B=
Br~
OH 0
H
CHO
0
(3 ) A= y<? B=
H~
CHO
0 OH 0
(4 ) A= B- I II
~ H Br~ H
Options :
1879806809. 1
1879806810. 2
1879806811. 3
1879806812. 4
P11-11flfula ｾ＠ ii FtlxRla ｾ＠ l3lffiG A a-m B ｾ＠ I
0
1. ~ 0
Cl 1. Br~
Buli, -78 °C /"-., Bul i, -78 °C
A I I - --'-- - B
2. HgCl2 s..___,,..s 2. HgCl2
0 0
(1) A=
B = H~
~H
(2 ) A= y<? B-
Br~
OH
I
0
II
H
CHO
0
(3 ) A= y<? B = H~
CHO
0 OH 0
(4 ) A= B- I II
~ H B r ~H
Options :
1879806809. 1
1879806810. 2
1879806811. 3
1879806812. 4
The correct order of the reactions involved in the following tran5fomJation is
0
1. ~
MeO
0 p / OMe
II
0
2. 0
(±) II
Li 0 ,,-~' 0Me C02Me
OMe
-78 °C-rt, TH F
(1) Michael addition, QtJasi-Favorskii reruTangement, Aldo! condensation
(2) QtJasi-Favorskii reaJTallgement, Michael addition, Aldo! condensation
(3) Michael addition, Aldo! condensation, Quasi-Favorskii rearrangement
(4) Aldo! condensation, Quasi-Favorskii reruTangement, Michael addition

Options :
1879806813. 1
1879806814. 2
1879806815. 3
1879806816. 4
P11-1ffl fula x,5q ia'-!01 ii fl l'A-ifc1 a ｾ＠ <ITT 'ff6f :mi:r ｾ＠
0
1. /V MeO
98% H2S04 p/ OMe
2.
(±)
-78 °c
0
II
Li 8..,.- ~, 0M e
OMe
-78 °C-rt, THF
ffi C0 2Me
II
0
Options :
1879806813. 1
1879806814. 2
1879806815. 3
1879806816. 4
The structure of the compollnd, which displays the following spectral data is
IR = 1690, 1100 cm-1
1H NMR: o2 .8 (s, 3H), 3.8 (s, 3H), 6.9 (d, J = 8 Hz, 2H), 7 .8 (d, J = 8 Hz, 2H)
13
c NMR: o 197, 165, 130, 129, 114, 56, 26
(3 ) ｾ＠
'o)l)
(4 ) ＠ｾ
llAo,.,
Options :
1879806817. 1
1879806818. 2
1879806819. 3
1879806820. 4
P11-1fflfula 'l-Q ct~~ 6llcb~ \ifl" ll·1fr1c15 1,1 ,:~ia <Pxa1 %'3-li c5l 'lixil"l l G"
IR = 1690, 1100 cm- 1
H NMR: o2 .8 (s, 3H), 3.8 (s, 3H), 6.9 (d, J = 8 Hz, 2H), 7 .8 (d, J = 8 Hz, 2H)
1
13 c NMR: o 197, 165, 130, 129, 114, 56, 26
(3 ) ｾ＠
' o)l)
(4 ) ＠ｾ
llAo,.,
Options :
1879806817. 1
1879806818. 2
1879806819. 3
1879806820. 4
The correct absolute configuration of th e following compounds is
II
( 1) I: M; II: R
(2 ) I: M; II: S
(3 ) I: P; II: R
(4 ) I: P; II: S
Options :
1879806821. 1
1879806822. 2
1879806823. 3
1879806824. 4
II
(1) I: M; II: R
(2 ) I: M; II: S
(3 ) I: P; II: R
(4 ) I: P; II: S
Options :
1879806821. 1
1879806822. 2
Examrace
1879806824. 4
The major produc.t fonned in the following reac.tion is
q>:9 BF3·0 Et2
(1) q>=o
(2 ) <:p-OH
(3 )
¢-
(4 )
cpOH
Options :
1879806825. 1
1879806826. 2
1879806827. 3
1879806828. 4
q:>:9 BF3·0Et2
(1) q>=o
(2 ) <:p-OH
(3 )
¢-
(4 ) cpOH
Options :
1879806825. 1
1879806826. 2
1879806827. 3
1879806828. 4
The compound that shows peaks in the EI mass spectnun at
m/ z 121, 105, 77, 44 is
(1)
(2 )
(3 )
(4 )
Options :
1879806829. 1
1879806830. 2
1879806831. 3
1879806832. 4
EI GUill l"l 't(lcf~ll q \Yil 4l frlcb m/ z 12 1, 105, 77, 44 tR ｾ＠ Gitlld l %, cffi %
(1)
(2 )
(3 )
(4 )
Options :
1879806829. 1
1879806830. 2
1879806831. 3
1879806832. 4
The major products A and B in the following reaction sequence are
A B
~ ?,;
(1)
A= l ~J,,
- - 0
ｾ＠
(2 ) A=
c±x 0
B=~
-
= o ,,
c±J
~ -·•' .•'
(3 ) B=
A= ~ O
-
= o ,,
(4 )
Options :
A=
ctl 0
B=
1879806833. 1
1879806834. 2
1879806835. 3
1879806836. 4
c& 0
A B
(1) B=
(2 ) B=
=o -
,,
V0 , ,,
(3 ) A=
ctl 0
B=
~
-
(4 ) A= ~
~ - -' B=
0
Options :
1879806833. 1
1879806834. 2
1879806835. 3
1879806836. 4
AcO p-TsNHNH 2
AcOH
(1)
(2 )
AcO
(3 )
(4 ) ｾ＠
Options :
1879806837. 1
1879806838. 2
1879806839. 3
1879806840. 4
AcO p-TsNHNH 2
AcOH
AcO, Jl
ｾ＠
(1)
(2 )
AcO
(3 )
Options :
1879806837. 1
1879806838. 2
1879806839. 3
1879806840. 4
TRUE statement regarding Hammett reaction constant (p) for the following tra11Sfonnations
given in equations A and B is
HO
e
EtOH (Equation A)
EtOH (Equation B)
(1) p for A and B is same and positive
(2 ) p for A and B is same and negative
(3 ) p for A is larger positive value than for B
(4 ) p for A is negative and for B is positive

Options :
1879806841. 1
1879806842. 2
1879806843. 3
1879806844. 4
,H41c5-101i A ~..rr B ii ｾ＠ P11---1 ~R!lct Xii 4ict-101i cf> ｾ＠ｾ＠ｾ＠ｾ＠ (p) cf> ｾ＠
ii ｾ＠ cl52R t
HO
e
(Equation A)
x~ C02Ei __H_o_e_ x~ cooe • EtO H (Equation B)
( 3) B ctr 3ltl'a-TT A cf> ｾ＠ p <ITT l!T--1 ｾ＠ tl -'I I,llcb %I
Options :
1879806841. 1
1879806842. 2
1879806843. 3
1879806844. 4
The reaction that gives (E)-2-methylhex-3-ene as the major product is
(1)
n
OH
ｾ＠
(2 )
hea t
(3 )
~o
t-BuOK
H
(4 )
~ o
LiHMD S
H
heat
Options :
1879806845. 1
1879806846. 2
1879806847. 3
1879806848. 4
(1)
n
OH
ｾ＠
(2 )
heat
(3 )
~ o
t-BuOK
H
(4 )
~o
LiHMDS
H
heat
Options :
1879806845. 1
1879806846. 2
1879806847. 3
1879806848. 4
1. CHCl3, KOH
H 0 - 0 -Et
(l ) HO - p - Et
HO
(2) H O - Q -Et
OH
Options :
1879806849. 1
1879806850. 2
1879806851. 3
1879806852. 4
1. CHCl3 , KOH
H 0 - 0 - Et
2. H2O2, NaOH
(l ) HO- p - E t
HO
(2) H O - Q -Et
OH
Options :
1879806849. 1
1879806850. 2
1879806851. 3
1879806852. 4
Products A and B fonned in the following transfonnation of alkylidenecarbenes are
ｾ＠
A
ｾ＠
B
H
(1) A=
toit •- ~
H
(2 ) A=
toit B= ~
(3 ) A=
ｾ＠ H
B= ~
(4 ) A=
ｾ＠ H
•· ~
Options :
1879806853. 1
1879806854. 2
1879806855. 3
1879806856. 4
C
ｾ＠
A
ｾ＠
B
H
(1) A=
tot{ •· ~
H
(2 ) A=
tot{ B= ~
(3 ) A=
ｾ＠ H
B= ~
Options :
1879806853. 1
1879806854. 2
1879806855. 3
1879806856. 4
(i-Prl3Si ｾ＠
(1) X
l ) _ _ ) - Si(i-Prh
Si(i-Prh
(3 )
0
Si(i-Prh
(4 )
Options :
1879806857. 1
1879806858. 2
1879806859. 3
1879806860. 4
(i-PrlJSi ~
( 1) ;____t::
l J _ _ ) - si(i-Prh
Si(i-Prh
(3 )
0
Si(i -Prh
(4 )
Options :
1879806857. 1
1879806858. 2
1879806859. 3
1879806860. 4
i. TiCl3
0 0 LiAIH4
~OMe
(1) ｾ＠
(2 ) CTO
(4 ) ｾ＠
0
Options :
1879806861. 1
1879806862. 2
1879806863. 3
1879806864. 4
i. TiCl 3
0 0 LiAIH4
~OMe ii. H30 •
(1) ｾ＠
(2) CTO
(4 ) ｾ＠
0
Options :
1879806861. 1
1879806862. 2
1879806863. 3
1879806864. 4
The maj or product fonned in the following reaction is
0- + _ ?i cat. NaCN
0 CHO Ph~ P h DMF
(1) OHC~ P h
HO Ph
f7\ HOV Ph/.

(2 ) O~ Ph
0
Ph 0
I/ \
(3 ) 0 Ph
0
Options :
1879806865. 1
1879806866. 2
1879806867. 3
1879806868. 4
cat. NaCN
+
DMF
(1) OHC ~ Ph
HO Ph
(2 )
ｾ＠ 0
Ph
Ph 0
I/ \
(3 ) 0 Ph
0
(4 ) OHC ~ Ph
Ph 0
Options :
1879806865. 1
1879806866. 2
1879806867. 3
1879806868. 4
The major product A and the byproduct5 B formed in the following reaction are
,r=i f7N
OH
N
1. ｾ＠ N n N ...._j-
s
ｾ＠ OH
2. P(OMelJ, 11
A + B
( 1) A= ｾ＠ B = CO2, S =P(OMe)J
(2 ) A= ｾ＠ B = O=C=S, O=P(OMeh
(3 ) A= _;=\_ B = CO 2 , S=P(OMeh
(4 ) B = O=C=S, O=P(OMe)3
Options :
1879806869. 1
1879806870. 2
1879806871. 3
1879806872. 4
OH
ｾ＠ OH
2. P(OMeh , 6
A + B
( 1) A= ｾ＠ B = CO2, S =P(OMe)J
(2 ) A= ｾ＠ B = O=C=S, O=P(OMeh
(3 ) A= _;=\_ B = CO 2 , S=P(OMeh
(4 ) B = O=C=S, O=P(OMe)3
Options :
1879806869. 1
Examrace
1879806871. 3
1879806872. 4

1. HBr
2. MeOH , H•
3. MeP(OEl )2
4. H30•
~ C02 Me
(1)
NH 2
(2 )
(3 )
0
II
(4 ) ,,- Pｾ＠ N H2
I
OH
Options :
1879806873. 1
1879806874. 2
1879806875. 3
1879806876. 4
1. HBr
2. MeOH, H•
3. MeP(OEt)i
4 .H3o•
~ C 02 Me
(1)
NH 2
(2 )
(3 )
0
II
(4 ) .,,- Pｾ＠ N H2
I
OH
Options :
1879806873. 1
1879806874. 2
1879806875. 3
1879806876. 4
The intennediate A and the maj or product B fom1ed in the following reaction are.
ｾ＠ H2
B
HO OH _[ndlar's [A) - --"-- -
catalyst
(1) [A) = ｾ＠
HO OH
B= ~ OH
(2 ) [A) =
~ ·-,,- OH
H
(3 ) JAi = B= ~ OH
~ OH
~OH
R
HO
(4 )
Options :
[A] •
n
HO OH
B= ~
~
H
OH
OH
1879806877. 1
1879806878. 2
1879806879. 3
1879806880. 4
ｾ＠ H2
B
HO OH l.lnd.ar's [A) - - - - -
catatyst
ｾ＠
(1) ｾ＠
(A (=
.
HO
,II OH
B• ~ OH
(2 ) [A) •
~ ·.,,._ OH
H
(3 ) IAI = B= ~
~
OH
OH
~ OH
R
HO
(4 )
Options :
[A] •
n
HO OH
B= ~
~
H
OH
OH
1879806877. 1
1879806878. 2
1879806879. 3
1879806880. 4
The spatial part of the dominant resonance stmcture of the LiH molecule is (only valance part
of the wavefonction is shown).
(1) 2sLl (r1) 2sLl(ri)
(2 ) 2su(n) lsH(n) + 2SLl(f'2) l SH(n)
(3 ) 2su(n) lsH(n) - 2sLl(f'2) lSH(n)
(4 ) lsH(r1) lsH(ri)
Options :
1879806881. 1
1879806882. 2
1879806883. 3
1879806884. 4
ｾ＠ L iH m\ mwf ｾ＠ '<1'(<-!"11 ｾ＠ ~..nfiw, 'l'!T'T ｾ＠ (CTM q,~1"1'i <r; <.fie@ ~-i<l'iv i<!" II •t!f'T
~ t) 1
(1) 2si; (r1) 2si;(ri)
(2) 2si;(n) lsH(n) + 2su(n) b'!!(n)
(3 ) 2si;(n) lsH(n) - 2su(n) lSH(n )
Options :
1879806881. 1
1879806882. 2
1879806883. 3
1879806884. 4
In linear variation method using two 01t hogonal basis function5, the two root5 obtained are
E0 and E1 (E0 < E1 ). The correct relation of these with exact ground and first excited state
energies, E0 and E1, respectively, is
(3) Eo < Eo and E1 < E1
Options :
1879806885. 1
1879806886. 2
1879806887. 3
1879806888. 4
ｾ＠ Ftlii -101 Fttfu "fi Gl ~if.lc!5 m 1:lx'FIT <ITT i34ll,l' I m LN mi:cr. GT 'f.'[ E
0 am E1
(E0 < E1 ) ｾ＠ I ｾ＠ <12TT2f P11--1a1-1 am W--R '3-a!"Zna 3lcR~ ｾ＠ ~ - ｾ＠ E0 am E1 .
,fl" ｾ＠ｾ＠ %I
Options :
1879806885. 1
1879806886. 2
1879806887. 3
1879806888. 4
The reducible representation, r, in the table is equal to the following supeiposition of the
irreducible representations of C2 v point group.
Czv E Cz (JV cr'V

Ai 1 1 1 1
Az 1 1 -1 -1
81 1 -1 1 -1
H2 1 - 1 - 1 1
r 8 -2 --6 4
(3) 5A1 EB Ai EB 2B1
Options :
1879806889. 1
1879806890. 2
1879806891. 3
1879806892. 4
\l lfzyjQ,i ｾ＠ (4,,,.,~,ll f.'t'{<,qo1, r, ｾ＠ｾ＠ C2 v <TT '61&,,,.,~,ll f.'t '{<,q o1 <f> f.'j..,fzyjf?!.ni oial lx'1qu1
cfi 'tfl'IA %
C2v E C2 (JV cr'V
A1 1 1 1 1
A2 1 1 -1 -1
81 1 -1 1 -1
82 1 -1 -1 1
r 8 -2 -6 4
(3) 5A1 ｾ＠ A2 ｾ＠ 2B1
Options :
1879806889. 1
1879806890. 2
1879806891. 3
1879806892. 4
In the pure rotational mi crowave spectrum of a XY molecule, the adjacent lines are separated by
4 cm- 1 . If the molecule isiJTadiated by a radiation of30,000 cm- 1, the first Stokes liJ1e
(in cm - 1 ) appears at
(1) 29988
(2 ) 30012
(3 ) 30004
(4 ) 29996
Options :
1879806893. 1
1879806894. 2
1879806895. 3
1879806896. 4
ｾ＠ｾ＠ XY cf5 ｾ＠ l-l1$,f>l<l<t ｾ＠ fticfS:,l-l ii Flc!5cqcft clWf 4 cm- 1 ｾ＠ 112TTP ｾ＠ I ｾ＠ｾ＠

<ITT 30,000 cm- 1 cf5 fcl fclHLI ｾ＠ fclixfolct fcnm ｾ＠ cTT J:lw:I ｾ＠ c'ITI[', WTc (cm- 1 li) ｾ＠
t
(1) 29988 tR
(2) 30012 tR
(3 ) 30004 tR
(4 ) 29996 tR
Options :
1879806893. 1
1879806894. 2
1879806895. 3
1879806896. 4
The Hiickel molecular orbital of benzene that is degenerate with the molecular orbital
f Cx2 + X3 - Xs - X6), is
(1)
(2 )
1
(3 ) ,/IT ( 2X1 - X2 - X3 + 2X4 - Xs - X6)
(4 )
Options :
1879806897. 1
1879806898. 2
1879806899. 3
1879806900. 4
½Cx2 + X3 - Xs - X6), ,:}j j p)Q cj'j '1!1f.lcci 'f-1 ~.-(i11'1 <ITT \ill Qcfi('I '1!1fuQcj'j -6l lf.lcci ｾ＠ ~-
ｾ＠ %
(1)
(2)
(3 )
(4 )
Options :
1879806897. 1
1879806898. 2
1879806899. 3
1879806900. 4
The degeneracy of the state having energy :::: for a paiiicle in a 3-D cubic box of length L is
(1) 4
(2) 3
(3 ) 2
(4 ) 1
Options :
1879806901. 1
1879806902. 2
1879806903. 3
1879806904. 4
(1) 4
(2 ) 3
(3 ) 2
(4 ) 1
Options :
1879806901. 1
1879806902. 2
1879806903. 3
1879806904. 4
Con5ider the gas phase reaction 2A(g) + 3B(g) ｾ＠ 2C(g) at a given temperature. When
2.0 moles of A(g) are reacted with 2.0 moles of B(g), 0.8 moles of C (g) are formed at
equilibrium at a total pressure of 2.0 bar. The value of the equilibrium constant, K p of this
reaction at the given temperature is closest to
(1) 0.3
(2 ) 0.9
(3 ) Z.4
(4 ) 19.1
Options :
1879806905. 1
1879806906. 2
1879806907. 3
1879806908. 4
"C!<l5 ｾ＠ crrq ｾ＠ｾ＠ ~-TT ｾ＠ + 3B(g) ｾ＠ 2C(g) ｾ＠ ftlw'! c6'tl\JI(! I ｾ＠
2A(g)
Gr.r 2.0 bar ~ \JI<! A(g) ct 2.0 J:iTffi cBJ B(g) cfi 2.0 J:iTffi "'H ｾ＠ cBJ ｾ＠ %"ITT 'tlTRl
3m~ ii C(g) cfi 0.8 l'frffi <ITT fti~ iFi mGT %I ｾ＠ｾ＠ cfi fc:r(! 'HTRl N$--ITTcn KP <ITT
i:rR ｾ＠ crrq ｾ＠ I\JI fl cfi f.icbcd ll %_ <ffi %
(1) 0.3
(2 ) 0.9
(3 ) 2.4
(4 ) 19.1
Options :
1879806905. 1
107900G90G. 2
1879806907. 3
1879806908. 4
The molar residual entropy (in J K- 1) of solid OCS would be closest to
(1) 0
(2 ) 2.9
(3 ) 5.8
(4 ) 8.7
Options :
1879806909. 1
1879806910. 2
1879806911. 3
1879806912. 4
(1) 0
(2 ) 2.9
(3 ) 5.8
(4 ) 8.7
Options :
1879806909. 1
1879806910. 2
1879806911. 3
1879806912. 4
The electrolyte solution that has the smallest Debye-length at 298 K is
(1) 0.01 MNaCl
(3 ) 0.0 lM CuCh
(4 ) 0.0 lM LaCh
Options :
1879806913. 1
1879806914. 2
1879806915. 3
1879806916. 4
(1) 0.01 MNaCl
(3 ) 0.0 l M CuCh
(4 ) 0.0 l M LaCh
Options :
1879806913. 1
1879806914. 2
1879806915. 3
1879806916. 4
The rate constant of a second order reaction 2A ＠ Z is k 2 . If the initial concentration of the
reactant is a 0 and the concentration of the product at ti.me t is x , then a linear function of t with
the slope k 2 a0 is
(1) In (2-)
ao - x
X
(2 )
(3 )
(4 ) J11 ( x )
• o(•o - x)
Options :
1879806917. 1
1879806918. 2
1879806919. 3
1879806920. 4
ｾ＠ c!>'rfc ctr ｾ＠ 2A ＠ Z <ITT U7T Filla jct, k 2 ｾ＠ I ｾ＠ｾ＠ ctr J:ITWlcl5
,m-i:al a 0 ｾ＠ am ｾ＠ t TT '3ttll <: ctr ~il-i:a l x ｾ＠ mt <ITT, 'R'lltl k 2 a{) cf> ｾ＠ｾ＠ Qlc'R
ｾ＠
(1) In (2.._)
ao - x
(2) '
•o(• o- x)
(3)
(4) J11 ( x )
• o(•o - x)
Options :
1879806917. 1
1879806918. 2
1879806919. 3
1879806920. 4
X-rays of 173 pm wavelength are reflected by the (111) plane of a cubic primitive crystal at
0 = 30°. The unit cell length (in pm) is closest to
(1) 173
(2) 300
(3) 346
(4) 600
Options :
1879806921. 1
1879806922. 2
1879806923. 3
1879806924. 4
l3c!> 31m ｾ＠ !Tuil-cc'I cf5 (111) '(i "lac'I 'ff 173 pm a~,,~w ctr x- ~ CITT 4~1qct"I 0 = 30°
q,r mm %I ｾ＠ 'ITT'f ctr c'I Ril l~ (pm ii) NNic/i Plc!ical-l %. UQ %
(1) 173
(2 ) 300
(3 ) 346
(4 ) 600
Options :
1879806921. 1
1879806922. 2
1879806923. 3
1870806024. 4
In a polymer of 1V monomer units, the root mean square separation between tl1e two ends is
proportional to
l
(1) Nz
(2 ) N
(3 ) •
N 'i.
(4 )
Options :
1879806925. 1
1879806926. 2
1879806927. 3
1879806928. 4
l
(1) Nz
(2 ) N
(3 ) Nz
•
(4 )
Options :
1879806925. 1
1879806926. 2
1879806927. 3
1879806928. 4
( Cp - Cv) for a non-ideal gas differs from ( Cp - Cv) for a perfect gas by the expression
(1)
(2 )
(3) 1
T
(av) (au)
oT p oV T
(4 )
Options :
1879806929. 1
1879806930. 2
1879806931. 3
1879806932. 4
"C!<l5 611 1<:~\ lTTf cf5 1m( (Cp - Cv ), "C!<n ｾ＠ lTTf c5J ( Cp - Cv) 'fl" ftm ｾ＠ 'fl" l11"', %,
ｾ＠ %
(1)
(2 )
(3 ) 1(av) (au)
TaTp aV T
(4 )
Options :
1879806929. 1
1879806930. 2
1879806931. 3
1879806932. 4
For the electrochemic~l cell AglAgCIIMCl(0.0lM) IMCl(0.02M) IAgCIIAg, the j unction potential
is the highest when M+is
(2 ) u+
(3 ) Na+
Options :
1879806933. 1
1879806934. 2
1879806935. 3
1879806936. 4
fclWl ~lili lllPlcb ｾ＠ AglAgCI IMCl(0.01M)IMCl( 0.02M)IAgCI IAg, Cfi ｾ＠ m fcmcr ｾ＠
%'(jj"E[ M+%
(2 ) u+
(3) Na+
Options :
1879806933. 1
1879806934. 2
1879806935. 3
1879806936. 4
The fonction, which is NOT an eigenfonc.tion of the indicated operator, is
Operator Function
(1) d2
- - x2
dx 2
Operator Function
(2) d2
2
dx2 +x
Operator Function
(3 ) d2 TIX
cos-
dx2 4
Operator Function
(4 ) d2 e4ix
dx2
Options :
1879806937. 1
1879806938. 2
1879806939. 3
1879806940. 4
Operator Function
(1) d2
- - x2
dx 2
Operator Function
(2 ) d2
2
dx2 +x
Operator Function
(3 ) d2 TIX
cos -
dx2 4
Operator Function
(4 ) d2 e4ix
dx2
Options :
1879806937. 1
1879806938. 2
1879806939. 3
1879806940. 4
The order of a surface catalyzed unimolecular reaction, at ve1y low and very high pressures of
the reactant, would be, respectively
(1) 0, 0
(2 ) 1, 0
(3 ) 0, 1
(4 ) 1, 1
Options :
1879806941. 1
1879806942. 2
1879806943. 3
1879806944. 4
ｾ＠ 1rG '3, ~ ｾ＠ , I (: 4, Ifoq4, ｾ＠ ifit <ITTft ｾ＠ <Tj 3lKI ｾ＠ '1m 3lKI ｾ＠ <:;,er tR
m,fr, m"l'm•
(1) 0, 0
(2 ) 1, 0
(3 ) 0, 1
(4 ) 1, 1
Options :
1879806941. 1
1879806942. 2
1879806943. 3
1879806944. 4
1.0 mo! of a perfect monatomic gas is put through the cycle shown in the figure. The total work
(in J) done during th e cycle is
(u5e I L-bar = 100 J, R = 8.3 J K- 1 moJ- 1 = 0.083 L-bar K- 1 moJ-1, h 1 2 = 0 .7)
2.0 - - - -A B
I
I
....n, I
I
~ 1.0 - - - -ID I
,c
a. I
I ''
I
'
I
I ''
I
'
23.24 46.48 92 .96
V/ L
(1) 930
(2 ) - 4183
(3 ) 883 1
(4 ) - 5113
Options :
1879806945. 1
1879806946. 2
1879806947. 3
1879806948. 4
3TTGW 'TT'! <fi 1.01-ITT'f cbT ｾ＠
"C!<f; 4·U·ll fuq cf5 ii ~,& lq ｾ＠ 'fl 'j,\Jll'-!I lfm ｾ＠ 'c!w ctr ｾ＠
ii fclxrr lfm ｾ＠ m (1 ii) ｾ＠
(W:ll71 <611\Jl q lL-bar = 100 J, R = 8.3 J K-1 moJ-1 = 0.083 L-bar K- 1 moJ- 1, h1 2 = 0.7)
2.0 - - - - A 8
.------:1----..:.
'-
"'
~1.0 - - --'----L--~---~,c
Q. :o I
I
I
23.24 46.48 92.96

V/L
(1) 930
(2 ) - 4 183
(3 ) 883 1
(4 ) - 5113
Options :
1879806945. 1
1879806946. 2
1879806947. 3
1879806948. 4
The oxidation of NO to N0 2 occurs via the mechanism given below.
k,
2NO N 20 2
k.,
k1
N10 1 + 0 1 2N0 2
d(:~21 in the presence of large excess of 0 2 can be written as
(1)
(2 )
(3 ) k1 (N0)2
k2
(4 )
Options :
1879806949. 1
1879806950. 2
1879806951. 3
1879806952. 4
k,
2NO N202
k. 1
kz 2N 0 2
N10 1 + O z
(1)
(2 )
(3 ) k1 (N0)2
k2
(4 )
Options :
1879806949. 1
1879806950. 2
1879806951. 3
1879806952. 4
In trans 1,2-dicWoroethylene, the IR inactive mode is
(1) C - Cl symmetric stretch
(2 ) C - Cl asymmetric stretch
(3 ) C - H asymmetric stretch
(4 ) In phase out of plane C - Cl bend
Options :
1879806953. 1
1879806954. 2
1879806955. 3
1879806956. 4
(1 ) C - Cl ~i'lf4a ff"FI
(2 ) C - Cl 3Hi"lf4a cFR
(3 ) C - H 6Hil-l f4 a ('ff"!
Options :
1879806953. 1
1879806954. 2
1879806955. 3
1879806956. 4
For the reaction K + Br2 ＠ KBr + Br, which follows the harpoon mechanism, the reactive
cross section is closest to
2
(Use - •- = 2.3 x 10- 28 J m, Ionization energy of K = 422.5 kJ mo1- 1 , electron affinity of
4nto
Br2 = 250 kJ mo1- 1 and NA = 6 x 1023 mol- 1 )
(1) 50 X 10- 18 m 2
(2 ) 2 X 10- 18 m2
(3 ) 64 X 10- 18 m 2
(4 ) 16 X 10- 18 m 2
Options :
1879806957. 1
1879806958. 2
1879806959. 3
1879806960. 4
ｾ＠ K + Br2 ＠ KBr + Br, ~ 61~'{1 fm ll lft119 cITT 6l j'lNUI cl5'IBI ~- Cfi ｾ＠

mfmll l~ cl ｾ＠ qR-.:>JiG ltiflcti Rcbcdll %, <ffi ｾ＠
(W:il71 <61Rsi q....::..
4neo
= 2.3 X 10- 28 J Ill, K ctr ｾ＠ｾ＠ = 422.5 kJ mo1- 1 , Br2 ctr
~cl ct~11 oiWf[ = 250 kJ mo1- 1 am NA = 6 x 1023 moJ- 1)
( 1) 50 X 10- 18 m 2
(2 ) 2 X 10- 18 m2
(3 ) 64 X 10- 18 m 2
(4) 16 X 10- 18 m 2
Options :
1879806957. 1
1879806958. 2
1879806959. 3
1879806960. 4

CSIR 2019 15 December Shift 2 Chemical Sciences

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CSIR 2019 15 December Shift 2 Chemical Sciences

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National Testing Agency

Question Paper Name: Chemical Sciences 15th December 2019 Shift 2

Part A Chemical Sciences

ｾ＠ ｾ＠ .fr ｾ＠ ｾ＠ ｾ＠ 'R 3R! Wal ii 1ffit ｾ＠ I 1ffiT 'R c!iJ ｾ＠ qi;,-:w, J; ｾ＠ ｾ＠ ｾ＠

A. The mean values of the quantities are nearly equal

B. The variations in the two quantities are nearly equal

C. Quantity 1 varies less over the given period as compared to Quantity 2

(1) Only A is true

(3 ) A and Care true

(4 ) and B are h11e

(1) twice longer

(2 ) three times longer

(3 ) four times longer

(4 ) eight times longer

(1) twice the probability that it hits the larger ring.

(2) half of the probability that it hits the larger ring.

(4) one-fotuth the probability that it hits the larger ring.

ｾ＠ •i'k ll<bN ｾ＠ <r; <Im dR -, cgffilll ｾ＠ lTT1T ｾ＠ Ri·N~ 1 if 7 <!ft ｾ＠ ｾ＠ ｾ＠ I ｾ＠

ｾ＠ ~ : 1Rf ｾ＠ ｾ＠ utr ,?j ｾ＠ <1>cRT ii ｾ＠ <1>cRT ,?j qr.fr frR m ｾ＠ 1 f.'11-,f2.1fula ｾ＠

b. Honnone A reduces food intake

(1) Impaired production ofhom1one A causes obesity

(2) Impaired action of honnone A causes obesity

(3) Obesity results into low levels of hom1one A

(4) Excess food intake cau5es depletion ofhom1one A

Part B Chemical Sciences

i( 2 Chlorophyilll > [NmCl4] 2- > [Cr(lli:0)6]2+ > [Mn(lli:0)6]2+

i( 3 [NiCfil4] 2- > Chlo:mphyll > [Cr(H20)6]- > [l\lfu.(Hi0)6]-

The expected number of Vco bands in the IR spectra of/ac-[Mo(PPh3)3(C0)3] and

(1) one and one

(2 ) hvo and two

(3 ) hvo and one

(4 ) three and one

(1) Gd3+ and Lu3+

(2 ) Sm3+ and Tb3+

(3 ) Eu3+ and Tb3+

(4 ) Sm3+ and Eu3+

(1) Gd3+ "t1m Lu3+

(2) Sm3+ -am Tb3+

In common glass electrode, alkaline eiTor caused at pH > 10 is least for

(1) 0.01M NaCl

(2) 1.0 M NaCl

Con5ider four species A, B, C, and D .

Oxidation of A with C in an ac.idic medium gives D . A, B, C and D are, respectively

ｾ＠ Rtcl ll'i ii A <ITT C 'f-1 6llfficf>~UI D ｾ＠ ｾ＠ I A, B, C ('f2TT D ~, ~ •

(1) Tetragonally elongated, dx2-y2

(2) Tetragonally compressed, dz'

(4 ) Tetragonally compressed, d.2-i

The common heptacity observed for coordination of C60 to a metal center is

(1) Hg lamp; nitric oxide flan1e

(2) Hg lamp; graphite furnace

(3) Hollow cathode lamp; graphite furnace

( 4) Hollow cathode lamp; acetylene-nitric oxide flame

(1) NF3 > SbF3 > SbCh

(2) SbCh > SbF3 > NF3

(3 ) Sbf3 > SbCh> Nf3

( 4) NF3 > SbCh > SbF3

(2 ) SbCh > SbF3 > NF3

(3 ) SbF3 > SbCh> NF3

ｾ＠ｾ＠ .fr ｾ＠ｾ＠ｾ＠ 'R 3R! Wal ii 1ffit ｾ＠ I 1ffiT 'R c!iJ ｾ＠ qi;,-:w, J; ｾ＠ｾ＠ｾ＠

ｾ＠ •i'k ll<bN ｾ＠ <r; <Im dR -, cgffilll ｾ＠ lTT1T ｾ＠ Ri·N~ 1 if 7 <!ft ｾ＠ｾ＠ｾ＠ I ｾ＠

ｾ＠ ~ : 1Rf ｾ＠ｾ＠ utr ,?j ｾ＠ <1>cRT ii ｾ＠ <1>cRT ,?j qr.fr frR m ｾ＠ 1 f.'11-,f2.1fula ｾ＠

ｾ＠ Rtcl ll'i ii A <ITT C 'f-1 6llfficf>~UI D ｾ＠ｾ＠ I A, B, C ('f2TT D ~, ~ •

P11-1ff1Rsla 4'1fl'1cB'i cf5 ｾ＠ FclcB1is1'1FcNkF1 ｾ＠ｾ＠ cITT ｾ＠ wi:i %

(1) Two, ｬｩｧ｡ｮ､＠ metal (o ＠ t2g and o ＠ a1g*)

(2 ) One, ｬｩｧ｡ｮ､＠ metal (o ＠ e,)

(3 ) Two, ｬｩｧ｡ｮ､＠ metal (o ＠ t2g and o ＠ e;J

(4 ) One, ｬｩｧ｡ｮ､＠ metal (o ＠ t2J

~ :a1,i' 11 1~c ('Im ;gr.'i>lJllll-1c ?fL011<i1'i cf5 fuC! Pl1--Jfc:iftrn q ｾ＠ｾ＠ cl52.R ｾ＠