Major Test - 2 (ADV) Chemistry Paper - 1 (Code : 12)

PART (B) : CHEMISTRY

SECTION-I : (MULTIPLE CORRECT ANSWER(S) TYPE)

This section contains 10 multiple choice questions. Each question has four choices (A), (B), (C)
and (D) out of which ONE or MORE than one is/are correct.

21. The incorrect IUPAC name of maleic acid is

(A) cis-but-2-enoic acid (B) trans-butanoic acid
(C) cis-butanoic acid (D) trans-but-2-enoic

22. Which of the following IUPAC names indicates Homocyclic compound?

(A) Cyclohexane-1,2-dicarboxylic acid (B) Cyclohexane-1,2-dicarboxylic anhydride
(C) Benzene carbonyl chloride (D) Cyclopent-3-en-1-ol

23. The true statement regarding glycerol is/are

(A) two 1o alcohol (B) Trihydric alcohol (C) one 2o alcohol (D) Monohydric alcohol

24. Which of the following carboanion is more stable from tertiary butyl caboanion?
(A) F  CH 2  CH 2  CH 2 (B) O 2 N  CH 2  CH 2  CH 2

(C) Cl  CH 2  CH 2  CH 2 (D) Me3 N  CH 2  CH 2  CH 2

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Major Test - 2 (ADV) Chemistry Paper - 1 (Code : 12)

25. Which of the following group is stronger +I power from isopropyl group?

(A) O (B)  CH3 3 C  (C) CH3  CH2  (D)  CT3 2 CH 

26. According to kinetic theory of gases, for a diatomic molecule which is (are) not correct?
(A) The pressure exerted by the gas is directly proportional to the mean speed of the molecule.
(B) The pressure exerted by the gas is directly proportional to the root mean square speed of the
molecule.
(C) The root mean square speed of the molecule is inversely proportional to the temperature.
(D) The mean transitional kinetic energy of the molecule is proportional to the absolute temperature.

  
27. For a real gas, following equation  P   Vm     RT , where  and  are positive constants.
 TVm2 
Select the correct option(s) :
8
(A) Critical temperature TC  (B) Critical volume Vc.m  3
27 R

(C) Second virial coefficient    (D) Third virial coefficient  2
RT

28. Select correct statement(s).

(A) In Bohr model it is possible to determine both position and momentum of electron
simultaneously.
(B) Energy of electron in second excited state of He+ is –13.6 eV.
h
(C) Angular momentum of electron moving in third orbit of H-atom is 3 .
2
(D) There are 3 radial nodes in 5p orbital.
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Major Test - 2 (ADV) Chemistry Paper - 1 (Code : 12)

29. From the following data, mark the option(s) where H is correctly written for the given reaction.
Given : H+ (aq) + OH– (aq) ––– H2O(l); H  57.3 kJ
H solution of HA(g) = –70.7 kJ/mol
H solution of BOH (g) = 20 kJ/mol
H ionization of HA(aq) = 15 kJ/mol and BOH is a strong base.
Reaction ΔH r (kJ/mol)
(A) HA(aq) + BOH(aq) –– BA(aq) + H2O –42.3
(B) HA(g) + BOH(g) –– BA(aq) + H2O –93
(C) HA(g) –– H+(aq) + A–(aq) –55.7
(D) B+(aq) + OH–(aq) –– BOH(aq) + H2O –20

30. Choose the correct statement(s).

(A) For phase transformation of liquid water at 1 atm, 373 K to water vapour at 1 atm, 373 K, G
will be zero.
(B) Two solid blocks of same material and same mass having different temperature are kept in an
isolated system then entropy of system must increase.
(C) Intensive properties are not additive in nature while extensive properties are additive in nature.
(D) No cyclic process is possible in which the sole result is absorption of heat from a hot reservoir
and its complete conversion into work.
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Major Test - 2 (ADV) Chemistry Paper - 1 (Code : 12)

SECTION-II : (INTEGER ANSWER TYPE)

This section contains 10 questions. The answer to each question is a NUMERICAL VALUE. For
each question, enter the correct numerical value (in decimal notation, truncated/rounded-off to the
second decimal place; e.g. 6.25, 7.00, 0.33, 30.27)

31. How many functional groups are present in the given compound?

32. Total number of 3o carbon atoms present in compound given below :

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Major Test - 2 (ADV) Chemistry Paper - 1 (Code : 12)

33. Number of carbon atoms in parent ‘C’ chain

34. How many of the followign groups are stonger –I from –OH group?

–F, –Cl,  NH3 , –NO2, CH  C  , CH2=CH–, Ph–, NC–, –COOH

35. Find total number of transformation(s) in which highest occupied molecular orbital HOMO and
magnetic behaviour both change –
(i) O 2  O 22  (ii) C 2  C 2 (iii) NO  NO+ (iv) N 2  N 22 
(v) B 22   B 2 (vi) N 2  N 22  (vii) O 22   O 2

36. A 3 L gas mixture of propane (C3H8) and butane (C4H10) on complete combustion at 25oC produced
10 L CO2. Assuming constant P and T conditions what was volume of butane present in initial
mixture?
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Major Test - 2 (ADV) Chemistry Paper - 1 (Code : 12)

37. A uniform cylinder with frictionless pistons A and B is held in shown position by mechanical
stoppers.

If the mechanical stoppers holding piston A and B as shown in figure are removed and in the mean
time, N2O4 and O3 gases separately undergo following reaction completely.
[Assume that temperature remains constant.]
N2O4  2NO2
2O3  3O2
Then the distance of piston B from left end is x cm, then find x.

38. For an hypothetical hydrogen atom, the mass of proton is twice the mass of electron. For such an
atom radius of ground state is x  0.529 Å . Then x is
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Major Test - 2 (ADV) Chemistry Paper - 1 (Code : 12)

39. Consider the following six conditions. (Series number 1 to 6). Select those conditions which
represent criteria for spontaneity. Consider the system to be closed.
[Report your answer by adding the serial number of selected conditions.]
Serial Number Conditions
1  dG  P, T  0
2  S universe  0
3  dU S , V  0
4  dH S, P  0
5  dS U, V  0
6.  dS H, P  0
All notations have their usual meaning.

40. How many of the followign have all type of carbon atoms, i.e., (1o, 2o, 3o and 4oC-atoms)?

(A) (B) (C)

(D) (E) (F)

(G) (H)

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