SF6 gas that is exposed to spark discharges, partial discharges or switching arcs can form toxic decomposition by-products, both gaseous and powder. The gaseous by-products include sulfur dioxide, hydrogen fluoride, and various sulfur and fluorine compounds. The powder by-products include fluorides of tungsten, aluminum and copper. Inhalation or ingestion of these by-products can cause irritation of the eyes, nose, throat and lungs and even pulmonary edema and damage.
SF6 gas that is exposed to spark discharges, partial discharges or switching arcs can form toxic decomposition by-products, both gaseous and powder. The gaseous by-products include sulfur dioxide, hydrogen fluoride, and various sulfur and fluorine compounds. The powder by-products include fluorides of tungsten, aluminum and copper. Inhalation or ingestion of these by-products can cause irritation of the eyes, nose, throat and lungs and even pulmonary edema and damage.
SF6 gas that is exposed to spark discharges, partial discharges or switching arcs can form toxic decomposition by-products, both gaseous and powder. The gaseous by-products include sulfur dioxide, hydrogen fluoride, and various sulfur and fluorine compounds. The powder by-products include fluorides of tungsten, aluminum and copper. Inhalation or ingestion of these by-products can cause irritation of the eyes, nose, throat and lungs and even pulmonary edema and damage.
• Decomposition by-products can take the form of gas or
powders • Other types of contaminants can include moisture and air (from handling or leakage), dust and particles (mechanical generation) • If by-products are ingested or inhaled cause: eye, nose and throat irritation, pulmonary oedema, and other lung damage, skin and eye burns, nasal congestion, Bronchitis, rashes
SF6 Decomposition By-products Chemical Name Chemical Formula Gaseous By-products Sulfur Dioxide SO2 Thionyl Sulfide (sulfur tetrafluoride) SOF2 (SF4) Hydrogen Fluoride HF Disulfur Decafluoride (sulfur pentafluoride) S2F10 (SF5) Sulfuryl Fluoride SO2F2 Sulfur Tetrafluoride Oxide SOF4 (SF4) a aSF4 is readily hydrolysed to SOF2. Powder By-products Tungsten, aluminum, copper fluorides WF6, WO3, AlF3, CuF2 S2 F10 is ordourless in pure form but its toxicity is on par with phosgene, the infamous chemical warfare pulmonary agent used during the First World War