MAHARISHI VIDYA MANDIR, BALASORE

TERM – II

CLASS – XI FULL MARKS : 35

SUBJECT : CHEMISTRY TIME - 2 HOURS

GENERAL INSTRUCTIONS:
1.There are 14 questions in the question paper.
2.SECTION -A :- Q No. 1 to 3 are very short answer questions carrying 2 marks each.
3.SECTION -B :- Q No. 4 to 11 are short answer questions carrying 3 marks each.
1.
4.SECTION -C :- Q No. 12 to 14 are long question & case based question carrying 5 marks each.
Answer any ONE of them.
5. Use of log tables and calculators are not allowed.

SECTION - A

1. Define extensive and intensive property. Give an example of each type.

2. Define conjugate acid and conjugate base. Give an example of each type.
3. Convert:
(i) Butene to Butane
(ii) Propene to 2 – Bromopropane

SECTION – B

4. Define Anomalous properties of Boron.

Or
Write the relationship between Kp and Kc .
5. Define Markovnikov’s rule and Antimarkovnikov’s rule.
Or
Write any three preparations of Alkane.
6. Prove: Cp – Cv = R
7. Define ideal gas equation.
8. What is photosynthesis? Give one example.
9. Define:
(i) Wurtz reaction
(ii) Ozonolysis
Or
Define Zeolite.

10. At 250 C and 760 mm of Hg pressure a gas occupies 600 mL volume. What will be its pressure at
night where temperature is 100 C and volume of the gas is 640 mL?
Or
On a ship sailing in Pacific Ocean where temperature is 23.40 C, a balloon is filled with 2L air. What
will be the volume of the balloon when the ship reaches Indian ocean, where temperature is
26.10 C?
 11. Define IUPAC name of the following compound.
(i) 𝐶𝐻3 − 𝐶𝐻 − 𝐶𝐻2 − 𝐶𝑂𝑂𝐻

𝐶𝐻3
(ii) 𝐶𝐻3 − 𝐶𝐻 − 𝐶𝐻2 − 𝐶𝐻 = 𝐶𝐻2

𝑂𝐻
(iii) 𝐶2 𝐻5
𝐶𝐻3

𝑂𝐻
SECTION – C
12. Define first law of thermodynamics. Write the mathematical expression for it.
Or
13. Derive the relationship between ∆𝐻 and ∆𝑈 for an ideal gas. Explain each term involved in the
equation.
Or
14.
CASE-BASED QUESTIONS

Read the given passage and answer the questions that follow:
Intermolecular forces are forces of attraction and repulsion between interacting particles. They are weak
forces and generally affect the physical and chemical properties of matter. Attractive intermolecular forces
are known as van der Waal’s forces. They vary considerably in magnitude. They include dispersion forces or
London-forces, dipole-dipole and dipole induced dipole forces.
London-forces exist between neutral atoms or non-polar molecules. The dipole-dipole forces exist
between dipole ends of polar molecules and are the strongest of all van der Waal’s forces. Dipole induced
forces exist between polar molecules having permanent dipole and molecules lacking permanent dipole H
bonding is a special type of dipole -dipole interaction.

(i) Why magnitude of interaction energy of London forces depends on polarizability of

particles?
(ii) Why are dipole-dipole interaction considered stronger than London-forces but weaker than
ion-ion interaction?
(iii) Out of HF and H2O, which has stronger H – bonding interaction?
(iv) Which type of intermolecular forces are present in the molecules HF, HCl, HBr, HI?
(v) Name the intermolecular forces between Cl2 and CBr4.

ALL THE BEST