MAHARISHI VIDYA MANDIR, BALASORE

PERIODIC ASSESSMENT – 3

CLASS – XI FULL MARKS : 40

SUBJECT : CHEMISTRY TIME - 2 HOURS

GENERAL INSTRUCTIONS:
1.There are 14 questions in the question paper.
2.SECTION -A :- Q No. 1 to 3 are very short answer questions carrying 2 marks each.
3.SECTION -B :- Q No. 4 to 11 are short answer questions carrying 3 marks each.
1.
4.SECTION -C :- Q No. 12 to 14 are long question & case based question carrying 5 marks each.
Answer any TWO of them.
5. Use of log tables and calculators are not allowed.

SECTION - A

1. Define extensive and intensive property with example.

2. Internal energy is a state or path function? Explain.
3. In adiabatic process, heat is neither absorbed nor evolved by the system. Will there be any change
in temperature of the system?

SECTION – B

4. Define Isothermal, Isobaric and Isochoric process.

5. Define Heat capacity, Specific heat capacity and Molar heat capacity.
6. If water vapour is assumed to be a perfect gas, molar enthalpy changes for vaporisation of 1 mole
of water at 1 bar and 1000C is 41 kJ mol-1. Calculate the internal energy change, when:
(i) 1 mole of water is vaporised at 1 bar pressure and 1000C.
(ii) 1 mole of water is converted into ice.
7. Calculate the work done in reversible isothermal expansion when 2 L of an ideal gas at a pressure of
10 atm expands isothermally against 1 atm pressure to a final volume of 10 L.
8. Differentiate between Reversible and irreversible process.
9. Derive the relationship between Cp and Cv .
10. Calculate ∆𝐻 of the reaction:

Bond energy for C – H bond and C – Cl bond are 415 KJ and 326 KJ respectively.

11. Calculate the enthalpy of formation of C2H5OH (l) using following heat of combustion data:
(i) 𝐶2 𝐻5 𝑂𝐻(𝑙) + 3𝑂2 → 2𝐶𝑂2 (𝑔) + 3𝐻2 𝑂 (𝑙): ∆𝐻 0 = −1380.7 𝑘𝐽 𝑚𝑜𝑙 −1
(ii) 𝐶(𝑠) + 𝑂2 (𝑔) → 𝐶𝑂2 (𝑔): ∆𝐻 0 = −394.5 𝑘𝐽 𝑚𝑜𝑙 −1
1
(iii) 𝐻2 (𝑔) + 𝑂2 (𝑔) → 𝐻2 𝑂 (𝑙): ∆𝐻 0 = − 286.6 𝑘𝐽 𝑚𝑜𝑙 −1
2
 SECTION – C
12. Define first law of thermodynamics. Write the mathematical formulation for first law of
thermodynamics.
13. Derive the expression for the work done in the isothermal and reversible expansion of an ideal gas.
14.
CASE-BASED QUESTIONS

Read the given passage and answer the questions that follow:
A thermodynamic system, delimited from the surroundings by real or hypothetical boundaries, can either
be (1) isolated, (2) adiabatic, (3) closed, or (4) open, depending on the type of exchange between the
system under consideration and the surroundings. A system is defined as isolated in the absence of any
exchange pf energy or matter with the surroundings, adiabatic if only work is exchanged, closed if only
energy is exchanged, and open if both energy and matter can be exchanged.
The state of thermodynamic system is defined by its internal energy , U, and enthalpy, S, as well as a
set of state variables, including temperature T, hydrostatic pressure p, volume V, and number of moles of
components n. the former two thermodynamic quantities are functions of the state variables. Among these,
temperature and pressure constitute intensive variables, which define properties independent of the size of
the system, whereas volume, internal energy and entropy constitute extensive variables, values of which
vary with size of the system. Intensive molar properties are obtained by dividing extensive properties by the
number of moles n. The molar volume Vm is defined, for instance, by Vm = V/n. It is important to point out
that the aforementioned state functions depend on the conditions, or in other words, the state of the
system, but not on the path, process or history that was followed to reach it.

(i) What do you understand by the terms system and surroundings?

(ii) Why do all living systems considered as open system?
(iii) What do you understand by the term thermodynamic equilibrium?
(iv) What type of systems does the following examples represents?
a) Hot tea placed in a cup.
b) Hot tea placed in a sealed metallic tea pot.
(v) Which one of the following is not an extensive state function?
Enthalpy change, Internal energy and pressure.

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