RYAN GROUP OF SCHOOLS

ACADEMIC YEAR 2022-23 YAN

EXAMINATION
CBSE, FIRST TERM
MARKS:70
STD: XIl
TIME 3 HRS.
SUB CHEMISTRY (SET-A)
General Instructions
each carrles one mark.
1. Section- A has Q.1 to Q.13, carries one mark.
2. Section-B has Q.14 to Q.21, each
caries one mark.
3. Section-C has Q.22 to Q.27, each
carries one mark.
4. Section- D has Q.28 to Q.30, each

SECTION-A
answer the
Q.1 Read the passage given below and
(1x5-5)
following questions dour. Primary
The lower aliphatic amines are gases with fishy
amines with three or more carbon atoms are liquid and still
amines are
higher ones are solid. Aniline and other aryl due to
usually colourless but get coloured on storage soluble
amines are
atmospheric oxidation. Lower aliphatic
in water because they can form hydrogen bonds with water
molecules. However, solubility decreases with increase in
molar mass of amines due to increase in size of
the
hydrophobic alkyl part. Higher amines are essentially
insoluble in water. Considering the electronegativity of
3.5
nitrogen of amine and oxygen of alcohol as 3.0 and
respectively, you can predict the pattem of solubility of
amines
and alcohols in water. Out of Butan--ol and Butan--amine,
which will be more soluble in water and why? Amines are
soluble in organic solvents like alcohol, ether and benzene.
You may remember that alcohols are more polar than
amines and form stronger intermolecular hydrogen bonds
than amines. Primary and secondary amines are engaged
in intermolecular association due to hydrogen bonding
between nitrogen of one and hydrogen of another molecule.

XIIChemt.(A)/1
than in secondary amines as there are two hydrogen atoms
available for hydrogen bond formation in it. Tertiary amines
do not have intermolecular association due to the absence
of hydrogen atom available for hydrogen bond formation.
Therefore, the order of boiling points of isomeric amines is
asfollows: Primary> Secondary> Tertiary.
in these questions a statement of assertion followved
by a statement of reason is given. Choose the correct
answer out of the following choices:
(a) Assetion and reason both are correct statements and
reason is correct explanation for assertion.
(6) Assertion and reason both are correct statements but
reason is not correct explanation for assertion.
(c) Assertion is correct statement but reason is wrong
statement.
Assertion is wrong statement but reason is correct
(d)
statement.
Assertion (A) : Amines are considered as
derivatives of ammonia.
Reason (R) Quaternary ammonium salts
are

used as surfactants.

liy Assertion : of amines decreasees

(A) Solubility
with increase in the molar mass of amines.
Reason (R) :The hydrophobic alkyl part
increases with increase in molar mass of amines.

i) Assertion (A): Primary amines with three or

more carbon atoms are liquids.
Reason (R) :The intermolecular association is
more in primary amines than in secondary amines.
(iv) Assertion (A): When the alkyl groupis small like
- CH, group, there is a steric hindrance to
hydrogen bonding.
Reason (R): In aniline or other aryl amines, the
- NH, group is attached directly to the benzene
ring.
XI/Chemt. (A)/Z-
 amines
(V) Assertion (A): Boiling point of isomeric
follows the order:
Primary> Secondary>Tertiary.
Reason (R): Out of CH,OH and CH, NH, the
latter is more soluble in water.
mixtures will show a a positive
Q2 Which of the following
(1)
deviation from
B) chloroform and acetone
A) ethanol and water
C) nitric acid and water D) phenol and aniline
Value of Henry's constant (1)
Q3 in temperature
A) increases with increase
decreases with increase in temperature
B)
C) remains constant

D) first increases then decreases

and NaCl are
Q4 The value of van't hoff factor for KCI
respectively (1)
2 and 1
B)
A) 2 and 2
C 1and 2 D) none of the above
blood and tissues of
Q.5 A Low concentration of oxygen in the
people living at high altitude is due to (1)
HO, the
Q6 On oxidation with a mild oxidising agent like Br,
glucose is oxidized to. (1)
(asaccharic acid (6) glucaric acid
c) gluconic acid (d) valeric acid
Q7 Glycosidic linkage is a (1)
a) amide inkage (b) ester linkage
(c) ether inkage (d) acetyl linkage
Q8 How many C-atoms are there is a pyranose ring? (1)
(c) 6 (d) 7
Ja) 3 (b) 5
Q9Phenol is less acidic than (4)
(a) ethanol (b) o-nitrophenol
Ac) o-methylphenol (d) o-methoxyphenol
Q.10 Which reagent cannot be used to prepare an alkyl halide
from an alcohol? (1)
(b) NaCl
(a) HCI+ZnCl
(c) PCI, (d) sOcl
XIChemt.(A)/3
 OximeS HlEI
TQ
Q.11 (1)
with
a) NH,NH b) NH
cNHNHCH, d) NHOH (1)
Q.12 The formula of wood spirit is
(a) CH,COOH (b) CH,OH
(d) None of these
(c) CHOH
Q.13 Case Study Question: answer the
Read the passage given
below and
(1x6-5)
following questions:
halides and aryl halides, the halogen (X) atom
In both alkyl
to the carbon atom. They are expected
is attached directly halides are
However, aryl
to exhibit similar reactivity.
little reactive, particularly towards
Comparatively very
substitution reactions. For
example, hydrolysis
nucleophilic
boiling with aqueous KOH.
of ethyl chloride occurs by simply
alkaline hydrolysis of c h l o r o b e n z e n e
On the other hand, the a s well as
a very
temperature (623 K)
requires a very high
high pressure. choice questions.
are multiple
The following questions
answer:
Choose the most appropriate bond?
has weakest C X
-

the following, which

Among (b) Bromobenzene
(a) Benzyl bromide
(d) Benzyl chloride.
(c) Vinyl bromide
when
The halide which does not give any precipitate
(i) solution is
warmed with alcoholic AgNO,
(a) Chlorobenzene (b) Benzal chloride
(d) Tert-butyl chloride
(c)Allylchloride
(ii) Benzene reacts with Cl, in the presence of FeCl, (and
absence of sunlight) to form:
(a) Benzyl chloride (b) Benzyl chloride
(c) Chlorobenzene (d) Benzene hexa chloride
(iv) Friedel Craft's reaction of bromobenzene with methyl
iodide gives:
(a) (b) p- Bromo toluene
o-Bromotoluene
(c)0-and p-Bromotoluene (d) m- Bromotoluene
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 to
Chlorobenzene is o and p-directing due
() (b) -eftect
(a)+effect
+R effect (d) All of these
(c)
SECTION -B
a.14 Which of the carbon atom present in the molecule given
bolow are asymmetric and why? (2)

QH H
HO
OH

What is the IUPAC of A' ? (1)

Q.15 (1) name

HC-CH-CH=CH, + HBr A
CH
Gi) Aryl halides are less reactive toward nucleophilic
substitution reaction than alkyl halides. Give reason.(1)
OR
hurt Sam is aa
Ravi is a student of class VI fell down and got
the doctor and the
boy class Xll immediately took him to
doctor dressed the wound with the halogen compound.
the compounds?
)What is the name and formula of
(i) Write any one methodname
of preparation.
reactions: (1+1)
Q.16 Illustrate the following
) Cannizzaro's reaction
Clemmensen reduction
(1) when aniline
Q.17 Write the structure of main products
reacts with the following reagents
Br, Br, water
Ci) Conc. H,SO, (1+1)
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 Q.18 Account for the following
) pkb of aniline s mors tharn that d rttrfarri
is
() Ethylamine is sohutle in water wteroas afirs
OR
How will you convert:
Ethanamine into methanarmirs
(i) Chlorobenzene to pchloroanms
a.19 Explain the following terms: :(Ary Two) 2)
) Reducing sugars
(i) Non- essential anino scidss
(i) Peptide linkage
Q.20 What is meant by denaturation tf a rten? Gve r e
example. (2)
Q.21 What happens when D-glucose is trested vith he foloirg
reagents? Write equations. (11)
) HI
i) HCN

SECTION C
Q.22 Calculate the boiling poirt of a soltion prepared vy ading
15.00 gm of NaCI to 250.0gm ofwater. (K tr wates z 0512
K kg mot Molar mass of NaCl= 5844 g) (3)
Q.23 Explain the following: (3)
aThe treatment of alkyl chlorides with aques KOH
leads to the formation of alcohos but in presence of
alcoholic KOH, alkenes are the najo producds
b) Haloalkanes react with KCN to forn alkys cyanides as
main product with AgCN fons
isocyarides as 'he chief
product.
Neopentyl bromide undesgoes nudleophila vsteitsion
reaction very slowly.
OR
Primary alkyl halide CHBr (A) reacted witn alcchoc KOH
togive (B) compound (B). is reacted vith Her to
which is an isomer of (A).When (A) is give (C)
reacted with durr
X11Chemt. (A)/=
 (A). (B), (C) and (D)
Q.24 Write the mechanism of acid dehydration of ethanol to yield
ethene (3)
Q.25 Give the major productsthat are formed by heating each
of the following ether with HI. (1)

CH
CHCHCH-CHO-CHCH,
Explain Reimer-Tiemann reaction with an example. (1)
Arrange the following sets of compounds in order of
their increasing boiling points:
Pentan-1-ol, butan-1-ol, butan-2-o, ethanol, propan-1
ol, methanol. (1)
Q.26 (A) )Arange the following compounds in increasing
order of their property as indicated.
Ethanal, Propanal, Propanone, Butanone.
núcleophilic addition reactions) (1)
CH,CH,CH(Br)CoOH, CH,CH(Br)CH,coOH,
(CH.)CHCoOH, CH,CH,CH,C0OH (acid
strength) (1)
(B) How willyou convert ethanal into
Butane-1,3-diol? (1)
Q.27 Complete each
synthesis by giving missing starting
material, reagent or products. (1x3-3)
CHCH coOH
KMnO SOCL
KOH, heat COOH heat

() CH,CHHO H,NCONHNH,

XIVChemt. (A)/7
 SECTION-D
(3+2)
Q.28 (A) Account the following- wateer
more soluble in
) Alcohols are comparatively
molecular
than hydrocarbons of comparable
masses.
a mixture of ortho and para
i) While separating the
name
nitrophenols by steam distillation,
isomer which will be steam volatile.
by acid dehydration of
Preparation of ethers
tertiary alcohols is not a suitable
secondary or

method.
each to distinguish
(B) Give one chemical test
between the following pairs of
compounds-
1- propanol and 2- propanol
phenol and Ethanol
i)
OR
carried out?
(A) How are the following conversions
) Propene>Propan-2-ol.
alcohol.
(i) Benzyl chloride > Benzyl
(ii) Ethyl magnesium chloride > Propan-1-ol.
reactions:
(B) Name the reagents used in the following
acid.
) Oxidation of a primary alcohol to carboxylic
(i) Bromination of phenol to 2,4,6-tribromophenol.
formula CH,O
Q.29 An organic compound (A) with molecular
and
forms an orange-red precipitate with 2,4-DNP reagent
with iodine in the
gives yellow precipitate on heating
presence of sodium hydroxide.
It neither reduces Tollens' or
Fehlings' reagent, nor does it decolourise bromine water or
Baeyer'sreagent. On drastic oxidation with chromic acid, it
gives a carboxylic acid (B) having molecular formula C,H.O,
Identify the compounds (A) and (B) and explain the reactions
involved. (5)
OR

XIUChemt. (A)/8
 (1x5-5)
account for the following:
How would you ketones towards
more
reactive than
Aldehydes a r e
()
nucleophiles. than
acid has a higher pKa value
Monochloro ethanoic
(i) dichloro ethanoic acid.
benzoic acid.
acid is a weaker acid than
Ethanoic acid
(ii) of esters from a carboxylic
(iv) During the preparation of an acid catalyst,
the
and an alcohol in the presence
soon
formed should be removed a s
water or the ester

it is formed.
as
acids do not give reactions of carbonyl group.
(v) Carboxylic (2+3)
State Henry's law and write its one applications.
Q.30 (a) like smell, is used for
with rotten egg
(b) H,S, a toxic gas of H,S in water
analysis.
the qualitative If the solubility
Henry's law constant.
at STP is 0.195 m, calculate
OR
from high blood pressure is
(a) Why a person suffering
of common salt? (1)
advised to take minimum quantity
(b) What is reverse osmosis? (1)
law constant for CO, in water is 1.67 x 108 Pa
(c) Henry's
298 K. Calculate the quantity of CO, in 500 mL of
at
2.5 atm CO, pressure
soda water when packed under
at 298 K. (3)

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