SPM PECUTAN KIMIA BERFOKUS TOPIK TINGKATAN 5

SMK ROSLI DHOBY, SIBU

SPM COHORT 2021

A. Chapter 1 Redox Equilibrium ( Form 5)

1. Definition [ 1 mark / 1 markah ]

Question Students answer Notes
State the meaning of redox Reaction in which both oxidation and
reaction. reduction take place (0 m)

State the meaning of Process whereby chemical compound is

electrolysis. broken down when electric current
passes through it. (0 m)

State the meaning of A chemical compound which can

electrolyte. conducts electricity. (0 m)

State the meaning of Substances that conduct electricity in

conductor. solid state. (0 m)

State the meaning of anode. A positive terminal of the battery (0 m)

State the meaning of A negative terminal of the battery (0 m)

cathode.

New KSSM

State the meaning of

standard electrode potential.

.......................................... produced when an ................................ is

established between metal ....... and the aqueous solution containing
metal .................... in a ...................... .

1
New KSSM

1. Diagram shows the standard electrode potential values from two half-cell reactions.

Zn2+ + 2e- Zn E0 = -0.76 V

Cu2+ + 2e- Cu E0 = +0.34 V

From the value of standard electrode potential in Diagram above, explain why displacement
reaction between zinc and copper(II) sulphate solution can occur at standard condition based
on the strength of oxidising agent and reducing agent.
Calculate the E0 cell value for the electrochemical cell. [5 marks]

...............................................................................................................................................................
...............................................................................................................................................................
...............................................................................................................................................................
...............................................................................................................................................................
...............................................................................................................................................................
...............................................................................................................................................................

2. Diagram below shows the apparatus set-up for the electrolysis of copper(II) sulphate solution
using carbon electrodes.

(a) (i) List of ions moving to the anode and cathode.

Anode : .........................................................
Cathode : ...................................................... [2 marks]

(ii) Which ion is chosen to be discharged at the anode and at the cathode? Give reasons.
Anode : ..............................................................................................................................
.............................................................................................................................

Cathode: ............................................................................................................................
.............................................................................................................................
[4 marks]

2
3
3. State the colour change of copper(II) sulphate solution. Explain your answer.

...............................................................................................................................................................
...............................................................................................................................................................
...............................................................................................................................................................
[3 marks]
4. The mining of bauxite are once caused Kuantan bauxite disaster year 2015 to 2016. The rivers,
highways and air in Kuantan turn red when bauxite dust was released from the processing plants
and during transportation.

Aluminium recycling is preferred to aluminium mining.

Using reasonable views, justify your opinion.

...............................................................................................................................................................
...............................................................................................................................................................
...............................................................................................................................................................
...............................................................................................................................................................
[4 marks]

5. Compare and contrast cell I and cell II. Include your answers the observations and half
equations for the reactions of the both electrodes in both cells.

Cell I Cell II

4
6. The food in a dented can that shown in diagram below is not safe to be consumed. Explain
your answers.

Coated by
tin

[6 marks/ 6 markah]

Answer scheme Markah hilang bila

P1 – − tulis kakis/hakis
P2 – − salah satu
keadaan tidak
dinyatakan
P3 – - tulis more reactive
P4 – - tidak dinyatakan
P5- - tidak dinyatakan
P6- - loya/pening/muntah

5
Section C (Penilaian dan Rekacipta)

1
2

[10 marks]

6
2. Diagram 11.3 shows the list of materials and apparatus provided to study transfer of
electrons at a distance.
Dilute sulphuric acid Connecting wire with crocodile clips
\
Acidified potassium manganate(VII) solution Carbon rod

Iron(II) sulphate solution Copper plate

Potassium iodide solution Galvanometer

Retort stand with clamp U-tube

Stopper

Describe a laboratory experiment to show a solution of oxidising agent and a solution of

reducing agent produces electricity that involve the transfer of electrons at a distance.
Draw a labelled set-up of apparatus by choosing suitable materials and apparatus given in
the diagram.

Answer scheme Markah hilang

bila
P1 - Functional diagram -no dash line for
P2 – Labelled solution
- carbon electrode
dipped into
sulphuric acid
- only one/two are
labelled

P3 - Dilute sulphuric acid is poured/filled into a U-tube until half -concentrated

full. sulphuric acid
P4 – Acidified potassium manganate (VII) solution is added slowly -no word solution /
to right arm of the U-tube. slowly
P5 - Iron (II) sulphate solution is added slowly to left arm of the U- -no word solution /
tube. slowly
P6 – Carbon electrodes are dipped into both arms of U-tube and -no word dipped
connected to galvanometer. /connected
-use word put
/place
P7: The apparatus is left for 20 minutes and The changes are
recorded
Observations :
P8 : The needle of galvanometer deflected

7
 P9 : The colour of acidified potassium manganate(VII) solution
changes from purple to colourless.
P10 : The colour of iron(II) sulphate solution changes from green to
brown.

A more reactive halogen can displace a less reactive halogen from its salt solution.
Halogen yang lebih reaktif boleh menyesarkan halogen yang kurang reaktif daripada
larutan garamnya.

3. By using suitable example, describe an experiment to verify the above statement. In your
answer include:
• Procedure
• Observation
• Chemical equation
• Chemical test to verify the product formed [10 marks]

Answer scheme Markah hilang bila

P1 – Potassium iodide solution and Chlorine water -Salah satu tiada

P2 – measure and pour 2 cm3 of KI solution into the test tube -bukan dalam julat 2 –
5 cm3

P3 – add with 2 cm3 of chlorine water -bukan dalam julat 2 –

5 cm3
P4– shake the mixture and observe any colour change
P5 – observation Tiada warna
Colourless solution turns brown
P6 – correct formula of reactants and products
P7 – balanced
2KI + Cl2 ➔ 2KCl + I2
P8 – Add a few drops of starch solution //
Add few drops of 1,1,1-trichloroethane into the test tube.
P9 –Dark blue colour formed / blue precipitate formed //Purple -tiada warna
colour is formed at 1,1,1-trichloroethane layer.
P10 – Chlorine is more reactive than iodine Tiada kenyataan

8
4. A students intends to electroplate an iron key with a suitable metal to beautify it. Design a
laboratory experiment to electroplate iron key.
Your answer should consists of the following:
• Procedures of the experiment
• Diagram showing the set-up of apparatus
• Chemical equation involved in the reaction
• Observation
[10 marks]

9
Chapter 2: Carbon Compound

Bahagian A ( soalan struktur )

1. Diagram shows steps in preparing sample ester in the laboratory.

By referring to the structural formula of ester, identify compound R.

Hence, write one chemical equation for the esterification reaction betwen propanol and
compound R.
[3 marks / 3 markah]

Answer scheme Markah hilang bila

P1 – -salah ejaan

P2 & P3

2. Diagram shows the percentage composition of saturated and unsaturated fats in three
types of cooking oils.

Which cooking oil is most suitable for frying at high temperature? Explain.
[3 marks / 3 markah]

10
 Answer scheme Markah hilang bila
P1 –

P2 – -perkataan peratus
tidak ditulis
P3 –

New KSSM

1. Alkynes are unsaturated hydrocarbons with a triple bond between two carbon atoms. State the
general formula of alkynes. Draw all the isomers of the alkynes with n=4 and name the isomers.
[7 marks]

2. Diagram 11.2 shows the pie charts for the composition of saturated fat and
unsaturated fat in oil A and oil B.

Saturated fat contains single covalent bonds between carbon atoms. It can
increase the level of cholesterol in blood stream but resist the oxidation at high
temperature. Unsaturated fat contains double covalent bonds between carbon
atoms. It is easily oxidised at high temperature to form carcinogenic
substances.
Puan Aminah chooses oil B to stir fry the mixed vegetable and to deep fry the
chicken. Does Puan Aminah make the correct choice? Give the reason with
reference to the effect of fats on health. [4 marks]

11
Bahagian B (Esei) (From N.Sembilan 2021)

12
13
Bahagian C (Penilaian dan Reka Cipta)

1. By using compound W ( ethanol ) and compound Y ( ethanoic acid ) that obtained ,

describe how ester A can be prepared in the laboratory.
In your description include :
• List of materials and apparatus
• Procedure
• Observations
• Chemical equation
• Name of the ester A

[ 10 marks / 10 markah ]

Answer scheme Markah hilang bila

P1 – − salah eja
Method I: Ethanol,ethanoic acid, concentrated sulphuric acid, − kurang salah satu
round bottom flask, Liebig condenser bahan atau radas
− guna conical flask
Method II: ethanol,ethanoic acid,concentrated sulphuric acid, − Tiada Liebig
boiling tube/test tube, beaker condenser

Test tube: (2- 5) cm3 per time

Boiling tube: (2 – 10) cm3 per time
Round bottom flask: (20 – 100) cm3 per time

P2- Measure [V] cm3 (absolute/pure) ethanol into - tidak nyatakan

isipadu yang
sesuai bagi alat
radas mengikut
kaedah
- salah ejaan/radas
- nyata kepekatan
P3 – pour ethanol into a boiling tube / round bottom flask - bikar, kelalang kon
P4 – Measure [V] cm3 (glacial) ethanoic acid - Nyatakan
kepekatan asid
P5 – Pour / add (glacial) ethanoic acid to ethanol - Salah ejaan
P6 – Add concentrated sulphuric acid - Tiada pekat
P7 – Heat / reflux the mixture - Tiada panas
P7- sweet smell/ fruity smell is produced // two layers form when - Lain-lain
the mixture is poured into beaker of water
P8 – Ethyl ethanoate -salah ejaan
Ethylethanoate //
etiletanoat
P9- correct reactants and products -salah satu salah
P10 - balanced

C2H5OH + CH3COOH CH3COOC2H5 + H2O

14
 B. Chapter 4: Thermochemistry

Bahagian A (soalan struktur)

1. Diagram 5 shows two experiments to compare the heat of displacement of copper by zinc with the heat
of displacement of copper by magnesium.

Diagram 5 / Rajah 5

(a) Based on the experiment, what is meant by heat of displacement?

____________________________________________________________________________

_______________________________________________________________________ [1 m]

(b) Explain the use of polystyrene cup in both experiments?

____________________________________________________________________________

_______________________________________________________________________ [1 m]

(c) (i) State one observation when zinc powder is added to copper(II) sulphate solution.

___________________________________________________________________ [1 m]

(ii) State the reason for the observation in (c) (i).

___________________________________________________________________ [1 m]

15
(d) Based on the information from Experiment II,

(i) Write an ionic equation for the displacement reaction of copper by magnesium.

___________________________________________________________________ [1 m]

(ii) Calculate the amount of heat released in this reaction.

[Use specific heat capacity of water is 4.2 J g-1 oC-1]

`
[2 marks]

(iii) Calculate the heat of displacement for this reaction.

[2 marks]

(iv) Draw an energy level diagram for this reaction.

[2 marks]

16
 (f) What is the conclusion for both experiments?

____________________________________________________________________________

_______________________________________________________________________ [1 m]

(Clone SPM 1999)

Figure 2

2. Experiment I is carried out to determine the heat of neutralisation between hydrochloric acid and sodium
hydroxide solution. The experimental result shows the heat of neutralisation for the reaction is -57 kJ
mol-1. The figure 2 above shows the energy level diagram for the reaction occurs between hydrochloric
acid and sodium hydroxide.

(a) What is meant by heat of neutralisation?

_______________________________________________________________________________

__________________________________________________________________________ [1 m]

(b) State two information that are given by the energy level diagram in the figure 2 other than the heat
of neutralisation.

1. __________________________________________________________________________
__________________________________________________________________________

2. __________________________________________________________________________
______________________________________________________________________ [2 m]

(c) (i)What will happen to the change of heat if hydrochloric acid is replaced by sulphuric
acid for complete neutralisation?
__________________________________________________________________ [1 m]

(ii) Explain your answer in (c) (i).

_______________________________________________________________________

__________________________________________________________________ [1 m]

17
(d) Experiment II is carried out under same conditions by adding 50 cm3 of 1.0 mol dm-3 ethanoic
acid to 50 cm3 of 1.0 mol dm-3 sodium hydroxide solution. The temperature of the mixture
increases 6.5oC.

Calculate the heat of neutralisation for the reaction between ethanoic acid and sodium
hydroxide. [3 marks]

(e) (i) Compare the heat of neutralisation obtained in Experiment I and II.
_______________________________________________________________________
[1 mark]
(ii) Explain your answer in (e) (i).
_______________________________________________________________________
_______________________________________________________________________
_______________________________________________________________________
[2 marks]
(f) If experiment II is repeated by adding 100 cm3 of 1.0 mol dm-3 ethanoic acid with 100 cm3 of 1.0
mol dm-3 of sodium hydroxide solution,
(i) Predict the temperature change in this experiment.
_______________________________________________________________________
[1 mark]
(ii) Explain your prediction in (e) (i).
_______________________________________________________________________
_______________________________________________________________________
_______________________________________________________________________
[2 marks]

18
Bahagian Esei

1. By using either acid E or acid J, describe an experiment to determine the heat of

neutralisation. Include the steps of calculation in your answer.
[ 10 marks / 10 markah ]

BI Markah hilang bila

P1 – measure and pour / add (20 – 100) cm3 of (0.1- 2.0) moldm-3 -tiada kuantiti
acid E into the plastic cup /polystyrene cup ( isipadu atau
kemolaran
-tiada perbuatan
(measure/pour )
- tiada radas
( cawan plastik )
P2 – measure and pour / add (20-100 cm3 of (0.1-2.0) moldm-3 -sama spt di atas
NaOH solution into the plastic cup/polystyrene cup
P3 – Record the initial temperature for both solution -tulis catat
-tiada rekod
P4– Pour // Add acid E into NaOH solution solution quickly -tiada tuang / tambah
-tiada cepat
P5 – stir the mixture -tiada stir

P6 – record the highest temperature -tiada catat

-tiada rekod
-suhu akhir
P7 – Result -Jangan guna nilai /
Initial temperature E = T1oC value ( mengandai )
Initial temperature NaOH = T2oC -mesti ada unit
Highest Temperature = T3oC
Temperature change, θ
= T3 - [T1 + T2]/ 2]
=aoC

P8 – number of mol of E / NaOH

= 0.5 x 20/1000
= 0.01 mol
P9 – heat change = mc θ Jika tiada keputusan
= 40 x c x a J eskperimen, tiada
=bJ markah untuk
penghitungan
P10 – heat of neutralisation Tiada tanda ‘ – ‘
0.01mol of H2O release b J

40×𝑐×𝑎
H = - 0.01×1000 kJ mol-1

19
 2. Diagram below shows how stock solution of sodium hydroxide is prepared by a lab
assistant.

Explain why the lab assistant uses ice to aid her preparation of sodium hydroxide solution.
When 1 mol of solid sodium hydroxide is dissolved in wate, it produces 44.51 kJ of heat.
Calculate the temperature change if 0.5 mol of sodium sodium hydroxide is dissolved in
800 cm3 of distilled water.
[4 marks / 4 markah]

Answer scheme Markah hilang bila

P1 – -without very or a lot
P2 –
P3 –

P4 – Temperature change with unit

3. Diagram below shows a cold pack.

Substance P + Water

What is substance P? State the type of reaction in the cold pack.

Explain how the reaction takes place when cold pack.
[4 marks]

20
4. Jadual 8.2 menunjukkan nilai bahan api bagi beberapa bahan api.
Table 8.2 shows the fuel value of several fuels.

Bahan api Nilai bahan api (kJ mol-1)

Fuel Fuel value (kJ mol-1)
Petrol 34
Natural gas (methane) 50
Hydrogen gas 143
Jadual 8.2
Table 8.2

Berdasarkan Jadual 8.2, pilih satu bahan api yang sesuai untuk menggantikan petrol
dalam kenderaan. Wajarkan jawapan anda.
Based on Table 8.2, choose the most suitable fuel to replace petrol in vehicles. Justify
your answer.

…………………………………………………………………………………………………….

……………………………………………………………………………………………………..

……………………………………………………………………………………………………...
[3 markah / marks]

21
Chapter 9: POLYMER

MRSM 2021

22
23
24
CHAPTER 5 : CONSUMER AND INDUSTRIAL CHEMISTRY
Section C (Penilaian dan Rekacipta)
Negeri Sembilan 2021

25
26
27
New KSSM : Application of Green Technology in Industrial Waste Management

1.

Rajah 7.2
Diagram 7.2

Rajah 7.2 menunjukkan pencemaran air yang berlaku akibat pembuangan air sisa dari
kilang kelapa sawit. Dengan menggunakan pendekatan Teknologi Hijau, cadangkan satu
kaedah saintifik yang menggunakan prinsip elektrolisis untuk mengatasi masalah
tersebut. Terangkan jawapan anda.
Diagram 7.2 shows water pollution that occurs due to wastewater disposal from oil palm
mills. Using the Green Technology approach, suggest a scientific method by using
electrolysis principle to overcome the problem. Explain your answer.

…………………………………………………………………………………………………….

……………………………………………………………………………………………………..

……………………………………………………………………………………………………...
[3 markah / marks]

28