Total No.of Printed Pages : 16 Rall No [: a 605 E (Ex-Regular) CHEMISTRY SCIENCE (As per 2015 to 2017 Sy! 2018(A) CHEMISTRY SCIENCE Full Marks : 70 abi) Time : 3 hours The figures in the right-hand margin indicate marks. @BI-AIGEN JOR AGN) GIO. YAY ISO FEA | Answer all the bit questions of a particular question serially at one place to ensure effective evaluation aaiel gen Faiaaa Gaur ag casMad te qo Ze6i0 PAT AP JIA QOH FUGACA GIP BPEO G2 | Uses of Calculator is prohibited. IP AGN HELIO RAGS / TE-70/12 (Turn over )@7 @t mw 4 te) Wheto faewing conditions is correc foraspontaneous reaction ? pqase asinine Hg qIEIES ERs cose O87 §7SGis-ve (@ aGiswve (i) Gis zero (W) Noneofthe above goa GB eciads got (9) Which of the following reactions is a zero order reaction ? IBGeg CRIS Qey gn gE aa 880 g eer? 0) GAA, + 01, S 2He1 @ 280,+0, Sue: 250, (@ PO, PCI, +c) 2 (@) None ofthese E~ me (4) Contd {g)_ Which of the following isa natural polymer 2 (h), ane Ue 7 9 rug 6ede gIgae ef ()_-Protein eqaaia (i) Teflon core (ii) Nylon RiGee (iv) Terylene soaae Which of the following chemicals liberates bromine from a solution of KBr? od aIGIAReQ KBr geaen AAEM eaiig Ade coe ? 1, TE-7D/12 (5) (i) Hi i) (iv) MgCl, The by-product of soap industry is Aign daca eagle s2aaa! aaid caas 7 (i) Giycol (i) Glucose (Tum over)(0) Answerthe following questions: 1% Aqhde gaqsea one Ge ()) State Hess's Law (i) Whatis the order of action, ithe unit ofrate constantis sec? sesage fan sas | cea Galea eae sec pu, cose sa -gOeq) Gadi era Gane? | (il Wte the IUPAC name of the following ‘compound a0 Go sAiea IUPAC gin cael CH,-O- GH -CH,-CH, CH (®) Which halogen acid is the weakest of “halogen acids? HE gioniseR Bagge mug coeds gaioon aicaiseg a 368? () Name two antbiotios R68 TSswGeA Fin CaS ape Sen TE-70A2 (8) Contd GRouP -8 g-Sara of the following 3, Answerany ten questions. ofthe fo pel tbs "> aageo mie 6 SNC o4S (a) WhyH,Sisnotdried by a H,S0,? giaaqiene 20TIRe gale palais ge oa © cciad oo 090 8S assing over cone (b) IdentifyA, B, Cand D A.B, Cx@ DEE 3" NH,OH dil He! is NA] “Gy Heat (2) ONANOD , (c} +f0]+ 4,0 (i) dit HCI = eye ae (c) Howathyl acetate can be prepared fro iodide ? TE~70/12 (9) =890.3 © ge the following acids in order of their G : inoreasing aig strength witheagons cH,£00H,CiCH, COOH and Gi,CCOOH (@) Write the structural formulae and give a,the IUPAC names of all pos: represented by the molecular formula ible amines Uh siinGaa eacag REAR Vaso FIRE BE IS cca og agg 2 on 605 R/E/Ser-a i4, Answer any seven questions of the following 4x Spage emg ca ad aso gga aaa Oa fg} Wate three differences between crystaline sndamorphoussolds, acid & aadeicia cA meNEA Genie aigies cae | What are interhalogen » compounds ? Explain with example aigioKRcer cHaegse o's ? BoIRaeae aeia | What are addition 4 > Give one example of exc polymers ? Give one example of caimige © aaRe ognagde oa ? geeiaa soiGN cashd GoIeNe Ga | Write three differences between ‘and chemical adsorption dae © aaiase aycaisa tea cides cae | ‘What is lanthanoid contractio ‘and condensation a physical 4 Geers yn 2 Write 190) a of its consequences. : cinaiea arcaien 67 wale 226 eel ) Write at : toon Sqaens Go6e. SA Sa FP wncm 181 aman note on denaturation of protein. contd. 6016-A] 8) The boiling point of benzene is 353-2 K. When 1-8 g of a non-volatile solute was dissolved in 90 g benzene the boiling point was raised to 354-1 K. Calculate the molecular mass ofthe solute (K, of benzene = 2:53 K kg mol!) SOA GORE 3592 K a6 | casoceco 184) ageaq 19 90 conGaca ostae SRR GORARA Geol” 354-1 K @ 9 Gian! giea aaée oge gaie eqi (608998 K,= 2-59 K kg mol!) Discuss the mechanism of S42 reaction $2 J9SA1a SaIGY aicaioal oa | 3 What are ionization and linkage ‘omersm ? Gus one example ofeach Met TAG AAI z cabo cogea gai aeeren i) Benaoic acid on treatment with Br, an FRB, eves the compound (A mea featment with NH, gives the comseuny {21 The compound (8) on heating omg the compound (C). Write the structions compounds ( A), ( B ) and (C) in the ne of reactions. G68 GBR (2) aoe ag gee NORA Sen cavag (4 B® Sig) ee Ne, GSg0y (2) Fee | da ‘86a Gaal a (299 saa aac, \c) Pe gece doen (BG (0) 9 GARI cag | SOS R//Ser4, rT FAA! cag | PTO,> tos wit Group ~¢ a- éaa Answer any three questions ca eG Genie aga aaa Ga Write the method of preparation of phenol from chlorobenzene by Dow's process, dnuatbapenecdhen phenol reacts with ff conc. H,80, and (i) acetyl chloride in pieabse lh egiediis NAOH solution ? a+22 ole a0% e1ei caiccicenGag Gea agea GG cae! ea CP care OHA (1 OR 1,80, 6 (i) EMI NaOH goa @ndgen weg eMAING Ge aKGAi eC? forang: the fellowing compounds in the order their increasing acid strength: 1 See dieneea edpae ania agse oq 99 920 eI cr x Define specific conductivity and molar conductivity. What is the effect of dilution ‘on them ? Melhe SGq oGeGe! @ craig adelgoia gal «RS | GOAIRE GacA ageaaa gale o's 7 Seca 110) Contd. 6016-A| At 25°C, the molar conductivities at ) infinite dilution of NH,Cl, NaOH and NaC; are 149-7, 2481 and 126-5 ohm! cm? mol! respectively. Calculate the molar conductivity at infinite dilution of NH,OH. 3 25°C @ BAA QTEREGA NHACI, NaOH @ NaCl © GAIWIA QoeeI aaIgcR 149-7, 248-190 1265 ohm! cm? mot! a6e 2AM AIERAGA NH,OHA GAIGIA goog gale ea 7. Discuss the principles involved in the Preparation of ammonia by Haber’s process What happens when (i) ammonia is heated wi oxygen in presence of platinum gauge at 500°C and (ji) ammonia is passed through copper sulphate solution 2 a+2+2 gee —aeeER acer Fariemase tags oa @) acaiRag ageie ag ager Soorcadia aA eaiaie 6 «iy OREOE GoE Atica aces ealane 8 Define moleculatity and order of reaction. Derive anf expression for the rat of'a zero-order reaction BEae zeae) SRI ve amen gSEqq © constant 1+ tite cos Rye/seua ae[6016-A The half-life period of a first order reaction is 30 minutes. How much time is required for 75% completion of the reaction ? (log 2 = 0301) How can you prepare methyl amine by Hofmann bromamide reaction ? Write the action of methyl amine with (ip CHCl, and alcoholic KOH solution and (ii) methyl iodide ? QEAIR GQIAIAIAS, gega, Falag ziFie, ge ecalhe ? (i) CHCL, ¢ AIRCMIRR KOH JB gee @ (ii) MAIAq aiaceiag ag Aalag aimien ge ‘Arrange the following, amines increasing order of their basicity GEAID aFaqGen slaeigel aleQ eg AGIA GAS : C,H, — NH, CH, —NH), C,H; —Pull Marks : 70 Time : 3 hours The figures in the right-hand margi (339act( 20 ) (i) acetyl chloride and (ii) CHyCHyOH? 1+1-2 @) XAsieg sqIdINg <2" fi) GAIAM inceiag (CH;CH,OH}Q VasiAgziag Gag age see? (b) How a it react with (i) hydrazine, a (i Tol : and ames mdti+i=-3 ~ ie 421 304 @ aagIae, fi) SEARS Adee nN a SO, a2 gegai eca? = Ae 3 9. (@) What tare Satie _—— of amines. a 1+1=2 . NaiFiegse 9'a? alaggea Saiaieaa “\ Osiiai) 4 4 (6) How are they distinguished by HNO,? 3 HNO, @iai aifingég Gad gaeieaa ala? tk k 8-21 (339) 605/502 R/E