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    Chemistry, CH-1003, 2015 & 2016

    Uploaded by

    Science Spirit

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    © All Rights Reserved
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    (27) a AUTUMN END SEMESTER EXAMINATION-2 1° Semester B.Tech & B.Tech Dual Degree CHEMISTRY °* CH1003 / CH-1003 (For 2016 & 2015 Admitted Batches) Time: 3 Hours Full Marks: 60 Answer any SIX questions. Question paper consists of four sections-A, B, C, D. Section A is compulsory. Attempt minimum one question each from Sections B, C, D. The figures in the margin indicate full marks. Candidates are required to give their answers in their own words as far as practicable and all parts of a question should be answered at one place only. SECTION-A. i: Answer the following questions. [2x 10] (a) Explain the geometry of [Ni(CN),]* on the basis of valence bond theory. (b) What is an chromophore? Give an example. (©) Arrange the following speciesin increasing order of bond dissociation energy..O2, 2 and O,". (d) What is a retarder? Explain with an example. (e) Explain pitting corrosion. (f) 5 moles of an ideal gas expands from a volume of 4 litres to 16 litres. Find the change in entropy accompanying this expansion. (g) A 1“ order reaction is 50% complete in 25 min at 27"C and in 5 min at 37 °C. Calculate the activation energy. (h) What is fingerprint region in IR spectroscopy? KIT-DU 2019 SOT Aun End Semester Examinavion-2019— (1) (i) How the storage cell is different from fuel cell? (j) Calculate the change in free energy accompanying the compression of one mole of an ideal gas at 27°C from 25 to 250 atm pressure. SECTION-B (a) The magnetic moment of [MnCNo]* is nearly 2.8 B.M. [4] On the basis of VBT, predict the type of hybridization of central metal and geometry of the ion. (b) Calculate CFSE of the complexes [Ti(H20).** and {4] [Cu(NH3)6]**. N 3. (a) What is a glass electrode? Explain how it is used to find [4] the pH of an unknown solution. (b) Two silver rods are placed in silver nitrate solution of [4] concentrations0.2 M and 0.02 M and forms an electrochemical cell. Represent the cell and calculate the emf of it. SECTION-C 4. (a) The mechanism for thermal decomposition of ozone is [4] ky 0; == 02+ 0 ka k 0,+O—> 20, Assuming that k2[Os3] <

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