Sri ChaitanyaIIT Academy, India 01/10/22_Jr.

Super60_Jee-Main_WTM-14_Key & Sol’s

Sri Chaitanya IIT Academy.,India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI
A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
SEC: Jr.Super60 JEE-MAIN Date: 01-10-22
Time: 09:30AM to 12:30PM WTM-14 Max. Marks: 300

KEY SHEET
PHYSICS
1 4 2 3 3 2 4 1 5 4 6 2
7 3 8 2 9 3 10 2 11 3 12 3
13 2 14 2 15 1 16 1 17 3 18 2
19 3 20 3 21 6 22 4 23 7 24 6
25 2 26 1 27 7 28 5 29 6 30 9

CHEMISTRY
31 3 32 3 33 1 34 4 35 3 36 1
37 2 38 1 39 4 40 3 41 3 42 3
43 1 44 3 45 3 46 1 47 3 48 1
49 4 50 2 51 3 52 11 53 9 54 37
55 5 56 7 57 7 58 9 59 4 60 6

MATHEMATICS
61 2 62 4 63 3 64 2 65 2 66 2
67 2 68 1 69 1 70 2 71 4 72 1
73 3 74 1 75 2 76 3 77 3 78 2
79 3 80 1 81 5 82 2 83 1 84 14
85 4 86 4 87 0 88 2 89 3 90 6

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 Sri ChaitanyaIIT Academy, India 01/10/22_Jr.Super60_Jee-Main_WTM-14_Key & Sol’s
SOLUTIONS
PHYSICS
1. When the ball is hit by cue, the linear impulse imparted to the ball = change in
momentum  mv0

Angular momentum = Moment of momentum

I 0   mv0  h
2 2 5v h
mr 0  mv0 h or 0  02
5 2r
2. For conservation of angular momentum about any fix point on the surface

0 r
   0 / 2  v   v  r 
2
3. By conservation of angular momentum,
I11  t   I 22  t  at all times t.
 I11  I 2 2

Also, 1   2 
4

I 2 mr 2
 2
I1 mr 2
2
 3 
 2  1  1 
2 2 4

 1  rad
6
4. From law of conservation of angular momentum
I  I ' '
Given P  I / n
  '  n or  ' n

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 Sri ChaitanyaIIT Academy, India 01/10/22_Jr.Super60_Jee-Main_WTM-14_Key & Sol’s

5. Melting of ice produces water which will spread over larger distance away from the axis
of rotation. This increases the moment of inertia so angular velocity decreases
6. Since no external torque act on gymnast, so angular momentum  L  I  is conserved.
After pulling her arms & legs, the angular velocity increases but moment of inertia of
gymnast, decreases in such a way that angular momentum remains constant.
7. When two small spheres of mass m are attached gently, the external torque, about the
axis of rotation, is zero and therefore the angular momentum about the axis of rotation is
constant
I1
 I11  I 22  2  1
I2
1 1
Here I1  MR 2 and I 2  MR 2  2mR 2
2 2
1
MR 2
2 M
 2   1  1
1 M  4m
MR 2  2mR 2
2
8. The M.I. about the axis of rotation is not constant as the perpendicular distance of the
bead with the axis of rotation increases. Also since no external torque is acting
dL
 ext   L  cons tan t  I   cons tan t
dt
Since, I increases,  decreases
9.

L  l
20 1
 5   0.02
1000 2
  2.5 rad / s
10. Using angular momentum conservation
I11  I 22   I1  I 2  
I11  I 22

I1  I 2
11. Since torque about O is zero, angular momentum of mass m is conserved
v
 mv  mv    x  ; v 
 x
12. Cons. Of ang. Momentum about P gives
2
1  2 M  2 L 
MV  
2 12
V 2 L

2 3
3V
 , counterclockwise
4L

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1
1
13. V2  V1;V1  3 V2 ie. e13  3r23  r1  3 r2 3
3
1 I I
I11  I 22 ; I r 2 ; T  ; 1  2
 T1 T2
r22 r22
T2  T1  2  T1  2/3 2
r1 3  r2
1 1
 T1  2/3  T1
3 2
14. I1   I1  I 2  2
mr 2
2 16
2  2 2
 
mr 1mr 17

2 24 4
Since radius of second disc is half that of the first its area is one fourth and hence mass is
one-fourth
1
15. I1   2m  4m  r 2  4mr 2
 2 
 1 
I 2   m  4m  r 2  3mr 2
 2 
 I1  I 2
4
 
3
1 1
KE  I 2 2  I1 2
2 2
2
1 4 1
  3m  r 2      4mr 2 2
2 3  2
2
1  4  
    3  4  mr 2 2
2   3  

2
 mr 2 2
3
16. Initial angular momentum of system

L1  I10
 Mr 2 
  mg r 2  mr 2  0
 2 
M 
 L1    mg  m  r 20
2 
Final angular momentum of system
L f  I f   m  v  r  r

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[v is w.r.t the rotating turntable and v  v1  r where vb is the actual velocity.]
 vbullet  v  r
M 
  r 2  mg r 2    mvr  mr 2
 2 
 M 
 L f    mg  m  r 2  mvr
 2 
But Li  L f (therefore angular momentum is conserved)
M  M 
   mg  m  r 20    mg  m  r 2  mvr
 2  2 
M 
 mv    mg  m  r    0 
2 
mv
  0   M
 
  mg  m  r
 2 
2
 2m  2 R   2
17. I  2mR 2    2   mR 2
12  3
8
 L  I  mR 2
3
Angular momentum is conserved, as no torque is exerted on the system
18. Impulse on the sphere  J  mvcm
2
J .h  mR 2 .  m vcm .R
3
For angular momentum about point of contact
vcm
 (for rolling)  vcm  R  J  mr
R
2
m R.h  m R 2  m R 2
3
5
 h  R  10 cm
3
19. Change in momentum of ball = mv-(-mu) = m(v+u) = Impulse exerted on the ball. (We
assume that the impulse acting on the ball is horizontal)
 Change in angular momentum of ball = momentum of impulse
I u  v
i.e.  m  u  v  h  r 
r
1
r  h  r  
m
2
For a uniform sphere, I  mr 2
5
2 2 h 7
r h  r  r  
5 r 5
20. Angular momentum about B(the first point of contact on the incline)

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I i  I 0  mv0 R cos 
v0
Angular velocity, 0 
R
Angular momentum about B after impact  LF
v
 mv R  I  ;  
R
Where v = required velocity align the inclined plane. (The normal reaction at B is
passing through the centre of the cylinder and hence it does not give any torque) Since
angular momentum about B remains conserved, we have
I u  m.v0 R cos   I   mvR
 I 
 2  m cos   13v
R
v  v0   0
I 15
m
R2
21. By liner momentum conservation impulse (J) = mV
l
By angular momentum conservation, angular impulse  J  I 
2
1 m l ml 6
So, mv  I  or    2
  6 rad / s
2 2I  ml  l
2 
 12 
22. Since  net external = 0

L is conserved
Li  L f
 MR 2   MR 2  M  2  M 2 
  0  0  0     R   R   f
 2   2  2   2 

  f  0  4 rad / s
2
23. Angular momentum conservation
 d   Md 2   d 2  
2  M     2  M    
 2   12   2  
 
12

7d
1 
KEi  2  M  2 
 2 
1 1  7 Md 2  2
KEi  I  2   
2 2  12 
1
KE  M 2
7
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KEi
7
KE
24. From angular momentum conservation,
I11  I 22
 MR 2 2 MR 2
  mR 
 1  .2
 2  2
 100  100
  60  10  .2
 2  2
2 110 10
2   22 rpm
100
25. By conservation of angular momentum about pivot
L  I
2
d  Md 2 d  
mv   m  
2  12  2  
mvd  md 2 md 2 
  
2  2 4 
mvd 3
 md 2
2 4
2

3d
26. As the net torque about A during the collision is zero, the angular momentum of the
system about A is conserved.
2
 L    L  mL 
2
 m0     m    
 2    2  3 
6V
  0 anticlockwise
7L
27. By applying conservation of angular momentum

2  2 '
m0 R  mR 2 0  m ' R  mR 2
5 2R 5 R
6 7 '
m0 R  m R
5 5
6
 '  0
7
28. L final  0 (About a point on ground)
1
mR 20  m0 R must also be zero
Lint ial 
5
50
So, 0
2R
5 1
Or, 0   5 rad / sec
2   0.5 

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29. After collision let velocity of centre rod is  ' and angular velocity 
Applying conservation of angular momentum about point ‘P’ on ground (see figure) we
get


MuL Mu ' L  ML2 
   ....  i 
2 2  12 
From conservation of momentum we get
 L 
MV  MV ;
  m V '   ......  ii 
momentum of rod
 2
momentum of particle

On solving eqns. (i) and (ii) we get   6 rad / sec

ml 2 l
30. (i) Li  L f ;   MV 
12 2
ml
V
6M

(ii) Pi  Pf ;0  MV  mV1
mV1
V
M
V   V1  Velocity of separation
(iii) e  1  
l Velocity of approach
 0
2
l ml l l  m 
V  V1  ;   ;   1  3
2 6M 6 2 M 
m
2
M
m
M   9 kg
2

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CHEMISTRY
31.   Cl2 & H 2
32. CO2 , NH 3
33. Na2O2  HCl , HCl acts as catalyst
34. Both 1& 2 correct
35. Conceptual
36. Cl2 and H 2
37. NaCl is not conductor of electricity
38. Brick red
39. Barium is least first ionization potential
40. BeH 2 cov alent polymer
41. Mg burns air to form MgO andMg 3 N 2
42. Ba  CN 2 , CaCN 2
43. Thermal stability of carbonates increases down the group
44. Be  OH 2 and Al  OH 3 both are amphoteric
45. Be and Al becomes passive on reaction with HNO3
46. BeCl2 is covalent compound
47. Plaster of paris, dead burnt plaster, lime
48. Size of hydrated ions Be 2  Mg 2  Cq 2
49. Both Ca  H 2 PO2 2 and PH 3 formed
50. BaSO4 formed which is insoluble
51.
H 2O
NaOH  H 2O2
00 C  P Q 

Na2O2

H 2O
NaOH  O2   H 2O2
250 C  P

Bond order of  0  0  in H 2O2  1

Bond order of  0, 0  in O2  2
52. 2 NaHCO3  Na2CO3  CO2  H 2O
2 moles of NaHCO3  1 moles of CO2
2  84 g  22.4 lit at STP
84g 
11.2 lit of CO2 liberated
53.
exposed
Na2CO3 .10 H 2O Na2CO3 .H 2O  9 H 2O
to air

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54. Na2 SO4 .10 H 2O

37 atoms
55. 5
56. MgSO4 .7 H 2O
57. X  SP 2 ; Y  SP3
p  3, q  4, p  q  7
1 3
58. CaSO4 . 2 H 2O  CaSO4 . H 2O  H 2O
2 2
6 mill moles gives 9 mill moles of steam
59. Four
60. MgCl2 .6 H 2 O

MATHEMATICS
  
 cos2   
 2 ax 
  
 2    1 
 sin 1 .
Lt   2ax   cos 2   Lt cos 
2  

  e 
x 0   
 2  bx 
61. e  2bx  x0

   
   
 
 2cos    sin         a  
  2  ax   2  ax    2  ax  2  
 2cos    sin  2 bx     b  
   2

= e x0 
Lt  2 bx    2  bx  

 
 
 
 
     
  a  
 sin  
     2 ax   2  ax 2  
Lt
cos  
x0  2 ax        
2

 ba      ba xLt0  sin  2 bx   2 bx    b  
  e   2bx   e 
   
 
 
a  a2
b a b2
e  e
b
Lt   4
Lt 1  x2  5x  3  4x
62. e x
 1  e x
   e 
 e0  1
x  x 2  x  3 
  x  x  x  3  
2

2cos2 x
1 1 1 1
 1  
 2   2  cos 2 x  3  cos2 x  4  cos 2 x  5  cos 2 x
 
63. Lt 6 cos x     1

x   6   
6
 
6
 
 6 
2
   2cos2 x
1 1 1 1 2cos 2 x
 
 1  cos2 x  1  cos2 x  2  cos2 x  5  cos2 x 
36 Lt          1
x   3  2 3 6

2 

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1 1 1 1 2cos 2 x
 
 1  cos2 x  1  cos 2 x  2  cos 2 x  5  cos2 x
36 Lt 2cos x   2
       1  1
x
  3   2 3  6 
2  
0 0  0  0 0
36 e  36 1  36
 e1/ x  e 1/ x 
64. Lt g  x   1/ x 1/ x  exists
x 0
e  e 
 e1/ x  e 1/ x   e1/ x  e1/ x 
Lt  g  x   1/ x 1/ x   Lt  g  x   1/ x 1/ x 
x0
 e  e  x0 e  e 
e 1/ x e2/ x  1 e1/ x 1  e2/ x 
Lt g  x  Lt   Lt g  x  . Lt 
x  0 x 0 e1/ x  e 2/ x  1 x 0 x 0 e1/ x 1  e 2/ x 

 x 0
 
 Lt  g  x   1  Lt g  x   1
x 0

This is true if Lt g  x   0 which is true for  g  x   x 2 
x0
1 x
 a 1  x   sin  x  1  1
65. Lt   
  x  1  sin  x  1  4
x 1

1 x
 sin  x  1 
 a 
  x  1   1 a 
11 2
 1   1 a  1
Lt    
x 1  sin  x  1   2  2  a 2
 1
  x  1 

1   r  r  1   r  r  1 
2 2
r r r
66. tr      
r 4  r 2  1  r 2  1 2   r  2  r 2  r  1 r 2  r  1 2   r 2  r  1 r 2  r  1 
 
1 1 1 
tr   2  2
2  r  r  1 r  r  1 
n
  tr  t1  t2  t3          tn
r 1

1  1 1   1 1   1 1   1 1 
                 2  2 
2  1 3   3 7   7 13   n  n  1 n  n  1 
1 1 
 1 2
2  n  n  1 

n
1 1  1 1
 Lt  tr  Lt 1  2   1  0 
n 
r 1
n  2
 n  n  1 2 2
2010 2010 2010

67. Lt
 x  1   x  2         x  10 
x 
x 1006
 1 2 x1004  1
2010 2010 2010
  1   2  10  
x 2010  1    1         1   
Lt   x   x  x   10
 5
x   1  1  2
x1006 .x1004  1  1006   2  1004 
 x  x 

SEC: Jr.Super60 Page 11

 Sri ChaitanyaIIT Academy, India 01/10/22_Jr.Super60_Jee-Main_WTM-14_Key & Sol’s
n n
 a 1 n b   n b  1
68. Lt   n  1  a 
  Lt
n 
 a   
n 1 1
Lt  b1/ n  1  Lt b1/ n  1 a log eb log e b1/ a  a
e n
   e a n
e e  b
 a  1/ n
1/ n
 en  1  en 
69. Let A  Lt    log A  Lt log  
n  
  n  n
 
n log e  log 
 Lt
n  n
log e  0
 Lt  log e
n  1
 log A  log e
 Ae
1
 
e elog1 x  x 1  1
1/ x 1/ x  
1 x  e elog 1 x   e  1
70. Lt  Lt  Lt
x0 x x0 x x0 x
e  e  1
M
log 1  x   x
 Lt . Lt
x 0 m x0 x2
log 1  x 
Where M  1
x
e  eM  1 e
L  Lt 
M 0 M 2
71. Domain of sin x is  1,1 & that g  x  is R; domain of f  x  is  1,1
1

sin 1 x  discontinuous at x  0,1

But f  0   f  0   0  continuous at x  0
 Pts. of discontinuous are  sin1, sin1, &1
72. Lt g  x   Lt f  x   f  x   Lt   2 x  1  2 x  1  2
x  0 x 0 x 0

73. The fn.is continuous at x  0  f  0   LT

x0
f  x
e tan x  e x log  sec x  tan x   x
f  0   Lt  Lt
x 0 tan x  x x0 tan x  x
x tan x  x
e e  1 log  sec x  tan x   x
Lt   Lt
x0 tan x  x x 0 tan x  x
tan x  x
 e  1 sec x  1
  Lt e x   Lt  Lt
 x 0   x 0 tan x  x  x0 sec2 x  1
1 1
 11  Lt  1  3 / 2
1  sec x
x 0 2
2 2
74. f  x    2 x   2 x   2 x   2 x    2 x   2 x
 2 x  2 x  2 2 x 
 4 x 2  4 x 2 x

SEC: Jr.Super60 Page 12

 Sri ChaitanyaIIT Academy, India 01/10/22_Jr.Super60_Jee-Main_WTM-14_Key & Sol’s
We know 2x is discontinuous at integers
Here 2  x  2  4  2 x  4
Integer values of 2 x  3, 2, 1, 0,1, 2,3 that
f  x   4 x  x  2 x  is continuous at x  0
Therefore the number of function of discontinuity = 6
sin x  e x ; x0

75. f  x    a   x ; 0  x  1
 2x  b ; x 1


f  x  is continuous
 f  0   f  0    f  0   0  e 0  a    0 
 1  a   1   a  0 
f 11   f 1   f 1  a  1  2  b
 ab  3 b  3
 x
76. f  x   x   ; 10  x  10 is discontinuous whenever  x / 2  is an integer. So possible
2
points of discontinuity are 0, 2, 4, 6, 8
But at x  0 f  0   f  0   0
Hence number of discontinuities = 8
77. Since the function is continuous f  0   f  0   f  0 
1/3
sin  a  2  x  sin x x1/3 1  3 x   x1/3
 Lt  b  Lt
x 0 x x 0 x 4/3
 1  3 x 1/3  11/3 
  a  2   1  b  3  Lt 
 x0 1  3 x   1 
1 
 a  3  b  3 
3
 a  2 b  1  a  2b  0
1  1  3x 
78. Lt log  k
x0 x
 1  2x 
1 1 
 3     2 
1  3x  1 2x 
Lt k 5
x0 1
 x  x
log  1    log 1   2 2
79. Lt   a   b   k  Lt cos  sin x  1
x0 x x  0
x2  1  1
1 1 1  1 

x  a  x 
1 1  b 
a b 2sin 2 x
Lt   k  Lt
x 0 1 x 0 2x
2 x2 1

SEC: Jr.Super60 Page 13

 Sri ChaitanyaIIT Academy, India 01/10/22_Jr.Super60_Jee-Main_WTM-14_Key & Sol’s
1 1
  k  4
a b
1 1 4
  4  1
a b k
1 1 4
    5
a b k
80. Clearly for f  x   5  x  2 max.ocurs at x  2    2 and minimum for g  x   x  1
accurs at x  1
   1
 x  1  x 2  5 x  6 
Lt
x2 x2  6x  8
Lt
 x  1 x  2  x  3   2  1 2  3
x2  x  2  x  4   2  4
1

2
81. f  x    sin x  cos x  is discontinuous whenever sin x  cos x is an integer is at
  3 3 7 
x   , ,  , ,  So, = 5
2 4 2 4 
82. Given f  x  is continuous at x  0
sin 2 x  A sin x  3cos x
 f  0   Lt
x 0 x3
  2 x 1   2 x 3  2 x 5   x3 x5 x 7   x2 x4 
      A  x          B 1      
 11! 31! 51!   31! 51! 71!   21! 41! 
f  0   Lt  3
=
x 0 x
integer
 B  2  8  A  3
B   2  A x   x  x 
 210   310 610 
 Lt  int eger
x 0 x3
 B  0 & A  2  0  A  2
 A  B  2
 A B  2
83. If Both f  x  & g  x  are continuous at x  0 , then g  f  x   will be continuous at x  0 .
But if both f  x  & g  x  are discontinues at x  0 , then also g  f  x   may be continuous
at x  0
Now if f  x  is continuous at x  0, 0  a  0  1  a  1
2
Now if g  x  is continuous at x  0, 0  1   0  1  b  b  0
a  b  1
   x  1   tan 2 x  sin 2 x 
84. Lt  a sin    x Lt   
x0
 2   0  bx3 
sin 2 x 1  cos 2 x 
 a  Lt 0
x 0 bx3 cos 2 x

SEC: Jr.Super60 Page 14

 Sri ChaitanyaIIT Academy, India 01/10/22_Jr.Super60_Jee-Main_WTM-14_Key & Sol’s
2
1 sin 2 x   sin x  1
 a   Lt  Lt 2   . Lt 
b  x  0 x  x 0  x  x0 cos 2 x
1 1
 a   2  .2 1 .   ab  4
b 1
 10  ab  10  4  14
85. sgn  x  1 x  2   is discntinuous. When  x  1 x  2   0  x  1, 2
 x  3 is discontinuous whenever x  3  integer
0  x  4  x  1, 2, 3, 4
f 1   1   4   3 f 1  0   2   2 f 1   1   2   3

 f 1   f 1   f 1  disc

f  2   1  2  3
disc
f  2   1  1  0
f  31   1  1  0
 disc
f  3   1  0  1
f  4   1  0  1
disc
f  4   1  1  2
1/ x
 2x  4 x  8x 
86. Lt    3 2.4.8  3 64  4
x0
 3 
 x 2x2 x3   x 2 x3   x x2 
ax 1          b  x        cx 1     
87. Lt  11! 21! 31!   2 3   11! 21!  2
2
x0 x sin x
b  a b c
 a  b  c  x   a   c  x 2      x 3    
 2   21! 3 2 
Lt 3
2
x0 x
Lt cos 2 x  cos3 x 1
88. e x0 2
.  ek
x cos 3 x
Lt cos 2 x  cos 3 x 1
e x0 2
.  ek
x cos 3 x
9 4
e 2
1  ek   k  5 / 2    2.5  2
x 2

89. 
Lt 2  cos x cos 2 x
x 0
 x2

Lt  x  2 
 e x0  2   2  cos x cos 2 x  1
 x 
Lt  x2

 e x0 1  cos x cos 2 x .  2 
 x 

x2 x4
cos x  1    ......
21! 41!

SEC: Jr.Super60 Page 15

 Sri ChaitanyaIIT Academy, India 01/10/22_Jr.Super60_Jee-Main_WTM-14_Key & Sol’s
2 4
4 x 16 x
cos 2 x  1   
21! 41!
1/ 2
 x2 x4   4 x 2 16 x 4 
cos x cos 2 x  1       1     
 21! 41!  21! 41! 
 dr. degree is x 2

We have to extract till the coefficient of x 2 in nr

Lt 
x2  1/2  x2
x0 1

 210 

 1 2 x
2
 . 2
 x
e
Lt  x2 1 2  x2
x0
1   2 x  . 2
 2 2  x
e
Lt  2  x 2 
x0 1 3 x
  
 2   x 2 
e
3
Lt  2  e 3  e     3
2
e x0
cos  sin x   cos x
90. f  0   Lt
x 0 x4
 sin x  x   sin x  x 
2sin  sin
 2   2 
f  0   Lt
x 0 x4
 sin x  x   sin x  x 
2.  .
 2   2 
 Lt
x 0 x4
x 2  sin 2 x
 Lt
x 0 x4
2 x
sin x  x 
 Lt 2 as x  0 sin x  x
x 0 x3
 cos x  1 1
 Lt 
x 0 3x 2 6
k  6

SEC: Jr.Super60 Page 16