CLASSROOM CONTACT PROGRAMME

PU D U C H E R RY (Academic Session : 2021- 2022)

CHEMISTRY WORKSHOP

C TOPIC : REDOX REACTIONS AND EQUIVALENT C

H H
E CONCEPT E
M M
I I
S S
T T
r
y
Work Sheet - II r
y
1. How many peroxy links are there in CrO5?
2. How many moles of electrons are involved in the conversion of 1 mol Cr2 O72 into Cr 3 ion?

3. How many sulphur atoms in Na 2S4 O6 have zero oxidation state?

4. 6 10 3 mole K 2Cr2O7 reacts completely with 9 10 3 mole x n to give XO3 and Cr 3 . the value of
n is:
5. The sum of oxidation number of nitrogen in NH4NO3 is:
6. Which of the following groups of molecules act both as oxidising agent as well as reducing agent?
(a) KMnO4, O3, SO3 (b) HClO4, HNO2, H2O2
(c) HNO2, SO2, H2O2 (d) HNO3, SO2, H2SO4
7. Which of the following agents is the most oxidising?
(a) O3 (b) KMnO4
(c) H2O2 (d) K2Cr2O7
8. Oxidation state(s) of chlorine in CaOCl2 (bleaching powder) is/are:
(a) +1 and -1 (b) +1 only
(c) -1 only (d) None of these
9. Balance the following equations by ion electron method: & oxidation number method
(i) MnO4 Fe2 Mn 2 Fe3 H 2 O(acidic medium)

(ii) MnO4 SnO22 H 2O MnO2 SnO32 OH (alkaline medium)

(iii) Cu NO3 8H Cu(NO3 )2 NO H 2 O(acidic medium)

(iv) Cl2 IO3 OH IO 4 Cl H 2 O(alkaline medium)
(v) I 2 NaOH NaIO 3 NaI H 2 O(alkaline medium)
(vi) Zn NO 3 OH ZnO 22 NH 3 H 2 O(alkaline medium)
10. Arrange the following in the order of
(a) Increasing oxidation number of iodine:
I2, HI, HIO4, ICI
(b) Increasing oxidation number of chlorine:
Cl2O7, Cl2O, HCl, CIF3, Cl2
(c) Increasing oxidation number of nitrogen:
NH3, N3H, N2O, NO, N2O5
11. Find the oxidation number of:
(i) I in KIO3 (viii) S in S2Cl2 (xv) Fe in Na 2 [Fe(CN)5 NO]
(ii) P in NaH2PO4 (ix) P in Mg2P2O7 (xvi) Cr in (NH 4 ) 2 Cr2 O 7

(iii) P in P2O74 (x) Cr in K2Cr2O7 (xvii) V in Rb 4 Na[HV10 O 28 ]

4
(iv) Fe in Fe(CN)6 (xi) Mn in MnO4 (xviii) Xe in BaXeO 6

(v) Ni in [Ni(CN)6 ]4 (xii) Pt in [PtCl6 ]2 (xix) Cl in Ca(ClO 2 ) 2

(vi) S in H2S2O8 (xiii) P in PH4 (xx) Ni in Ni(CO)4

(vii)N in NO3 (xiv) C in C12H22O11

12. Which substance/ion is oxidised and which substance/ion is reduced in the following reactions?
(i) PbS 4H 2 O 2 PbSO 4 4H 2 O

(ii) H 2S 2FeCl3 2FeCl2 2HCl S

(iii) MnO 2 4HCl MnCl2 2H 2 O Cl 2

(iv) SnCl 2 2FeCl3 SnCl4 2FeCl2

(v) 2MnO4 16H 5C2 O42 2Mn 2 8H 2 O 10CO2

(vi) 3N 2 H4 2BrO3 3N 2 2Br 6H 2 O

(vii)Cl2 SO32 H2 O 2Cl SO42 2H

(viii) 2I Cl2 2Cl I2