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Pellet Plant
Merchant Mill
Long Products
Fines
Sinter Plant
New Bar Mill
Iron Ore
CUSTOMER
Hot
Wire Rod Mill
Metal
Flat Products
Furnaces
Coke Plant
Coal Steel Making
Converter
Cold Rolling Mill
3
3
Some Details of 6 MT Integrated Steel Plant
Main Raw Materials: Piping and Instrumentation diagram (P&ID):
A piping and instrumentation diagram is a
Iron ore detailed diagram in the process industry which
shows the piping and process equipment
Coke together with the instrumentation and control
Sinter devices
The technique was established very early in the history of the system safety discipline. It was formally
instituted and promulgated by the developers of MIL-STD-882.
PHL Methodology
PHL Methodology
PHL Methodology
PHL Worksheet
Hazard Checklist: Hazardous Energy Sources
Missile head
WCS – Weapon Control System
Ace Missile System Conceptual Information
PHL for Ace Missile
Preliminary Hazard Analysis (PHA)
INTRODUCTION
i. The preliminary hazard analysis (PHA) technique is a safety analysis tool for identifying
hazards, their associated causal factors, effects, level of risk, and mitigating design
measures when detailed design information is not available.
ii. The PHA provides a methodology for identifying and collating hazards in the system and
establishing the initial system safety requirements (SSRs) for design from preliminary
and limited design information.
iii. The intent of the PHA is to affect the design for safety as early as possible in the
development program. The PHA normally does not continue beyond the subsystem
hazard analysis (SSHA)
PHA Overview
INTENTION - The intention defines how the plant is expected to operate in the absence of
deviations at the study nodes.
DEVIATIONS - These are departures from the intention which are discovered by systematically
applying the guide words (e.g., "more pressure").
CAUSES - These are the reasons why deviations might occur. Once a deviation has been shown to
have a credible cause, it can be treated as a meaningful deviation. These causes can be equipment
failures, human errors, an unanticipated process state (e.g., change of composition), external
disruptions (e.g., loss of power), etc.
CONSEQUENCES - These are the results of the deviations should they occur (e.g., release of toxic
materials). Trivial consequences, relative to the study objective, are dropped.
HAZOP Process Parameters (Characteristic to particular process)
• Flow
• Volume
• Pressure
• Composition
• Temperature
• Viscosity
• Time
• Agitation
• Level
• Reaction
• Concentration • Component
• Phase
• Power
Guide Words and Meanings (Characteristic to particular parameter)
▪ Along the top of the matrix are process parameters such as flow, pressure, and
temperature
▪ Down the left-hand column are deviation guidewords such as High, Reverse,
and Wrong type of
▪ Some of the cells may be omitted if they are inappropriate to a particular node
▪ For example, the process keyword “flow” is not used when analyzing a vessel
Node number:
1 High
Too much
More
Too long
2 Low
Too little
Less
Too short
3 Backwards
Reverse
4 None / off
5 Wrong type of
Action missed
6 As well as
Other than
Part of
Wrong time
7 Miscellaneous
HAZOP FLOW DIAGRAM
DIVIDE SYSTEM INTO
STUDY NODES
SELECT A NODE
NOT SURE
NEED MORE
INFORMATION
HAZOP Procedure
1. Divide process flow into sections, i.e. reactor, storage.
6. Determine cause(s).
HAZOP Procedure
7. Evaluate consequences/problems.
PHOSPHORIC ACID
STUDY
B NODE 1
STUDY STUDY
AMMONIA NODE 2 NODE 3
C
DIAMMONOUM
PHOSPHATE (DAP)
Continuous Process Example for HAZOP
• In this process, the phosphoric acid and ammonia are mixed, and a
NP fertilizer, diammonium phosphate (DAP) results, if the reaction of
ammonia is complete.
Parameter :Flow
Guide word: NO
Deviation: NO & FLOW (no flow at study node 1)
Causes:
• Valve A falls closed
• Phosphoric acid supply exhausted
• Plug in pipe, pipe ruptures
Consequences: Excess ammonia in reactor and release to work area
(excess pressure – pressure relief valve rupture, ammonia with
down stream products leading to a death, sub-consciousness)
Suggested Action: Automatic closure of valve B on loss of flow
from phosphoric acid supply.
For Study Node 1
i. Repeat the same process for the other parameters, characteristic to the process such as
Temperature, Pressure, etc.
ii. Total deviations ,causes , gaps recommendations for the node -1 is done
Similarly…
• Each action and the person responsible for completing the action
is recorded on the record sheet.
R-1
Node: 301 Propane Storage System P&ID No. G/P&I/6654/2013
Design Intent Tanker to Storage
Deviation Cause Consequence Safeguard Recommendation Remark/Action
Lower Pressure Covered in Less flow
Higher Temperature External fire Fire and Explosion Hazard PRV-01 and PG-01,12,13,14 Provided
PSV provided.
Lower Temperature No Issue
Higher Level Transfer not stopped at Tank Pressurization LT-11/21/31 ,PT11,21,31 are provided in the
high level tank same will close respective ROV-11/21/31
(Storage Tank T-1,2,3)
Lower Level No Issue
Concentration NA
Impurity NA
Utility Failure Power No Transfer of Propane All ROV and SV will Close DG should be provided for
from Tanker to Storage backup power for the
Tank. operation of Propane
storage system
Compressor C-01, C-02 &
C-03 will stop. R-2
Start-up
Proper SOP is to be made for attending
Start Up & Shutdown of Propane system
Shut-down
Proper Isolation,
N2-purging &
Maintenance
Permit System
Fall In temperature
EFV-16/26/36 provided
Excess flow Pipe line
Leakage
More Flow
More consumption from
EFV-16/26/36 provided
Customer side
Covered in higher
Higher Pressure
Temperature below
Covered in Low
Lower Pressure
flow
Node: 302 Propane Storage System P&ID No. G/P&I/6654/2013 R1
Design Intent To Supply Propane to Consumer
Remark/Acti
Deviation Cause Consequence Safeguard Recommendation
on
Higher Level
WLI-41/51/61
Water in vaporizer SV-42/52/62 stuck open No Issue
indicates
V-1/2/3
Lower
NA
Concentration
Impurity NA
Design
To Supply Propane to Consumer
Intent
Deviation Cause Consequence Safeguard Recommendation Remark/Action
Maintenance To be considered later i. Proper Isolation,
iv. S OP
(Air)
Higher Level NA
Lower Level NA
Impurity/ Contaminant Dust Improper mixture Filter Provided-TIF-1 Bypass line to be Provided for the Filter
(R-4)
Other
NA
material
Calorimeter will not Battery backup may be provided for
Utility Failure Power failure (Covered Above) No
work Dilution system (R-7).
Sampling NA
Proper Isolation, N2-purging &
Maintenance To be considered later Permit System Should be
included , S OP
During any leakage in the field, in the
Propane Dilution area for taking
Fire/Explosion immediate action , One/ or two CCTV
Leak detector and
Propane Pipe line failure/ Flange or Gasket camera may be provided in the field, so
Loss of Firefighting System
Fall in temperature Proper SOP to be made to attend
containment/ Failure that any leakage in the system is
Provided
in Pipeline immediately noticed by the Control leakage/ Emergency Handling
Leakage Methyl Mercaptan pipe line failure.
Gas masks and Analyzer Room official and proper action can be
Toxic release
taken without delay.
(R-8)
Methyl Mercaptan atmospheric
HSE/
Gas masks and Portable concentration meter may be provided
ergonomic Methyl Mercaptan Toxic release
Analyzer near working area for continuous
issues
monitoring..(R-9)
Regulatory
None
issues
Proper SOP is to be made for
Start-up To be considered later attending Start Up & Shutdown
of Propane system
When I was working with hazardous integrated Iron & steel plant, very often used to hear about HAZOP studies,
to study the hazards and reduce the risks of a process. People used to feel a sigh of relief in this process. We used to
work with ineffective techniques for hazard analysis and risk reduction in other important areas like construction,
maintenance etc. The result is so many incidents resulting into injuries, property loss and more importantly delays
in the goals.
Having understood this HAZOP methodology, always used to ask ‘why not we use HAZOP methodology to these
disciplines’. Nobody used to support or appreciate, this idea ,brushing away with the comments like not possible,
very expensive, no skills , no body tried etc. It gave me great consolation ,when Dave Macdonald supported this
idea in his book titled ‘Practical Hazop’s ,Trips and Alarms’.
Now IIT could develop ‘Hazop for all Disciplines’ and help the industries.
Learning : Do not leave any idea to solve important problems even discouraged by the experts or practitioners as
they have fixed minds, till achieve the goal
65
Hazops, we have seen are operated on a very simple set of principles:
If we look at the operations of the industries, from construction to decommissioning, some elements or activities
contribute, most for the incidents and these elements are called Incident Critical Elements (ICE’s). Maintenance is
one of the important activities to retain the integrity of the equipment or process. Some of the ICE’s for the
maintenance activities are mentioned below.
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Table 1 Comparison between Hazop and Maintenance operability study (MOP)
Used to manage hazards of processes Used to manage the hazards during maintenance activities
Deviation Less flow, no flow, over flow Deviation Implemented in electrical, Not implemented in gas lines
70
Maintenance Operability Study Guide Words
1. To find out the adequacy requirement and availability of each of ICE , the following guide words may be
used for most of the parameters by the Mop team.
(a) Is the requirement fully complied?
(b) Is the requirement partially complied?
(c) Is the requirement not complied?
For a ICE like Quality of the spare part, guide word could be Standard specification followed, standard supplier
etc may be used
1. From this , one can understand what is available, causes for inadequacy.
2. Estimate their consequences.
3. Then, necessary interventions could be designed and implemented so that maintenance
activities are carried out safely.
71
Case study-1 on Maintenance Operability Study (Mop)
In the steel plant operations, the slabs are cast to a weight of 28 tons (based on the downstream coil sizes and
the yield requirements).Each cast from the slab caster will have a run of around 25000 tons. It means, this
25000 tons slab continuously coming out of slab caster has to cut into approximately 893 slabs at hot
condition. Propane continuous gas cutting machine is used for this purpose. The propane is a hazardous gas
and comes from the propane underground tanks. These in turn filled by the road tankers. The P&ID of the
propane gas plant is attached. The storage bullet has worked for five years and hence requires preventive
maintenance activity to be done.
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Figure 1 P&ID of propane storage and distribution 73
Maintenance activities can be divided as follows
1. Cleaning the tank, manually.
2. Inspection of all joints by die penetration test ,inside and outside of the joints.
74
Activity (Node) Detail of Activity System Page number
75
Parameters or Incident Critical
Maintenance Operability Study (Mop) of Propane Tank Elements(ICE’s)
1. Energy isolation
Maintenance activities can be divided as follows 2. Material handling(Cranes failure, Rigging
defects)
1. Cleaning the tank, manually. 3. Explosion
4. Work at height
2. Inspection of joints by die penetration test, inside and outside of the joints. 5. Welding
6. Gas cutting
3. Change the two valves. 7. Confined space requirements
8. Slip, trip, fall
4. Paint the external surface of the tank 9. Access
10. PPE’s
11. Handling Facilities
List of Nodes/ Activities used in the Mop of Propane tank 12. Procedures
13. Ergonomics
14. Communication
15. Skills and Training
Activity Detail of Activity System Page 16. Moving Equipment
(Node) number 17. Lifting tools
18. Hand tools
101 Cleaning the tank, manually. Propane gas storage
19. Permit to work(PTW)
102 Inspection of joints by die penetration Propane gas storage 20. Mechanical Integrity
test, inside and outside of the joints. 21. Supervision
103 Change the two valves. Propane gas
Guide words applied
unloading and filling i. Partially done/ Not done
104 Paint the external surface of the tank. Propane gas storage ii. Partially suitable/ Not suitable
iii. Partially adequate/ Not adequate
Ventilation assurance Not felt the Air circulation systems Arrangement of air
Asphyxiation in the tank Available -----
Partial or no implementation requirement. arrangement. compressor lines
Poor consequence
Rescue mechanism and
Rescue mechanism Partial management. Fatal
Non availability Not planning earlier trained people, within Available -----
or no implementation implication, in case of
the team
emergency.
Non provision of ladders for No provision into the Trip and fall. Could be Availability of proper
Work at height going up and into the tank. design.
No planning earlier
any consequence. ladders
Wooden ladders available Suggest to use metallic ladders.
77
Parameter/ ICE Deviation Cause Root Cause Consequence Safeguard Available Recommendation
Mobile cranes, chain blocks, Not suitable/ fit mobile Fall of people, materials Assurance of fit and Tested and fit mobile Make a process that tested
System not existing to check
Handling facilities trolleys for material transfer. cranes, chain blocks and
these parameters.
resulting in serious an suitable cranes, chain equipment and chain and fit mobile equipment
Partial or not suitable trolleys. Incident. blocks trolleys etc. blocks not available only available for work.
Live maintenance critical System of developing and Standard Operating Only few general
Maintenance critical and non- May result into catastrophe Develop MCP’s and train
procedures for important maintaining maintenance procedures (SOP’s) should procedures available. No
Procedures critical procedures. Partial or
maintenance activities critical procedures (MCP) not
while execution and after
be developed and maintenance procedures
people and make these
not suitable execution. procedures available.
not available. existing. available. available.
78
Parameter/ ICE Deviation Cause Root Cause Consequence Safeguard Available Recommendation
Lack of systems to
Systems, equipment Good systems in
ensure access to fire Systems should be Fire systems and fire
and use of fire May result into place for fire Ensure access to
tenders, fire hydrant available to keep fighting standards
Fire fighting fighting equipment. property and human fighting, but access emergency equipment’s
systems fitness and dynamic fire fighting and implementation
Partially adequate or loss to fire tenders not like fire tenders.
fire fighting and fire hydrants. at the site.
not adequate clear.
knowledge
Good PTW
People allowed to
Loose procedures People may get into procedures and
work place without
and lenient hazards and training to the
Permit to making work area No PTW procedures PTW given without Implement with zero
implementation. consequence may be concerned should be
work(PTW) safe to work. followed physical verification. tolerance.
Work force do not fatal to them and to there with audit,
Partially adequate or
see value in PTW the machines. observation and
not adequate
consequence.
Supervisors should
Supervisors given
have competencies
There is no method The whole group competency
on work and Supervisors do not Competent
Supervision of evaluation of the will be at risk due to certificate after -----
standards. Partially have competencies. supervisors available
supervisors. weak supervision. training and
adequate or not
verification
adequate
79
References
• Ericson, C. A. (2015). Hazard analysis techniques for system safety. John Wiley & Sons.
• Henley, E. J., & Kumamoto, H. (1996). Probabilistic risk assessment and management for
engineers and scientists. IEEE Press (2nd Edition).
• J. Maiti, Industrial Safety Engineering. Web-based course on National program on Technology
Enhanced Learning, IIT Kharagpur,2018. Available at
https://nptel.ac.in/courses/110/105/110105094/.
Note: Some images used in this presentation are taken from various sources (published literatures, books, etc.) for educational and learning purposes only. The
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