K.D.

AMBANI RELIANCE FOUNDATION SCHOOL

Revision Worksheet, Session 2022- 23
Class- 11, Subject: Chemistry (043)
Topic: STRUCTURE OF ATOM

Name of the Student: ___________________ Roll No.: _________

Class: _____ Section: ______ Date: ____________

1. With respect to atomic spectrum, each line in the Lyman Series is due to electrons returning
(a) From a particular higher energy level to n = 3
(b) From a particular higher energy level to n = 2
(c) From a particular higher energy level to n = 1
(d) From a particular higher energy level to n = 4
2. Orbital angular momentum depends on
(a) l (b) n and l
(c) n and m (d) m and s
3. The number of unpaired electrons in Ni (atomic number = 28) are
(a) 1 (b) 2
(c) 3 (d) 4
4. The questions given below consist of an Assertion and the Reason. Use the following key to choose the
appropriate answer.
a) If both assertion and reason are CORRECT and reason is the CORRECT Explanation of the assertion.
(b) If both assertion and reason are CORRECT, but reason is NOT THE CORRECT explanation of the
Assertion.
(c) If assertion is CORRECT but reason is INCORRECT.
(d) If assertion is INCORRECT but reason is CORRECT.
Assertion (A) : Black body is an ideal body that emits and absorbs radiations of all frequencies.
Reason (R) : The frequency of radiation emitted by a body goes from a lower frequency to higher
frequency with an increase in temperature.
5. Define Pauli’s exclusion principle.
6. How many electrons are possible in all shells with n+1 = 7?
7. Out of electron and proton which one will have, a higher velocity to produce matter waves of the same
wavelength? Explain it.
8 Calculate the energy and frequency of the radiation emitted when an electron jumps from n = 3 to n =
2 in a hydrogen atom.
9. What are quantum numbers? What permitted values can these have? Give the significance of each
quantum number.

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10. Draw the shapes of all the five d-orbitals.
11. Give the difference between orbit and Orbital.
12 Calculate and compare the energies of two radiations one with a wavelength of 800 nm and other with
wavelength of 400 nm.
13 What is the wavelength of light emitted when the electron in hydrogen atom undergoes transition
from an energy level with n = 4 to an energy level with n = 2 ? What is the colour of the radiation?
14. Briefly explain the postulates of Bohr’ model and give its drawbacks.
15. What is the maximum number of electrons that may be present in all the atomic orbitals with principal
quantum number 3 and azimuthal quantum number 2 ?
16. What is photoelectric effect? State the result of photoelectric effect experiment that could not be
explained based on laws of classical physics. Explain this effect on the basis of quantum theory of
electromagnetic radiations.
17. Write the electronic configuration of elements of atomic numbers 10, 17, 25, 29 and 37
18. How many unpaired electrons are present in the ground state of (i) P (Z = 15) (ii) Fe 2+ (Z = 26) (iii) Cl – (Z
= 17) ?
19. What is the maximum number of electrons that may be present in all the atomic orbitals with principal
quantum number 3 and azimuthal quantum number 2 ?
20. Hydrogen atom has only one electron, so mutual repulsion between electrons is absent. However, in
multielectron atoms mutual repulsion between the electrons is significant. How does this affect the
energy of an electron in the orbitals of the same principal quantum number in multielectron atoms?
21. Read the passage given below and answer the following questions:
Orbitals are regions or spaces where there is a maximum probability of finding electrons. Qualitatively,
these orbitals can be distinguished by their size, shape, and orientation. An orbital of small size means
there is more chance of finding the electron near the nucleus. Shape and orientation mean the
direction in which the probability of finding the electron is maximum. Atomic orbitals can be
distinguished by quantum numbers. Each orbital is designated by three quantum numbers n, l, and ml
(magnetic quantum number) which define energy, shape, and orientation but these are not sufficient
to explain spectra of multi-electrons atoms. Spin quantum number (ms ) determines the spin of
electrons. Spin angular momentum of the electron has two orientations relative to the chosen axis
which are distinguished by spin quantum numbers ms which can take values +1/2 and –1/2.
(i) How many orbitals are associated with n = 3?
(ii) Describe the orbitals represented by (i) n = 2, l = 1 (ii) n = 4, l = 0.
(iii) How many electrons are possible in an orbital? Why?
(iv) What are the shapes of ‘s’ and ‘p’ orbitals?
(v) Name two d-orbitals that are present on-axis.

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