PARAS VIDYA VIHAR

SESSION – 2021-22

CLASS- 11th

CHEMISTRY

ONLINE EVALUATION-3

Time- 40 min. M.M. 40 marks

Directions-

1.Section-A contain 10 questions 1 marks each.

2. Section- B contains 5 questions 2 marks each

3. Section- C contains 4 questions 5 marks each.

SECTION – A

1. The value of which enthalpy is always negative :

a. Enthalpy of formation
b. Enthalpy of solution
c. Enthalpy of combustion
d. Enthalpy of fusion
2. According to the first law of thermodynamics –
a. ∆E = q+W
b. ∆E= q- W
c. ∆E= q+ PV
d. W= ∆E – q
3. In adiabatic expansion of an ideal gas is always:
a. Temperature increases
b. ∆H=0
c. q= 0
d. W= 0
4. Enthalpy of atomization of CH4 is 1664 KJ mol-¹ , then bond energy of C-H will be-
a. 416 KJ mol-¹
b. 832 kJ mol-¹
c. 1248 kJ mol-¹
d. 1664 kJ mol-¹
5. A chemical reaction is in equilibrium when:
a. The reactants are completely converted to the products
b. The rate of forward reaction is equal to rate of backward reaction
c. Formation of products is minimum
d. Reactants and products are equal in quantity.
6. At equilibrium, free energy change for reversible reaction will be:
a. 0
 b. >0
c. Infinity
d. 1
7. Whose pH value is maximum-
a. CH3COOK
b. Na2CO3
c. NH4Cl
d. NaNO3
8. Ethene is –
a. 5 Sigma and one pie bond
b. 6 Sigma bond
c. 4 sigma and 2 pie bond
d. 5 sigma bond
9. The hybridization orbital of carbon in benzene is –
a. sp³
b. sp²
c. sp
d. dsp³
10. Which of the following alkane is not obtained by Wurtz reaction-
a. CH4
b. C2H6
c. C3H8
d. C4H10

SECTION- B

11. What is exothermic reaction? Explain with example.

12. What is meant by Entropy? Explain the change in entropy with an example.
13. Ammonia is a Lewis base. Why?
14. What do you mean by ionization of water?
15. Draw Newman’s projection figures of staggered and eclipsed confirmations of butane.
SECTION- C
16. Explain following reaction with example-
a. Peroxide effect
b. Duma process
c. Markownikoff's rule
d. Formation of BHC
e. Kolbe reaction
17. a. Realtion between kp and kc.
b. Explain Ostwald dilution law and prove it.

18.a. Prove that cp- cv = R

b. What is the first law of thermodynamics and write its mathematical form.

19. a. Difference between reversible and irreversible reaction.

b. Explain Gibbs free energy with its equation.