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Chapter 1
Chapter 1
THERMODYNAMIC
HEAT ENGINE and REFRIGERATOR
Lout
Example
Refrigerator
Lin
Example
CHAPTER 1
MAIN CONCEPTS
1.1 Working fluid and thermodynamic system
1.2.1. Temperature
- Definition: Parameter represents for hot or cold
status of things. If two bodies are in thermal
equilibrium if both have the same temperature
reading even if they are not in contact.
- Temperature units:
- Celsius scale (toC): ice and steam points were assigned the
values 0 and 100oC
- Kelvin scale (T [K]) : t = T + 273
- Temperature measurement: fluid thermometer
(water, mercury, ethanol) based on the expansion of
fluid; electrical resistant sensor, thermocouple
temperature sensor, transmission temperature sensor.
1.2. State parameters
V
v = ; m 3 kg
G
G 1
= = ; kg m 3
V v
1.2. State parameters
1.2.3. Pressure
- It is defined as a normal force exerted by a fluid per unit area.
- Unit: N/m2 (Pa)
1 bar = 105 Pa = 750 mmHg = 1.03 at
1 kPa = 1000 Pa,
1 Mpa = 106 Pa
1 at = 0.98 bar = 735.5 mm Hg
- Absolute pressure: is actual pressure at a given position
1.2. State parameters
1.2.6. Ehthalpy
- Definition by formula:
I = U + pV và i = u + pv
- For open system: I = U + D và i = u + d
- For ideal gas:
Because p.v = RT and u = f(T)
i = f(T)
di = CpdT; Di = i2 – i1 = Cp(T2 – T1)
Cp: Heat capacity at the constant pressure
Consider only enthalpy change
1.2. Status parameters
1.2.7. Entropy
- S( J/K) or s (J/kgK)
- Definition: it is the quotient of an infinitesimal
amount of heat to the instantaneous temperature.
dq
ds =
T
1.2. Status parameters
1.2.8 Exergy
- E (J) or e (J/kg)
- Difinition: exergy is the work potential of the source
– that is a mount of energy we can extract as useful
work.
q=e+a
a: anecgy is waste energy and is not worthy of
consideration
1.3 Thermodynamic process
q = Tds
s1
T = const q = T (s2 − s1 )
2. Difinition and classification of heat capacity
1.4.2. Work
- Definition: In thermodynamics, work performed by a
system is energy transferred by the system to its
surroundings, by a mechanism through which the
system can spontaneously exert macroscopic forces
on its surroundings.
- Unit of work: 1 J = 1 N.m
- Unit of power: 1 W = 1 J/s
- For 1 kg working fluid: J/kg, W/kg
- Work is positive if work done by system, negative if
work on by system
1.4.2. Work
3. Effective work
Ln (J) or ln (J/kg)
- Is total work done by system
- Systems do work by: volumetric expansion, kinetic
energy reduction, potential energy reduction, flow
energy reduction
12 − 22
ln = l 12 + ( d1 − d 2 ) +
12
2
22 − 12
ln12 = l 12 − ( d 2 − d1 ) −
2
2
ln12 = l12 − D (d ) − D ( )
2
2
dln = dl − d ( pv ) − d
2
Close system: ln12 =l 12 dln = dl = pdv
Open system:
2 2
dln = dl − d ( pv ) − d ; dln = pdv − pdv − vdp − d
2 2
2 22 − 12 D 2
dln = dlkt − d ; ln12 = lkt12 − = lkt12 −
2 2 2
D 2
lkt12 = ln12 +
2
ln12 = lkt12
1.4.3. Total energy of one system
- In general:
2
W = U + D + Wd + Wt = U + Gpv + G + Ggh
2
- If potential energy is negligible
2
W = U + D + Wd ; w = u + d +
- For close system: 2
Wk = U ; wk = u; DWk = U 2 − U1 ; Dwk = u2 − u1
- For open system:
2 D 2
Wh = I + Wd ; wh = i + ; DWh = DI + DWd ; Dwh = Di +
2 2
1.4.4. First thermodynamic law
- Close system:
q = Du + l12
dq = du + pdv = du + pdv + vdp − vdp = du + d ( pv ) − vdp = di − vdp
- Open system:
D 2 D 2
q = Di + + lkt12 − = Di + lkt12
2 2
dq = di + dlkt = di − vdp = du + pdv
1.4.4. First thermodynamic law
dq = du + pdv
dq = di − vdp
• For ideal gas:
dq = Cv dT + pdv
dq = C p dT − vdp
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