Date

Page (12
Sadu haD ONeae pllosíng Alcaholupaud 6q
ain o asuifble _g oand uag ane
methaua

duiu X
altohol_

90pmp maqnulum hnd

iduiy

Cyelohé
N

y a waguu im bronud

Onn Cenplen thalin ing Reaiuenl

C u UC Cu TCyB
1
1! 1
 Na BHy uolutuing ngput aud tt
Aleleyctad kotone, to
Alcohdl i l6ksh'toueT6)double
CUaC0-CaH

Na8H
-
AaBH4 SecliumborDiuydude
1Loplex Cemp ouna

CY-CH= Cu-CsCuD ur
NaBHu Cu u=cu =y-Dy

bv d

ChemicalPrnpextioa
wiiA
oi Alcolaalg aud Phehclk.
Alcohalh ave vey acui molecuu tuy uudniga teu
pes o uahk
Kàchen uwolisgainghe cleavage bemd ntiu
case aleohal
oill ot as nucleoplila
CH
NA
CH-D + H+
4
Nucleoplilu) w
Readuen in whtch cleva4e.C-bbeol u takug plau
I n thee eatseultoual att as elechophuu

Me DH n
3 Readinminwhich Alcohol tha whal] molecula takig
Paut
 1 11h, Date
Page
Keace in uelaic Hue dlevage H bemd
take place

Renclinit Mealyactiie like Nak.Alete

awnenlbuoluact wt ue YMolal Hi( Hyduogen
Lgas pHnelutadtuu hous ha Alcohali as
ouaiiu nalm
Mse- CHTbHt Ng 2 C 0-Na -+L

MCCAOH+\A C cu0) A1 +H
Aluminium ethoxIcla
Alcoholu doll noilact uuh NadH a
Phénolp -uactuuwitte sbdiwn potasiunAl,Ccmetals
glix Huduogein ga slouoto hei Audre
pYopelie

C6HEOH+ Na
CAr=o) Al+Ha
CsMED- Na H
ai sodium phuuoxtu alumindum puxtole)
Pheuo.yAtt with NabM to giua s.bddum phonbxid
0d AUAu HuaxM ooshad pkaualk: axa moHe
aLioli uan aleolaa.
O u NaDH
CGHD -Na +HLD
sadiwn phunnx td
 Date
Page18
niend a alcolualk auoir in nálusa2
Alkokoh aHe aridte ih nalus due o
H hena palato
o- beberehnex palasu dun tu
dexut u euADLaga alinu b[uw oan aud Hyduog
0htm acqui - clauge Qnd uyclungen clom
uey clhauged o tu bd ber sme polayeua Ao it

S
Nd

uaua i thivaN
MzC-CaD4 H o
(etuoyidaim dungun ien

pe altb.a
CH C43
AsCD- CM C0=M 4C 0-
Suouehiald
CH33

nCale o Alcohol uu ne alky gunup Txanudenutas

alcolal k qunupk oMa tug etoo
ateatem n th
iAn Alcokolreaale ouaupe kaueu tue to oy M

bendbend x b elihaAiA13 Altoal aud mdxlquwm în

Alcohol MoHeDve ta Catbaunupn llSe
 Date
Page 1 9 )

Jaauti stable razo 1ieaubaiuan un mast glasle:

mrs CHzahinn atuh C3
0- 43 0

fuu ky pluaau aue noue kioe ha Alcololt

Aw n phennly atey ihu lou 4 potom_ hunoxtdle ien

puDcluid Katclk stabi lied b uDuancLwal
uu iu wo HADuaut iu ulkoxidn len pHoduao rem
altehal
IN /Yat

wA n A No uADuau-

Ou Phenoxled fegs M stuhle daan 1Phenm wy2

Sn plhenbxtds lem the is pmly negaluu clhange me
shecteililal.w pheualu e bot4 eiieaud poihiu
auge ax puieukzi Negg catga i m Caxber ad
posba o n 0Xuoenutattha mcukes themleA
Stauble
 Date

Ci0-4

esAcidte Thasn oaliy

Alcahols axe even
C u 3 - C u a - 0 + H t

H a C - c u - d u

()
+ DU

polauiu o beaad i Js
Beraue alollal u
d o t b u l n watu tau i
dun tn Jlu iuducuy balLii muL, aualicHhaun
nDaueiy e co
alealsal

Cadey aAciolbi oheugth

1Phenoli> Water Alokol

m the aLadlui
Ouu a t u t u i e l a subshituuuliu
Sheugih ohplalau n
avauliso lype otubshtauui ougoupA
he
Nelnines4 cdenaya 9oup E.D.GL]_hke NHa, 0 Cu
CH3 CH
Alecren witacluáuotugayoupa OG)ikeNOL.CnN
 Date 121p
elechen doádw 9 1 Page

O-

cu3

N R
0-tdL o-methoXy phuuol1
-
NH
1

CH
ai O7amno phanl)u tmsp
halia kubi

(p- ud1)
CHR
elecon doualugups C puAeu n fhe benene
Hh i ui Mal wlthduauu e m 0ugeA
th polaui oondlbevd lwill be loae
lg Audu heng th uALhcleLe
0 O-

M-0UoL
CH3
to induchiuu eteer
to te i a Pnly
dut idacthe
hheet aud Hpexo
gallej
 Date
Page2
Out ol D-amiopheual aud heD Xy pnol
oCH wAL aUoluú berame1elufto
utdtauo tha e- fem rig] bu
MoHe,ihan N.
O

DCH3 NMa

D-mahn amLno phnol

1phana Dmaelelurbinegaliu than N 1o.ik el
tndetaus e rom benans LAG mau dil,

Pka log ka
Ka i th diuouinhe cenatan quda aio moue iu Ka
Jw will be u PKa admoue uid be the aidle
skengta Ther Pka Naur asoe Bhi phuaa aN
al V ,t

Cem DoLoll
Phanal

m-Hubl O.08 .08

4 ULDl

0Niho pal 23
m-Niho phaol .4-0
Nio phunol
4 dinike phunol 40
4,6 hini ro pwno D.71
 Date
Page (
ElechrolO iucluauntug aunupka uie 0n ie
Beun Rio-

N=o

ND

oN=D

Ew.t ay wueut on dhi beizuul uiq tay uill

wil witkcltaio dl een ad Ha o'wil
wtdyad tha e rem yebungem AD bvd ill be
polax oHbed].
K0 Niko pheuol iaJusauohe than piniro pns)
beraune blidbuamolecula Haberdliguy HadeA
noee

fo dinial
 atnd Dafe
Poge
Mou au dlWiko Uiou,hou wil be ta Aúdit

Shogth-p p-H
N0 DEN
-0-

oNED
N2D
Becauue N0a fake, eren beu
sobtstq att.eo oX19enie,uy 0
un w avealkoxldeieni Sken4bauet a CAmpud
CHycluoxicduie h tan ldoval lamapain
wa eanilshexe.
beLau at a leuu
base Cs e
duettwettl|
0 and DH
GH
Recaue o dhe inducuj ellet he e clniby will
intAnie n alkoxidi iena it uill be mou bouie
Ond CoA diuplatu u Hycluoglw pOmOaly

- D + LHoH R-DH+ OH

LRatón d Alcaal with Cauboxyie Aws

Tki Muacluan involvwa tha clawage o -M. bevd,
Ad
a d fhpDcul ourhud ax èsteuanol ttis an
ad colayged uacie ad iu sHveuusble 40, tu
ou puoclud oluuwg h HLALLon Shada be.
LMDued ConninuaLs Ly
 Date
Page (2S)
icuslo HOC
ogid talalyned uaeh

My -CuD Cu, +HaD

Reaohm o £li Culodh Athano chlouith
u incha teuke 2plon te putener op
- ..
luich ceniundH pipohieid eluuna Hdline
ch
ud uae puncluut auwnaal tauunsiah ea teu ty
CHanoalu]6
**

Kadb 'wit 4oe hnhy.oluiola

n Thi Kadiby ala eutou aE a maLA RHDduet.
acieydalke plaul i thauak baiel raolium,l.e
ha pkuten o Pyuidins
iLCH3 uPytidunk CU-Cu-
:th etharad
Cug coo4
aetic acio7
phnsluae
Phendls u g with Be oy1 uleuola to tovm pluu upat
e ugDOn u, k|a schotlew Bauuma uay .Date
--CausPAxtsluiy iosHt Page1
Bengoyl ehloual
Pheol clo no uat t u Caubon auas
Phenolugd withasiy calauuos
u3.

phery dtLauoal
uuta dai Anhcuia
Keacho a Plhane
ln tiu uadhenphau easaoai u puaclutd aud
Lalan ali auis i fostlhntd
:
CU3 CR Pyrid tCHCo04
o a CH3lC
atil
O
s

ReacienJnvo luing ho Clewugg o 6emod

ihenDlop not giu u uadionu involvig t th

cleaoige rakiugaC-0O 6edbecdue
bod atawiul double bend clhaacd
du to ADhauL
vt sliss ur3 ,
afe
-

745 7 Page.

-4

4leohala.'uolaxg.a thsadiieminonlui a
elewage onelo anolootidn elut plul
MC- CUa tO

puoaleaaol o Jki2uuactuent ualuin4

D

Cu
y 1
43 C CH
Cu3 (3
 Date
Page
In eoue 0 3 Alohsk he olaxitp a = o u pmax
imum, akd huiaks eail
imum, unt ibnast su4cti
MueDo he 3 Cboriey puocuud duwuuq ts uay
s mutshble due t H 1 ep ouclie

Reactuy uth Hakd Haloaid

Hu Cu-Cya-U+ Hou

HB CuS-CH-Brt DH

Cu3ua + Hou

PU C4S-UHA-u +3PD3

L Pusu CH 1 u +H

SOUaaiga @u -Ut
 Dafe
Poge 2
K Ahous uwill jeldutiiquuidaid u Jhuwtigs al

iwiuAloiolgO cliutiguiihedukbs Lludk Roaget e

Li 'anhclunuzndarao
Add add tR ado L:R

3
wTAlcohe gleoho aleohol
wan ybidii9tutbidly u puoelund inatawutauenuulu a
t minutn iy hi tuubiclitappea
Altoho T HAu tl aiu alcalanl u
Dainlolo
ime thgiven
Neahol 3

Jehyelyaluoy a Alaluol
15 ax'a4 waly moleuuo i kla Deluyclaalteq he
mastcemmancluayeluallLuq ageuidu lclhenucal au
AlunaiugAlaD3-
AnhyZnca
Png plunue cAuc Hs PDu
Phosplhnuau_pedaoxfclo Paoe
Cene Sulplunie Aud HasD-
 stod Date
Page
whew alshala axu Subjed ia dulyelxatuon Alkna
QNUDcud au hmpexaluu u 443K

1aC- -OH CLont:scu= HA + d

2 = Cy- u
Masoy
Cue=u+Md
1
O

CondkuC-e=u +HaD

Orcy o ualint S> '>|