Tag Number C-202 Equipment Name Distillation Column

Objective Separate paraxylene from other heavier side products

Operating Parameters
Feed Liquid Distillate Bottoms
Stream S-212 S-213 S-214
Quantity (kg/hr) 69496.72 5879.54 616.19
Temperature 427.04K 414.82K 478.15K
Pressure (atm) 1.410875223 1.085615515 1.549688989
Materials
paraxylene 5880.84 5879.13 1.714
2,5 hexanedione 55.02 0.4065 54.61
water 0 0 0
ethylene 0 0 0
2,5-dimethylfuran 0.00056 0.00055 0
1-ethyl-2,4-dimethylbenzene 560.86 0.000011 560.86
hexane 0.0011 0.0011 0
Associated Components Tag number
Reflux Accumulator RA 202
Reboiler HXR 202
Condenser HXC 202
Reflux pump PRF 202
Reboiler pump PRB 202
Fenske Method
Components Mass feed (mf) (xf) Distillate Xd Bottoms
paraxylene 5880.8400 0.9052 5879.1263 0.9999 1.7137
2,5 hexanedione 55.0200 0.0085 0.4067 0.0001 54.6133
2,5-dimethylfuran 0.0006 0.0000 0.0006 0.0000 0.0000
1-ethyl-2,4-dimethylbenzene 560.8624 0.0863 0.0024 0.0000 560.8600
hexane 0.0011 0.0000 0.0011 0.0000 0.0000
Total 6496.7241 1.0000 5879.5371 1.0000 617.1870
1. PAG NAG EXCEED 10 BAR(P) = 9.86923 DI NA PWEDE IASSUME IDEALLITY ano nga conversion ng bar papuntang atm
2. PERCENTAGE ERROR MAX OF 0.5

Xb
0.0028
0.0885
0.0000
0.9087
0.0000
1.0000
 kg/hr Composition
paraxylene 0.9999
2,5 hexanedione 0
2,5-dimethylfuran 0
1-ethyl-2,4-dimethylbenzene
multiply by 0.9869 from Perry's hexane

kg/hr Composition
paraxylene
2,5 hexanedione
2,5-dimethylfuran
1-ethyl-2,4-dimethylbenzene
hexane
 5878.715557 0.004758198
2.81332E-05 4.832590337
Reflux ratio 0.75824
Distillate to feed ratio 0.65
P by trial and error 1.09
STEP 2: Flash calculations for distillate and bottoms
DISTILLATE STREAM P(atm) 1.0856 T=414.82K or 141.67 BOTTOMS STREAM P(atm)
COMPONENT p^O (atm) K-VALUE (partial P/Total Pressure)
XXd/K-Value COMPONENT p^O (atm)
paraxylene 1.091354295 1.0012 0.9987 paraxylene 4.484136968
2,5 hexanedione 0.899509447 0.8252 0.0001 2,5 hexanedione 15.82714596
2,5-dimethylfuran 3.712343263 3.4058 0.0000 2,5-dimethylfuran 13.53284
1-ethyl-2,4-dimethylbenzene 0.275097651 0.2524 0.0000 1-ethyl-2,4-dimethylbenzene 1.477166
hexane 6.201279856 5.6892 0.0000 hexane 19.72288
TOTAL 12.17958451 11.1739 0.9988 TOTAL 55.04416893

Step 3 Evaluate Geometric Relative Volatility with respect to paraxylene

COMPONENT alpha at distillate alpha at the bottom alpha mean
paraxylene 1 1 1 heavy key
2,5 hexanedione 0.824213962 3.529585754 2.176899858 low key
Step 4 Compute for
dxi
0
 OMB
FEED
DISTILLATE
llate and bottoms BOTTOMS
1.09 T=478.15K or 205 DIFFERENCE
K-VALUE (partial P/Total Pressure)
yP^o x Kvalues
4.113887127 4.1085 1
14.52031739 1.2849 2
12.41544954 0.0000 3
1.355198165 1.2315
18.09438532 0.0000
50.49923755 6.6

NOT SURE
PACONSULT
6496.7241
5879.5371
617.1870
0.0000
scratch: using antoine equation in getting p^o
A in mmhg B in mmhg C in mmhg
2,5 hexanedione 10.84115 2752.5925 202.132 #REF! #VALUE!
2,5 dimethylfuran 7.3108 1435.5826 230.21 #REF! #VALUE!
1-ethyl-2,4-dimethylbenzene 7.30983 1843.9455 227.893 #REF! #VALUE!
ethylene 6.96867 649.8057 262.73 #REF!

For relative volatility alpha

A = heavy key - paraxylene
B = light key - 2,5 hexandione

alpha AB = (Ya/Xa)/(1-Ya)(1-Xa) -1009.706167 note: not yet final

SCRATCH P= 6.8046 atm
Components Mass feed (mf) (xf) Distillate Xd Bottoms
paraxylene 5880.84 0.905200825 5879.13 0.999930579 1.714
2,5 hexanedione 55.02 0.008468884 0.4065 6.91381E-05 54.61
water 0 0 0 0 0
ethylene 0 0 0 0 0
2,5-dimethylfuran 0.00056 8.61973E-08 0.00055 9.35448E-08 0
1-ethyl-2,4-dimethylbenzene 560.86 0.086330036 0.000011 1.8709E-09 560.86
hexane 0.0011 1.69316E-07 0.0011 1.8709E-07 0
Total 6496.724086 1 5879.538161 1 617.187

STEP 2: Flash calculations for distillate and bottoms

DISTILLATE STREAM T=414.82K or 141.67 141.67 BOTTOMS STREAM
COMPONENT p^O (atm) K-VALUE (partial P/Total Pressure)
XXd/K-Value COMPONENT p^O (atm)
paraxylene 1.091354295 0.773529988 0.118504405 paraxylene 4.484136968
 Xb
0.003
0.088
0
0
0
0.909
0
1

llate and bottoms

T=478.15K or 205
K-VALUE (partial P/Total Pressure)
yXb/K-Value
0.081464341 0.00161318 1
2,5 hexanedione 0.899509447 0.637554217 8.17762E-06 2,5 hexanedione 15.82714596
water 0 0 0 water 0
ethylene 0 0 0 ethylene 0
2,5-dimethylfuran 3.712343263 2.631234289 1.1259E-08 2,5-dimethylfuran 0
1-ethyl-2,4-dimethylbenzene 0.275097651 0 2.37033E-10 1-ethyl-2,4-dimethylbenzene 1.477165533
hexane 6.201279856 4.39534252 2.21625E-08 hexane 0
TOTAL 12.17958451 8.437661014 0.118512617 TOTAL 21.78844846

PRESSURE 1.410875223
0.287535379 0.005693856 2
0 0 3
0 0
0 0
0.026836004 0.000531414
0 0
0.395835724 0.00783845
Tag Number C-201 Equipment Name Distillation Column
Objective Separate hexane from paraxylene and heavier components
Operating Parameters
Feed Liquid Distillate Bottoms
Stream S-210 S-211 S-212
Quantity (kg/hr) 18562.10 12065.3739 6496.34
Temperature 318.15K 335.59K 427.21K
Materials
paraxylene
2,5 hexanedione
water
ethylene
2,5-dimethylfuran
1-ethyl-2,4-dimethylbenzene
hexane
Associated Components Tag number
Reflux Accumulator RA 201
Reboiler HXR 201
Condenser HXC 201
Reflux pump PRF 201
Reboiler pump PRB 201

Components Mass feed (mf) (xf) Distillate Xd Bottoms

paraxylene 5893.9248 0.3175 13.0848 0.0011 5880.8400
2,5 hexanedione 55.0200 0.0030 0.0000 0.0000 55.0200
water 8.8400 0.0005 8.8400 0.0007 0.0000
2,5-dimethylfuran 43.7100 0.0024 43.7094 0.0036 0.0006
1-ethyl-2,4-dimethylbenzene 560.8624 0.0302 0.0000 0.0000 560.8624
Xb
0.9052
0.0085 OMB
0.0000 FEED 18562.0980
0.0000001 DISTILLATE 12065.3739
0.0863 BOTTOMS 6496.7241
hexane 11999.7408 0.6465 11999.7397 0.9946 0.0011
Total 18562.0980 1.0000 12065.3739 1.0000 6496.7241

STEP 2: Flash calculations for distillate and bottoms

DISTILLATE STREAM P(atm) = 1.0856 T=335.59K or 62.44 BOTTOMS STREAM T=427.21K or 154.06
COMPONENT p^o K-VALUE (partial P/TotalXXd/K-Value
Pressure) COMPONENT p^O (atm)
paraxylene 0.075178411 0.069250563 0.014440316 paraxylene 1.494186072
2,5 hexanedione 0.003600738 0.003316819 0 2,5 hexanedione 1.708058825
water 0.220097645 0.202742857 0.003615417 water 0
ethylene 0 0 0 ethylene 0
2,5-dimethylfuran 0.334594226 0.308211336 0.012978108 2,5-dimethylfuran 0
1-ethyl-2,4-dimethylbenzene 0.011964 0.011020634 0 1-ethyl-2,4-dimethylbenzene 0
hexane 0.818283822 0.753761811 1.32004565 hexane 7.918336853
TOTAL 1.463718843 1.348304019 1.351079491 TOTAL 11.12058175

A in mmhg B in mmhg C in mmhg DISTILLATE BOTTOMS

2,5 hexanedione 10.84115 2752.5925 202.132 2.74 1298.124707
2,5 dimethylfuran 7.3108 1435.5826 230.21 254.291612 3757.713483
1-ethyl-2,4-dimethylbenzene 7.30983 1843.9455 227.893 9.09264 303.4964099
ethylene 6.96867 649.8057 262.73 93392.74503 256801.6474
 0.0000002
1.0000000 DIFFERENCE 0.0000

toms
P(atm) = 1.41
K-VALUE (partial P/TotalyPressure)
1.059706434 0.905
1.211389238 0.008
0 0
0 0
0 0 NOT SURE
0 0 NO MOVEMENT
5.61584174 0.086
7.886937411 0.999

paulit yung k value

Tag Number D-201 Equipment Name Decanter
Objective To remove water from organics
Operating Parameters
Feed Liquid 1 Liquid 2
Stream S-208 S-210 S-209
Quantity (kg/hr) 19646.66 18562.09 1084.55
Temperature (K) 313.15 318.15K 318.15K

Materials Feed (Mf) Compositions (Xf) ML1 XL1 ML2

paraxylene 5894.047 0.300 5893.92 0.3175 0.12
2,5 hexanedione 68.82 0.004 55.020 0.0030 13.80
water 1064.56 0.054 8.84 0.0005 1055.73
ethylene 0 0.000 0 0.0000 0.00
2,5-dimethylfuran 58.56 0.003 43.71 0.0024 14.84
1-ethyl-2,4-dimethylbenzene 560.87 0.029 560.86 0.0302 0.00
hexane 11999.8 0.611 11999.73 0.6465 0.06
Total 19646.657 1.000 18562.09 1.0000 1084.55

DIFFERENCE 0.017
XL2
0.0001
0.0127
0.9734
0.0000 Material Balance
0.0137 F = Li + Lo
0.0000 (Mf)(Xf) = (ML1)(XL1) + (ML2)(XL2)
0.0001
1.0000
Tag Number R-201 Equipment Name Reactor
Objective Reacts DMF with ethylene in hexane to produce paraxylene
Operating Parameters VAPOR LIQUID VAPOR MIXED
Gas feed Liquid feed Gas effluent Liquid effluent
Stream S-201 S-203 S-205 S-204
Quantity (kg/hr) 1800.00 17854.29997 8.491110879 19666.49514
Pressure (atm)
Temperature 623.15 K 623.15 K
Materials mfg xgf mlg xlf mgo xgo mlo xlo
paraxylene 0 0 0 0 0 0 5893.127773 0.2997
2,5 hexanedione 0 0 0 0 0 0 70.2086871 0.0036
water 0 0 0 0 0 0 1085.164154 0.0552
ethylene 1800.00 1 0 0 8.49 1 0 0.0000
2,5-dimethylfuran 0 0 5854.51 0.327904763 0 0 57.374198 0.0029
1-ethyl-2,4-dimethylbenzene 0 0 0 0 0 0 560.8203251 0.0285
hexane 0 0.00 11999.79 0.672095237 0 0 11999.8 0.6102
Total 1800.00 1 17854.29997 1 8.491110879 1 19666.49514 1

19654.30 19674.98625
 C6H8O+C2H4->C8H10+H2O
C6H8O+H2O->C6H10O2
C8H10+C2H4->C10H14

conversion (C2H4) 0.9801

Molar mass kg/kmol conversion (H2O) 0.0101
paraxylene 106.16 conversion (p-Xylene) 0.07
5893.127773 2,5 hexanedione 114.14
water 18 dmf reacted 5797.1358
ethylene 28.05 h2o formed 1096.2361
2,5-dimethylfuran 96.13 h2o react 11.071985
1-ethyl-2,4-dimethylbenzene 134.222 p-xylene formed 6336.6965
hexane 86.18 p-xylene react 443.56876
x's ethylene 1
eth-dmf 1674.3061
eth-dimeben 117.20143
ethylene reacted 1791.5075
Tag Number HX-202 Equipment NameCountercurrent heat exchanger Material Carbon steel
Objective To cool stream prior to decanter
Operating Parameters
Inlet Outlet
Stream S-206 (Mixed) S-207 (L)
Tube
Temperature (K) 478.71K 313.15K
Pressure (atm) 61.1733 atm 61.1733 atm mass in = mass out
Shell (Mi)(Xi) = (Mo)(Xo)
Temperature (K) - -
Pressure (atm) 0 0
S206 xi S-207 xo
paraxylene 5894.047 0.3000 5894.047 0.3000
2,5 hexanedione 68.82 0.0035 68.82 0.0035
water 1064.56 0.0542 1064.56 0.0542
ethylene 0 0.0000 0 0.0000
2,5-dimethylfuran 58.56 0.0030 58.56 0.0030
1-ethyl-2,4-dimethylbenzene 560.87 0.0285 560.87 0.0285
hexane 11999.8 0.6108 11999.8 0.6108
Total 19646.657 1.0000 19646.657 1.0000

Tag Number HX-201 Equipment NameCountercurrent heat exchanger Material Carbon steel
Objective Effluent feed heat exchanger
Operating Parameters
Inlet Outlet
Tube
Stream S-202 S-203
Temperature (K) 364.26 523.15
mass in = mass out
(Mi)(Xi) = (Mo)(Xo)

Qt
Pressure (atm) 60.49 60.49
Shell
Stream S-204 (mixed) S-206 (mixed)
Temperature (K) 623.15 478.71
Pressure (atm) 60.49 60.49

at shell
S-204 xi S206 xo
paraxylene 5894.047 0.3000 0.0000
2,5 hexanedione 68.82 0.0035 68.82 0.0050
water 1064.56 0.0542 1064.56 0.0774
ethylene 0 0.0000 0 0.0000
2,5-dimethylfuran 58.56 0.1044 58.56 0.1044
1-ethyl-2,4-dimethylbenzene 560.87 0.0285 560.87 0.0408
hexane 11999.8 0.6108 11999.8 0.8725
Total 19646.657 1.0000 13752.61 1.0000

at tube
S-202 (liq) xi S-203 (liq) xo Mass in = Mass out
paraxylene 0 0 0 0 (Mi)(Xi) = (Mo)(Xo)
2,5 hexanedione 0 0 0 0
water 0 0 0 0
ethylene 0 0 0 0
2,5-dimethylfuran 5854.51 0.3279 5854.51 0.3279
1-ethyl-2,4-dimethylbenzene 0 0 0 0
hexane 11999.79 0.6721 11999.79 0.6721
Total 17854.29997 1 17854.29997 1
Mass in = Mass out
(Mi)(Xi) = (Mo)(Xo)
Tag Number C-104 Equipment Name Distillation Column
Objective Removes hexane and concentrate DMF
Operating Parameters
Feed Liquid Distillate Bottoms
Stream S-133 S-134 S-135
Quantity (kg/hr)
Temperature (K) 327.04 315.93 358.15
Materials xf xd xb
glucose 0.0000 0.0000 0 0 0 0
water 138.6375 138.6375 0 0.00176 0.00228 0
butanol 0.0083 0.0083 0 0.0000001 0.0000001 0
NaCl 0.0000 0.0000 0 0 0 0
HCl 0.0000 0.0000 0 0 0 0
levulinic acid 0.0000 0.0000 0 0 0 0
formic acid 0.0000 0.0000 0.00 0 0 0
hydroxymethylfurfural 0.0000 0.0000 0 0 0 0
H2 0.0000 0.0000 0 0 0 0
CO2 0.0000 0.0000 0 0 0 0
2,5-dimethylfuran 6087.3270 232.8170 5854.51 0.0775 0.0038 0.3279
hexane 72327.5260 60327.7360 11999.79 0.9207 0.9939 0.6721
Na+ 0.0000 0.0000 0 0 0 0
H+ 0.0000 0.0000 0 0 0 0
Cl- 0.0000 0.0000 0.00 0 0 0
paraxylene 0.0000 0.0000 0 0 0 0
2,5 hexanedione 0.0000 0.0000 0 0 0 0
ethylene 0.0000 0.0000 0 0 0 0
1-ethyl-2,4-dimethylbenzene 0.0000 0.0000 0 0 0 0
TOTAL 78553.4988 60699.198790 17854.3000 1.00000 1 1
Associated Components Tag number
Reflux Accumulator RA 104
Reboiler HXR 104
Condenser HXC 104
Reflux pump PRF 104
Reboiler pump PRB 104
Feed Distillate Bottoms
Materials mf xf md xd mb xb
glucose 0.0000 0 0 0 0 0
water 138.6375 0.760667696 138.63749 0.228400857 0 0
butanol 0.0083 4.57627E-05 0.0083 0.000013674 0 0
NaCl 0.0000 0 0 0 0 0
HCl 0.0000 0 0 0 0 0
levulinic acid 0.0000 0 0 0 0 0
formic acid 0.0000 0 0 0 0.00 0
hydroxymethylfurfural 0.0000 0 0 0 0 0
H2 0.0000 0 0 0 0 0
CO2 0.0000 0 0 0 0 0
2,5-dimethylfuran 6087.3270 33.39957327 232.817 0.383558605 5854.51 32.7904763
hexane 11999.7900 65.83971327 60327.736 99.38802686 11999.79 67.2095237
Na+ 0.0000 0 0 0 0 0
H+ 0.0000 0 0 0 0 0
Cl- 0.0000 0 0 0 0.00 0
paraxylene 0.0000 0 0 0 0 0
2,5 hexanedione 0.0000 0 0 0 0 0
ethylene 0.0000 0 0 0 0 0
 FEED 18225.7628
DISTILLATE 371.4612993
BOTTOMS 17854.215
DIFFERENCE 0.086499031
1-ethyl-2,4-dimethylbenzene 0.0000 0 0 0 0 0
Total 18225.7628 100 60699.19879 100 17854.29997 100

STEP 2: Flash calculations for distillate and bottoms

DISTILLATE STREAM T=315.93K OR 42.78 BOTTOMS STREAM T=358.15K OR 85
COMPONENT p^o K-VALUE (partial P/TotalXXd/K-Value
Pressure) COMPONENT p^O (atm) K-VALUE (partial P/Total Press
glucose glucose 0
water 0.084414562 water 0
butanol 0.029234666 butanol 0
NaCl 0 NaCl 0
HCl 0 HCl 0
levulinic acid 0 levulinic acid 0
formic acid 0 formic acid 0
hydroxymethylfurfural 0 hydroxymethylfurfural 0
H2 0 H2 0
CO2 0 CO2 0
2,5-dimethylfuran 0.148336988 2,5-dimethylfuran 0.750961316
hexane 0 hexane 0
Na+ 0 Na+ 0
H+ 0 H+ 0
Cl- 0 Cl- 0
TOTAL 0.261986216 TOTAL 0.750961316

A in mmhg B in mmhg C in mmhg DISTILLATE BOTTOMS

2,5 dimethylfuran 7.3108 1435.5826 230.21 112.7361112 570.7306
yXb/K-Value
Tag Number C-103 Equipment Name Distillation Column
Objective Removes butanolfrom DMF and hexane.
Operating Parameters
Feed Liquid Distillate Bottoms
Stream S-130 S-131 S-132
Quantity (kg/hr) 80739.44 66224.48602 14300.10
Temperature (K) 328.43 327.04 408.15
Materials xf xd xb
glucose 0.0000 0.0000 0.0000 0 0 0
water 138.6375 138.6375 0.0000 0.0015 0.0018 0
butanol 14131.2369 0.0083 14131.2286 0.1522 0.0000001 0.9882
NaCl 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
HCl 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
levulinic acid 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
formic acid 0.3892 0.0000 0.3892 0.0000 0.0000 0.00003
hydroxymethylfurfural 0.0000 0.0000 0.0000 0.0000 0.0000000 0.0000
H2 0.0000 0.0000 0.0000 0.0000 0.0000000 0.0000
CO2 0.0000 0.0000 0.0000 0.0000 0.0000000 0.0000
2,5-dimethylfuran 6255.7957 6087.3270 168.4687 0.0674 0.0775 0.0118
hexane 72327.5260 72327.5260 0.0000 0.7789 0.9207 0
Na+ 0.0000 0.0000 0.0000 0.0000 0.0000000 0.0000
H+ 0.0000 0.0000 0.0000 0.0000 0.0000000 0.0000
Cl- 0.0000 0.0000 0.0000 0.0000 0.0000000 0.0000
Total 92853.5853 78553.4988 14300.0865 1.0000 1.0000 1
Associated Components Tag number
Reflux Accumulator RA 104
Reboiler HXR 104
Condenser HXC 104
Reflux pump PRF 104
Reboiler pump PRB 104
Feed Distillate Bottoms
Materials mf xf md xd mb xb
glucose 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000
water 138.637490 0.675422 138.637490 2.226760 0.000000 0.000000 OMB
butanol 14131.236900 68.845348 0.008341 0.000134 14131.228560 98.819183 FEED
NaCl 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 DISTILLATE
HCl 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 BOTTOMS
levulinic acid 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 DIFFERENCE
formic acid 0.389190 0.001896 0.000000 0.000000 0.389190 0.002722
hydroxymethylfurfural 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000
H2 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000
CO2 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000
2,5-dimethylfuran 6255.795700 30.477334 6087.327000 97.773106 168.468700 1.178096
hexane 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000
Na+ 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000
H+ 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000
Cl- 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000
Total 20526.059280 100.000000 6225.972831 100.000000 14300.086450 100.000000

STEP 2: Flash calculations for distillate and bottoms

DISTILLATE STREAM T=327.04K or 53.86 BOTTOMS STREAMT=408.15K or135
COMPONENT p^o K-VALUE (partial P/Total
XXd/K-Value
Pressure) COMPONENT p^O (atm) K-VALUE (partial
yXb/K-Value
P/Total Pressure)
glucose 0 glucose 0
water 0.147455471 water 3.084684149
butanol 0.056594557 butanol 1.782304452
NaCl 0 NaCl 0
HCl 0 HCl 0
levulinic acid 0 levulinic acid 0
20526.05928
6225.972831
14300.08645
0
formic acid 0 formic acid 0
hydroxymethylfurfural 0 hydroxymethylfurfural 0
H2 0 H2 0
CO2 0 CO2 0
2,5-dimethylfuran 0.237883166 2,5-dimethylfuran 3.156057987
hexane 0 hexane 0
Na+ 0 Na+ 0
H+ 0 H+ 0
Cl- 0 Cl- 0
TOTAL 0.441933194 TOTAL 8.023046588

A in mmhg B in mmhg C in mmhg DISTILLATE BOTTOMS

2,5 dimethylfuran 7.3108 1435.5826 230.21 180.7912058 2398.60407
Tag Number LLE-101 Equipment Name Liquid-Liquid Extractor
Objective To extract hexane
Operating Parameters
Feed 1 Feed 2 Extract Raffinate
Stream S-127 S-124 S-129 S-128
Quantity (kg/hr) 60781.38 23397.37 80739.44186 3247.133967
Temperature (K) 318.9 379.56 328.69 328.69
Materials Xf1 Xf2 Xe Xr
glucose 0.000000 0.000000 0.000000 0.000000 0.0000 0.000000 0.000000 0.000000
water 138.637000 0.190689 3242.764588 13.700080 138.6375 0.149308 3242.764098 92.138049
butanol 0.008300 0.000000 14131.230000 59.701829 14131.2369 15.218838 0.000000 0.000000
NaCl 0.000000 0.000000 0.000000 0.000000 0.0000 0.000000 0.000000 0.000000
HCl 0.000000 0.000000 0.194200 0.000820 0.0000 0.000000 0.194200 0.005518
levulinic acid 0.000000 0.000000 0.000000 0.000000 0.0000 0.000000 0.000000 0.000000
formic acid 0.000000 0.000000 0.389198 0.001644 0.3892 0.000419 0.000008 0.000000
hydroxymethylfurfural 0.000000 0.000000 0.000000 0.000000 0.0000 0.000000 0.000000 0.000000
H2 0.000000 0.000000 0.000000 0.000000 0.0000 0.000000 0.000000 0.000000
CO2 0.000000 0.000000 0.000000 0.000000 0.0000 0.000000 0.000000 0.000000
2,5-dimethylfuran 237.000000 0.325982 6295.099000 26.595627 6255.7957 6.737269 276.303300 7.850724
hexane 72327.7255 99.483318 0.000000 0.000000 72327.5260 77.894166 0.199500 0.000057
Na+ 0.000000 0.000000 0.000000 0.000000 0.0000 0.000000 0.000000 0.000000
H+ 0.000000 0.000000 0.000000 0.000000 0.0000 0.000000 0.000000 0.000000
Cl- 0.000000 0.000000 0.000000 0.000000 0.0000 0.000000 0.000000 0.000000
Total 72703.370800 99.999989 23669.676990 100.000000 92853.585280 100.000000 3519.462506 99.994348
 F1 + F2 = E + R

OMB
FEED1 72703.370800
FEED2 23669.676990
E 92853.585280
R 3519.462506
DIFFERENCE 0.000000

Feed1 + Feed2 96373.047790

6.810236294x10-3
Tag Number M 101 Equipment Name Mixer
Objective To extract hexane
Operating Parameters
Feed 1 Feed 2 Product
Stream S-126 S-134 S-127
Quantity (kg/hr) 12004.17 60699.20 72703.3713
Pressure (atm) 1.00 1.09 1
Temperature (K) 298.15 315.93 318.9
Materials
glucose 0 0 0.0000
water 0 138.6375 138.6375
butanol 0 0.0083 0.0083
NaCl 0 0 0.0000
HCl 0 0 0.0000
levulinic acid 0 0 0.0000
formic acid 0 0 0.0000
hydroxymethylfurfural 0 0 0.0000
H2 0 0 0.0000
CO2 0 0 0.0000
2,5-dimethylfuran 4.1830 232.817 237.0000
hexane 11999.9895 60327.736 72327.7255
Na+ 0 0 0.0000
H+ 0 0 0.0000
Cl- 0 0 0.0000
Total 12004.1725 60699.19879 72703.3713

72703.37129
Tag Number IE 1-101 Equipment Name Ion exchange column
Objective Removal of levulinic acid from the system
Operating Parameters
Feed Product 1 Product 2 Xf Xp1 Xp2
Stream S-125 S-137 S-136
Quantity (kg/hr)
Temperature (K) 400.5389 400.5389 400.5389
Materials
glucose 0.0000 0.000000 0.0000
water 0.0000 0.0000 0.0000
butanol 40822.9141 0.0000 40822.9141 98.4718 98.7765
NaCl 0.0000 0.0000 0.0000
HCl 0.0000 0.0000 0.0000
levulinic acid 127.8900 127.8900 0.0000 0.3085 100.0000
formic acid 0.0080 0.0000 0.0080 0.0000 0.0000
hydroxymethylfurfural 407.1696 0.0000 407.1696 0.9822 0.9852
H2 0.0000 0.0000 0.0000
CO2 0.0000 0.0000 0.0000
2,5-dimethylfuran 8.3901 0.0000 8.3901 0.0202 0.0203
hexane 0.0000 0.0000 0.0000
Na+ 35.4383 0.0000 35.4383 0.0855 0.0857
H+ 0.0000 0.0000 0.0000
Cl- 54.6518 0.0000 54.6518 0.1318 0.1322
Total 41456.4619 127.8900 41328.5719 100.0000 100.0000 100.0000
Tag Number C-102 Equipment Name Distillation Column
Objective
Operating Parameters
Feed Liquid Distillate Bottoms Xf Xd Xb
Stream S-123b S-124 S-125
Quantity (kg/hr) 65126.1389 23669.6770 41456.4619
Temperature (K) 323.16083333 K 370.56088889 K 400.54377778 K
Materials
glucose 0 0.000000 0.0000 0.0000 0.0000 0.0000
water 3242.7646 3242.7646 0.0000 0.0498 0.1370 0.0000
butanol 54954.1441 14131.2300 40822.9141 0.8438 0.5970 0.9847 40822.9141
NaCl 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
HCl 0.1942 0.1942 0.0000 0.000003 0.00001 0.0000
levulinic acid 127.8900 0.0000 127.8900 0.0020 0.0000 0.0031 OMB
formic acid 0.3972 0.3892 0.0080 0.00001 0.00002 0.0000002 FEED
hydroxymethylfurfural 407.1696 0.0000 407.1696 0.0063 0.0000 0.0098 DISTILLATE
H2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 BOTTOMS
CO2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000 DIFFERENCE
2,5-dimethylfuran 6303.4891 6295.0990 8.3901 0.0968 0.2660 0.0002
hexane 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
Na+ 35.4383 0.0000 35.4383 0.0005 0.0000 0.0009
H+ 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
Cl- 54.6518 0.0000 54.6518 0.0008 0.0000 0.0013
Total 65126.1389 23669.6770 41456.4619 1.0000 1.0000 1.0000

Associated ComponentsTag number

Reflux Accumulator RA 104
Reboiler HXR 104
Condenser HXC 104 NOT SURE PA
 0.0000 0.000000
3243.1854 3242.764588
54884.6768 14131.230000
0.0000 0.000000
0.0196 0.194200
127.8932 0.000000
65126.1389 0.3973 0.389198
23669.6770 407.1696 0.000000
41456.4619 0.0000 0.000000
0.0000 0.0000 0.000000
6031.3406 6295.099000
0.0000 0.000000
35.4383 0.000000
0.0000 0.000000
54.6518 0.000000
64784.7727 23669.676990
Reflux pump PRF 104
Reboiler pump PRB 104

STEP 2: Flash calculations for distillate and bottoms

DISTILLATE T=370.5609 or 97.4109 BOTTOMS T= 400.5438 Kor 127.3938
COMPONENT p^o K-VALUE (partial P/Total
XXd/K-Value
Pressure) COMPONENT p^O (atm) K-VALUE (partial
yXb/K-Value
P/Total Pressure)
glucose 0 glucose 0
water 0.910548553 water 2.46
butanol 0.462983215 butanol 1.39
NaCl 0 NaCl 0.00
HCl 225.0504847 HCl 0.00
levulinic acid levulinic acid
formic acid 0.90909966 formic acid 2.11
hydroxymethylfurfural hydroxymethylfurfural
H2 0 H2 0.00
CO2 0 CO2 0.00
2,5-dimethylfuran 0.008379974 2,5-dimethylfuran 0.02
hexane 0 hexane 0.00
Na+ 0 Na+
H+ 0 H+ 0.00
Cl- 0 Cl- 37.07
Total Total
mmHg sila
A in mmhg B in mmhg C in mmhg D E DISTILLATE BOTTOMS
2,5 hexanedione 10.84115 2752.5925 202.132
2,5 dimethylfuran 7.3108 1435.5826 230.21 849.1009 1978.5632
1-ethyl-2,4-dimethylbenzene 7.30983 1843.9455 227.893
ethylene 6.96867 649.8057 262.73
HCl 43.5455 -1.63E+03 -1.52E+01 1.38E-02 -1.50E-11 171038.3684 248718.302
Na 7.2828 -5.42E+03 1.54E+01 -2.02E-04 3.70E-08
Tag Number HX-105 Equipment Name Countercurrent heat exchanger Material Carbon steel
Objective To cool stream prior to purification of DMF
Operating Parameters
Inlet Outlet
Stream S-122 S-123
Tube
Temperature (K) 323.15
Pressure (atm) 9.8692301 9.8692301
Shell
Temperature (K) - -
Pressure (atm) 0 0
xi xo
glucose 0.0000 0.0000 0.0000 0.0000
water 3242.7672 5.0055 3243.1854 5.0061
butanol 54884.6768 84.7190 54884.6768 84.7185
NaCl 0.0000 0.0000 0.0000 0.0000
HCl 0.0196 0.0000 0.0196 0.0000
levulinic acid 127.8932 0.1974 127.8932 0.1974
formic acid 0.3973 0.0006 0.3973 0.0000
hydroxymethylfurfural 407.1696 0.6285 407.1696 0.6285
H2 0.0000 0.0000 0.0000 0.0000
CO2 0.0000 0.0000 0.0000 0.0000
2,5-dimethylfuran 6031.3406 9.3099 6031.3406 9.3098
hexane 0.0000 0.0000 0.0000 0.0000
Na+ 35.4383 0.0005 35.4383 0.0547
H+ 0.0000 0.0000 0.0000 0.0000
Cl- 54.6518 0.0844 54.6518 0.0844
Total 64784.3545 99.9458 64784.7727 99.9994
Tag Number HX-104 Equipment Name Countercurrent heat exchanger Material Carbon steel
Objective
Operating Parameters
Inlet Outlet
Tube
Stream S-118 S-119
Temperature (K) 394.49 453.15
Pressure (atm) 9.8692301 9.8692301
Shell
Stream S-121 S-122
Temperature (K) 465.38
Pressure (atm) 9.8692301 9.8692301

at shell
S-121 xi S-122 xo
glucose 0.0000 0.0000 0.0000 0.0000
water 3242.7672 0.0501 3242.7672 0.0501
butanol 54884.6768 0.8472 54884.6768 0.8472
NaCl 0.0000 0.0000 0.0000 0.0000
HCl 0.0196 0.0000 0.0196 0.0000
levulinic acid 127.8932 0.0020 127.8932 0.0020
formic acid 0.3973 0.0000 0.3973 0.0000
hydroxymethylfurfural 407.1696 0.0063 407.1696 0.0063
H2 0.0000 0.0000 0.0000 0.0000
CO2 0.0000 0.0000 0.0000 0.0000
2,5-dimethylfuran 6031.3406 0.0931 6031.3406 0.0931
hexane 0.0000 0.0000 0.0000 0.0000
Na+ 35.4383 0.0005 35.4383 0.0005
H+ 0.0000 0.0000 0.0000 0.0000
Cl- 54.6518 0.0008 54.6518 0.0008
Total 64784.3545 1.0000 64784.3545 1.0000

at tube
S-118 Xi S-119 Xo
glucose 0.0000 0.0000 0.0000 0.0000
water 1032.5037 0.0160 1032.5037 0.0160
butanol 54884.6768 0.8521 54884.6768 0.8521
NaCl 0.0000 0.0000 0.0000 0.0000
HCl 0.0196 0.0000 0.0196 0.0000
levulinic acid 127.8932 0.0020 127.8932 0.0020
formic acid 0.3972 0.0000 0.3972 0.0000
hydroxymethylfurfural 8143.3937 0.1264 8143.3937 0.1264
H2 0.0000 0.0000 0.0000 0.0000
CO2 0.0000 0.0000 0.0000 0.0000
2,5-dimethylfuran 134.3928 0.0021 134.3928 0.0021
hexane 0.0000 0.0000 0.0000 0.0000
Na+ 35.4383 0.0006 35.4383 0.0006
H+ 0.0000 0.0000 0.0000 0.0000
Cl- 54.6518 0.0008 54.6518 0.0008
Total 64413.3671 1.0000 64413.3671 1.0000
Tag Number R-102 Equipment Name Reactor
Objective Reaction of HMF and hydrogen to make DMF
Operating Parameters
Gas feed Liquid feed Gas effluent Liquid effluent
Stream S-100 S-119 S-120 S-121
Quantity (kg/hr) 370.67 64415.0574 65.0333 64784.3545
Pressure (atm) 9.86666 9.86666 9.86666 9.86666
Temperature (K) 298.15 453.15 465.37 465.37
Materials mfg xgf mlg xlf mgo xgo mlo xlo
water 0 0 1034.3460 1.6058 0 0 3242.7672 5.0055
butanol 0 0 54884.6768 85.2047 0 0 54884.6768 84.7190
HCl 0 0 0.0196 0.0000 0 0 0.0196 0.0000
levulinic acid 0 0 127.8932 0.1985 0 0 127.8932 0.1974
formic acid 0 0 0.3973 0.0006 0 0 0.3973 0.0006
hydroxymethylfurfural 0 0 8143.3919 12.6421 0 0 407.1696 0.6285
H2 370.67 100 0.0000 0.0000 65.0333 100 0.0000 0.0000
2,5-dimethylfuran 0 0 134.2425 0.2084 0 0 6031.3406 9.3099
Na+ 0 0 35.4383 0.0550 0 0 35.4383 0.0547
Cl- 0 0 54.6518 0.0848 0 0 54.6518 0.0844
Total 370.67 100 64415.0574 100.0000 65.0333 100 64784.3545 100.0000

done na this
64785.7274
64849.3878 \

Conversion C6H6O3+2H2O>C5H8O3+CH2O2
C6H6O3+H2>C6H8O+2H2O
HMF 0.95
water 18
butanol 74.12
HCL 36.46
levulinic acid 116.11
formic acid 46.03
HMF 126.11
DMF 96.13
Na+ 22.99
Cl- 35.45

h2O react 2208.421243

dmf react 5897.098169
%excess 1
h2-h2O 180.1537352
h2-dmf 125.483005
305.6367401
Tag Number C-101 Equipment Name Distillation Column
Objective To get the concentrated HMF by removing water and butanol
Operating Parameters
Feed Liquid Distillate Bottoms Xf Xd Xb
Stream S-113 S-114 S-117
Quantity (kg/hr) 656521.03 592107.6619 178.81
Temperature (K) 323.15 K 373.01833 K 394.2132 K
Materials
glucose 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
water 46391.7407 45359.2370 1032.5037 0.0707 0.0766 0.0160
butanol 599195.5208 544310.8440 54884.6768 0.9127 0.9193 0.8521
NaCl 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
HCl 0.6592 0.6396 0.0196 0.000001 0.000001 0.0000003
levulinic acid 127.8932 0.0000 127.8932 0.0002 0.0000 0.0020
formic acid 47.5708 47.1736 0.3972 0.0001 0.0001 0.00001
hydroxymethylfurfural 8143.3937 0.0000 8143.3937 0.0124 0.0000 0.1264
H2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
CO2 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
2,5-dimethylfuran 2524.1606 2389.7677 134.3928 0.0038 0.0040 0.0021
hexane 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
Na+ 35.4383 0.0000 35.4383 0.0001 0.0000 0.0006
H+ 0.0000 0.0000 0.0000 0.0000 0.0000 0.0000
Cl- 54.6518 0.0000 54.6518 0.0001 0.0000 0.0008
total 656521.0290 592107.6619 64413.3671 1.0000 1.0000 1.0000

ito yung S-117 hindi equal sa S-118 yes

kapag inalis yung Na+ at Cl- magbabalance 0.0000 balance na
 0 0.0000
45359.2370 46391.74069 1032.5037
544310.8440 599195.5208 54884.6768
0.6396 0 0.0000
0.659173 0.0196
OMB 127.893226 127.8932
FEED 656521.0290 47.570802 0.3972
DISTILLATE 592107.6619 8143.393714 8143.3937
BOTTOMS 64413.3671 0 0.0000
DIFFERENCE 0.0000 0 0.0000
yare 2524.160573 134.3928
> check mo nga ulit equate mo sa s113 at 117 0 0.0000
0 35.4383
0.00 0.0000
0.00 54.6518

okay na yey <3

 STEP 2: Flash calculations for distillate and bottoms
DISTILLATE 373.01833 Kor 99.86833 BOTTOMS T= 394.2132 Kor 121.0632
COMPONENT p^o K-VALUE (partial P/Total
XXd/K-Value
Pressure) COMPONENT p^O (atm) K-VALUE (partial P/Total
yXb/K-Value
Pressure)
glucose 0 glucose 0
water 0.994680491 water 2.02
butanol 0.511419832 butanol 0.11
NaCl 0 NaCl 0.00
HCl HCl
levulinic acid 0 levulinic acid
formic acid 0.979410859 formic acid 1.79
hydroxymethylfurfural 0 hydroxymethylfurfural
H2 0 H2 0.00
CO2 0 CO2 0.00
2,5-dimethylfuran 1.2043925 2,5-dimethylfuran 0.95
hexane 0 hexane 0.00
Na+ Na+
H+ 0 H+ 0.00
Cl- Cl- 37.07
Total Total
P total @ atm 1.09 mmHg sila
A in mmhg B in mmhg C in mmhg D E DISTILLATE BOTTOMS
2,5 hexanedione 10.84115 2752.5925 202.132
2,5 dimethylfuran 7.3108 1435.5826 230.21 915.3383 1674.9507
1-ethyl-2,4-dimethylbenzene 7.30983 1843.9455 227.893
ethylene 6.96867 649.8057 262.73
HCl 43.5455 -1.63E+03 -1.52E+01 1.38E-02 -1.50E-11
Na 7.2828 -5.42E+03 1.54E+01 -2.02E-04 3.70E-08
Cl- (not an ion) 28.8659 -1.68E+03 -8.52E+00 5.38E-03 -7.79E-05
water 29.8605 -3.15E+03 -7.30E+00 2.42E-09 1.81E-06 783.5978 1593.4733
butanol (n-butanol) 39.6673 -4.00E+03 -1.03E+01 -3.26E-10 8.67E-07 376.5144 830.2532
formic acid 27.9278 -2.60E+03 -7.25E+00 6.41E-10 3.94E-06 725.7906 1335.4431
Tag Number HX-107 Equipment Name Countercurrent heat exchanger
Material Carbon steel
Objective Trim heater for the feed to F-101
Operating Parameters
Inlet Outlet
Stream S-112b S-112c
Tube liq MIXED DAW
Temperature (K) 332.87 447.15
Pressure (atm) 1.9738467 1.9738467
Shell
Temperature (K)
Pressure (atm)
S-112b xi S-112c (mixed) xo
glucose 3594.0678 3.4547 3594.0678 0.0345
water 50129.8447 0.4819 50129.8447 0.4819
butanol 537.6165 0.0052 537.6165 0.0052
NaCl 48990.0307 0.4709 48990.0307 0.4709
HCl 574.6902 0.0055 574.6902 0.0055
levulinic acid 2.3562 0.0000 2.3562 0.0000
formic acid 0.9204 0.0000 0.9204 0.0000
hydroxymethylfurfural 158.5017 0.0000 158.5017 0.0015
H2 0.0000 0.0000 0.0000 0.0000
CO2 0.0000 0.0000 0.0000 0.0000
2,5-dimethylfuran 46.2920 0.0004 46.2920 0.0004
hexane 0.0000 0.0000 0.0000 0.0000
Total 104034.3201 4.4186 104034.3201 1.0000

Tag Number HX-106 Equipment Name Countercurrent heat exchanger

Material Carbon steel
Objective Heat the recycled aquaeous phase to be fed into F-101
Operating Parameters
Inlet Outlet
Tube
Stream S-112a S-112b
Temperature (K) 323.15 K 332.87 K
Pressure (atm) 18.75154195 18.75154195
Shell
Stream S-112e S-112f
Temperature (K) 447.03266667 K 354.95183333 K
Pressure (atm) 18.75154195 18.75154195

at shell
S-112e xi S-112f xo
glucose 3593.7987 6.2621 3593.7987 0.0626
water 4583.5872 0.0799 4583.5872 0.0799
butanol 64.3051 0.0011 64.3051 0.0011
NaCl 48987.9760 0.8536 48987.9760 0.8536
HCl 0.9568 0.0000 0.9568 0.0000
levulinic acid 2.1792 0.0000 2.1792 0.0000
formic acid 0.1121 0.0000 0.1121 0.0000
hydroxymethylfurfural 151.8036 0.0026 151.8036 0.0026
H2 0.0000 0.0000 0.0000 0.0000
CO2 0.0000 0.0000 0.0000 0.0000
2,5-dimethylfuran 4.9369 0.0001 4.9369 0.0001
hexane 0.0000 0.0000 0.0000 0.0000
Total 57389.6557 7.1995 57389.6557 1.0000

at tube
ok na to
 S-112a Xi S-112b Xo
glucose 3594.0678 3.4547 3594.0678 0.0345
water 50129.8447 0.4819 50129.8447 0.4819
butanol 537.6165 0.0052 537.6165 0.0052 note:
NaCl 48990.0307 0.4709 48990.0307 0.4709
HCl 574.6902 0.0055 574.6902 0.0055
levulinic acid 2.3562 0.0000 2.3562 0.0000
formic acid 0.9204 0.0000 0.9204 0.0000
hydroxymethylfurfural 158.5017 0.0015 158.5017 0.0015
H2 0.0000 0.0000 0.0000 0.0000
CO2 0.0000 0.0000 0.0000 0.0000
2,5-dimethylfuran 46.2920 0.0004 46.2920 0.0004
hexane 0.0000 0.0000 0.0000 0.0000
Total 104034.3201 4.4201 104034.3201 1.0000
Tag Number HX-103 Equipment Name Countercurrent heat
Material
exchanger Carbon steel
Objective Trim cooler for effluent R-101
Operating Parameters
Inlet Outlet
Stream S-108 S-109
Tube MIXED DAW
Temperature (K) 488.663 K 323.15 K
Pressure (atm) 18.75154195 18.75154195
Shell
Temperature (K)
Pressure (atm)
S-108 xi S-109 xo
glucose 3991.6129 0.5168 3991.6129 0.0052
water 102965.4680 13.3318 102965.4680 0.1333
butanol 598741.9284 77.5242 598741.9284 0.7752
NaCl 54431.0844 7.0477 54431.0844 0.0705
HCl 639.1838 0.0828 639.1838 0.0008
levulinic acid 130.8983 0.0169 130.8983 0.0002
formic acid 51.1330 0.0066 51.1330 0.0001
hydroxymethylfurfural 8805.6522 1.1401 8805.6522 0.0114
H2 0.0000 0.0000 0.0000 0.0000
CO2 0.0000 0.0000 0.0000 0.0000
2,5-dimethylfuran 2571.7758 0.3330 2571.7758 0.0033
hexane 0.0000 0.0000 0.0000 0.0000
Total 772328.7367 100.0000 772328.7367 100.0000
Tag Number HX-101 Equipment Name Countercurrent heat
Material
exchanger Carbon steel
Objective Heat the feed to R-101 and cool
Operating Parameters
Inlet Outlet
Tube
Stream S-104 S-105
Temperature (K) 365.86 443.49
Pressure (atm) 18.75154195 18.75154195
Shell
Stream S-107 S-108
Temperature (K) 453.0600556 488.663
Pressure (atm) 18.75154195 18.75154195

at shell
S-107 xi S-108 xo
glucose 3991.6129 0.5168 3991.6129 0.5168
water 102965.4680 13.3318 102965.4680 13.3318
butanol 598741.9284 77.5242 598741.9284 77.5242
NaCl 54431.0844 7.0477 54431.0844 7.0477
HCl 639.1838 0.0828 639.1838 0.0828
levulinic acid 130.8983 0.0169 130.8983 0.0169
formic acid 51.1330 0.0066 51.1330 0.0066
hydroxymethylfurfural 8805.6522 1.1401 8805.6522 1.1401
H2 0.0000 0.0000 0.0000 0.0000
CO2 0.0000 0.0000 0.0000 0.0000
2,5-dimethylfuran 2571.7758 0.3330 2571.7758 0.3330
hexane 0.0000 0.0000 0.0000 0.0000
Total 772328.7367 100.0000 772328.7367 100.0000
at tube
S-104 Xi S-105 Xo
glucose 15966.4514 2.0649 15966.4514 2.0649
water 99376.2069 12.8518 99376.2069 12.8518
butanol 599792.8708 77.5681 599792.8708 77.5681
NaCl 54431.0844 7.0393 54431.0844 7.0393
HCl 639.1838 0.0827 639.1838 0.0827
levulinic acid 33.4220 0.0043 33.4220 0.0043
formic acid 12.4981 0.0016 12.4981 0.0016
hydroxymethylfurfural 423.3981 0.0548 423.3981 0.0548
H2 0.0000 0.0000 0.0000 0.0000
CO2 0.0000 0.0000 0.0000 0.0000
2,5-dimethylfuran 2571.7758 0.3326 2571.7758 0.3326
hexane 0.0000 0.0000 0.0000 0.0000
Total 773246.8912 100.0000 773246.8912 100.0000

Tag Number HX-102 Equipment Name Countercurrent heat

Material
exchanger Carbon steel
Objective Trim cooler for effluent R-101
Operating Parameters
Inlet Outlet
Stream S-105 S-106
Tube
Temperature (K) 443.15 453.15 K
Pressure (atm) 18.75154195 18.75154195
Shell
Temperature (K)
Pressure (atm)
S-105 xi S-106 xo
glucose 15966.4514 2.0649 15966.4514 2.0649
water 99376.2069 12.8518 99376.2069 12.8518 ok na to
butanol 599792.8708 77.5681 599792.8708 77.5681
NaCl 54431.0844 7.0393 54431.0844 7.0393
HCl 639.1838 0.0827 639.1838 0.0827
levulinic acid 33.4422 0.0043 33.4422 0.0043
formic acid 12.4981 0.0016 12.4981 0.0016
hydroxymethylfurfural 423.3981 0.0548 423.3981 0.0548
H2 0.0000 0.0000 0.0000 0.0000
CO2 0.0000 0.0000 0.0000 0.0000
2,5-dimethylfuran 2571.7758 0.3326 2571.7758 0.3326
hexane 0.0000 0.0000 0.0000 0.0000
Total 773246.9114 100.0000 773246.9114 100.0000
Tag Number F-101 Equipment Name Flash vessel
Objective Remove a slurry of solids from the aquaeous recycle
Operating Parameters
Feed Vapor outlet Liquid outlet
Stream s-112c s-112d S-112e
Quantity (kg/hr) 104034.3201 46644.66 57389.6557
Temperature (K) 447.04 447.04 447.04

Materials mf xf mo1 xo1 mo2 xo2

glucose 3594.0678 3.4547 0.2690 0.0000058 3593.7987 0.0626
water 50129.8447 0.4819 45546.2575 0.9764516 4583.5872 0.0799
butanol 537.6165 0.0052 473.3114 0.0101472 64.3051 0.0011
NaCl 48990.0307 0.4709 2.0547 0.0000441 48987.9760 0.8536
HCl 574.6902 0.0055 573.7334 0.0123001 0.9568 0.0000
levulinic acid 2.3562 0.0000 0.1770 0.0000038 2.1792 0.0000
formic acid 0.9204 0.0000 0.8083 0.0000173 0.1121 0.0000
hydroxymethylfurfural 158.5017 0.0015 6.6981 0.0001436 151.8036 0.0026
H2 0.0000 0.0000 0.0000 0.0000000 0.0000 0.0000
CO2 0.0000 0.0000 0.0000 0.0000000 0.0000 0.0000
2,5-dimethylfuran 46.2920 0.0004 41.3551 0.0008866 4.9369 0.0001
hexane 0.0000 0.0000 0.0000 0.0000000 0.0000 0.0000
Total 104034.3201 4.4201 46644.6645 1.0000000 57389.6557 1.0000
ok na to
Tag Number D-101 Equipment Name Decanter
Objective To separate two liquid phases
Operating Parameters
Feed Liquid 1 Liquid 2
Stream S-109b S-113 S-110
Quantity (kg/hr) 773021.56 656521.03 116590.62
Temperature (K) 323.15 323.15 323.15
Outlet stream
Materials Feed (Mf) Compositions (Xf) ML1 XL1 ML2 XL2
glucose 3991.612856 0.516 0 0.0000 3991.61 3.4131
water 102965.468 13.314 46391.74069 7.0673 56573.73 48.3748
butanol 599792.8708 77.555 599195.5208 91.2808 597.35 0.5108
NaCl 54431.0844 7.038 0 0.0000 54431.08 46.5427
HCl 639.1837705 0.083 0.659173 0.0000 638.52 0.5460
levulinic acid 130.8983212 0.000 127.893226 0.0195 3.01 0.0000 OMB
formic acid 51.13301428 0.000 47.570802 0.0072 3.56 0.0000 FEED
HMF 8805.652182 1.139 8143.393714 1.2406 662.26 0.5663 LIQ1
H2 0 0.000 0 0.0000 0.00 0.0000 LIQ2
CO2 0 0.000 0 0.0000 0.00 0.0000 DIFF
2,5-dimethylfuran 2571.775752 0.333 2524.160573 0.3845 47.62 0.0407
hexane 0 0.000 0 0.0000 0.00 0.0000
Na+ 0 0.000 0 0.0000 0.00 0.0000
H+ 0 0.000 0.00 0.0000 0.00 0.0000
Cl- 0 0.000 0.00 0.0000 0.00 0.0000
Total 773379.6791 99.977 656430.939 99.9999 116948.74 99.9944

0.00
 Equipment Name Mixer
Objective
Outlet stream
Feed Liquid 1 Liquid 2
Stream S-110 S-112a S-111
Quantity (kg/hr)
Temperature (K)

Materials Feed Liquid 1 Liquid 2 Xf XL1 XL2

glucose 3993.41 3594.0678 399.3409 0.0343 0.0343 0.0343
water 56699.05 51029.8447 5669.2016 0.4863 0.4863 0.4864
butanol 597.35 537.6165 59.7352 0.0051 0.0051 0.0051
NaCl 54431.08 48990.0307 5441.0537 0.4669 0.4669 0.4668
HCl 638.54 574.6902 63.8545 0.0055 0.0055 0.0055
levulinic acid 2.62 2.3562 0.2618 0.0000 0.0000 0.0000
773021.56 formic acid 1.02 0.9204 0.1023 0.0000 0.0000 0.0000
656430.939 HMF 176.11 158.5017 17.6113 0.0015 0.0015 0.0015
116590.62 H2 0.00 0.0000 0.0000 0.0000 0.0000 0.0000
0.001 CO2 0.00 0.0000 0.0000 0.0000 0.0000 0.0000
2,5-dimethylfuran 51.44 46.2920 5.1436 0.0004 0.0004 0.0004
hexane 0.00 0.0000 0.0000 0.0000 0.0000 0.0000
Na+ 0.00 0.0000 0.0000 0.0000 0.0000 0.0000
H+ 0.00 0.0000 0.0000 0.0000 0.0000 0.0000
Cl- 0.00 0.0000 0.0000 0.0000 0.0000 0.0000
Total 116590.62 104934.3202 11656.3046 1.0000 1.0000 1.0000

0.00
Tag Number R-103 Equipment Name Reactor
Objective Decomposes formic acid into H2 and CO2
Operating Parameters
Liquid feed Gas effluent Liquid effluent
Stream S-114 S-115 S-116
Quantity (kg/hr) ########### 47.173606 ###########
Pressure (atm) 1.0856 1.0856 1.0856
Temperature (K) 373.15 373.15 373.15
glucose 0.000000 0.0000 0.000000 0.0000 0.000000 0.0000
water 45359.237000 7.6606 0.000000 0.0000 45359.237000 7.6613
butanol ########### 91.9277 0.000000 0.0000 ########### 91.9350
NaCl 0.000000 0.0000 0.000000
0.000000000274876976*100
0.000000 0.0000
HCl 0.639565 0.0001 0.000000 0.0000 0.639565 0.0000
levulinic acid 0.000000 0.0000 0.000000 0.0000 0.000000 0.0000
formic acid 47.173606 0.0080 47.173606 100.0000 0.000000 0.0000
hydroxymethylfurfural 0.000000 0.0000 0.000000 0.0000 0.000000 0.0000
H2 0.000000 0.0000 0.000000 0.0000 0.000000 0.0000
CO2 0.000000 0.0000 0.000000 0.0000 0.000000 0.0000
2,5-dimethylfuran 2389.767731 0.4036 0.000000 0.0000 2389.767731 0.4036
hexane 0.000000 0.0000 0.000000 0.0000 0.000000 0.0000
Na+ 0.000000 0.0000 0.000000 0.0000 0.000000 0.0000
H+ 0.000000 0.0000 0.000000 0.0000 0.000000 0.0000
Cl- 0.000000 0.0000 0.000000 0.0000 0.000000 0.0000
Total ########### 100.0000 47.173606 100.0000 ########### 99.9999
CH2O2>CO2+H2
** since there is no CO2 and H2 in the feed the ratio of the liquid and gas effluent is 1:1

%excess 1
Tag Number R-101 Equipment Name Reactor
Objective Reaction of glucose to produce HMF Conversion:
Operating Parameters Glucose 0.75
Liquid feed Liquid effluent HMF 0.25
Stream S-106 S-107
Quantity (kg/hr) 773246.9114 773379.6791
Pressure (atm) 18.78 18.78
Temperature (K) 453.15 453.15
S-106 Flow rate %xlf xle
glucose 15966.4514 2.0649 3991.6129 0.0052 water 18
water 99376.2069 12.8518 102965.4680 0.1331 HMF 126.11
butanol 599792.8708 77.5681 599792.8708 0.7755 DMF 96.13
NaCl 54431.0844 7.0393 54431.0844 0.0704 Glucose 180.16
HCl 639.1838 0.0827 639.1838 0.0008 levulinic acid 116.11
levulinic acid 33.4422 0.0043 130.8983 0.0002 formic acid 46.03
formic acid 12.4981 0.0016 51.1330 0.0001
hydroxymethylfurfural 423.3981 0.0548 8805.6522 0.0114
2,5-dimethylfuran 2571.7758 0.3326 2571.7758 0.0033 h2O feed 3589.261116
total 773246.9114 100.0000 773379.6791 1.0000 hmf feed 8382.254062
levulinic acid feed 97.45610118
fromic acid 38.63495252
S-107 Flow rate %xle
glucose 3991.6129 0.5161
water 102965.4680 13.3137
butanol 599792.8708 77.5548
NaCl 54431.0844 7.0381
HCl 639.1838 0.0826
levulinic acid 130.8983 0.0169
formic acid 51.1330 0.0066
C6H12O6>C6H6O3+3H2O
C6H6O3+2H2O>C5H8O3+CH2O2

99376.2069
423.3981
33.4422
12.4981
hydroxymethylfurfural 8805.6522 1.1386
2,5-dimethylfuran 2571.7758 0.3325
total 773379.6791 100.0000
Tag Number M-100 Equipment Name Mixer
Objective Mix the entering feeds into one homogenous phase
Operating Parameters
Feed 1 Feed 2 Feed 3 Feed 4
Stream S116 b S112f S-132 S-136
Quantity (kg/hr) ########### 57389.655660 69.5105 41278.64831
Pressure (atm) 1.0856 18.75154195
Temperature (K) 373.15 332.87 K
glucose 0.000000 0.0000 3593.7987 6.2621 0.0000 0
water 45359.237000 7.6613 4583.5872 7.9868 0.0000 0
butanol ########### 91.9350 64.3051 0.1121 64.1931 92.3501 40822.9141 98.8960
NaCl 0.000000 0.0000 48987.9760 85.3603 0.0000 0
HCl 0.639565 0.0000 0.9568 0.0000 0.0000 0
levulinic acid 0.000000 0.0000 2.1792 0.0000 0.0000 0
formic acid 0.000000 0.0000 0.1121 0.0000 0.3892 0.5599 11.9968 0.0291
hydroxymethylfurfural 0.000000 0.0000 151.8036 0.2645 0.0000 271.5945 0.6580
H2 0.000000 0.0000 0.0000 0.0000 0.0000 0.0000
CO2 0.000000 0.0000 0.0000 0.0000 0.0000 0
2,5-dimethylfuran 2389.767731 0.4036 4.9369 0.0086 4.9283 7.0900 172.1429 0.4170
hexane 0.000000 0.0000 0.0000 0.0000 0.0000 0
Na+ 0.000000 0.0000 0.0000 0.0000 0.0000 0
H+ 0.000000 0.0000 0.000000 0.0000 0.0000 0
Cl- 0.000000 0.0000 0.000000 0.0000 0.0000 0
Total ########### 99.9999 57389.655660 99.9944 69.5105 41278.64831

########### 14364.1039

55251.2112
11.9968
Feed 5 Feed 6 Product
S-101 S-102 S-103
61806.0354 6247.206342 773215.6484

12372.6527 20.0185 0 15966.4514 15966.4514 2.064941576

49433.3827 79.9815 0 99376.2069 99376.2069 12.85232743
0 166.5105388 2.665359997 599792.8708 599792.8708 77.57122764
0 5443.1084 87.12868027 54431.0844 54431.0844 7.039573567
0 637.5874 10.20595973 639.1838 639.1838 0.082665654
0 0 2.1792 2.1792 0.000281836
0 0 12.4981 12.4981 0.00161638
0 0 423.3981 423.3981 0.054758087
0 0 0.0000 0.0000
0 0 0.0000 0.0000
0 0 2571.7758 2571.7758 0.332607825
0 0 0.0000 0.0000
0 0 0 0.0000
0 0 0 0.0000
0 0 0 0.0000
61806.0354 6247.206342 773215.6484 773215.6485
 172.1429

stream 116b
101
102 s-103
112f

136 mixer 2
132
Tag Number Evaporator 2 Equipment Name
Objective
Operating Parameters
Feed Liquid product Vapor
Stream S-016 S-101 S-017
Quantity (kg/hr) 0 0
Pressure (atm)
Temperature (K)
Materials
glucose 12373.6527 18.52575961 12373.6527 20.01981266 0
water 54417.95508 81.47424039 49433.3827 79.98018734 4984.572383
butanol 0 0 0
NaCl 0 0 0
HCl 0 0 0
levulinic acid 0 0 0
formic acid 0 0 0
hydroxymethylfurfural 0 0 0
H2 0 0 0
CO2 0 0 0
2,5-dimethylfuran 0 0 0
hexane 0 0 0
Na+ 0 0 0
H+ 0 0 0
Cl- 0 0 0
Total 66791.60778 61807.0354 4984.572383

Tag Number Crystallizer Equipment Name

Objective
Operating Parameters
 Feed Recycle product Product
Stream S-012 S-013 (solid) S-016
Quantity (kg/hr) 0 0
Pressure (atm)
Temperature (K)
Materials
glucose 27190.62687 33.31834253 14816.97417 12373.6527 18.52575961
water 54417.95508 66.68165747 0 54417.95508 81.47424039
butanol 0 0 0
NaCl 0 0 0
HCl 0 0 0
levulinic acid 0 0 0
formic acid 0 0 0
hydroxymethylfurfural 0 0 0
H2 0 0 0
CO2 0 0 0
2,5-dimethylfuran 0 0 0
hexane 0 0 0
Na+ 0 0 0
H+ 0 0 0
Cl- 0 0 0
81608.58195 14816.97417 66791.60778
Tag Number M-002 Equipment Name Recycle Mixer
Objective
Operating Parameters
Feed 1 Feed 2 Product
Stream S-013 S-013b S-014
Quantity (kg/hr)
Pressure (atm)
Temperature (K)
Materials
glucose 14816.97417 100 0 14816.97417 19.25305568
water 0 62142.104 62142.104 80.74694432
butanol 0 0 0
NaCl 0 0 0
HCl 0 0 0
levulinic acid 0 0 0
formic acid 0 0 0
hydroxymethylfurfural 0 0 0
H2 0 0 0
CO2 0 0 0
2,5-dimethylfuran 0 0 0
hexane 0 0 0
Na+ 0 0 0
H+ 0 0 0
Cl- 0 0 0
14816.97417 76959.07817

Tag Number HX001 Equipment Name Heat Exchanger

Objective
Operating Parameters
Inlet Outlet
Stream S-014 S-015
Quantity (kg/hr)
Pressure (atm)
Temperature (K)
Materials
glucose 14816.97417 19.25305568 14816.97417
water 62142.104 80.74694432 62142.104
butanol 0 0
NaCl 0 0
HCl 0 0
levulinic acid 0 0
formic acid 0 0
hydroxymethylfurfural 0 0
H2 0 0
CO2 0 0
2,5-dimethylfuran 0 0
hexane 0 0
Na+ 0 0
H+ 0 0
Cl- 0 0
76959.07817 76959.07817
Tag Number EV001 Equipment Name
Evaporator 1
Objective
Operating Parameters
Feed Liquid product Vapor
Stream S-009 S-011 S-010
Quantity (kg/hr)
Pressure (atm)
Temperature (K)
Materials
glucose 27190.62687 16.70170025 27190.62687 33.31834253 0
water 135610.9231 83.29829975 54417.95508 66.68165747 81192.968
butanol 0 0 0
NaCl 0 0 0
HCl 0 0 0
levulinic acid 0 0 0
formic acid 0 0 0
hydroxymethylfurfural 0 0 0
H2 0 0 0
CO2 0 0 0
2,5-dimethylfuran 0 0 0
hexane 0 0 0
Na+ 0 0 0
H+ 0 0 0
Cl- 0 0 0
total 162801.55 81608.58195 81192.968
C6H12O6(s)+H2O-C6H12O6(aq)+H2O
Tag Number R001 Equipment Name
Objective
Operating Parameters
Feed Liquid product
Stream S-008 S-016
Quantity (kg/hr)
Pressure (atm)
Temperature (K)
Materials
glucose 27190.62687 16.70170024 27190.62687 C6H12O6(s)+H2O-C6H12O6(aq)+H2O
water 135610.9231 83.29829976 135610.9231 This reactor was only used to isomerized glucose but the ratio
butanol 0 0
NaCl 0 0
HCl 0 0
levulinic acid 0 0
formic acid 0 0
hydroxymethylfurfural 0 0
H2 0 0
CO2 0 0
2,5-dimethylfuran 0 0
hexane 0 0
Na+ 0 0
H+ 0 0
Cl- 0 0
162801.55 162801.55
Tag Number M-001 Equipment Name
Recycle Mixer OMB
Objective FEED 1 85842.4718
Operating Parameters FEED 2 76959.07817
Feed 1 Feed 2 Product PRODUCT 162801.55
merized glucose but the ratio is 1:1. Therefore mass in = mass out
Stream S-007 S-015 S-008 0
Quantity (kg/hr)
Pressure (atm)
Temperature (K)
Materials
glucose 12373.6527 14.4143714 14816.97417 19.25305568 27190.62687 16.70170024
water 73468.8191 85.5856286 62142.104 80.74694432 135610.9231 83.29829976
Total 85842.4718 100 76959.07817 100 162801.55 100
Tag Number AE 001 Equipment Name
Anion Exchanger
Objective
Operating Parameters
Feed Product
Stream S-006 S-007
Quantity (kg/hr)
Pressure (atm)
Temperature (K)
Materials
glucose 12373.6527 14.4143714 12373.6527 14.4143714
water 73468.8191 85.5856286 73468.8191 85.5856286
Total 85842.4718 100 85842.4718 100

Tag Number CE 001 Equipment Name

Cation Exchanger
Objective
Operating Parameters
Feed Product
Stream S-005 S-006
Quantity (kg/hr)
Pressure (atm)
Temperature (K)
Materials
glucose 12373.6527 14.4143714 12373.6527 14.4143714
water 73468.8191 85.5856286 73468.8191 85.5856286
Total 85842.4718 100 85842.4718 100

Tag Number CF-001 Equipment Name

Activated Carbon filter
Objective
Operating Parameters
Feed Product Filter residue
Stream S-003 S-005 S-004
Quantity (kg/hr)
Pressure (atm)
Temperature (K)
Materials
glucose 12373.6527 14.38278848 12373.6527 14.4143714 0 0
water 73468.8191 85.39810438 73468.8191 85.5856286 0 0
Ash 188.5 0.219107138 0 0 188.5 100
Total 86030.9718 100 85842.4718 100 188.5 100

Tag Number RT-001 Equipment Name

Rotary filter
Objective
Operating Parameters
Feed Product Filter residue
Stream S-001 S-003 S-002
Quantity (kg/hr)
Pressure (atm)
Temperature (K)
Materials
glucose 12373.6527 13.90298056 12373.6527 14.38278848 0 0
water 73468.8191 82.54923494 73468.8191 85.39810438 0 0
Ash 188.5 0.211797753 188.5 0.219107138 0 0
Proteins and oils 2969.0282 3.335986742 0 0 2969.0282 100
Total 89000 100 86030.9718 100 2969.0282 100