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Answer Key & Solution: JEE MAIN-2015
Answer Key & Solution: JEE MAIN-2015
Answer Key & Solution: JEE MAIN-2015
A
CODE - A
Ques. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15
DI
Ans. 3 2 3 3 2 3 2 1 3 * 3 2 2 1 3/4
Ques. 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30
Ans. 2 4 3 1 2 3 4 2 1 4 2 1 3 3 1
Ques. 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
1 3 4 4 2 2 2 1 1 3 4 1 2 4
Ans.
Ques.
Ans.
Ques.
2
4
46
61
47
4
62
48
2
63
N 49
3
64
50
1
65
51
1
66
52
1
67
53
2
68
54
4
69
55
4
70
56
3
71
57
2
72
58
1
73
59
3
74
60
1
75
SI
Ans. 1 3 3 4 3 2 1 2 2 3 1 4 3 4 3
Ques. 76 77 78 79 80 81 82 83 84 85 86 87 88 89 90
Ans. 4 3 4 3 3 4 4 4 3 1 1 4 1 1 4
OO
ET
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PHYSICS
1. Two stones are thrown up simultaneously form the edge of a cliff 240 m high with initial
speed of 10 m/s and 40 m/s respectively. Which of the following graph best represents
the time variation of relative position of the second stone with respect to the first
(Assume stones do not rebound after hitting the ground and neglect air resistance, take g
= 10 m/s2)
The figure are schematic and not draw to scale)
A
DI
(1) (2)
Ans.
(3)
(3)
N (4)
SI
Sol: y1 = 10t – 5t2
y2 40t 5t 2
And y2 – y1 = 30 t for t ≤ 8 s
OO
At t = 8s, first stone is on the ground and the second stone is at the edge of the diff &
moving down.
So at t = 8 s, y2 – y1 = 240 m
1
For t > 8 y2 – y1 = 240 – 40 t - g t2
2
Hence option (3)
ET
L
2. The period of oscillation of simple pendulum is T= 2 . Measured value of L is 20.0
g
cm known to 1 mm accuracy and time for 100 oscillations of the pendulum is found to be
90 s using wrist watch of 1 s resolution. The accuracy in the determination of g is
(1) 2% (2) 3% (3) 1% (4) 5%
Ans. (2)
4 2 L
Sol: g 2
T
g L 2T
g L T
1 21
= 2.72% 3%
200 90
correct option (2)
3.
A
Given in the figure are two blocks A and B of weight 20 N and 100 N, respectively.
These are being pressed against a wall by a force F as shown. If the coefficient of friction
between the blocks is 0.1 and between block B and the wall is 0.15, the frictional force
DI
applied by the wall on block B is
(1) 100 N (2) 80 N (3) 120 N (4) 150 N
Ans. (3)
Sol. The solution is based on the assumption that the blocks are in equilibrium.
20
A
20 20 100
B
f
N
SI
f = 120 N
Correct option (3)
OO
4. A particle of mass m moving in the x direction with speed 2v is hit by another particle of
mass 2m moving in the y direction with speed v. If the collision is perfectly inelastic, the
percentage loss in the energy during the collision is close to :
(1) 44% (2) 50% (3) 56% (4) 62%
Ans. (3)
Sol. From law of conversation of linear momentum
2
Centre of Mass(x-direction) m.2v = 3mvx vx = v
ET
3
2
(y-direction) 2m.v = 3mvy vy = v
3
1 2 1 2 1 4 4
m 2v .2m v 3m . v2 v2
2 2 2 9 9
% Loss = = 56%
1 2 2
m 2m .2m v
2 2
correct option (3)
5. Distance the centre of mass of a solid uniform cone form its vertex is Z0. If the radius of
its base is R and its height is h then Z0 is equal to:
h2 3h 5h 3h 2
(1) (2) (3) (4)
4R 4 8 8R
Ans. (2)
y
r
dy
A
H
M r 2 ydy
Centre of mass
O
1 2 M
R H
DI
3
H 2
3 3 R
2 r 2 y.dy 2 2 y3 .dy
R HO R H H
3
4
H
correct option (2)
N
SI
6. From a solid sphere of mass M and radius R cube of maximum possible volume is cut.
Moment of inertia of cube about an axis passing through its centre and perpendicular to
one of its faces is:
OO
MR 2 MR 2 4MR 2 4MR 2
(1) (2) (3) (4)
23 2 16 2 9 3 3 3
Ans. (3)
Sol. For maximum volume of cube, body diagonal of cube = Diameter of sphere
a 3 2R a = side of cube
3
2R
ET
Volume of cube = V =
3
3
M 2R 2M
Mass of cube m
4 3 3 3
R
3
m 2 4 MR 2
Moment of Inertia = side
6 9 3
correct option (3)
R
7. From a solid sphere of mass M and radius R, a spherical portion of radius is removed,
2
as shown in the figure. Taking gravitational potential V = 0 at r = , the potential at the
centre of the cavity thus formed is: (G = gravitational constant)
A
M
“–ve” mass of cavity M1 =
8
GM
DI
Potential due to complete sphere V1
2R 3
3R 2 r 2
R 11GM
r v1
2 8R
M
N
Potential due to cavity V2 =
3GM
3GM
2R
1
1
3G
R
8
SI
V2
8R
Now net potential at the given point
11GM 3GM
OO
V V1 V2
8R 8R
GM
V
R
Correct option (2)
8. A pendulum made of a uniform wire of cross sectional area A has time period T. When
an additional mass M is added to its bob, the time period changes to TM. If the Young’s
ET
1
modulus of the material of the wire is Y then is equal to :
Y
(g = gravitational acceleration)
TM 2 A TM 2 Mg
(1) 1 Mg (2) 1 A
T T
TM 2 A T 2 A
(3) 1 (4) 1
T Mg TM Mg
Ans. (1)
Mg
Y
A.
Sol. T 2
g mg
A.y
T2 l
Tm2 1
1
T2
Tm2 Mg
2
1
T AY
2
Tm Mg
2 1
A
T AY
1 Tm2 A
2 1
DI
Y T Mg
9. Consider a spherical shell of radius R at temperature T. The black body radiation inside it
can be considered as an ideal gas of photons with internal energy per unit volume
U
N 1 U
u T 4 and pressure. p . If the shell now undergoes an adiabatic expansion
V 3 V
the relation between T and R is :
SI
1 1
(1) T e R (2) T e3R (3) T (4) T 3
R R
Ans. (3)
Sol: U T4V
OO
dU T 4 dV 4T 3V.dT
U T4
dW P.dV dV dV
3V 3
dQ dW dU 0
T4
.dV T 4 .dV 4T3 V.dT 0
ET
3
4 dV dT
4 0
3 V T
1
ln V ln T Constant
3
TV1/3 Constant
T V 1/3
T R 1
10. A solid body of constant heat capacity 1 J/oC is being heated by keeping it in contact with
reservoirs in two ways:
(i) Sequentially keeping in contact with 2 reservoirs such that each reservoir supplies
same amount of heat.
(ii) Sequentially keeping in contact with 8 reservoirs such that each reservoir supplies
same amount of heat.
In both the cases body is brought form initial temperature 100oC to final temperature
200oC. Entropy change of the body in the two cases respectively is
(1) ln2, 4ln2 (2) ln2, ln2 (3) ln2, 2ln2 (4) 2ln2, 8ln2
Ans. (No Answer)
T T
Sol. S C ln 1 c ln f
Ti T1
T 473
s1 C ln f ln ln1.27
Ti 373
A
T T T
s 2 c ln 1 C ln 2 ....c ln f
Ti T1 T7
DI
T 473
c ln f ln ln1.27
Ti 373
None of the given options is correct.
11. N
Consider an ideal gas confined in an isolated closed chamber. As the gas undergoes an
adiabatic expansion, the average time of collision between molecules increases as Vq,
Cp
SI
where V is the volume of the gas. The value of q is:
Cv
3 5 3 5 1 1
(1) (2) (3) (4)
6 6 2 2
OO
Ans. (3)
mean free path
Sol: t
v
T
and v T
P
T
ET
t
P
1/ 2
T V
1
2
V
12. For a simple pendulum, a graph is plotted between its kinetic energy (KE) and potential
energy (PE) against its displacement d. Which one of the following represents these
correctly?
(graphs are schematic and not drawn to scale)
E
KE E PE
(1) PE (2) KE
d d
E KE E PE
(3) d (4)
KE
PE
Ans. (2)
Sol: In SHM
A
1 1
KE = mv 2 m2 (A 2 d 2 );
2 2
1 1
DI
PE = Kd 2 m2 d 2 ;
2 2
'KE' Vs 'd' is a parabola opening downward
'PE' Vs 'd' is a parabola opening upward
option (2) is correct.
13.
N
A train is moving on a straight track with speed 20 ms-1. It is blowing its whistle at the
frequency of 1000 Hz. The percentage change in the frequency heard by a person
standing near the track as the train passes him is (speed of sound = 320 ms-1) close to:
SI
(1) 6 % (2) 12 % (3) 18 % (4) 24 %
Ans. (2)
V
OO
1 1
f0 V
= V Vs V Vs 100
f0 V
V Vs
2Vs 2 20
= 100 = 100 12% (approx.)
V Vs 340
14. A long cylindrical shell carries positive surface charge in the upper half and negative
surface charge in the lower half. The electric field lines around the cylinder will look
like figure given in :
(figure are schematic and not drawn to scale)
(1) (2)
(3) (4)
A
Ans. (1)
Sol: The shell can be considered as a dipole as shown
+
DI
P
E E
-
So, at equatorial points
figure 1.
N
the electric lines has to opposite to P . This satisfied only in
SI
15. A uniformly charged solid sphere of radius R has potential V0 (measured with respect to
) on its surface. For this sphere the equipotential surfaces with potentials
3V0 5V0 3V0 V
, , and 0 have radius R1 , R 2 , R 3 and R 4 respectively. Then
OO
2 4 4 4
(1) R1 0 and R 2 (R 4 R 3 ) (2) R1 0 and (R 2 R1 ) (R 4 R 3 )
(3) R1 0 and R 2 (R 4 R 3 ) (4) 2R R 4
Ans. (3), (4)
Sol: For uniformly charged solid sphere at internal points the potential is greater than that on
KQ
the surface Vsurface = V0
ET
R
KQ
Vint (r R) = 3R 2 r 2
3
2R
3 KQ 3
At center (r = 0); V V0
2 R 2
3V
at R1 0 , V1 0
2
At R2;
KQ 5 5 KQ
2R 3
3R 2 R 22 V0
4 4 R
5 2
3R 2 R 22 R
2
R2 R
R 22 R 2
2 2
3
At R3; V V0 (which is less then V0) So R3 should be outside the sphere.
4
KQ 3 KQ 4R
R3
R3 4 R 3
KQ 1 KQ
Similarly at R4; R 4 4R
R4 4 R
A
4R 8R
Now, R 4 R 3 4R
3 3
So, R 2 R 4 R 3
DI
So, option (3) is correct. 2R < R4 hence option (4) is also correct.
Q2 Q2
C C
1F 3F 1F 3F
(3) Charge (4) Charge
Q2 Q2
ET
C C
1F 3F 1F 3F
Ans. (2)
Sol:
1 F
C C 3 F
2 F
E E
3C
Ceq
C3
3CE
Q Ceq .E
A
C3
Q 2 2CE
Q2
3 C3
DI
dQ 2 C 3 2E 2CE 6E
2 2
dC C 3 C 3
dQ 2
Since
dC N
is decreasing with increase in value of C
option (2) is correct.
SI
17. When 5V potential difference is applied across a wire of length 0.1 m, the drift speed of
electrons is 2.5 104 ms 1 . If the electron density in the wire is 8 1028 m 3 , the
resistivity of the material is closed to:
OO
(1) 1.6 108 m (2) 1.6 107 m (3)1.6 106 m (4) 1.6 105 m
Ans. (4)
Sol: j = E
I V
(1) where I = neAVd,
A l
I
Now, neVd
ET
A
V 1V
From (1), neVd neVd
l l
V 5
neVd l 8 10 1.6 10 2.5 104 0.1
28 19
= 1.6 10-5 m .
18.
6V P 2
E
1 9V
E
3 Q 3
In theEcircuit shown,Ethe current in the 1 resistor is:
(1) 1.3 A, from P to Q (2) 0 A
(3) 0.13 A, from Q to P (4) 0.13 A, from P to Q
Ans. (3)
A
Sol:
6V 9V
i 3 P 5
DI
3 x i1
9V
(–6V) 1
i2
Q
i1 i2 i3
9x x6 x
N
SI
5 3 1
27 3x 5x 30 15x
3
x
23
OO
(1) F1 F2 0
(2) F1 is radially inwards and F2 is radially outwards
(3) F1 is radially inwards and F2 = 0
(4) F1 is radially outwards and F2 = 0
Ans. (1)
Sol: Magnetic field due to the inner coil at external points will be zero.
So magnetic force (iLB) on the outer coil will be zero.
The magnetic field at any current element of inner coil due to outer coil is perpendicular
to it.
As per Fleming’s Left Hand rule (or dF I dl B the force will be radially.
So net force on inner coil is also zero. (Every loop of inner coil is a uniform magnetic
field)
So. F = 0
A
I I
DI
gL gL
(1) sin (2) 2sin
0 cos 0 cos
gL gL
Ans.
Sol:
(3) 2
(2)
0
tan
N (4)
0
tan
SI
Assume length of the wire is 1 m
Since the wire is in equilibrium ,
o I2 T
T sin = (1)
OO
I
B B
I
I
(c) I y (d) I y
I I
A
x x I
If there is a uniform magnetic field of 0.3 T in the positive z direction, in which
orientations the loop would be in (i) stable equilibrium and (ii) unstable equilibrium?
DI
(1) (a) and (b), respectively (2) (a) and (c), respectively
(3) (b) and (d), respectively (4) (b) and (c), respectively
Key: (3)
Sol. MB sin
U MB cos
In (a) = 90
(b) = 00
(c) = 90
N
SI
(d) 180
So, (b) is stable equilibrium
& (d) is unstable
OO
22. An inductor (L = 0.03H) and a resistor (R = 0.15 k) are connected in series to a battery
of 15V EMF in a circuit shown below. The key K1 has been kept closed for a long time.
Then at t = 0, K1 is opened and key K2 is closed simultaneously. At t = 1ms, is closed in
the circuit will be e5 150
0.03H 0.15k
ET
K2
K1
15V
(1) 100 mA (2) 67 mA (3) 6.7 mA (4) 0.67 mA
Key: (4)
Sol. At t= when K1 is closed
15 1
I0 A.
150 10
When K1 is opened & K2 is closed.
L 0.03
I I 0 e t / & 3
2 104
R 0.15 10
103
1 4
I e 210
10
1 5
e
10
1
e 5 0.67mA
10
23. A red LED emits light at 0.1 watt uniformly around it. The amplitude of the electric field
of the light at a distance of 1m from the diode is:
A
(1) 1.73 V/m (2) 2.45 V/m (3) 5.48 V/m (4) 7.75 V/m
Key: (2)
1
Sol. P 0 E02 A C
DI
2
1
P 0 E02 A C
2
12
2 0.1
N
8.85 10 4 12 3 108
2.45 V / m
SI
24. Monochromatic light is incident on a glass prism of angle A. If the refractive index of the
material of the prism is , a ray, incident at an angle , on the face AB would get
transmitted through the face AC of the prism provided:
OO
A
B C
ET
1 1
(1) sin 1 sin A sin 1 (2) sin 1 sin A sin 1
1 1
(3) cos 1 sin A sin 1 (4) cos 1 sin A sin 1
Key: (1)
Sol.
A
r1 c
A r1 C
r1 A C
Using snell’s law on first face
sin sin r1
sin A C
A
1
sin A sin 1
DI
1
sin 1 sin A sin 1
For transmission through face AC
N 1
sin 1 sin A sin 1
SI
25. On a hot summer night, the refractive index of air smallest near the ground and increases
with height from the ground. When a light beam is directed horizontally, the Huygen’s
principle leads us to conclude that as it travels, the light beam:
OO
26. Assuming human pupil to have a radius of 0.25 cm and a comfortable viewing distance of
25 cm, the minimum separation between two objects that human eye can resolve at 500
ET
nm wavelength is:
(1) 1 m (2) 30 m (3) 100 m (4) 300 m
Key: (2)
1.22 y
Sol.
d D
1.22 500 109 y
2
0.50 10 25 102
y 30.50 106 m
30 m
27. As an electron makes a transition from an excited state to the ground state of a hydrogen-
like atom/ion:
(1) its kinetic energy increases but potential energy and total energy decrease
(2) kinetic energy, potential energy and total energy decrease
(3) kinetic energy decreases, potential energy increases but total energy remains same
(4) kinetic energy and total energy decrease but potential energy increase
Key: (1)
kZe2
Sol. KE
2r
kZe 2
PE
r
kZe 2
A
TE
2r
DI
28. Match List-I (Fundamental Experiment) with List-II (its conclusion) and select the
correct option from the choices given below the list:
List-I N
(A) Franck-Herts Experiment.
(B) Photo-electric experiment
List-II
(i) Particle nature
(ii) Discrete energy levels of atom
SI
(C) Davision-Germer Experiment. (iii) Wave nature of electron
(iv) Structure of atom
(1) (A) – (i) (B) – (iv) (C)-(iii)
OO
30. An LCR circuit is equivalent to a damped pendulum. In an LCR circuit the capacitor is
charged to Q0 and then connected the L and R as shown below:
R L
A
L2 L1
t t
2 2
Q Q
DI
Max Max
L1 Q0 (For both L 1 and L 2)
(3) L2 (4)
t t
Key. (1)
Sol:
q
C
IR L
q dq
dI
dt
0
dI
N
SI
R L
C dt dt
Comparing with equation of damped oscillation
R
OO
Fdamp bv
L
R
Hence, b
L
1
b
L
b
t
ET
2m
As A A0 e
b
t
2m
Q Q0 e
b
t
2 2 m
Q Q e 0
CHEMISTRY
31. The molecular formula of a commercial resin used for exchanging ions in water softening
is C8H7SO3Na (Mol.wt.206). What would be the maximum uptake of Ca2+ ions by the
resin when expressed in mole per gram resin?
1 1 2 1
(1) (2) (3) (4)
103 206 309 412
Key. (4)
Sol. Na+ ion of resin will be exchanged with Ca2+ ion
2C8 H 7SO3 Na Ca 2 C8 H 7SO3 2 Ca 2Na
1 1
So maximum uptake of Ca2+ ion by the resin molg 1 of resin.
206 2 412
A
o
32. Sodium metal crystallizes in a body centered cubic lattice with a unit cell edge of 4.29 A .
The radius of sodium atom is approximately :
DI
o o o o
(1) 1.86 A (2) 3.22 A (3) 5.72 A (4) 0.93 A
Key. (1)
Sol. For B.c.c. unit cell
4r 3a
33.
r
3 4.29
4
o
1.86 A
N
Which of the following is the energy of a possible excited state of hydrogen?
SI
(1) 13.6 eV (2) 6.8 eV (3) 3.4 eV (4) 6.8 eV
Key. (3)
13.6 12
OO
34. The intermolecular interaction that is dependent on the inverse cube of distance between
the molecules is
(1) ion – ion interaction (2) ion – dipole interaction
(3) London force (4) hydrogen bond
ET
Key. (4)
Sol. Dipole –dipole interaction energy between stationary polar molecules (as in solids) is
1
proportional to 3 .
r
Hydrogen bond is a special case of dipole-dipole interactions.
A
substance was dissolved in 100 g of acetone at 20oC, its vapour pressure was 183 torr.
The molar mass (g mol-1) of the substance is
(1) 32 (2) 64 (3) 128 (4) 488
DI
Key. (2)
Po P5
Sol. X solute
P0
1.2
185 183
P o
1.2
M 58
M
100
N
SI
2 1.2 58 1.2 100
Assume
185 M 100 M 58
1.2
M 64.38
OO
2 100
37. The standard Gibbs energy change at 300 K for the reaction 2A B C is 2494.2 J.
1 1
At a given time, the composition of the reaction mixture is A , B 2 and C .
2 2
The reaction proceeds in the : [ R = 8.314 J/K/mol, e = 2.718]
(1) forward direction because Q > KC (2) reverse direction because Q > Kc
ET
(3) forward direction because Q < Kc (4) reverse direction because Q < Kc
Key. (2)
Sol. G o RT ln K c
2494.2 8.314 300ln Kc
ln Kc 1
1 1
K c e 1 =
e 2.718
Qc
B C
A2
1
2
2 4
2
1
2
Reverse direction as Qc > Kc
38. Two Faraday of electricity is passed through a solution of CuSO4. The mass of copper
deposited at the cathode is : (at.mass of Cu = 63.5 amu)
(1) 0 g (2) 63.5 g (3) 2 g (4) 127 g
Key. (2)
Sol. 1 Faraday of electricity deposits 1 equivalent Cu
2 Faraday of electricity deposits 2 equivalents of Cu
1 mol of Cu = 63.5 g
A
39. Higher order (>3) reactions are rare due to
(1) low probability of simultaneous collision of all the reacting species
(2) increase in entropy and activation energy as more molecules are involved
DI
(3) shifting of equilibrium towards reactants due to elastic collisions
(4) loss of active species on collision
Key. (1)
Sol. Higher order (>3) reactions are rare due to low probability of simultaneous collision of all
40.
the reacting species.
N
3 g of activated charcoal was added to 50 ml. of acetic acid solution (0.06 N) in a flask.
After an hour it was filtered and the strength of the filtrate was found to be 0.042 N. The
SI
amount of acetic acid adsorbed (per gram of charcoal) is
(1) 18 mg (2) 36 mg (3) 42 mg (4) 54 mg
Key. (1)
Sol. No. of millimols of acetic acid before adsorption = 50 0.06 3
OO
41. The ionic radii (in Å) of N3, O2 and F are respectively
(1) 1.36, 1.40 and 1.71 (2) 1.36, 1.71 and 1.40
(3) 1.71, 1.40 and 1.36 (4) 1.71, 1.36 and 1.40
Key: (3)
Sol: N 3 O 2 F
As the charge increase on anion its size increases due to decrease in Zeff.
42. In the context of the Hall – Heroult process for the extraction of Al, which of the
following statements is false?
(1) CO and CO2 are produced in this process
(2) Al2O3 is mixed with CaF2 which lowers the melting point of the mixture and brings
conductivity
(3) Al3+ is reduced at the cathode to form Al
(4) Na3AlF6 serves as the electrolyte
Key: (4)
Sol: CaF2 or Na3AlF6 reduce melting point and increase the conductivity.
43. From the following statements regarding H2O2, choose the incorrect statement:
(1) It can act only as an oxidizing agent
(2) It decomposes an exposure to light
(3) It has to be stored in plastic or wax lined glass bottle in dark
(4) It has to be kept away from dust
Key: (1)
Sol: It act as both OA/RA due to intermediate OS of oxygen.
A
44. Which one of the following alkaline earth metal sulphates has its hydration enthalpy
greater than its lattice enthalpy?
DI
(1) CaSO4 (2) BeSO4 (3) BaSO4 (4) SrSO4
Key: (2)
Sol: BeSO4 soluble in water, the hydration energy greater than its lattice energy.
Key:
Sol:
(1) Cl2
(4)
N
(2) Br2 (3) I2 (4) ICl
Inter Halogen compounds are more reactive due to improper overlapping than halogen.
SI
46. Match the catalysts to the correct process:
Catalyst Process
(A) TiCl3 (i) Wacker process
OO
48. The number of geometric isomers that can exist for square planar
[Pt(Cl)(py)(NH3)(NH2OH)]+ is (py – pyridine)
(1) 1 (2) 3 (3) 4 (4) 6
Key: (2)
Sol: planar [Pt(Cl)(py)(NH3)(NH2OH)]
Cl NH3 Cl Py Cl Py
Pt Pt Pt
A
(3) L M charge transfer transition
(4) - * transition
Key: (3)
DI
Sol: MnO 4
O
O
O Mn
O
N
SI
Color is due to charge transfer from oxide ion to empty ‘d’ orbital of Mn.
50. Assertion : Nitrogen and Oxygen are the main components in the atmosphere but
these do not react to form oxides of nitrogen.
OO
Reason: The reaction between nitrogen and oxygen requires high temperature.
(1) Both assertion and reason are correct, and the reason is the correct explanation for the
assertion
(2) Both assertion and reason are correct, but the reason is not the correct explanation for
the assertion.
(3) The assertion is incorrect, but the reason is correct.
(4) Both the assertion and reason are incorrect
ET
Key: (1)
Sol: The bond enthalpy of N2 is much higher hence the process is endothermic.
N2 + O2 2NO - Heat
51. In Carius method of estimation of halogen, 250 mg of an organic compound gave 141 mg
of AgBr. The percentage of bromine in the compound is: (at. Mass Ag = 108, Br = 80)
(1) 24 (2) 36 (3) 48 (4) 60
Key (1)
Sol. Mass of AgBr precipitated 0.141 g
80 0.141
% of Br = 100 24
188 0.250
52. Which of the following compounds will exhibit geometrical isomerism?
(1) 1 – Phenyl – 2 – butene (2) 3 – Phenyl – 1 – butene
(3) 2 – Phenyl – 1 – butene (4) 1, 1, - Diphenyl – 1 – propene
Key (1)
PhCH2 CH3 PhCH2 H
Sol. C=C C=C
H H H CH3
Geometrical Isomers
53. Which compound would give 5 – keto – 2 – methyl hexanal upon ozonolysis?
CH3 CH3
CH3 CH3
CH3 H3C
A
(1) (2) (3) (4)
CH3 CH3
Key (2)
DI
CH3
O
ozonolysis
H3 C – C– CH2CH2 – CH –CHO
Sol.
CH3
N CH3
5 - keto - 2 methyl - hexanal
SI
54. The synthesis of alkyl fluorides is best accomplished by :
(1) Free radical fluorination (2) Sandmeyer’s reaction
(3) Finkelstein reaction (4) Swarts reaction
OO
Key (4)
Swart
Sol. H3C Br AgF reaction
CH 3 F AgBr
55. In the following sequence of reaction :
KMnO4 SOCl2 H 2 / Pd
Toluene A B
BaSO 4
C
The product C is
(1) C6H5COOH (2) C6H5CH3 (3) C6H5CH2OH (4) C6H5CHO
ET
Key (4)
O
CH3 COOH C – Cl CHO
(A) (B)
56. In the reaction
NH2
CH3
The product E is
COOH
H3 C CH3
(1) (2)
A
CH3
CN
DI
CH3
(3) (4)
Key (3)
CH3
NH2
N
N2 Cl CN
SI
NaNO2/HCl CuCN/ K CN
N2 +
Sol. 0-5°C
OO
A
N DI
SI
OO
ET
MATHEMATICS
61. Let A and B be two sets containing four and two elements respectively. Then the number
of subsets of the set A B , each having at least three elements is :
(1) 219 (2) 256 (3) 275 (4) 510
Key. (1)
Sol. No. of elements in A B will be 4 2 8
Now no. of subsets of A B having at least 3 elements is
8
C3 8C4 8C5 .... 8C8 28 1 8 28
256 37 219
62. A complex number z is said to be unimodular if z 1 . Suppose z1 and z2 are complex
A
z1 2z 2
numbers such that is unimodular and z2 is not unimodular. Then the point of z1
2 z1 z2
DI
lies on a
(1) straight line parallel to x-axis (2) straight line parallel to y-axis
(3) circle of radius 2 (4) circle of radius 2
Key. (3)
Sol.
z1 2z 2
2 z1 z2
1
2
z1 2z 2 2 z1 z2
N2
SI
z1 2z 2 z1 2z2 2 z1 z2 2 z1z 2
z1 z1 2z1 z2 2z1z2 4z2 z2 = 4 2z1z 2 2z1 z2 z1 z1z2 z2
OO
2 2 2 2
z1 4 z 2 4 z1 z 2
2 2 2 2
z1 z 2 z1 4 z 2 4 0
z 1
2
4 z 2
2
1 0
z1 2 or z2 1
But z 2 1 z1 2
ET
A
Put n = 10
a 2a 8
10 3
DI
2a 9
1 2 2
64. If A 2 1 2 is a matrix satisfying the equation AA T 9I , where I is 3 3 identity
a 2 b
Key.
(1) (2, –1)
(4)
N
matrix, then the ordered pair (a,b) is equal to
(2) (–2, 1) (3) (2, 1) (4) (–2, –1)
SI
1 2 2
Sol. A 2 1 2
a 2 b
OO
1 2 a
A 2 1 2
T
2 2 b
1 2 2 1 2 a
A.A 2 1 2 2 1 2
T
ET
a 2 b 2 2 b
9 0 a 4 2b
0 9 2a 2 2b 9I
a 4 2b 2a 2 2b a 2 4 b2
a 4 2b 0 … (1) and 2a 2 2b 0 … (2)
Solving (1) and (2) a 2, b 1
65. The set of all values of for which the system of linear equations
2x1 2x 2 x 3 x1
2x1 3x 2 2x3 x 2
x1 2x 2 x3
has a non-trivial solution,
(1) is an empty set
(2) is a singleton
(3) contains two elements
(4) contains more than two elements
Key. (3)
Sol. Rewrite the equation
2 x1 2x 2 x 3 0
2x1 3 x 2 2x 3 0
x1 2x 2 x3 0
A
For non trivial solution
2 2 1
DI
2 3 2 0
1 2
1 2 2 3 0
1 3 1 0 1, 3
66.
N
The number of integers greater than 6,000 that can be formed, using the digits 3, 5, 6 7
and 8, without repetition, is :
SI
(1) 216 (2) 192 (3) 120 (4) 72
Key. (2)
Sol. Case (i) number of ‘4’ digit numbers will be 3 4 3 2 72
Case (ii) number of ‘5’ digit numbers will be 5! 120
OO
Sol. Let x y
50
1 2y a 0 a1 y a 2 y2 a 3 y3 a 4 y 4 ....
Put y = 1
1 a 0 a1 a 2 a 3 a 4 ....
… (1)
Put y = –1
350 a 0 a1 a 2 a 3 a 4 ....
… (2)
Adding (1) and (2)
350 1
a 0 a 2 a 4 ....
2
68. If m is the A.M. of two distinct real numbers and n ( , n > 1) and G1,G2 and G3 are
three geometric means between and n, then G14 2G 24 G 34 equals.
(1) 4 2mm (2) 4m 2 n (3) 4 mn2 (4) 4 2m2 n2
Key. (2)
n
Sol. m n 2m
2
,G1 ,G 2 ,G 3 , n are in G.P
Let common difference be r
1/4
n
A
n .r r
4
1/ 4
n
G1 . 3/ 4 .n1/ 4
DI
G2 n
1/ 2 1/ 2
G 3 1/ 4 .n 3/ 4
Then G14 2G 24 G 34
3n 2 2 n 2 n 3
n 2 2 n n 2
N
SI
2
n n 4m 2 n
13 13 23 13 23 33
69. The sum of first 9 terms of the series .... is
OO
1 1 3 1 3 5
(1) 71 (2) 96 (3) 142 (4) 192
Key. (2)
3
n n 2 n 1
2
Sol. Tn
n2 4.n 2
2
ET
n 1
4
n 2 1 2n
Tn
4
1
n 2 2n 1
4
1
Sn Tn n 2 2 n n
4
1 n n 1 2n 1 n n 1
2 n
4 6 2
1 9 10 19 9 10
S9 2 9
4 6 2
1
15 19 9 10 9 96
4
70. lim
1 cos 2x 3 cos x is equal to
x 0 x tan 4x
1
(1) 4 (2) 3 (3) 2 (4)
2
Key. (3)
lim
1 cos 2x 3 cos x
Sol. x 0 x tan 4x
A
2
2 sin x 3 cos x
Lt
x 0 tan 4x
x2 .4
DI
4x
2
4 2
4
k x 1, 0 x 3
71. If the function : g x
(1) 2 (2)
N
mx 2, 3 x 5
16
, is differentiable, then the value of k + m is
(3)
10
(4) 4
SI
5 3
Key: (1)
Sol: g(x) is continuous at x = 3
k 3 1 = 3m + 2
OO
2k = 3m + 2 (1)
for g(x) to be differentiable,
g ' 3 g ' 3
k
m k = 4m (2)
4
ET
A
73. Let f(x) be a polynomial of degree four having extreme values at x = 1 and x = 2. If
f x
lim 1 2 3, then f(2) is equal to
DI
x 0
x
(1) 8 (2) 4 (3) 0 (4) 4
Key: (3)
Sol: Let f(x) = ax4 + bx3 + cx2
f(1) = 0 4a + 3b + 2c = 0
f(2) = 0 32a + 12b + 4c = 0
f x
lim 1 2 = 3
N (1)
(2)
SI
x 0
x
c=2 (3)
By using (1), (2) and (3),
OO
a = 1/2, b = 2 and c = 2.
x4
Hence, f(x) = 2x 3 2x 2
2
f(2) = 0
dx
74. The integral x equals
ET
3/4
2
x 4
1
1/4
x4 1 1/4
(1) 4 C (2) x 4 1 C
x
1/4
1/ 4 x4 1
(3) x 1 4
C (4) 4 C
x
Key: (4)
dx dx
Sol: x 3/ 4
3/ 4
2
x 2
1 1
x 5 1 4
x
1
Put, 1 + =t , 4x 5 dx dt ,
x4
1/4
1
1/4
x 4 1
I = 1 4 C
x x
(4) is correct.
4
log x 2
75. The integral dx is equal to
2 log x log 36 12x x
2 2
A
Sol: I (1)
2 log x 2 log 36 12x x 2
4
log 6 x
2
DI
I (2)
2 2
log 6 x log x 2
4
Adding (1) and (2), 2I = dx
2I = 2 I = 1
Option (3) is correct
N2
SI
76. The area (in sq. units) of the region described by
{(x, y): y2 2x and y 4x – 1} is
7 5 15 9
(1) (2) (3) (4)
OO
32 64 64 32
Key: (4)
Sol: y2 = 2x, y = 4x – 1
2y2 = y + 1
2y2 – y – 1 = 0
y = 1, y = 1/2
x = ½, x = 1/8
ET
1 1
y 1 y2 y 2 y y3
Area = dy =
1/2
4 2 8 4 6 1/2
9
32
dy
77. Let y(x) be the solution of the differential equation x log x y 2x log x, x 1 .
dx
then y(e) is equal to
(1) e (2) 0 (3) 2 (4) 2e
Key: (3)
dy 1
Sol: y2
dx x log x
1
x log x dx log log x
I. F. = e e log x
Solving, y log x 2.log x.dx 2 log x x x C
y. log x = 2(log x – 1)x + C, since C = 2 y (e) = 2
78. The number of points, having both co-ordinates as integers, that lie in the interior of the
triangle with vertices (0, 0), (0, 41) and (41, 0) is
(1) 901 (2) 861 (3) 820 (4) 780
Key: (4)
Number of points = 39 + 38 + (0, 41)
A
37 + ….+ 1 (1, 40)
39 40
= 780
2 (1, 39)
DI
(40, 1)
(1, 1)
(0, 0) (1, 0) (40, 0) (41, 0)
79.
N
Locus of the image of the point (2, 3) in the line (2x – 3y + 4) + k(x – 2y + 3) = 0, k R ,
SI
is a
(1) straight line parallel to x-axis (2) straight line parallel to y-axis
(3) circle of radius 2 (4) circle of radius 3
OO
Key: (3)
Sol: The point of concurrency of the given family of lines is (1, 2)
So, therefore the locus of the image of the point (2, 3) in the line
(2x – 3y + 4) + k(x – 2y + 3) = 0 will be a circle; whose centre is (1, 2) and radius is
distance between (1, 2) and (2, 3).
Hence the equation of the required locus will be (x – 1)2 + (y – 2)2 = 2.
80. The number of common tangents to the circles x2 + y2 – 4x – 6y – 12 = 0 and
ET
x2 + y2 + 6x + 18y + 26 = 0, is
(1) 1 (2) 2 (3) 3 (4) 4
Key: (3)
Sol: Given circles are
x2 + y2 – 4x – 6y – 12 = 0 (1)
2 2
and x + y + 6x + 18y + 26 = 0 (2)
C1 = (2, 3); r1 = 4 9 12 5
C2 = (3, 9); r2 = 9 81 26 64 8
C1C2 = 25 144 13
C1C2 = r1 + r2
Circles touch externally each other, hence number of common tangent are three.
81. The area (in sq. units ) of the quadrilateral formed by the tangents at the end points of the
x 2 y2
latera recta to the ellipse 1 , is:
9 5
27 27
(1) (2)18 (3) (4)27
4 2
Key (4)
2x y
Sol. Eq. of tangent at (2, 5/3) is 1
9 3
(0,3)
(2, 5/3)
A
(9/2, 0)
N DI
1 9
Area 4 3 27 sq.units
2 2
SI
82. Let O be the vertex and Q be any point on the parabola, x 2 8y . If the point P divides
the line segment OQ internally in the ratio 1:3, then the locus of P is:
(1) x 2 y (2) y2 x (3) y2 2x (4) x 2 2y
OO
Key (4)
Sol. Let P h, k
2
.t 3 0 x =8y
h t = 4h …(1)
4
t2
. 3 0 Q(t, t2 /8)
k 8 t2 = 32k …(2) 1:3
ET
4 P
Eliminating t, we get
x 2 2y O
83. The distance of the point (1,0,2) from the point of intersection of the line
x 2 y 1 z 2
and the plane x-y+z=16, is:
3 4 12
(1) 2 14 (2)8 (3) 3 21 (4) 13
Key (4)
Sol. Let point of intersection 3t 2, 4t 1,12t 2
3t 2 4t 1 12t 2 16
t=1
Point of intersection (5,3,14)
2 2 2
distance 5 1 3 0 14 2
=13
84. The equation of the plane containing the line 2x-5y+z=3; x+y+4z=5, and parallel to the
plane, x+3y+6z=1, is :
(1) 2x 6y 12z 13 (2) x 3y 6z 7
(3) x 3y 6z 7 (4) 2x 6y 12z 13
A
Key (3)
Sol. Required plane is 2x 5y z 3 x y 4z 5 0
Or
DI
x 2 y 5 z 4 1 3 5 0 ……..(i)
x 3y 6z 1 0 ………..(ii)
As (i)and (ii) are parallel
2 5 4 1
1
11
3
6N
SI
2
Required plane is
x+3y+6z=7
85. Let a , b and c be three non-zero vectors such that no two of them are collinear and
OO
1
a b c b c a. If is the angle between vectors b and c , then a value of sin is:
3
2 2 2 2 2 3
(1) (2) (3) (4)
3 3 3 3
Key (1)
1
c.b a c.a b b c a
ET
Sol.
3
1
c.b b c
3
and c.b 0
1
cos
3
2 2
sin
3
86. If 12 identical balls are to be placed in 3 identical boxes, then the probability that one of
the boxes contains exactly 3 balls is :
11 10 12 11
55 2 2 1 1
(1) (2) 55 (3) 220 (4) 22
3 3 3 3 3
Key (1)
Sol. Required probability
12C3 29
312
11
12 11 10 29 55 2
6 312 3 3
87. The mean of the data set comprising of 16 observations is 16.if one of the observation
valued 16 is deleted and three new observations valued 3, 4 and 5 are added to the data,
then the mean of the resultant data, is:
A
(1) 16.8 (2)16.0 (3)15.8 (4)14.0
Key (4)
16
DI
xi
i 1
Sol. 16
16
16
xi 256
i 1
16
N 252
x i 16 3 4 5 252
18
=14
SI
i 1
88. If the angles of elevation of the top of a tower from three collinear points A,B and C, on
a line leading to the foot of the tower, are 30 0 , 450 and 60 0 respectively, then the ratio is,
AB:BC, is :
OO
x
tan 30o x 3 AC y
y AC
3x y AB BC ….(3)
y 3 BC y
BC y 3 1 …(4)
3 y 3 y AB BC
N
A
AB 2 3 1 3 1
2 3 2 3 3 3 1 3
BC 3 1 3 1
DI
2x 1
89. Let tan 1 y tan 1 x tan 1 2
,where x .Then a value of y is :
1 x 3
3x x 3 3x x 3 3x x 3 3x x 3
(1) (2) (3) (4)
Key
Sol.
(1)
1 3x 2 N 1 3x 2
T F T F F T F `F
F T F T T T F F
F F T T F T F F