Hydrogen bond - attraction between a covalently bound
hydrogen atom to covalently bound electronegative atom (O, N, F, Cl). This amazing fact has not yet found an unambiguous explanation. Of course, water plays a huge role in the origin and existence of life on our planet. This is largely due to properties that its closest neighbors and analogues do not have. First of all, you need to understand why water can be in a liquid and even in a solid state under conditions in which similar compounds of hydrogen with heavier elements are gaseous. A hydrogen bond requires two polar covalent bonds, of which one involves a hydrogen atom bearing an effective positive charge, and another – an electronegative atom (oxygen, nitrogen, halogen) with an effective negative charge. Normally, the hydrogen bonds play a crucial role in the intermolecular interaction, although there are numerous examples of intramolecular hydrogen bonds (e.g. in proteins). The hydrogen bond is a key interaction in supramolecular chemistry. It defines the structure of proteins, DNA double helix, water and ice, supramolecular assemblies and polymers, and influences the properties of many solutions. For the formation of hydrogen bonds, it is important that the molecules of the substance contain hydrogen atoms associated with small but electronegative atoms, for example: O, N, F. This creates a noticeable partial positive charge on the hydrogen atoms. On the other hand, it is important that electronegative atoms have lone pairs. When the electron-depleted hydrogen atom of one molecule (acceptor) interacts with the lone electron pair on the N, O, or F atom of another molecule (donor), a bond appears similar to a polar covalent bond. The energy of a hydrogen bond varies within a wide range from 5 to 100 kJ / mol, but usually a hydrogen bond is much weaker than a covalent bond Depending on the energy, the hydrogen bond has a different character: from purely electrostatic (weak bond) to predominantly covalent (strong bond). References: