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Study of Machinability Aspects of SMA
Study of Machinability Aspects of SMA
a r t i c l e i n f o a b s t r a c t
Article history: Memory metals or memory alloys or smart metals are those alloys which get deformed when cold and
Received 28 September 2020 returns to their preformed shape when subjected to heating. Their exquisite properties make these alloys
Received in revised form 15 October 2020 an ideal material for several engineering applications. The recent developments in these materials have
Accepted 14 November 2020
attracted the interest of the scientific community. In this context, an attempt has been made to provide
Available online 30 December 2020
an overview of the shape memory alloys (SMAs) along with their deformation mechanism. The study fur-
ther explores the classifications and advantages of different shape memory alloys. Various machining
Keywords:
processes adopted for machining shape memory alloys as well as the making of these alloys have been
Shape memory alloy
Smart metal
also articulated in this review. Besides all these, a light has been also thrown on the significant charac-
SMAs teristics of these materials in addition to their applications in automobile, aerospace, robotic, and
Unconventional process biomedical fields.
Shape memory polymers Ó 2021 Elsevier Ltd. All rights reserved.
Selection and peer-review under responsibility of the scientific committee of the International Confer-
ence on Materials, Processing & Characterization.
https://doi.org/10.1016/j.matpr.2020.11.390
2214-7853/Ó 2021 Elsevier Ltd. All rights reserved.
Selection and peer-review under responsibility of the scientific committee of the International Conference on Materials, Processing & Characterization.
S. Kumari, Dinbandhu and K. Abhishek Materials Today: Proceedings 44 (2021) 1336–1343
densities. When an SMA undergoes a cooling process, the transfor- which is more reliable, powerful, and is used extensively in
mation tends to reverse to the martensite which is termed as many engineering areas. The difference of transition tempera-
martensite start-temperature (Ms), and completes when it reaches tures between heating and cooling can be measured by Hystere-
to martensite-finish-temperature (Mf). Md is termed as the highest sis (i.e. DT = Af Ms), which can be usually defined between the
temperature at which no further stress can be induced into temperatures at which the material transforms 50% to marten-
martensite, and above this peak temperature, an SMA starts deforming site on cooling and transforms 50% to austenite on heating. For a
to the plastic deformation stage like other metallic material [38]. specific technical application, selection of SMA material
Super elasticity (or pseudoelasticity) and SME which are termed depends on the hysteresis property and requires careful consid-
as shape change effects, can be classified further into three shape eration, for instance, within a large temperature range, a
memory characteristics as follows: requirement of large hysteresis is a must, to regain the prede-
fined shape (such as in pipe joining and deployable structures)
OWSME (One-way shape memory effect): In one-way when an [8] and whereas for fast actuation applications, a small hystere-
external load is applied it undergoes the deformation and its sis is required (such as robotics and MEMSs).
original state is retained upon releasing the applied load subse-
quently heating it. 1.1. Deformation mechanism
Reversible SME or TWSME (Two-way shape memory effect):
When an SMA has the tendency to reverse to its pre deforma- High stresses are applied to the material in almost all the man-
tion state or has the tendency to regain its original shape at both ufacturing processes. The complete process may consist of a com-
low and high temperatures, then an SMA is considered to have bination of many different loading types and for this reason, shear
the tendency of TWSME. Although, TWSMA is less viable com- and tension mechanisms are described below. The most common
mercially as for the same material [5] it produces nearly half loading that is applied to the material is tension; in this type of
of the recovery strain in contrast OWSMA also at high temper- loading, the material is loaded axially subsequently the stress gen-
atures strain tends to deteriorate quickly [6]. Therefore, a reli- erated is distributed uniformly inside that material. However, the
able and economical solution is provided by OWSMA [7]. material moves in a fairly low range. It is to be noted, that in this
Super elasticity (SE) or Pseudo elasticity (PE): When the orig- mode of loading, the normal stress comes out to be directly propor-
inal shape of an SMA is regained by loading the SMA component tional to the applied load. A dominant mechanism that occurs dur-
mechanically at a temperature between Af and Md, then shape ing the machining of a component is the Shearing. Various studies
change effect is termed as Super elasticity. At a macroscopic have been performed to research the effects caused by the shear
(structural) level, besides the ‘material TWSME’ as mentioned mechanism to superelasticity and shape memory effect of the
above, an OWSMA actuator acts as a ‘mechanical TWSME’; SMA materials. The cause of difficulty in studying the various
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S. Kumari, Dinbandhu and K. Abhishek Materials Today: Proceedings 44 (2021) 1336–1343
Fig. 2. Maximum bandwidth versus specific energy and maximum strain for different classes of active materials [1].
Table 1
HTSMA groups and their properties [11,14,15].
Table 2
Comparing the properties of SMA and SMP [1,48].
Manufacturing of Shape memory polymers (SMPs) is relatively The term machining means the removal of unwanted material
easier. In comparison to SMAs, SMPs are considered a better alter- from the workpiece to give it the desired shape with the help of
native because of their lower cost approximately 10% cheaper. a tool called a cutting tool. Unwanted material from the workpiece
Besides, SMPs are biodegradable, possess better efficiency, and is removed in form of chips. Chips are formed due to strain harden-
superior to SMAs in terms of mechanical properties (see Table 2). ing of the metal when a wedge-shaped tool makes a contact with
When triggered by either by heating [18] or by cooling [19], mag- the workpiece provided there should be relative movement
netic field [20], electricity [21], light [22], or water [23,24] SMPs between tool and workpiece. Such processes are usually referred
can sustain two or more shape changes [25,26]. Table 2 summa- to as conventional machining processes which include turning,
rized some of the characteristics of SMPs. milling and drilling, etc. Another very well-known process called
SME has three working mechanisms in polymeric materials: grinding, in which cutting takes place by abrasive action, carries
Dual-component mechanism (DCM), Partial-transition mechanism a lot of weightage in the conventional machining industry. Other
(PTM), and Dual-state mechanism [18]. The almost 100% recovery non-conventional machining operations like electro-discharge
precision of SMPs, makes it suitable for engineering applications machining, water jet machining, laser machining, and electro-
which are high in demand [27]. Depending on the composition of chemical machining that do not have physical contact between
the material used, the SME of SMPs varies, i.e. the molecular the workpiece and cutting tool and that do not have a cutting tool
weight of the polymer-chain employed and weight fraction of as possessed by the conventional processes, such processes utilize
the switching segments. SMPs offer advantages because of their chemical or thermal energy for machining. Due to work hardening
biodegradable nature and hence SMPs offer more economical and or strain hardening, it is quite a difficult task to achieve quality and
effective treatments. cost goals. One of the most common issues that need to be dealt
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S. Kumari, Dinbandhu and K. Abhishek Materials Today: Proceedings 44 (2021) 1336–1343
with, while machining using non-conventional methods is of small the ultrashort laser pulses, though, it performs better than other
material removal rates besides high tool wear. Therefore, consider- lasers. Huang, Zheng, and Lim [31] investigated the femtosecond
ing the importance of machining in the Engineering world, the fol- laser machinability of NiTi. In comparison to Nd: YAG laser
lowing paragraphs describe the conventional and non- machining, it was found that the heat-affected layer and a re-
conventional machining processes which SMAs can be subjected deposition layer were quite thinner when machining was carried
to. Aspects associated with the machining process like cutting out by femtosecond laser. Biffi and Tuissi investigated the laser
tools, feed, and cutting conditions are considered, investigated drilling of ferromagnetic [32] and they summarized that the laser
and thus results are presented. machining of micro-features can be carried out with limited
restriction.
3.1. Conventional machining
4. Making of shape memory alloys
Considering the importance and wide variety of applications of
Nitinol, conventional machining of SMAs is mainly conducted on Various ways of producing shape memory alloys have been dis-
NiTi or alloys of NiTi, this causes the study to be focused mainly cussed as follows:
on these materials. To gain an insight into the machinability char-
acteristics of Nickel and Titanium alloys one needs to have a very
4.1. Melting
sound knowledge of the phenomena that take place during
machining i.e. machining of high strength alloys at elevated tem-
Vacuum melting is one of the most significant methods by
peratures, which results in a rise in temperatures at the tool-chip
which SMA can be produced. Not only vacuum melting but also
interface, workpiece distortions, rapid tool wear and high dynamic
other techniques like which can be adopted to produce SMA are
loads [12]. Apart from Titanium alloys, Nickel based alloys and
plasma melting and electron beam melting. Electromagnetic
Super-alloys, are also considered alloys which are hard to machine
induction is the principle on which Vacuum induction melting
and possess very high strength. Various cutting tools like uncoated
works, in this process, electrical eddy currents are induced in the
and coated cemented carbide, ceramic inserts, and cubic boron
metallic charges and the graphite crucible. Melt is stirred and
nitride were investigated. The research’s summarized as extensive
mixed by the adoption of electrodynamic force. Electro graphite
tool wear was found in the case of uncoated cemented carbide,
crucible is used in SMA to achieve low carbon concentrations
while reduced wear was found in the case of coated cemented car-
[33]. A low viscosity electron beam comes out from a hollow
bide tools. Regardless of the cutting parameters, machining of NiTi
plasma cathode in the plasma melting method. The chief benefit
alloys was not possible by ceramic cutting tools because of its inca-
offered by this method is the drastic reduction in the loss of the
pability to do so. It was also observed that the tool wear was higher
alloy element.
in CBN as compare to coated cemented carbide tools. Moreover,
CBN tools are not preferable because of its cost. In contrast to what
is recommended by the relevant literature, it was observed that 4.2. Heat treating
coated cemented carbide tools can be used to machine NiTi that
too at higher cutting speeds. Improvement in the surface finish is Optimized properties of NiTi samples can be achieved by cold
observed at cutting speed of 110 m/min and tool wear was working of the samples, before heat treatment. For superelastic
reduced. Formation of burrs and the effects of cutting fluids on chip nitinol, the heat treatment process is carried out at 500 °C temper-
breaking and was discussed by Weinert and Petzoldt [28]. Guo ature, in the case of shape memory alloys, the range of temperature
et al. [29] studied the milling of a NiTi alloy which has got its usage at which heat treatment is carried out is between 350 °C and
in the field of biomedical. (50.8 at. % Ni–49.2 at% Ti). Split- 450 °C. The addition of Nickel at a composition of 55.5(wt. %)
Hopkinson pressure bar compression tests were conducted by enhances its unique properties like pseudoelasticity and SME.
these researchers to evaluate the mechanical properties of the Enhancement in its unique properties at high temperatures can
material. It was observed from the test that in comparison to Ti be achieved by solution treatment. Transformation temperature
or Ni-based superalloys, NiTi is more difficult to be machined is increased by varying the composition of the matrix.
because of the high strength possessed by the material under static
and dynamic loading conditions. 4.3. Powder metallurgy
3.2. Non-conventional machining An efficient way of producing net shape components of NiTi
alloys is Powder Metallurgy. Grain refinement is targeted to
It is also known as the Unconventional machining process, in enhance the fatigue properties of copper-based shape memory
this category of machining processes, machining takes place with- alloys. Two types of powder metallurgy techniques which are in
out physical contact between the tool and the workpiece. Thus, in practice mostly for the preparation of NiTi alloys are alloy powder
these processes tool wear is minimized drastically, or in some sintering and raw metal powder sintering. For producing NiTi alloy,
cases, it is diminished. Non-conventional processes are being used various powder metallurgy techniques have been developed where
in machining SMA, where components to be machined have very both pre-alloyed powders and elemental powders are used as ini-
small dimensions. Most of the non-conventional machining pro- tial materials by hot isostatic pressing (HIP), pulverization [34],
cesses are carried out by (EDM) electro-discharge machining or hydrating. Amongst all the sintering techniques, the HIP is the
(WEDM) wire electro-discharge machining of NiTi SMAs. The most commonly practiced in which in evacuated powder is filled,
machining of NiTi SMAs by the Laser machining process is an and the pressure to the powder is applied by the gas-tight welded
encouraging machining process. Laser machining leaves consider- cans. Samples made by this method have advantages of high
ably much lower heat-affected zones on the workpiece in contrast homogeneity and theoretical density.
to the EDM process which has large heat-affected zones. For the
production of micro-devices which are to be made by machining 4.4. Thermal spray
of NiTi alloys, Fe MP laser is used [30]. A minor drawback of this
laser is the significant development of the recast layer due to the To produce components like thin-walled mill products, NiTi
process being thermal and the high ablation rates cause due to tubes, NiTi foils, and other 3D shapes, the thermal spray technique
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S. Kumari, Dinbandhu and K. Abhishek Materials Today: Proceedings 44 (2021) 1336–1343
5. Properties of SMA
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S. Kumari, Dinbandhu and K. Abhishek Materials Today: Proceedings 44 (2021) 1336–1343
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S. Kumari, Dinbandhu and K. Abhishek Materials Today: Proceedings 44 (2021) 1336–1343
CRediT authorship contribution statement [25] J. Hu, Y. Zhu, H. Huang, J. Lu, Recent advances in shape–memory polymers:
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