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Materials Today: Proceedings 44 (2021) 1336–1343

Contents lists available at ScienceDirect

Materials Today: Proceedings


journal homepage: www.elsevier.com/locate/matpr

Study of machinability aspects of shape memory alloys: A critical review


Soni Kumari a,⇑, Dinbandhu b, Kumar Abhishek b
a
Department of Mechanical Engineering, GLA University, Mathura 281406, UP, India
b
Department of Mechanical Engineering, Institute of Infrastructure Technology, Research and Management, Ahmedabad 380026, Gujarat, India

a r t i c l e i n f o a b s t r a c t

Article history: Memory metals or memory alloys or smart metals are those alloys which get deformed when cold and
Received 28 September 2020 returns to their preformed shape when subjected to heating. Their exquisite properties make these alloys
Received in revised form 15 October 2020 an ideal material for several engineering applications. The recent developments in these materials have
Accepted 14 November 2020
attracted the interest of the scientific community. In this context, an attempt has been made to provide
Available online 30 December 2020
an overview of the shape memory alloys (SMAs) along with their deformation mechanism. The study fur-
ther explores the classifications and advantages of different shape memory alloys. Various machining
Keywords:
processes adopted for machining shape memory alloys as well as the making of these alloys have been
Shape memory alloy
Smart metal
also articulated in this review. Besides all these, a light has been also thrown on the significant charac-
SMAs teristics of these materials in addition to their applications in automobile, aerospace, robotic, and
Unconventional process biomedical fields.
Shape memory polymers Ó 2021 Elsevier Ltd. All rights reserved.
Selection and peer-review under responsibility of the scientific committee of the International Confer-
ence on Materials, Processing & Characterization.

1. Introduction studies which resulted in more than 20,000 patents related to


SMA worldwide and out of the 10,000 in the USA only.
The shape-memory effect (SME) and superelasticity (SE), these SMAs (shape memory alloys) are those alloys that undergo a
two properties make such material a smart material. These proper- memorization process between two transformations, which is a
ties also place them as the center of studies in the field of Material magnetic field or temperature-dependent. This incident of trans-
Science for the various researchers on the globe. One of the most formation is known as (SME) the shape memory effect. The princi-
common shape memory alloys is made up of Titanium and Nickel ple of such alloys is quite simple i.e. these alloys will get deformed
and intermetallic compounds, known as Nitinol alloy or NiTi alloy, when subjected to an external force or load, and when subjected to
and hence most of the research is referred to it. The market is occu- heating beyond a specified temperature either by internal or exter-
pied by Nitinol alloys-based shape memory products in the market. nal heating, will regain to its pre deformed state. Practically, SMAs
One chief reason for this is the excellent mechanical and electrical exhibit two different kinds of phases that possess three different
properties besides high fatigue life and high corrosion resistance, kinds of crystal structures (i.e. detwinned martensite, austenite,
possessed by Nitinol. Two very important factors that derive the and twinned martensite) and six possible transformations [3,4]
manufacturing technology are better quality and reduced cost. (see Fig. 1).
SMAs are highly desirable in today’s industrial requirements which The martensite structure stabilizes at lower temperatures while
generally demands high dimensional and fine surface finish prod- the austenite structure stabilizes at a higher temperature. When
ucts at a nominal cost. Low machining cost is always preferable heat is supplied to an SMA, a transformation from the martensite
which can be achieved by increasing (MMR) material removal rate phase into the austenite phase takes place. There are two temper-
and enhanced tool life this holds great importance from an eco- atures involve during transformation i.e. the austenite-start-
nomic point of view. Considering the worth of this material for temperature (As) and the austenite-finish-temperature (Af). The
the engineering world, a lot of researchers have carried out their temperature where this transformation begins is known as the
austenite-start-temperature (As) and where this transformation
completes is known as the austenite-finish-temperature (Af). The
transformation that occurs as mentioned above, is possible even
⇑ Corresponding author.
when subjected to high loads, this results in high actuation energy
E-mail address: soni.1802@gmail.com (S. Kumari).

https://doi.org/10.1016/j.matpr.2020.11.390
2214-7853/Ó 2021 Elsevier Ltd. All rights reserved.
Selection and peer-review under responsibility of the scientific committee of the International Conference on Materials, Processing & Characterization.
S. Kumari, Dinbandhu and K. Abhishek Materials Today: Proceedings 44 (2021) 1336–1343

Fig. 1. SMA crystal structures and phases [1,2].

densities. When an SMA undergoes a cooling process, the transfor- which is more reliable, powerful, and is used extensively in
mation tends to reverse to the martensite which is termed as many engineering areas. The difference of transition tempera-
martensite start-temperature (Ms), and completes when it reaches tures between heating and cooling can be measured by Hystere-
to martensite-finish-temperature (Mf). Md is termed as the highest sis (i.e. DT = Af Ms), which can be usually defined between the
temperature at which no further stress can be induced into temperatures at which the material transforms 50% to marten-
martensite, and above this peak temperature, an SMA starts deforming site on cooling and transforms 50% to austenite on heating. For a
to the plastic deformation stage like other metallic material [38]. specific technical application, selection of SMA material
Super elasticity (or pseudoelasticity) and SME which are termed depends on the hysteresis property and requires careful consid-
as shape change effects, can be classified further into three shape eration, for instance, within a large temperature range, a
memory characteristics as follows: requirement of large hysteresis is a must, to regain the prede-
fined shape (such as in pipe joining and deployable structures)
 OWSME (One-way shape memory effect): In one-way when an [8] and whereas for fast actuation applications, a small hystere-
external load is applied it undergoes the deformation and its sis is required (such as robotics and MEMSs).
original state is retained upon releasing the applied load subse-
quently heating it. 1.1. Deformation mechanism
 Reversible SME or TWSME (Two-way shape memory effect):
When an SMA has the tendency to reverse to its pre deforma- High stresses are applied to the material in almost all the man-
tion state or has the tendency to regain its original shape at both ufacturing processes. The complete process may consist of a com-
low and high temperatures, then an SMA is considered to have bination of many different loading types and for this reason, shear
the tendency of TWSME. Although, TWSMA is less viable com- and tension mechanisms are described below. The most common
mercially as for the same material [5] it produces nearly half loading that is applied to the material is tension; in this type of
of the recovery strain in contrast OWSMA also at high temper- loading, the material is loaded axially subsequently the stress gen-
atures strain tends to deteriorate quickly [6]. Therefore, a reli- erated is distributed uniformly inside that material. However, the
able and economical solution is provided by OWSMA [7]. material moves in a fairly low range. It is to be noted, that in this
 Super elasticity (SE) or Pseudo elasticity (PE): When the orig- mode of loading, the normal stress comes out to be directly propor-
inal shape of an SMA is regained by loading the SMA component tional to the applied load. A dominant mechanism that occurs dur-
mechanically at a temperature between Af and Md, then shape ing the machining of a component is the Shearing. Various studies
change effect is termed as Super elasticity. At a macroscopic have been performed to research the effects caused by the shear
(structural) level, besides the ‘material TWSME’ as mentioned mechanism to superelasticity and shape memory effect of the
above, an OWSMA actuator acts as a ‘mechanical TWSME’; SMA materials. The cause of difficulty in studying the various
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S. Kumari, Dinbandhu and K. Abhishek Materials Today: Proceedings 44 (2021) 1336–1343

Fig. 2. Maximum bandwidth versus specific energy and maximum strain for different classes of active materials [1].

2.1. High-temperature shape memory alloys

Due to the increasing demands for high-temperature applica-


tions which is quite common in the engineering field, HTSMAs
are being focused extensively for the research purpose [11–13].
Practically, HTSMAs can be defined as those SMAs which operate
at temperatures above 100 °C. They can be categorized into three
groups and classification is based on their martensitic transforma-
tion ranges [11] (see Table 1). At room temperature, HTSMA pos-
sesses poor fatigue resistance and limited ductility which makes
it exceedingly difficult to process them, further this makes HTSMAs
expensive alloys to manufacture. Because of this reason, alternate
options such as cobalt and copper which have low cost, have been
researched.

2.2. Magnetic shape memory alloys


Fig. 3. Stress–strain temperature of NiTi SMA [49].

Another name given to these alloys is (FSMAs) i.e. Ferromag-


effects caused due to shearing lies with the fact that a pure shear- netic Shape Memory Alloys. These alloys can be actuated (up to
ing of a material is a difficult phenomenon [9]. In order to define 1 kHz) at higher frequencies. Actuation energy causes this actua-
the effects of shear stresses in Ni-Ti based shape memory alloys, tion which is transmitted by magnetic fields which is not
Daly et al. [9] performed a shearing test in Nitinol samples. The obstructed by the relatively slower mechanism of heat transfer
results showed that the shear deformation-induced was fairly [16]. The strain rate possessed by piezoelectrics and magnetostric-
homogenous, thus hindering the formation of differentiating bands tive active elements has matched with the FSMA’s strain rate (see
of deformation. This behavior is found exactly opposite to the one Fig. 2, [11]). FSMA has the capacity of providing specific power
noticed during the tension of Nitinol. Huang et al. [10] observed matched by the specific power provided by SMAs (see Fig. 2,
the similar in their test conducted on Nitinol samples, but the [11]). FSMA’s have maximum strain which is approximately 32
method used for inducing shear stresses was different in this case, times greater than the magnetostrictive Terfenol-D (TbDyFe2)
Fig. 3. In this case as well the final distribution of the deformation [16]. As a result, FSMAs are found worthy of filling the technolog-
in the NiTi samples appeared homogenous. ical gaps between magnetostrictive materials and SMAs, and thus
It was also noted that an increase in the maximum value of the it offers great benefits for valve applications and the motor [17]
critical shear strain was caused by a lower strain rate. A typical requiring significant larger displacement at lower actuation force.
shear stress-shear strain curve can be seen in Fig. 3. The results Yet, the design issues for MSMA and SMAs remain the same.
showed that for higher values of temperature the critical stress is
increased, while with an increase in temperature, the superelastic
attitude of the material showed a progressively deteriorating
pattern. 2.3. Shape memory material thin film

Advancement of fabrication technology leads to the evolution of


thin films SMM, to make micro-actuators. SMMs are made to
deposited directly onto the micromachined materials. NiTi thin
2. Types of shape memory materials films have become the actuator of choice at the micro-scale level,
this is because of the rapid growth of (MEMSs) micro-electro-
SMAs have various disadvantages or limitations like constraints mechanical systems. Another reason for becoming an actuator of
on the extent of deformation, operating temperature constraint, choice is its characteristics as mentioned above i.e. displacement
high manufacturing cost, and low bandwidth, this forced the and higher actuation force. The flexibility of thin film of NiTi with
researchers to explore some other types of SMMs. SMMs can be compact structure and multiple degrees of freedom expands the
classified as Ni–Mn–Ga and Co-Ni–Ga. Out of these two Ni–Mn– usage of NiTi in consumer products applications, automotive, aero-
Ga can be categorized further as HTSMA and MSMA. space, biomedical.
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S. Kumari, Dinbandhu and K. Abhishek Materials Today: Proceedings 44 (2021) 1336–1343

Table 1
HTSMA groups and their properties [11,14,15].

Group Alloy Transformation temperature Thermal Strain Recovery Comments


composition range (°C) hysteresis (°C) (%) (%)
100–400 Ti-Ni-Pd 100–530 20–26 2.6– 90PE–100 High work output, most commercial ready and high material
(°C) 5.4 cost
Ti-Ni-Pt 110–1100 31–55 3–4 100 Reasonable SME, large hysteresis, and relatively low
Ni-Ti-Hf 100–400 60 3 100 materials cost
Ni-Ti-Zr 100–250 54 1.8 100 Low cost, poor to reasonable SME, and brittle in tension (Cu-
Cu-Al-Ni 100–400 21.5 3–5PE 80–90PE Al-Ni)
Cu-Al-Nb 100–400 59–170 5.5– – Good workability, large hysteresis, and high-temperature PE
Co-Al 121 7.6 90 (Co-Ni-Al)
2
Co-Ni-Al 100–300 15.5 5PE 100PE Low material cost, low hysteresis, and poor tensile ductility
Ni-Al – – –
Ni-Mn 100–670 20 3.9 90 Good ductility and workability but poor SME
Ni-Mn-Ga 100–400 85 10 70 Good ductility and SME but suspect to oxidation and contain
Zr-Cu 100–600 70 8 44 Uranium (U-Nb)
Ti-Nb 100–200 50 2–3 97–100
400–700 U-Nb 100–200 35 7 – Good ductility (Ti-Pd), but high materials cost (Ti-Pt)
(°C) Ti-Pd 100–510 40 10 88
Ti-AU 100–630 35 3 100
˃ 700 (°C) Ti-Pt-Ir 990–1184 66.5 10PE 40PE High yield strength.
Ta-Ru 900–1150 20 4 50 Stable microstructural, but poor oxidation resistance and
small hysteresis

Table 2
Comparing the properties of SMA and SMP [1,48].

S. No. Characteristics SMA SMP


1 Strain (%) Up to 8% Up to 400, and possibly above 800
2 Phase transformations Martensitic transformation Glass transition
3 Density (gcm3 ) 6–8 0.9–1.25
4 Transition breath (°C) 5–30 10–50
5 Deform stress (MPa) 50–200 1–3
6 Recovery stress (MPa) 130–300 1–3
7 Recovery speeds (s) < 1s < 1 s to several minutes
8 Young’s modulus (GPa) 83 (NiTi) 28–41 0.01–3ð0:1  10Þ  103
9 Thermal conductivity (W/m K) 18 (NiTi, Austenite) 0.15–0.30
10 Condition at low temperature Soft Hard
11 Condition at high temperature Hard Soft
12 Corrosion performance Excellent Excellent
13 Biocompatibility & degradability Not all biocompatible, not biodegradable High
14 Fabrication/processing condition >1000 °C, high pressure <200 °C, low pressure
15 Shape training Difficult Easy & quick
16 Cost Expensive Cheap

2.4. Shape memory polymers 3. Machining of SMA

Manufacturing of Shape memory polymers (SMPs) is relatively The term machining means the removal of unwanted material
easier. In comparison to SMAs, SMPs are considered a better alter- from the workpiece to give it the desired shape with the help of
native because of their lower cost approximately 10% cheaper. a tool called a cutting tool. Unwanted material from the workpiece
Besides, SMPs are biodegradable, possess better efficiency, and is removed in form of chips. Chips are formed due to strain harden-
superior to SMAs in terms of mechanical properties (see Table 2). ing of the metal when a wedge-shaped tool makes a contact with
When triggered by either by heating [18] or by cooling [19], mag- the workpiece provided there should be relative movement
netic field [20], electricity [21], light [22], or water [23,24] SMPs between tool and workpiece. Such processes are usually referred
can sustain two or more shape changes [25,26]. Table 2 summa- to as conventional machining processes which include turning,
rized some of the characteristics of SMPs. milling and drilling, etc. Another very well-known process called
SME has three working mechanisms in polymeric materials: grinding, in which cutting takes place by abrasive action, carries
Dual-component mechanism (DCM), Partial-transition mechanism a lot of weightage in the conventional machining industry. Other
(PTM), and Dual-state mechanism [18]. The almost 100% recovery non-conventional machining operations like electro-discharge
precision of SMPs, makes it suitable for engineering applications machining, water jet machining, laser machining, and electro-
which are high in demand [27]. Depending on the composition of chemical machining that do not have physical contact between
the material used, the SME of SMPs varies, i.e. the molecular the workpiece and cutting tool and that do not have a cutting tool
weight of the polymer-chain employed and weight fraction of as possessed by the conventional processes, such processes utilize
the switching segments. SMPs offer advantages because of their chemical or thermal energy for machining. Due to work hardening
biodegradable nature and hence SMPs offer more economical and or strain hardening, it is quite a difficult task to achieve quality and
effective treatments. cost goals. One of the most common issues that need to be dealt

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S. Kumari, Dinbandhu and K. Abhishek Materials Today: Proceedings 44 (2021) 1336–1343

with, while machining using non-conventional methods is of small the ultrashort laser pulses, though, it performs better than other
material removal rates besides high tool wear. Therefore, consider- lasers. Huang, Zheng, and Lim [31] investigated the femtosecond
ing the importance of machining in the Engineering world, the fol- laser machinability of NiTi. In comparison to Nd: YAG laser
lowing paragraphs describe the conventional and non- machining, it was found that the heat-affected layer and a re-
conventional machining processes which SMAs can be subjected deposition layer were quite thinner when machining was carried
to. Aspects associated with the machining process like cutting out by femtosecond laser. Biffi and Tuissi investigated the laser
tools, feed, and cutting conditions are considered, investigated drilling of ferromagnetic [32] and they summarized that the laser
and thus results are presented. machining of micro-features can be carried out with limited
restriction.
3.1. Conventional machining
4. Making of shape memory alloys
Considering the importance and wide variety of applications of
Nitinol, conventional machining of SMAs is mainly conducted on Various ways of producing shape memory alloys have been dis-
NiTi or alloys of NiTi, this causes the study to be focused mainly cussed as follows:
on these materials. To gain an insight into the machinability char-
acteristics of Nickel and Titanium alloys one needs to have a very
4.1. Melting
sound knowledge of the phenomena that take place during
machining i.e. machining of high strength alloys at elevated tem-
Vacuum melting is one of the most significant methods by
peratures, which results in a rise in temperatures at the tool-chip
which SMA can be produced. Not only vacuum melting but also
interface, workpiece distortions, rapid tool wear and high dynamic
other techniques like which can be adopted to produce SMA are
loads [12]. Apart from Titanium alloys, Nickel based alloys and
plasma melting and electron beam melting. Electromagnetic
Super-alloys, are also considered alloys which are hard to machine
induction is the principle on which Vacuum induction melting
and possess very high strength. Various cutting tools like uncoated
works, in this process, electrical eddy currents are induced in the
and coated cemented carbide, ceramic inserts, and cubic boron
metallic charges and the graphite crucible. Melt is stirred and
nitride were investigated. The research’s summarized as extensive
mixed by the adoption of electrodynamic force. Electro graphite
tool wear was found in the case of uncoated cemented carbide,
crucible is used in SMA to achieve low carbon concentrations
while reduced wear was found in the case of coated cemented car-
[33]. A low viscosity electron beam comes out from a hollow
bide tools. Regardless of the cutting parameters, machining of NiTi
plasma cathode in the plasma melting method. The chief benefit
alloys was not possible by ceramic cutting tools because of its inca-
offered by this method is the drastic reduction in the loss of the
pability to do so. It was also observed that the tool wear was higher
alloy element.
in CBN as compare to coated cemented carbide tools. Moreover,
CBN tools are not preferable because of its cost. In contrast to what
is recommended by the relevant literature, it was observed that 4.2. Heat treating
coated cemented carbide tools can be used to machine NiTi that
too at higher cutting speeds. Improvement in the surface finish is Optimized properties of NiTi samples can be achieved by cold
observed at cutting speed of 110 m/min and tool wear was working of the samples, before heat treatment. For superelastic
reduced. Formation of burrs and the effects of cutting fluids on chip nitinol, the heat treatment process is carried out at 500 °C temper-
breaking and was discussed by Weinert and Petzoldt [28]. Guo ature, in the case of shape memory alloys, the range of temperature
et al. [29] studied the milling of a NiTi alloy which has got its usage at which heat treatment is carried out is between 350 °C and
in the field of biomedical. (50.8 at. % Ni–49.2 at% Ti). Split- 450 °C. The addition of Nickel at a composition of 55.5(wt. %)
Hopkinson pressure bar compression tests were conducted by enhances its unique properties like pseudoelasticity and SME.
these researchers to evaluate the mechanical properties of the Enhancement in its unique properties at high temperatures can
material. It was observed from the test that in comparison to Ti be achieved by solution treatment. Transformation temperature
or Ni-based superalloys, NiTi is more difficult to be machined is increased by varying the composition of the matrix.
because of the high strength possessed by the material under static
and dynamic loading conditions. 4.3. Powder metallurgy

3.2. Non-conventional machining An efficient way of producing net shape components of NiTi
alloys is Powder Metallurgy. Grain refinement is targeted to
It is also known as the Unconventional machining process, in enhance the fatigue properties of copper-based shape memory
this category of machining processes, machining takes place with- alloys. Two types of powder metallurgy techniques which are in
out physical contact between the tool and the workpiece. Thus, in practice mostly for the preparation of NiTi alloys are alloy powder
these processes tool wear is minimized drastically, or in some sintering and raw metal powder sintering. For producing NiTi alloy,
cases, it is diminished. Non-conventional processes are being used various powder metallurgy techniques have been developed where
in machining SMA, where components to be machined have very both pre-alloyed powders and elemental powders are used as ini-
small dimensions. Most of the non-conventional machining pro- tial materials by hot isostatic pressing (HIP), pulverization [34],
cesses are carried out by (EDM) electro-discharge machining or hydrating. Amongst all the sintering techniques, the HIP is the
(WEDM) wire electro-discharge machining of NiTi SMAs. The most commonly practiced in which in evacuated powder is filled,
machining of NiTi SMAs by the Laser machining process is an and the pressure to the powder is applied by the gas-tight welded
encouraging machining process. Laser machining leaves consider- cans. Samples made by this method have advantages of high
ably much lower heat-affected zones on the workpiece in contrast homogeneity and theoretical density.
to the EDM process which has large heat-affected zones. For the
production of micro-devices which are to be made by machining 4.4. Thermal spray
of NiTi alloys, Fe MP laser is used [30]. A minor drawback of this
laser is the significant development of the recast layer due to the To produce components like thin-walled mill products, NiTi
process being thermal and the high ablation rates cause due to tubes, NiTi foils, and other 3D shapes, the thermal spray technique
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S. Kumari, Dinbandhu and K. Abhishek Materials Today: Proceedings 44 (2021) 1336–1343

is used predominantly. The thermal spray process is carried out in


two ways, one is low-pressure wire arc spraying and another way
of carrying out the thermal spray method is the vacuum plasma
spraying technique. NiTi alloys which are difficult and expensive
to manufacture are generally made by conventional methods.
Low-pressure thermal spraying method is employed to reduce pro-
duction cost and production lead time for semi-finished NiTi foils,
technology is generally employed. To improve NiTi foils’
microstructure hot rolling is performed [34].

5. Properties of SMA

Various significant properties of shape memory alloys have


Fig. 5. SMA pseudoelastic loading cycle [49].
been discussed as follows:

5.1. Shape memory effect

The molecular structure of SMA is twinned during the marten-


sitic phase transformation. The shape and size of the undeformed
martensite phase resemble with the cubic austenitic phase when
seen on a macroscopic scale, Variables such as MS, Mf, AS, Af are
used to characterize the starting and finishing temperature of the
parent austenitic phase and daughter martensitic phase. MS and
Mf are the martensite start and martensite finish temperature
respectively upon cooling, while AS and Af are the austenite start
and finish temperatures respectively during heating. When SMA
temperature reaches below Mf, the Shape memory effect (SME) is
observed and SMA will be recovered to its original shape when
the specimen is heated above Af. No transformation strains are
induced in one-way SME during cooling, while transformation
strains are persuaded during cooling or heating of SMA in two - Fig. 6. Phase diagram and two possible pseudoelastic loading paths [49].
way SME [35]. Two-way SME is a developed characteristic and
not an essential one (Fig. 4).
formation (RT) from martensite to austenite occurs that causes
5.2. Pseudo elasticity inelastic strains to recover. Regaining of thermoelastic strains iden-
tifies the final element of the loading path (e-a); which upon com-
When the component is unloaded at a temperature above Af, pletion of the path, leads to zero macroscopic strains. In a
Pseudo elasticity of SMA shows stress-induced strain recovery. hysteresis, this transformation process is concluded (Figs. 5 and 6).
Where de-twinned martensite is found stable which is at zero
stress state, form there super elastic thermomechanical loading
path starts. The quasi-static process generates latent heat which 5.3. Damping properties
is dissipated during the phase transformation. The transformation
occurred from austenite to martensite at critical stress levels dur- The property which predominantly deals with the dissolution of
ing loading at a temperature above Mf and that stress is called mechanical energy into heat. Damping property is considered as
transformation stress (a-b). On path (b-c), this phase transforma- the vital property for all the engineering materials to be used in
tion is observed. Elastic strains seem to be developed during the a specified application. In comparison to the remaining materials,
thermoelastic critical stress level. On further increment of load, SMA possesses a remarkably high damping capacity. Many irre-
any more phase transformation is not produced by de- twinned versible events e.g. dislocation movements and production defects
martensite region (c-d), though re-orientation of martensite twins
may occur during multi-axial loading. At a point, (d) Reverse trans-

Fig. 7. Elastic modulus vs. temperature for a frequency of 13 Hz and strain


Fig. 4. Temperature Hysteresis in SMA [36]. amplitude of 104 [50].

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S. Kumari, Dinbandhu and K. Abhishek Materials Today: Proceedings 44 (2021) 1336–1343

application [42,43]. Another interesting use of SMA is VGC which


is a device known as a variable geometry chevron that was being
developed by Boeing with SMA actuators and the same has been
installed on a GE90-115B jet engine used in passenger aircraft.
By maximizing the chevron deflection this device proved its worth
in reducing noise during take-off, and by minimizing the chevron
deflection during the remainder of the flight [44,45] it increased
its cruise efficiency.

6.3. Robotic applications

Sreekumar et al. [46] explained the applications of SMAs as


micro-actuators in a diversifying range of commercial robotic sys-
tems. Biologically inspired SMA robotic applications (i.e. biome-
Fig. 8. Damping factor Vs temperature for a frequency of 13 Hz strain amplitude of chanics) have a wide variety of applications in biomedical areas.
104 [50].
Not only in the biomedical field but also other fields, SMA has been
used extensively. The foremost challenges in the robotics domain
etc will occur. One of the energy dissipations observed during areas: to enhance the brainpower of the integrated system (i.e.
pseudoelastic characteristics is Hysteresis. During the transforma- autonomous, reliable, faster, and smaller) and increment in the
tion cycle of isotropic materials, the ratio of dissolute energy to the extent of miniaturization and functioning of the hardware compo-
total energy obtained will be developed. This ratio depends on nents. However, out of the several flaws, some of these have been
amplitude, temperature, and excitation frequency (Figs. 7 and 8). resolved by selecting control techniques, feedback sensors, and
suitable modeling techniques. For example, the necessity of addi-
tional sensors can be eliminated with the resistance feedback con-
6. Applications of SMA
trol which is ideal for micro-robots.
SMA has varieties of applications. It has a lead role to play in the
Automobile industries. It is widely used in electric generators 6.4. Biomedical applications
which makes use of exhaust heat to generate electricity. SMA has
got varieties of uses such as automatic valves, mini actuators, sen- Buehler et al. in 1962 discovered SME in nitinol, they studied
sors, actuators, SMA is also used for noise reduction as in Solenoids. and suggested to use SMA based material for dentistry implants.
It has its great importance where application demands of increas- A few years later in 1971, a researcher called Andreasen introduced
ing efficiency by reducing weight. SMA finds its applications in the first NiTi alloy based super elastic braces. It is introduced in
biomedical fields, slow response times, low efficiency, small strain minimally invasive surgery (MIS) [47] and later on, SMA-made
output, large hysteresis. One of the SMA applications is Intelligent components made a significant contribution to the biomedical
Reinforced Concrete (IRC) which uses wires embedded with the domain. After the approval of the US Food and Drug Administration
concrete. SMA in such applications can sense initially developed (FDA), biomedical applications of SMA are developed and hence
cracks and helps in reducing large scale sized cracks. Because of introduced into the market in September 1989, this became
the biocompatibility property possesses by SMA, it is widely used possible.
in endodontic files and orthodontic devices. SMA can have a rem-
edy in case of broken bones too.
7. Conclusions
6.1. Automotive applications
The review yields the following conclusions:
There is a surge in demand for vehicles offering more comfort
and safer than before besides better performance which is a must, i. The exquisite properties of shape memory alloys make them
all this has become reality due to increases in the usage of sensors a well suitable material for several engineering applications
and actuators, thus the scope of SMA has widened. As the technol- in aerospace, automobile, and biomedical fields. Within SMA
ogy in the Automotive sector is emerging SMA actuators become based communities, the development of a more effective and
the alternative to electromagnetic actuators [37–39]. Many com- efficient knowledge-sharing platform.
ponents function as active thermal actuators (e.g. carburetion ii. Machining plays a significant role in the end-user usages and
and engine lubrication, engine temperature control, and power implementation of shape memory alloys in the aforemen-
train clutches) [38,40], and as linear actuators. Besides this, SMA tioned application fields. With the advancement in fabrica-
has applications in other areas too, such as aesthetics and tion technologies and with the development of composites
aerodynamics this is due to the SMAs’ attractive morphing capabil- and hybrid SMMs, SMAs can be made more durable and
ity (active and adaptive structures). stable which increases its scope for the application in a
broad range of industries.
iii. There is a need of developing fresh design guidelines and
6.2. Aerospace applications
approaches for the creation of novel shape memory alloys
for their widespread applications in science and technology.
Aerospace is a critical application field and the unique proper-
iv. This work has a future scope of developing computational
ties of SMA draw its inclination towards this field, components in
models and their optimization for a robust output. An explo-
an aerospace application are subjected to geometric space con-
ration of thermal analysis, chemical analysis, and wear anal-
straints and high dynamic loads. A few examples of such applica-
ysis is also needed for understanding the SMA’s widespread
tions are structural connectors, vibration-dampers, actuators
applications.
[1,41], release or deployment mechanisms, sealers, the pathfinder

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S. Kumari, Dinbandhu and K. Abhishek Materials Today: Proceedings 44 (2021) 1336–1343

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