Soaping Agent Composition

(for reactive dyeing and production method thereof)

Abstract
The invention provides a soaping agent composition for dyeing fabric and a production method
thereof, and relates to the technical field of textile dyeing, and especially relates to soaping
agent composition for dyeing fabric and a production method thereof. A formula of the
composition comprises, by weight, 10-25% of fatty alcohol polyoxyethylene ether, 5-15% of fatty
alcohol sulfate, 2-6% of alpha-alkenyl sulfonate, 4-8% of chelating auxiliary agent, 3-6% of
resist printing salt S and 55-65% of water. Composition of the ingredients has good soaping and
anti-contamination effects on reactive dyes of cotton, blending fabric and polyester cotton fabric,
etc; a good soaping fastness can be realized without acid neutralization and high temperature
soaping; besides, a process is simple, saves time and reduces consumption of water, electricity
and steam, so as to lower cost and increase working efficiency.

Description
Textile dyeing is with soaping agent compsn and working method thereof
Technical field
The present invention relates to the textile dyeing technical field, related in particular to a kind of
textile dyeing with soaping agent compsn and working method thereof.
Background technology
As everyone knows, hydrolysis can take place last when dyeing set in reactive dyestuffs, and
hydrolyzed dye is adsorbed on the colour fastness that can have a strong impact on dyeing
product on the fiber, thereby must soap after the reactive dyeing.The main purpose of soaping is
exactly in order to remove the hydrolysed dye that attaches on fiber, not set dyestuff and other
impurity. Usually use the basic soap lotion, cloth cover pH value be 10-11 in bathing when
soaping, and is alkalescence, and reactive dyestuffs are prone to scission of link takes place
when high temperature is soaped, so after the reactive dyestuffs alkali fixation, must wash
through three times, and could get into the bath of soaping after making cloth cover pH value
near neutrality carries out soap boiling.Nonetheless, the finished product that can not guarantee
to dye is being accepted to soap under nearly neutrality condition; Acid scouring agent is also
arranged on the market, but washing effect and poor stability, and contain higher toxicity in the
prescription, environment is caused very major injury, so the prior art existing problems have
much room for improvement.

Summary of the invention

The objective of the invention is to provide a kind of good stability to the problems referred to
above, and the textile dyeing of environmental protection is with soaping agent compsn and
working method thereof.
Technical scheme of the present invention is following: the soaping agent compsn is used in
textile dyeing; Form by weight percentage by following prescription:
AEO : 10-25%
aliphatic alcohol sulfate : 5-15%
α-sodium olefin sulfonate : 2-6%
chelating auxiliary agent : 4-8%
reserve hao S : 3-6%
water : 55-65%
wherein: the chelating auxiliary agent be YD 30, nitrilotriacetic acid or Citrate trianion wherein
any.
Preferably, said soaping agent compsn is made up of following prescription by weight
percentage: AEO: aliphatic alcohol sulfate 24%: α-sodium olefin sulfonate 5%: chelating
auxiliary agent 3%: reserve hao S 5%: 5% and water: 58%.
Said soaping agent composition manufacturing method comprises the steps
Steps A, in the reaction kettle that whisking appliance is housed, add chelating auxiliary agent
and water, the powerful stirring half a hour forms solution; Step B, AEO, aliphatic alcohol sulfate
and α-sodium olefin sulfonate are joined in the said solution; Under constantly stirring, be
heated to 55～60 ℃, make it to dissolve the back and add reserve salt, stirred 45 minutes; And
insulation reaction 1～2 hour, be cooled to 30 ℃ of dischargings.
The effect one of soaping agent is to have stronger washing power, the 2nd, have
dissemination, and it has following performance: A, solubilising: increase the auxiliary agent that
remains on the fabric and reach the not solvability of combination dye; B, chelating: play
sequestering action with high violence metal ion, the softening washing water; C, dispersion: the
solid dirt is had anti-freezing effect of gathering and dissemination; D, washing: the auxiliary
agent and the unconjugated dyestuff that will remain on the fabric wash; E, emulsification and
anti-contamination effect: auxiliary agent, the dyestuff of washing are emulsified in the solution
equably, form micella, prevent to stain again on the fabric, form micella at fabric face on the
other hand, prevent that auxiliary agent, dyestuff that washing is got off from staining on the
fabric again; F, an alkaline shock absorption: replace using in the general washing alkaline
matters such as soda ash.
The soaping agent compsn is used in textile dyeing provided by the present invention, adopts
the plurality of raw materials formulated in combination to form, and wherein:
AEO (secondary AEO-9) has emulsification, decomposition, washing, anti-contamination effect;
Aliphatic alcohol sulfate has emulsification, infiltration, decontamination, solubilising function;
α-sodium olefin sulfonate has solvability, infiltration and water purification preferably;
Chelating selection of auxiliary YD 30, nitrilotriacetic acid or citrate trianion wherein any, have
good chelating, dispersion and pooling feature;
Reserve Hao S, another name: the 3-nitrobenzene sodium sulfonate has solubilising,
anti-stains, improves the doing of fabric, fastness to wet rubbing and soaping fastness.
The compsn of these components all has good soaping and anti-contamination effect to reactive
dyestuffs of cotton textiles, BLENDED FABRIC, polyester-cotton fabric etc.; Need not to carry
out the acid neutralization; Do not need high temperature to soap, can reach good soaping
fastness, and technology simple, save time and reduce water, electricity, the steam consumption
and use; Reduce cost, increase work efficiency.

Embodiment
Embodiment 1
1, textile dyeing is with the prescription (weight percent) of soaping agent compsn: AEO:
aliphatic alcohol sulfate 14%: α-sodium olefin sulfonate 12%: YD 30 4%: reserve hao S 5%:
water 3%: 62%;
2, in the reaction kettle that whisking appliance is housed, add 5 kilograms of YD 30s and 62 kg
of water, the powerful stirring half a hour forms solution; 14 kilograms of AEOs, 12 kilograms of
aliphatic alcohol sulfates and α-sodium olefin sulfonate are joined in the solution for 4 kilograms;
Under constantly stirring, be heated to 58 ℃, make it to dissolve the back and add 3 kilograms
of reserve salts, stirred 45 minutes; And insulation reaction 1.5 hours, be cooled to 30 ℃ of
dischargings and be finished product. Adopt following method to be applied on the fabric: to
take by weighing 0.4 kilogram of soaping agent composition dissolves in 93.6 kg of water, add 6
kilograms of cottons and knit active emerald green DYED FABRICS, be warming up to 95
degree and soaped 12 minutes, cooling, cold wash oven dry.
Embodiment 2
1, by following formulated soaping agent compsn: AEO: aliphatic alcohol sulfate 24%: α-sodium
olefin sulfonate 5%: Citrate trianion 3%: reserve hao S 5%: 5% and water: 58%.
2, in the reaction kettle that whisking appliance is housed, add 5 kilograms of Citrate trianions
and 58 kg of water, the powerful stirring half a hour forms solution; 24 kilograms of AEOs, 5
kilograms of aliphatic alcohol sulfates and α-sodium olefin sulfonate are joined in the solution for
3 kilograms; Under constantly stirring, be heated to 55 ℃, make it to dissolve the back and add
5 kilograms of reserve salts, stirred 45 minutes; And insulation reaction 1 hour, be cooled to 30
℃ of dischargings and be finished product.Adopt following method to be applied on the fabric: to
take by weighing 0.3 kilogram of soaping agent composition dissolves in 93.7 kg of water, add 6
kilograms of cottons and knit reactive violet red colouring fabric, be warming up to 96 degree
and soaped 8 minutes, cooling, cold wash oven dry.
Embodiment 3
1, textile dyeing is with the prescription (weight percent) of soaping agent compsn: AEO:
aliphatic alcohol sulfate 19%: α-sodium olefin sulfonate 7%: nitrilotriacetic acid 3%: reserve hao
S 6%: water 4%: 55%;
2, in the reaction kettle that whisking appliance is housed, add 6 kilograms of nitrilotriacetic
acids and 55 kg of water, the powerful stirring half a hour forms solution; 19 kilograms of AEOs,
7 kilograms of aliphatic alcohol sulfates and α-sodium olefin sulfonate are joined in the solution
for 3 kilograms; Under constantly stirring, be heated to 55 ℃, make it to dissolve the back and
add 4 kilograms of reserve salts, stirred 45 minutes; And insulation reaction 1.5 hours, be
cooled to 30 ℃ of dischargings and be finished product.Adopt following method to be applied on
the fabric: to take by weighing 0.35 kilogram of soaping agent composition dissolves in 93.65 kg
of water, add 6 kilograms of cottons and knit active purple DYED FABRICS, be warming up to
95 degree and soaped 8 minutes, cooling, cold wash oven dry.

What should explain is; Above embodiment is only unrestricted in order to technical scheme of
the present invention to be described; Although with reference to preferred embodiment the
present invention is specified, those of ordinary skill in the art should be appreciated that and
can make amendment or be equal to replacement technical scheme of the present invention;
And not breaking away from the spirit and the scope of technical scheme of the present
invention, it all should be encompassed in the middle of the claim scope of the present
invention.

Claims (4)
Hide Dependent
1. the soaping agent compsn is used in textile dyeing, it is characterized in that: be made up of
by weight percentage following prescription:
AEO 10-25 %
Aliphatic alcohol sulfate 5-15 %
α-sodium olefin sulfonate 2-6 %
Chelating auxiliary agent 4-8 %
Reserve Hao S 3-6 %
Water 55-65 %

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