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4Thefirsttofourthionisationenergiesoffourelementsareasfollows:
4 The first to fourth ionisation enersiesof four elementsare as follows:

Ioni sation ene gykJ mol 1

lonisationenergy/kJmol-
Elem ent
Elemenl
First
First Second
Second Thir d
Third Fo urth
Fourth
P 577
577 1820
1820 2740
2740 11600
11600
o 418
418 3070
3070 4600
4600 5860
5860
n 736
136 1450
t450 7740
1140 105 00
10500
,s 494
494 4560
4560 6940
6940 9540
9540

WhichstatementaboutP,Q,RandSistrue?
Which statementabout P, Q, R urd S is true?
AQ
A Q ism oreeelectronegative
is more lectronegativeth anS
than S..
BMeltingpointofSishigherthanthatofR.
B Melting point of S is higher than that of R.
CEnthalpyofvapourisationofQishigherthanthatofR.
C Enthalpy of vapourisationof Q is higher than that of R.
D
D OxideOismorebasicthanoxideP.
Oxide Q is more basic than oxide P.

5AcompoundXwithahighmeltingpointdissolvesinwaterandconductselectricityinmoltenstate.
5 A compoundX with a high melting point dissolves n water and conductselectricity in molten state.
Comp oundXmo
Compound stpro
X most bablycould
probably could be
be
Apotassiumcarbonate
A potassium carbonate C
C aluminumchloride
aluminium chloride
Bmagnesiumoxide
B magnesiumoxide D
D strontiumsulphate
strontium sulphate

6Polyatomicmoleculesandionshavevariedgeometries.Whichspeciesandgeometrycorrespond
6 Polyatomic molecules and ions have varied geometries.Which speciesand geometry correspond
orrectly?
ccorrectly?
Species
Species Ge ometry
Geometry
A NH;
NH; Linear
Linear
B
B H,O+
HrO* Trigonalplanar
Trigonal planar
C SSiCl4
iCI, Sq uareplanar
Squareplanar
D
D IC l
IC13 T-shaped
T-shaped

7Basedonthebandtheory,theconductivityofmetalisduetodelocalisedelectronsintheconduction
7 Basedon the band theory, he conductivity of metal is due to delocalisedelecffons n the conduction
band.Howmanyelectronsarefoundintheconductionbandofa10.0gmagnesiummetalstrip?
band. How many elecffons are found in the conduction band of a 10.0 g strip?
[RelativeatomicmassofMgis24.0;Avogadroconstantis6.02X1023mol-1.]
fRelative atomic massof Mg is 24.O;Avogadro constant s 6.02 X 1023mol-1.]
A2.51X1023
A 2.5r x 1023 C 2.5
C X 102
2.5I1X 4
1024
B 5.0
B 2X
5.02 X 1023
1023 D3.01X1024
D 3.01 x 1024

8TherateequationforthereactionbetweenXandYisasfollows:
8 The rate equation or the reaction betweenX and I is as follows:

Rate=k[X][Y]7
Rate ktxlln,
When0.20molgasXand0.10molgasYaremixedina2.0dm'vesselat300°C,theinitialrate
When 0.20 mol gas Xand 0.10 mol gas I are mixed in a 2.0 dm3 vessel at 300 'C, the initial rate
is 3.2 X 10r mol dm 3 s-1.Which statement s true of the reaction?
is3.2X10-4moldm-3s-.Whichstatementistrueofthereaction?
ATherateofreactioniseighttimeslowerina4.0dm?vessel.
A The rate of reaction is eight times lower in a 4.0 dm3vessel.
BThenumericalvalueofkis0.16at300°C
B The numerical value of t is 0.16 at 300 'C.
CTherate-determiningstepisbimolecular.
C The rate-determining step is bimolecular.
DTheunitofkisdm3mol-Is-1.
D The unit of k is dm3mol-r s-1.

9Hydrogenperoxideandiodideionreactinthepresenceofhydrogeniontoproduceiodineand
9 Hydrogen peroxide and iodide ion react in the presenceof hydrogen ion to produce iodine and
wateraccordingtotheequation
water according to the equation

H,O,+21+2H*>2H,0+L.
HrO., + 2I- + 2H. * 2HrO + Ir.

Therateequationforthisreactioncanberepresentedby
The rate equation for this reaction can be representedby

rate = kfHzO,l,[ ]n[H*]'.

rate=kH,O,PUTHT.
Inthekineticexperimentofthereactionabove,thefollowinggraphsareobtained.
In the kinetic experiment of the reaction above, the following graphsare obtained.

Actual2009STMChemistryExaminationPaper591
Actual 009 TPM hemistryxaminailonfufer,.
91

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HAPER Time: hr 45 min

Section A

Four suggestedanswers labelled A, B, C and D are given for each question in this section. Choose
one correct answer.

1 An element X with the electronic configuration of ls22s22p63s23p64s23dto4p1

xists as isotopes X
and aY which have 38 and 40 neutrons respectively.What is the percentageabundanceof *X?
[Relative atomic massof X is 69.7.]
A 35.0 c 54.5
B 45.5 D 65.0

2 A phase iagram f water s shownbelow.

Pressure/Pa

273.16 Temperature/K

What can be deduced rom the phasediagram?

A An increase n pressurewill decrease he freezing point of water.
B An increase n pressurewill decrease he boiling point of water.
C Ice sublimes at a pressurehigher than 611 Pa.
D Water exists as liquid at a pressureof 611 Pa and a temperatureof 298 K.

Transition of electrons between energy levels in an atom will cause an absorption or emission
of light. Which energy level diagram shows the transition of electrons that emits light with'the
shortestwavelength?
A B t- TI

h- R a-E F
n=5
^-
=-
--T--
--^-A _n=4 __n=4 n=4
___n=3

:_[ n=2 n =2
o o
6 6 o 6
g q c c
uJ IJJ ul uJ

_="n=1 -n= l

59O Actual 2009 STPMChemistry Examination aper

--- --\
-----.--.=- r-
--

5000 7500
I rme/s

What is the order of the reaction with respect o H,O,, I- and H*?
H^O^ r H-
A b- | 2
81 10
cl 12
D2t0
10 A mixture of 0.60 mol of c arboxylic acidX,0.50 mol of alcohol Y,0.60 mol of esterZ and 0.40
mol of water of total volume V dm3 s refluxed in the presenceof hydrochloric acid.At equilibrium,
only 0.40 mol of X remains.What is the numerical value of K" for the reaction
X(aq) + I(aq) Z(aq) + H"O(l)?
A 0.25 - B 4.0 c 6.7 D 40.0
11 An equilibrium system s subjected o the following changesseparately:
(i) Decreasingpressureat a constant emperature
(ii) Increasing emperatureat a constantpressure
The equilibrium system whose reaction product will increase n quantity when subjected o the
above hangess
A' 2SOr(s) O,(B)+ 2SO.(S) A11= negative
n N,(e)+ 3H,(s):2NH,(e) A11 = negative
C Hr(s)+ I,(B);- 2HI(g) A11- positive
D CaCOr(s);- CaO(s) CO'(S) AF1- positive
t2 The equilibrium constantsof two equilibrium systemsare as follows:
(CHr)rNH(aq)+ HrO(l): (CH3)AHr*(ag) + OH-(aq) Ko= 5.4 x 10-4
NHrOH(aq) + HrO(l): NH3OH*(aq)+ OH (aq) Ko=9.1 X 10-e
Which statementabout the species n the above reactions s true?
A N{OH* is a strongeracid than (ClI3)rNHr.. C NHrOH is a stronger acid than HrO.
B NHrOH is a stronger base han (CH3)rNH. D (CH3)rNH is a strongerbase han OH .
13 Which pair of solutions will yield a buffer solution with a pH value of about 11 when the solutions
of equal volume and concentrationare mixed toeether?
A CH3COOHand CH,COONa C C2H5NH2 and HCI
B CH3COOH and NaOH D C2H'NH2 and CrHrNHr*Cl

14 Lead(II) chromate,PbCrO4, s a yellow pigment.The solubility product of PbCrOoat 25 "C is 2.8 X

10-13mo12 m{. What will happen f a few drops of an aqueoussolution of lead(Il) nitrate is added
to a saturatedsolution of PbCrOo?

592 Actual2009 STPMChemistryExamination aper

A The yellow solid of PbCrO4dissolves.

B The concentration of CrO,2l ions is less than 5'29 x 10r mol dmr'
C The concentration of Pb2* ons equals that of CrOo2- ons'
D The solubility product of PbCrO* exceeds2.8 x 10-13molz dm{'
mixture formed
l5 When an organic compound S goes through steam distillation at 101.0 kPa, the
distillate obtained contains
boils at 9g "C. The vapour pressureof water at 98 'C is 93.9 kPa. The
s?
20vo ofcompound s by mass. what is the relative molecular mass of compound
848 C6O D 84
AzI

16 The cell diagram for an electrochemical cell is shown below'

P(s) | Fe'z.(aq), e3*(aq) ll Ag.(aq) | lgtO
Which statement
The e.m.f. of the cell is 0.03 V under standard conditions and is 0 V at equilibrium.
about the cell is not true?
A The massof the cathode ncreases t equilibrium'
B There is no net ffansfer of electrons at equilibrium'
C The equilibrium constant at 25 "C is 3'22 dm3 mol-''
D The e.m.f. of,the cell increaseswhen NaCl is added o Ag*(aq)/Ag(s) half-ce1l.
an aqueous
17 A mass of 2.0 gof silver is deposited when a quantity of electric current passes hrough
an aluminium
solution of silver nitrate. If the same quantlty of electricity is used n the anodisationof
object, what is the maximum increase n the massof the object?
Ag is 108'0'l
lRllative atomic mass of O is 16.0, Al is 27.0 and
A 0.049g B 0.12 C 0.15 D 0.47g

reduction potentials of
18 One of the alloys used in a dental filling is AgrSn. The standard
respectively. which
Al3.(aq)/Al(s) and snr*(aq)/Ag,Sn(s) half-cells are -t.66 V and -o'05 v
filling?
statement is true when u pit"" of ulo-ittiu.tt comes into contact with the dental
A The -f""u value of the electrochemicalcell created s +1'61 V'
B The eleitrons flow from the dental filling to aluminium'
C The aluminium metal acts as the cathode'
D The Sn2* on is Produced.

19 Which compound has the highest lattice energy?

A NarO B NaCl C MgO D MgCl,

of the
20 Which statement best explains why the thermal stability of the carbonates of Group 2 metals
Periodic Table increases going down the group?
A The polarisation power of the metal ion towards the COr2- on decreases'
B The strength of ionic bond in the metal carbonate increases'
C The radius of the metal ion increases.
D The electronegativity of the metal decreases'
formula
2l Most ores contain zeolite which is a type of aluminosilicate with an empirical
NaAlSi2O6'HrO. Which statementabout the use of zeolite is not true?
A As a catalyst in petroleum refining
B As a superconductor in a microelectronic chip
C As an ion exchange esin in the softening of water
D As a dehydration agent in the petrochemical industry

)t which tetrachloride can bleach the colour of litmus paper at room temperature?
B GeClo C SnCl, D PbCl4
A SiCl4
kept away from
23 A prism is made of lead glass which contains PbO and SiO2. It should be
unstable.
A an acidic substance ecausePbO is a base. C heat becausePbO is thermally
are soluble'
B an alkaline substancebecauseSiO, is acidic. D water because PbO and SiO,
qgg
Acrual2009STPMChemistryExamit#i+.#ffi

 { Ammonia which is used as a fertiliser can be prepared in the laboratory. A 2.00 g of ammomum
chloride reacts with 2.00 g of calcium hydroxide. What is the volume of ammonia gas formed at
room temperature?
[Relative molecular mass of NH"CI is 53.5 and Ca(OH), is 74.0; molar volume of gas at room
temperature is 24 400 cm3.l
L 329 crfi B 456 cm3 C 678 cm3 D 912 crfi

25 X is an element in Group 17 of the Periodic Table. The percentage dissociation of hydrogen halide
HX at 2000 oC is shown in the table below.

HX }IF HCI HBr HI

Pe centage di ssociation 6XlO_5 o.4 4 30

Which statement explains the thermal stability of IIX on descending the group?
A The relative molecular mass ncreases. C The ionic characterof H-X bond decreases.
B The length of the H-X bond increases. D The intermolecular force increases.

26 Which reagent when added n excess o an aqueoussolution containing copper(tr) ions will produce
a dark blue solution as the final product?
A Aqueous ammonia C Aqueous sodium hydroxide
B Aqueous potassium odide D Aqueous potassiumhexacyanoferrate(Il)

27 Which reaction equation and catalyst conespond correctly?

Reaction equation CatalYst
A 2CO + Or- 2CO, CU O
B C6H6 Cl, CuHrCl + HCI Pt
-
C nCHr-{H = CH2 - CH2+, Ni
- +CH(CH3)
D CH3-(CHr),-CH = CHz+ H, * CH, - (CHr)*1 CH3 TiCl4

28 Aspartame is an artificial sweetenerwhich has the structural formula as follows:

H2N-qH-C-NH
??
CH-C-OCH3
-ll
CH, 9H ,
rl
cooH

Which functional group is not found in the aspartame molecule?

v
'.At

A Ester C Carboxyl group

B Amino acid D Carbonylgroup

29 A bromine molecule does not have a dipole moment such as in a hydrogen bromide molecule but
shows the sametype of reaction when reacted with ethene. This is so because
A the bromine molecule has a lone pair of electrons.
B the bromine molecule has a higher electron density.
C an induced dipole is formed when the bromine molecule approachesan ethene molecule.
D the Br-Br bond in bromine molecule is weaker than H-Br bond in hydrogen bromide molecule.

30 CH3CHTBT eacts with an aqueous solution of potassium hydroxide forming CH3CH2OJI, whereas
= C(CU,), as the
1CH,;,Cnr reactswith an ethanolic solution of potassiumhydroxide forming C4
major product. Which statement s true of the two reactions?
A The reactions occur at room temperature.
B The reactions occur through the formation of carbocation.
C The reactions are nucleophilic substitution and elimination respectively.
D The rate ofeach reaction s independentofthe concentrationofOH- ions.

594 ectual Z0O9STPM ChemistryExamination aper

from jasmine flowers 2-methylundecanal are the perfume industry'

31 Jasmone
The structural formulae of the compounds are shown below'
o
il
cH 2c*=c HcH2cHg cH3(cH2)8cH(cH3)CH
,,)\./,
\/ 2-Methylundecanal
1c".
Jasmone

Which reagent can be used to differentiate the two compounds?

A Acidified potassium C Alkaline iodine solution
B Ammoniacal silver nitrate solution D 2,4-Dinitrophenylhydrazinesolution

product which has two chirality

32 Air alkene reacts with bromine in tetrachloromethane to form a
centres. alkene could be
A 2-methylproPene C 2-methyl-2-butene
B 1-butene D 2-pentene

product does not phenol in its

33 phenol is an important commercial chemical. Which commercial
manufacturing?
A Food flavouring C
B D Dye

34 The reaction scheme of Z some reagents s shown below.

KMnOo/H. Fehling'ssolution
-Z ----_-_---+ No precipitate
White <'-_-:-- Compound
o
| 2,4-DinitroPhenylhYdrazine
V
ReddishYellowPreciPitate

Compound Z conldbe
/=\
A CqCHTCHO c ( ]FCHO
@"H2oH
acid to produce a compound
35 An active component in tear gas reacts with hot diluted hydrochloric
with a structural formula as follows:

,'cooH
cH=c.
-cooH

What is the structural formula for the comPonent?

A r^\
\ 2h"t=c.cH,
.CH, " @."="{il
u D ,,n ,CH,OH

@"'="(:i \9ftt=t..",on

36 Which reaction does not occur?

A + CH,NH, C6H5CONHCH,+
-
B C{COOH + C'HTOH O- CHTCOOCF, + HrO

C CH3CH2COCI+ CH,CHTOH - CH3CHTCOOCHTCH, HCI

D C6H5COOH+ CH,NH, O- C.HTCONHCH3+ HrO

Actual 20O9SIPM Chemistry Examination apet -595

37 A solution containing 7.3 x I02 g of an unknown amino acid reacts with excessnitrous acid to
produce 24.0 cm3of nitrogen gas at20'C. What is the unknown amino acid?
[Relative atomic massof C is 12.0,H is 1.0,Na is 14.0,and O is 16.0; 1 mol of gas occupiesa
volume of 24.0 dm3at 20 'C.l
A H3C-CH-COOH c H2N(CH2)4 H-COOH
I I
NH, NH,
o o
I
B HO-CH-COOH D HrN-C-CH2-CH{-OH
I I
NH, NH,

38 An organic compound has the following properties:

(i) It liberates white fumes with phosphoruspentachloride.
(ii) It dissolves n water to give a solution with a pH of more than 7
(iii) It can act as a buffer solution.
The structuralformula of the compound could be
A HrN-CH-CH2OH c HrN-CH-COOH
I I
(cHr)rNH, (cH2)4NH'
B HrN-CH-COOH D H2N-CH-CONH'
I I
cH2oH cH2cH3

39 Teflon, +CFr-CFr+, is a polymer which is used to coat cooking utensils.Which statementabout

Teflon is true?
A It is brittle. C It is thermally unstable.
B It is chemically inert. D Its softening temperature s low.

40 Parr of the structuralformula of a polymer is shown below.

ooo o
ililll
- NH-(CHr)5-C-NH-(CHr)5-C-NH-(CH2)5-C-NH-(CH,)5-{ -

Which statement s true of the polymer?

A Its monomer is optically active. C Its monomer is NH'(CH2)5CONH2.
B Its monomer dissolves n water. D Its monomer has a low melting point.

Section B
Search EN Upload Read free for 30 days

For each question n this section, one or more of the three numberedstatements to 3 may be
Download nowcorrect. The responsesA lo D should be of 19 (
17 selectedas follows:
) * Search document +

I and2 only are 2 and 3 only 1,2 and are i

correct. correct.
A= 1' ---r
slare
41 Which statement(s)about element X with an electronic configuration 1s22s22p63s23p63ff4s2
true?
1 X is situated n Group 2 of the Periodic Table.
2 X forms X2* andX3* ions.
3 X forms a complex on.

596 Actual ZO09STPMChemistryExaminationPaper

are three of Which

42 ammonia and
the bonding in the three molecules s/are true?
1 The hybridisation of C, N and O atoms s spr'
2 Thebond length in descendingorder is C-H, N-H' O-H'
at the of their atoms n an order N'
3 The number of pair elections
y the following equation:
43 A reversible reaction at a certain temperaturecan be represented
k.
+ B(g): C(g) AIf = negative
K-t

Whichstatement(s)aboutthereactionis/aretruewhenthetemperatureisincreased?
1 The increases n the value of ft r is more than that of k,'
The value ofK" decreases.
3 The values of and K" are same'

:2NO(g) varies with temperature

The equilibrium constant K" for the reaction Nr(e) + Or(g)
f in graPhbelbw.

1
T

Which statement(s) s/are fiue of the above reaction?

1 The forward reaction is endothermic'
T\epercentage of the NO decreaseswhen temperature ncreases'
3 T h e p e r c e n t a g eo f t h e p r o d u c tN o i n c r e a s e s w h e n th e p r e s s u r e i n c r e a s es .
are shown below'
45 The standard eduction potentials or severalhalf-cell reactions

Half-cell E"lV
Fe2*(aq) r"-----. 4.44
Fe3'(aq) + 3g ,------.Fe(s) -o.04
Fe3*(aq)+ e- . '-. Fe2*(aq) +0.17
3 Qt](5) +0.34
a solution mixture containing Cu2*'Fez',
which reaction(s)will occur when iron powder is added o
and Fe3* ons each having a concenffationof 1'0 mol dm-3?
, -
2 Fe(s) + Cu2*(aq) Fe2*(aq)+ Cu(s)
---. Cu2+(aq) 2Fe2*(aq)
3 Cu(s) + 2Fe3*(aq) :

step the Ostwald process, nitrogen dioxide reacts with water to form nitric acid'
46 In last
Which statement(s) s/are true of this step?
1 Platinum is used as a catalYst.
2 Disproportionation reaction occurs'
Nitrogen monoxide gasformed is recycled'

4'.1Which complex ion(s) is/are of octahedralshape?

2 [Ni(H2O)6]" 3 [CuClrl2-
1 [Fe(H,Oj6]h

Actual 2009 ChemistryExamination aper

48 Two organic compounds P and Q have the hydroxyl group in their molecules. Compound P forms
a salt when it dissolves n aqueoussodium hydroxide, while Q does not. What could compound P
and Qbe?
o
/=\
I (]FoH cH3oH

2 Hs{O
-
ot (cH3)rcHoH
\-,/
s cH3cH2oH
@cr,on
49 Benzete undergoes a nitration reaction according to the following equation:

rAl . 3 ?" + H,o

v -t
"*o" 55'c (n)
v
Which statement(s)s/are true of the reaction?
I The sulphuric acid acts as a catalyst.
2 The NOr* ion acts as a Lewis acid.
3 The mechanism nvolved is an elecffophilic substitution reaction.

50 What is/are the intermediate species formed when 2-propanol reacts with hydrogen chloride gas to
produce 2-chloropropane?

1 CH3CHCH3 2 CH3CHCH3 3 CH3CHCH3

I
o 9H,
{i i.lli{fritER- ;i T im e: 2hr 30 min
SectionA[40 marks]

Answer all questions n this section.

1 A real gasX behavesalmost ike an ideal gas.For n mol of gasX at pressure , the graph of volume
V versus temperature Z is shown below.

Volume V/cm360

598' Actual 2009 STPMChemistryExaminationPaper

(a) (D What is the most probable dentity of gasX? Explain your answer. 13marksl
Gas X'.

Explanation:
(ii) On the graph above, sketch and label a graph of the variation in volume with temperature
at a lower pressurep' while other conditions remain constant. fl markl
(iii) At pressure and temperature0 oC, a gas I showsa negative deviation from an ideal gas.
Mark the expectedvolume of gas I on the above graph.Explain your answer. [3 marksl

Explanation:
(b) 18 elements n the Period 4 of the Periodic Table can be classified into the s, p and d-blocks
elements.
(i) Why are the elementsGa to Kr classified as p-block elements? fl mark]

(ii) Why is the third ionisation energy of manganese igher than that of iron? 12 marksl

2 (a) The boiling point-composition curves or the mixture of ethanol and water at constantpressure
is shown in the graph below.