MATERIAL SAFETY DATA SHEET

ANTIOXIDANT CS 1101

SECTION 1 CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Substance: 4,4'-Thiobis(6-tert-butyl-m-cresol)

Trade Names/Synonyms: antioxidant CS 1101

4,4'-Thiobis-(2-tert-butyl-5-methyl-phenol); 4,4'-Thiobis-(6-tert-butyl-3-methyl-phenol); C22-H30-O2-S

Chemical Family: Hindered phenol

Manufacturer's Name: Guangzhou Chengshuai New Material Co.,Ltd.

Address: No.10, Jiqingxiang, Shiyicun, Shilou Town, Panyu Dist., Guangzhou

E-Mail: info@hhochem.com

Emergency Telephone Number : 86-20-84697353

Information Telephone Number: 86-20-34708468 Fax: 86-20-84697353

SECTION 2 COMPOSITION, INFORMATION ON INGREDIENTS

Ingredient Name CAS No. EC Number % Exposure Limits

Y (Hazardous)
15 mg/m3 (PNOR) (OSHA PEL TWA)
Not established (OSHA PEL STEL)
4,4'-Thiobis(6-tert-butyl
96-69-5 202-525-2 Min. 98 Not established (OSHA PEL CEIL)
-m-cresol)
10 mg/m3 (PNOS) (ACGIH TLV TWA)
Not established (ACGIH TLV STEL)
Not established (ACGIH TLV CEIL)
Indented chemicals are components of previous ingredient.
PNOR = Particulates Not Otherwise Regulated
PNOS = Particulates Not Otherwise Specified

SECTION 3 HAZARDS IDENTIFICATION

NFPA Ratings (Scale 0-4): Health=NR(Not Rated) Fire=NR Reactivity=NR

Emergency Overview:

Phenolic odor, white to off-white Powder

May cause allergic skin reaction.

Dusts can form an explosive mixture with air.

Potential Health Effects:

Inhalation: As with any dust, mechanical irritation is possible to mucous membranes and the respiratory tract.

Skin Contact: May cause allergic skin reaction. May cause slight skin irritation.

Eye Contact: May cause slight eye irritation.

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Ingestion: Not expected to be a hazard in normal industrial use.

Carcinogen status:

OSHA: N

NTP: N

IARC: N

SECTION 4 FIRST AID MEASURES

Eyes: Flush with large volumes of water for at least 15 minutes. Get medical attention.

Skin: Wash with large volumes of soap and water for at least 15 minutes. If irritation develops, get medical attention.

Ingestion: If conscious, give person 1 to 2 glasses of water. Get medical attention immediately.

Inhalation: Remove person to fresh air. Get medical attention.

Antidotes: No information available

Notes to Physicians and/or Protection for First-Aiders: No information available

SECTION 5 FIRE FIGHTING MEASURES

Fire And Explosion Hazard: Under fire conditions, toxic and irritating fumes may be emitted.

Dust-air mixtures may ignite or explode.

Extinguishing Media:

Dry chemical, carbon dioxide(CO2), water spray or regular foam.

Firefighting:

Move container from fire area if you can do it without risk.

Wear a self-contained breathing apparatus and protective clothing to prevent skin and eye contact in fire situations.

Use agents suitable for type of surrounding fire. Avoid breathing hazardous vapors, keep upwind.

Flash Point: 215℃(419℉)

Autoignition Point: 370℃(698℉)

Lower Flammable Limit: 30mg/㎥

Upper Flammable Limit: No data available.

Hazardous Combustion Products: Thermal decomposition products may include toxic oxides of carbon and
oxides of sulfur.

SECTION 6 ACCIDENTAL RELEASE MEASURES

Accidental Release Measures: Shut off all sources of ignition.

Wearing appropriate personal protective equipment, carefully sweep up material

and place in suitable labeled containers for disposal.

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Avoid creating a dusting condition.

Use only non-sparking tools.

Personal Precautions: See Section VIII.

Environmental Precautions: Avoid releasing to the environment.

SECTION 7 HANDLING AND STORAGE

Handling: Use appropriate personal protection equipment.

Avoid eye, skin and clothing contact.

Avoid breathing dust.

Avoid creating a dusting situation.

Keep away from heat, sparks and flame.

Prevent buildup of static electricity.

All equipment should be properly grounded.

Storage: Store in a cool, dry, well-ventilated area away from incompatible materials.

Store away from heat, sparks, and flame.

Keep container tightly closed.

SECTION 8 EXPOSURE CONTROLS, PERSONAL PROTECTION

Exposure Limits: See Section 2.

Ventilation: Use local exhaust to minimize dusting.

Use mechanical ventilation for general area control.

Eye Protection: Chemical safety glasses with side shields or chemical safety goggles.

Skin And Body Protection: Working clothes, closed footwear.

Respirator Protection: Effective dust mask.

Hand Protection: Protective gloves.

Work Hygienic Practices: Wash thoroughly after handling. Wash contaminated clothing before reuse.

Do not eat, drink, chew gum, use tobacco products, or apply cosmetics in work areas.

SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES

Description: Phenolic odor, white to off-white Powder.

Molecular Weight: 359

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Molecular Formula: C22-H30-O2-S

Boiling Point: Not available. (Decomposes at 572℃)

Melting Point:160-164 ℃

Vapor Pressure: 6.7KPa at 20℃

Vapor Density: Not available

Specific Gravity: 1.1(20℃)

Water Solubility: 0.08%(25℃)

Octanol/Water Partition Coefficient: Log Pow >8.24

Viscosity: Not available

pH: Not available

Odor Threshold: Not available

Evaporation Rate: Not available

SECTION 10 STABILITY AND REACTIVITY

Reactivity: Stable under normal temperatures and pressures.

Conditions To Avoid: None.

Incompatibilities: Strong oxidising agents.

Hazardous Decomposition: Thermal decomposition products may include toxic oxides of carbon and oxides of

sulfur.

Polymerization: Hazardous polymerization has not been reported to occur under normal temperatures and
pressures.

SECTION 11 TOXICOLOGICAL INFORMATION

Toxicity Data: > 5,010mg/Kg dermal-rabbit LD50;

4,750mg/Kg oral-mouse LD50;

50mg/Kg Intraperitoneal-mouse LD50;

3,200mg/Kg oral-rabbit LD50;

2,345mg/Kg oral-rat LD50;

SECTION 12 ECOLOGICAL INFORMATION

Environmental Impact Rating (0-4): No data available

Acute Aquatic Toxicity: 0.16 mg/L LC50 in Trout (96H); (48H) = 0.15 mg/L; (24H) = 0.27 mg/L.

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>1000 mg/L LC50 in midge (24H); (48H) >1000 mg/L; NOEC = 100 mg/L.

0.73 mg/L LC50 in bluegill (24H); (48H) = 0.29 mg/L; (96H) - 0.24 mg/L.

0.21 mg/L LC50 in fathead minnows (24H); (48H) = 0.17 mg/L; (72H) =0.15 mg/L; (96H) = 0.14mg/L

0.70 mg/L LC50 in fathead minnows (24H) =; (48H) = 0.54 mg/L; (96H) = 0.36 mg/L

>0.36 mg/L LC50 in chironomus tentans

0.23 mg/L EC50 in Daphnia magna (24H); (48H) = 0.16 mg/L; NOEC = 0.063 mg/L.

0.7 mg/L EC50 in Daphnia magna (48H)

126 mg/L EC50 in algae (96H)

Degradability: No data available

Log Bioconcentration Factor (BCF): No data available

Log Octanol/Water Partition Coefficient: Log Pow >8.24

SECTION 13 DISPOSAL CONSIDERATIONS

Disposal Considerations: Dispose of waste at an approved chemical disposal facility in compliance with all

current Local, State/Province, Federal/Canadian laws and regulations

SECTION 14 TRANSPORT INFORMATION

U.S. DOT

Proper Shipping Name: Not regulated

AIR - ICAO OR IATA

Proper Shipping Name: Not regulated

WATER – IMDG

Proper Shipping Name: Not regulated

SECTION 15 REGULATORY INFORMATION

TSCA Inventory Status: Y

CERCLA Section 103 (40CFR302.4): N

SARA Section 302 (40CFR355.30): N

SARA Section 304 (40CFR355.40): N

SARA Section 313 (40CFR372.65): N

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ANTIOXIDANT CS 1101

OSHA Process Safety (29CFR1910.119): N

California Proposition 65: N

SARA Hazard Categories, SARA Sections 311/312 (40 CFR 370.21)

Acute Hazard: N

Chronic Hazard: Y

Fire Hazard: N

Reactivity Hazard: N

Sudden Release Hazard: N

SECTION 16 OTHER INFORMATION

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