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History of Atomic

Structure
Democritus 460 BC

Greek Philosopher
Suggested world was made of two things –
empty space and “atomos”
➢ Atomos – Greek word for uncuttable
2 Main ideas
➢ Atoms are the smallest possible
particle of matter
➢ There are different types of atoms for
each material
John Dalton’s
Atomic Theory 1804

1. All matter is made of atoms.


2. Atoms of one element are all the
same.
3. Atoms cannot be broken down into
smaller parts
4. Compounds form by combining atoms
Dalton’s Early
Atomic Model “Billiard Ball” model
he envisioned atoms
as solid, hard
spheres,
like billiard(pool)
balls, so he used
wooden balls to mod
el the atoms
J.J. Thomson

• 1897
• Discovered the electron

• He was the first scientist


to show the atom was made
of even smaller things
JJ Thomson
Used the Cathode ray tube to discover electrons
Thomson’s Experiment
Voltage source
- +

Vacuum tube

Metal Disks
Thomson’s Experiment
Voltage source
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Thomson’s Experiment
Voltage source
- +
Thomson’s Experiment
Voltage source
- +

Passing an electric current makes a


beam appear to move from the
negative to the positive end
Thomson’s Experiment
Voltage source
- +

Passing an electric current makes a


beam appear to move from the
negative to the positive end
Thomson’s Experiment
Voltage source
- +

Passing an electric current makes a


beam appear to move from the
negative to the positive end
Thomson’s Experiment
Voltage source
- +

Passing an electric current makes a


beam appear to move from the
negative to the positive end
Thomson’s Experiment
Voltage source

-
By adding an electric field
Thomson’s Experiment
Voltage source

-
By adding an electric field
Thomson’s Experiment
Voltage source

-
By adding an electric field
Thomson’s Experiment
Voltage source

-
By adding an electric field
Thomson’s Experiment
Voltage source

-
By adding an electric field
Thomson’s Experiment
Voltage source
+

-
-
Adding an electric field cause the beam to
move toward the positive plate.
Thomson concluded the beam was made of
negative moving pieces.
Thomson’s “Plum Pudding” Atom
Model
Atomic Structure: Electrons
■ Cathode-Ray Tubes: J. J. Thomson (1856-1940) proposed that cathode rays
must consist of tiny negatively charged particles. We now call them
electrons.

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0
Atomic Structure: Electrons
■ The strength of the deflecting magnetic or electric field. The
stronger the magnet or the higher the voltage on the charged
plate, the greater the deflection.

■ The size of the negative charge on the electron. The larger the
charge on the particle, the greater its interaction with the
magnetic or electric field and the greater the deflection.

■ The mass of the electron. The lighter the particle, the greater its
deflection (just as a PingPong ball is more easily deflected than a
bowling ball).

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Atomic Structure: Electrons
■ By measuring the amount of deflection caused by
electric and magnetic fields of known strength,
Thomson calculated charge-to-mass ratio (e/m) of
an electron.

■ Where e is the magnitude of the charge on the


electron in coulombs (C) and m is the mass of the
electron in grams.

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2
Democritus, Dalton, Thomson
Video
Millikan’s Oil Drop Experiment
• Determined the charge on an electron
• Used Thomson’s charge to mass ratio to
calculate the mass of an electron
Millikan’s Oil Drop Experiment
■ R. A. Millikan (1868–1953) devised a method for
measuring the mass of an electron.

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5
Millikan’s Oil Drop Experiment
■ With the plates voltage and the mass of the
droplets known, Millikan calculated the
charge on a droplet as 1.602176 x 10-19C.
■ Substituting the value of e into Thomson’s
charge-to mass ratio:

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