CPP FIITJEE BIOMOLECULES

1. Which of the following zwitter ionic form is not correctly represented for an amino
acid?
H3N
H3N COO
COO

(A) (B)

NH2
H2N
COO

H3N
COO
(C) (D)

NH COOH
C
H2N NH2

2. Which of the following amino acid is not correctly represented with its name?
COOH
COOH
H NH2
H2N H
(A) HO H (B)
CH2Ph
CH3
L-phenyl lalanine
L- threonine
COOH
COOH
H2N H
(D H CH3
(C) H3C H
) NH2
C2H5
L - alanine
L - isoleucine

i NH4Cl;KCN equimolar 

3.  X 
 ii H  aq
 CH3 CH NH2  COOH

Compound[X] is

O
(A) Cl (B)

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 O O
(C) (D)
H NH2

4. Amino acid whose isoelectric point is 5.4.

H2N
COOH
H2N
COOH
(A) (B)
COOH

H2N
COOH
H2N
COOH
(C) (D)
CONH2

NH2

5. Force is not responsible for the stability of 2o and 3o structure.

(A) Hydrogen bonding (B) Salt bridges (Ionic interections)
(C) Hydrophobic interections (D) Ion-dipole interection

6. Total number of atoms present in a plane in a single peptide bond are

(A) 4 (B) 8
(C) 2 (D) 6

7. Select the correct statement?

(A) Denautration of protein disturb the 2o and 3o structure of protein
(B) 1o structure arises because of folding of polypeptide chain
(C) 3o structure is stabilized only by hydrogen bond
(D) Selective hydrolysis of protein can be carried out using 6 M HCl

8. 
H3 N CH  CO  NH  CH  CO  NH  CH  CO  NH  CH  COO 

H G1 G2 H
Tetrapeptide which will be negatively charged at pH = 7, when G1 and G2 are
respectively
(A) –CH2CONH2 and CH3 (B) –CH2COOH and –CH2CONH2
(C) –CH2OH and CH3 (D) H and CH3

9. Which of the following property does not conform the dipolar structure of amino
acids?
(A) High melting point (B) High dipole moment
(C) High dissociation constant (D) High solubility in polar solvent

10. Presence of which amino produces a ‘Kink’ in the - helix of a protein.

(A) Tyrosine (B) Proline
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 (C) Glycine (d) Lysine

PART – B

1. Compound which gives same osazone as given by

CHO

CH 2OH
(A) CHO (B) CH 2OH

CH2OH CHO
(C) CHO (D) CH 2OH

CH2OH CHO

2. Which of the following is an epimer of  – D – glucopyranose.

(A ) (B)

HO H H OH
C C
O O

CH 2OH CH2 OH

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 (C) (D)

H OH HO H
C C
O O

CH2OH CH 2OH

3. Which of the following is correct chair conformation of  – D – glucopyranose.

OH CH 2OH (B) H CH2OH
(A) O O
H HO
H OH
H HO H OH
OH HO
H OH H H H H
(C) H CH2OH (D) H CH2OH
O O
HO HO
H H
H H H OH
HO HO
H OH OH H HO H

4. Select incorrect statement.

(A) Starch consist of D-glucose units
(B) Cellulose consist of D-glucose units
(C) In starch glucose units are linked through 1, 4 –   glycosidic linkages
(D) In cellulose glucose units are linked with 1, 2 –  glycosidic linkages

5. Select incorrect statement about sucrose

(A) Sucrose is a non reducing sugar
(B) Sucrose on hydrolysis gives an equimolar mixture D(+) – glucose and D(+) –
fructose
(C) linkage between glucose and fructose is 
(D) It does not undergo mutarotation

6. A and B are aldohexoses. Compounds A and B yield the same optically active alditol
when they are reduced with hydrogen and a catalyst. A and B yield different
phenylosazones when treated with phenylhydrazine. Compound A and B are
respectively.
(A) CHO CHO (B) CHO CHO

and and

CH2OH CH2OH CH2OH CH2OH

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 (C) CHO CHO (D) CHO CHO

and and

CH2OH CH2OH CH2OH CH2OH

7. D – Galactose is a C – 4 epimer of D – glucose structure of L – Galactose is

(A) CHO (B) CHO

CH 2OH CH 2OH
(C) CHO (D) CHO

CH 2OH CH 2OH

8. D – Mannose is given as
CHO

CH 2OH
Than L – Mannose
(A) CHO (B) CHO

CH 2OH CH 2OH

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FIITJEE Ltd., N-W Centre, 31, 32, 33, Central Market, West Avenue Road, Punjabi Bagh, New Delhi - 26, Ph: 011-45634000
 (C) CHO (D) CHO

CH 2OH CH 2OH

Br  H O
9. 2 2
Glu cose  Product is
(A) Glucaric acid (B) Gluconic acid
(C) Hexanoic acid (D) Bromo hexane

10. Which of the following represents the anomer of the compound shown?
HOCH2 O H

H H
H OH

OH OH
O H O OH
HOCH2 HOCH2

(A) OH H (B) H H
H H H
OH

H OH OH OH
O OH
H

HO
(C) OH (D) None of these
HOCH2 H

H H

ANSWERS
PART – A

1. B 2. A 3. C 4. D
5. D 6. D 7. A 8. B
9. C 10. C
PART – B
1. B 2 A 3. D 4. D
5. B 6. D 7. D 8. D
9. A 10. B

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FIITJEE Ltd., N-W Centre, 31, 32, 33, Central Market, West Avenue Road, Punjabi Bagh, New Delhi - 26, Ph: 011-45634000