Sri Chaitanya IIT Academy.,India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI

A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
SEC: Jr.C-IPL WTA-12 Date: 30-10-22
Time: 10:00AM to 01:00PM JEE-ADV_ (2021-P2) Max. Marks: 180

KEY SHEET
PHYSICS

1 B 2 C 3 C 4 D 5 C
6 C 7 7 8 9 9 2 10 8
11 1 12 3 13 A 14 B 15 C
16 D 17 4 18 5 19 2

CHEMISTRY

20 ABCD 21 CD 22 AB 23 BC 24 BD
25 AB 26 5 27 2 28 5 29 1
30 4 31 8 32 B 33 C 34 D
35 C 36 4 37 6 38 9

MATHEMATICS

39 AD 40 AB 41 ABD 42 AB 43 ABCD
44 BC 45 2 46 0 47 2 48 6
49 3 50 1 51 A 52 B 53 A
54 C 55 8 56 2 57 2
 Sri Chaitanya IIT Academy 30-10-2022_Jr.C-IPL_Jee-Adv(2021-P2)_WTA-12_Key & Sol's

SOLUTIONS
PHYSICS
1. 4 4 
Net mass ,M =    2 R   R   Where  is the density of the material of sphere. So,
3 3

3 3 
M  3M  GM1 GM 2
  3
Now V=V2R at -VR at V2R =- and VR =
4   28 R 
  2 R   R  2R 2R
3 3 centre centre

3
4  8 4  M
Where, M1       2 R  M and M 2       R 
3 3

3  7 3  7
9GM
substituting in equation (1), we get V=-
14R
2.  v  v0   2  1
% age increase = e
 v   100  % age increase =    100  40%
0  1 
3. dV
Since E=   dV=Edx  dV=Kx -3dx    dV=K  x -3dx
dx
 x -3+1  K
 -V=K   V=
 -3+1 2x 2
4.
n n  n-1
Total number of interactions = C2 =
2
5.  GMm
  , rR

U r    r
 GMm , r  R

 R
6.


R Horizontal

At height h=R, the distance of the particle from centre of earth is r =2R. Let v be
the velocity at that point . They by Law of conservation of mechanical Energy, we have
GMm 1 2 GMm 1 2
 U+Ksurface =  U+Kat h   R
 mve  
2
 mv
RR 2
2GM 1 GMm GMm GMm
Since ve   mv 2    
R 2 R R 2R
GM
v Let  be the angle of its velocity with horizontal , then by Law of
R

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conservation of angular Momentum about centre of earth , we have

 
mve R cos 450  mvr cos 

2GM 1
R
 cos  
R 2  1    600
GM 2
 2 R
R
7. 3
4 3 4 R 1
Mass of complete sphere M   R  Mass removed M’ =      M
3 3 2 8
Force due to hollow sphere F2 and P equals force due to solid sphere at P minus force due to
removed mass at P.

 M
G  m
GMm  8  GMm  1 4 
 F2 = -  F2 = 
4R 2
 3R 
2 2 
R  4 9  8 
 
2
GMm  1 1  GMm  9  2  7 GMm
 F2 =   F =  F =
R 2  4 18  R 2  36 
2 2
36 R 2

8. F1 GMm 36R 2 9
= × =
F2 4R 2 7GMm 7
9. If m be the mass of satellite, then by Law of conservation of Angular momentum, we have
mv1  2R  =mv2  4R   v1  2v2 ...............(1)
Also, by Law of conservation of Mechanical Energy , we have
GmM 1 2 GmM 1 2
 U+K 2R =  U+K 4R   2R
 mv1 
2 4R
 mv2
2
GM  1 1 
2

1 2

v1  v22 
R 2 4
2 2 GM
    4v2  v2  2 R  v2 
GM
6R
Since , v1  2v2

2GM
 v1 =
3R
10. mv12 GmM 4R 2 2  4R 2   2GM  8R
=  r = v =
1     r =
 2R  2  GM   3R 
1 1
r1 GM 3

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 Sri Chaitanya IIT Academy 30-10-2022_Jr.C-IPL_Jee-Adv(2021-P2)_WTA-12_Key & Sol's
11.  GMm
 ,r  R
F   r2

 0 ,r  R
12.  GMm
 ,r  R
 r2
F (r )  
 4 Grm , r  R

 3
13. T12 r13 1 r13
2
= 3  3  r2  4r1  r2  4×104km
T2 r2 64 r2

 v1 
2 r1
and v2 
2 r2
 v1 
2 104  
kmh 1 And
T1 T2 1

2  4  104 
v2     104 kmh -1  Speed of S2 relative to S1 is v21
8

v21    104kmh-1

14. v2  v1

r2  r1

15. GMm GMm 1 GMm mgR

U i =- U f =-  U=U f -U i   U 
R R 5 R 5
R+
4
16. 1 2
By law of Conservation of Energy U  mv 2  v = gR
2 5

17. 4 4
G  r3D  r3D r6
GMM
F  3 3 F   F r 4
 2r 
2
 4r 
2
r 2

18.  h  1 g mg 100
Given mg= 100N g 1  g 1    g 1     mg1    50 N
 R  2 2 2 2

19. 2GM
Ve 
Rh

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 Sri Chaitanya IIT Academy 30-10-2022_Jr.C-IPL_Jee-Adv(2021-P2)_WTA-12_Key & Sol's

CHEMISTRY

 AB  B
20. AB2 
 pAB  pB 200  200
g g g Kp    100
600 0 0
pAB2 400
600  x x x  600  x  800
400 200 200 x  200

%    
x  a   200  600      33.3%
 100   100 

k p  kc  RT  ; n   n p  nR  gases If n     ve then kp  kc
n
21.

If n    ve then kp  kc If n  0 then kp  kc Option (C) & (D) have

n    ve

22.  2 O3

1O2 
 
  
3  2   5  MO 32
1     M eq   2
 
 1   2   1.06  2  0.6 
1 0
2
 3  3
1 
3  3  3
2
1 
3
3
 ,  %  60%
5

32
M eq   40
0.8

 2O3 ;  0.6
3O2 

 2  10 
2

    25   1 
 PO3 
2
kp        0.2

3 0.8 
kp   125   5 
 PO2   1 
3 3

 10 
 0.8 

23. Iodination is reversible reaction

R – H + I2 
 R – I + HI

24. Conceptual
25.

26. 
 H 2O  CO
H 2  CO2   x  x 
   
0.6 0.6 0 0 kc   1  1  4
x
 2  H 2Oeq  x  0.4M
 0.6  x   0.6  x  0.6  X
 0.6  x   0.6  x  x x 
 1  1 
 
1 1 1 1

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 Sri Chaitanya IIT Academy 30-10-2022_Jr.C-IPL_Jee-Adv(2021-P2)_WTA-12_Key & Sol's
27. NH 4C s

 NH 3  HCl


 vap   g  K p  P1  P1  81  P1  9atm
p1 p1

Ptotal  9  9  18atm   2  9   x  9 x  2

Active mass of gas at STP    

28. n 1mole  1 
 M
 V  22.4lit  22.4 

29. n 2 1000
M   0.1M
v 40  500
30. Conceptual
31. Conceptual
n   np  nR    2  2  0 k p  kc  RT  k p  kc  RT   kc k p  kc  49
n 0
32.

33.   22.4  
 0.5     700 
p
nRT
PH 2  PI2    273   PH 2  PI2  4.1atm
V  7 
 
 

 2x
2
 2HI 4.14.10  4.1  x  4.1  x  2x K p 

H 2  I 2 
  49
 4.1  x 
2

2x
 7  x  3.188 Ptotal   4.1  x    4.1  x   2x  4.1  4.1  8.2atm
 4.1  x 
34. Conceptual
35. When alkyl fluorides are primary and secondary it is poor leaving group.
36. 2 A  2B 2C  2D

 C  D     A B  
2
1
K C      1 C  D A  B K c*      2
  A B   16  C  D  

 C  D     A B  
2 2

 KC   K c   1 * KC
1
 
2
* 2
   
*
 1 K c*  4
         
A B C D 16

37. KC  K1  K 2  K3 K C  2  4  3  24

38. Conceptual

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MATHEMATICS
39. 
Common domain of sin 1 x,cos1 x,tan 1 x is 1,1 & sin   x
 cos 1 x 
2
       3
a   tan 1  1    b  tan 1 1   
2 2 4 4 2 2 4 4
2 
 
40.
2 2  1  3  2 tan 1 2 2  1  2 tan 1 3  2.  A 
3 3
1 1  23  3 
Now 3sin  sin 1    sin 1  0.851  sin 1 
3  27  2 3
3 3    
Again Sin  sin 1  0.6  sin 1
-1
 B    2
5 2 3 3 3 3
1  1  1  1  -1  1 
41.
Clearly n term=n +n+1 Sn  tan    tan    ....tan  2`
th 2
 3  7  n +n+1
 n 1 n 
  tan 1  
 1  n  n  1 

  tan 1  n  1  tan 1 n 
 tan 1 2  tan 11  tan 1 3  tan 1 2  ......  tan -1  n+1 -tan -1  n 
 n  1  1  n 
 tan 1  n  1  tan 1 1  tan 1    tan 1 
 1  n  1  n  2 
 10   5   
 s10  tan 1    tan 1   S   
 12   6 2 4 4
 6  10 
S6  tan 1    tan 1  3 / 4 S20  tan 1    cot 1 1.1
 8  11
42. Clearly lim f  x   lim f  x  .Also lim f  x = lim f  x New
x1 x1 x 2 x 2

 5 0  x 1

f 1  x   8 x  3 1  x  2 lim f 1  x   lim f '  x   f is not differentiable at x=2
x 2 x 2
 3 
 x 2

43. sin  x  2 ,cos  x  2 are continuous everywhere 4  x  6  2  x  2  4

 8<  x-2 <64  a>64
3

 a  c  x  c  2  x 2  
44. a c
b 
2
 f  0
2
f is continuous  ltx0
x2
a c
 a  c  0, c  2  0  b   0  c  2, a  2 ,1  b  1  0
2 2
 b  2  a  b  c  2  a  b  4 f is differentiable

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 x 2
x  4
 x  3
 x x 2 x3 
a 1     bx  x    c  1      2 x
 2! 4!   3!   1! 2! 3! 
 ltx0 3
x
1 1 1
 c  2   f '  0  1/ 3.
3! 3! 3
45. tan  x-y 1+tanxtany  tan  x  y   y  1  tan x tan y 
g  y   lt  lt .
x y y-x y-x
+ tanxtany
x y  x  y  1  tan x tan y 
y y

g  y   y  g  x   x The graph of h  x  min  f  x , g  x   min  x 2 ,  x is

X
1 1

Clearly f(x) is continuous x  R. No. of discontinuities =0 clearly f(x) is

non differentiable at two points i.e at x  0, 1

46. tan  x-y 1+tanxtany  tan  x  y   y  1  tan x tan y 

g  y   lt  lt .
x y y-x y-x
+ tanxtany
x y  x  y  1  tan x tan y 
y y

g  y   y  g  x   x The graph of h  x  min  f  x , g  x   min  x 2 ,  x is

X
1 1

Clearly f(x) is continuous x  R. No. of discontinuation =0 clearly f(x) is

non differentiable at two points i.e at x  0, 1

47. f  x f  y =f  x +f  y +f  xy -2

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x=1=y   f 1   f 1  f 1  f 1  2  f (1)  2
2

 1  1
Put y  1 / x f  x  f   =f  x  +f    f  x  x  1
n
  x   x

f  2  5  2n  1  5  n  2 f '  x  2 x  f '  3  6

48. f  x f  y =f  x +f  y +f  xy -2

x=1=y   f 1   f 1  f 1  f 1  2  f (1)  2

2

 1  1
Put y  1 / x f  x  f   =f  x  +f    f  x  x  1
n
  x   x

f  2  5  2n  1  5  n  2 f '  x  2 x  f '  3  6

49. a  cos1  cos20  20  6 b  cos1  cos30  10  30

c  sin 1  sin  4  10  10  3 Now a+b+c = 

 
sin 1  sin x  x    x   
2 

 Greatest integer is 3

50. 5sec1 x  10sin 1 y  10  x  1, y  1

   

 tan tan 1  1  cos 1 0  tan  
 4
  1
2

   
51. 1 1
f  x  sin cot 1  x  1  cos tan 1 x  
x2  2 x  2 x2  1

Sec: Jr.C-IPL Page 9

 Sri Chaitanya IIT Academy 30-10-2022_Jr.C-IPL_Jee-Adv(2021-P2)_WTA-12_Key & Sol's
1  x2 1
a b   1  x2 f  x  0  x 2  2 x  2  x 2  1  x 
2  x2 2

   
52. 1 1
f  x  sin cot 1  x  1  cos tan 1 x  
x2  2 x  2 x2  1

1  x2 26 1 2 1 24
a b   1  x2 a 2   x2  b  1  x2  1  
2  x2 51 25 25 25

53. f  x  x 2n g  x 
f  x = x +ax+3 g  x =x+b f  x  lim
2
n 1+x 2n

f  x  +x 2n g  x  f  x  +x 2n g  x 
lt F  x  lt  F  x  lt  . lt  lt  lt
x1 x1 x1 x 1+x 2n x1 x 1+x 2n

 lt  f  x   lt  g  x  1  a  3  1  b  b  a  3
x1 x1

54. f  x  x 2n g  x 
f  x = x +ax+3 g  x =x+b f  x  lim
2
n 1+x 2n

lt F  x  lt  F  x  lt  g  x   lt  f  x   1- a+3 = -1+b  a+b=5

x1 x1 x1 x1

55. f  x  3x , o  x  3  0  3x  9  f is discontinuous at x = 1,2,3,4,5,6,7,8, i.e 8 points

of discontinuity

56.  x  1 x  1 is differentiable at x =-1, x  2 is not differentiable at x=2, sin x not

differentiable at x =0

K  K  1  
57. n
1  1 
 n

1  1  
3   cot 1  2.
1
  2      
3 tan  2 
k  k  1 
n 1 k 1 n 1 k 1

1

 1     1 1


3       3.   2  .......  3. 4  1
n 1  
 2 4 
n 1 4 4  11/ 4

Sec: Jr.C-IPL Page 10