Concept Adv (1) 4 Soln

1
AITS-CRT-IV (Paper-1)-PCM (Sol)-JEE(Advanced)/16
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ANSWERS, HINTS & SOLUTIONS
CONCEPT RECAPITULATION TEST – IV

Top 500 All India Ranks bagged by FIITJEE Students from All Programs have qualified in JEE (Advanced), 2015.
(Paper-1)
ALL INDIA TEST SERIES
Q. No. PHYSICS CHEMISTRY MATHEMATICS

1. A, C A, C B, C, D
2. A, C B, C, D C
3. A, B, C A, B, C B, C
4. B, C A, C A, B
5. A, B, C, D A, C B, D
6. A, B, C B A, B, D
7. A, B A, B, C A, B
8. A, B, D B, C, D A, D
9. B, C, D A, B, C A, D
10. A, B A, C C, D
(A)  (q, r, s) (A → (q, r, t) (A)  (r)
(B)  (p, s) (B → (p, q, s) (B)  (p)
1.
(C)  (p) (C → (p) (C)  (q)
(D)  (q, r) (D → (r, s) (D)  (s)
(A) (q) (A → (p, q, s) (A)  (p, r)
(B) (r) (B → (r, t) (B)  (q)
2.
(C) (p) (C → (p) (C)  (t)
(D) (s) (D → (r, t) (D)  (p, q, r, s)
1. 4 7 2
2. 1 4 1
3. 1 6 4
4. 5 3 6
5. 6 4 3
6. 2 1 4
7. 2 6 2
8. 3 8 6
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Physics PART – I
SECTION – A
1. Asteroid  I Asteroid  II
GM GM  R 
Field E = 3 x Field EII = 3  
R R 2
FI 2x R/2

FII R x
3
2 R R
TI =
4 GM
1 GM  R  2
R=   TII
2 R3  2 
R3
TII = 2
GM
2. R is independent of freq.
(A) is true.
Current becomes maximum at resonance
(B) cannot be true
XL  L  2fL
(C) is true
1 1
Xc  
C 2fC
(D) cannot be true.
4 3 2 y
  2R  0  R3R
3 3 R
3. xcm = 
4  3 2 3 15
 2R  R
3 3
4 3 2 3R
  2R  0  R3 (R, 3R/8)
ycm = 3 3 8  R
4  3 2 3 (0, 0) x
40 C
 2R  R (R, 0)
3 3
zcm = 0
4. Conservation of angular momentum

2 2 
0  5m  R2    5m  R2  mR2  mR2     = 0/2
5 5 
5. (A) Time when ball move 40 m in horizontal direction = 40/20 = 2 sec

 
Angle rotated by plate = .2  (just vertical)
4 2
 
(B) Ball collide at the highest point so velocity of the ball just after collision = 20 +  .20   2
4 
= 20 + 10
(C) Time after which ball again collide with the ground surface = 2 sec
So distance from plate = (20 + 10 )2
So distance from projection point = 40 + 20   40 = 20 m
3
6. At time t,
x1 = 3 + 3t, y1 = 0
x2 = 0, y2 = 9 + 6t
m x  m2 x 2
xcm = 1 1 =1+t (1)
m1  m2
m y  m2 y 2
ycm = 1 1 = 6 + 4t (2)
m1  m2
from (1) and (2) y = 4x + 2
First particle will stop after time t1 = v1/g = 1.5 sec
Second particle will stop after time t2 = v2/g = 3.0 sec
Hence centre of mass will stop when both particles stop.
So, after 3 sec.
Mass 1 kg will stop at
v2
x1 = 3 + 1 = 5.25 m
2g
y1 = 0
Mass 2 kg will stop at
v2
y2 = 9 + 2 = 18 m
2g
x2 = 0
m x  m2 x 2
xcm = 1 1 = 1.75 m
m1  m2
m1 y1  m2 y 2
ycm = = 12 m
m1  m2
7. If r1 and r2 are the resistances of the first and the second coils and v = mains voltage.
V 2 t1 V 2 t2 r t 1
Q= =  1  1 
r1 r2 r2 t 2 2
In series req = r1 + r2
v 2 t3 v 2 t1
 Q=   t3 = 3t = 45 min
r1  r2 r1
In parallel
v 2 t 4  r1  r2  v 2 t1
Q= 
r1r2 r1
r2
 t4 = t = 10 minutes.
r1  r2
8. i1 = 30, i2 = 90, A = 60

 r1 + r2 = 60
sini2 sin  30 
Now  = 
sin r2 sin r1
Or r1 = sin1(1/2) similarly, r2 = sin1(1/)
 sin1(1/) + sin1(1/2) = /3
4
  
9. P = Q + R
10. Maximum velocity of A and B = A
 v  vD   v  vD 
max =    0 and min =   0
 v  vs   v  vs 
SECTION – C
N N 
 2 
1. N =  n  2n 2 
2 2 
Where n is no of half lives elapsed for species A
N 5  1 1 
Now,    n 
N 32  2n 1 1
 2 2 
 n=4
2. Say the sphere is moved down through a distance x. Then elongation in the spring = x cos 30
 Restoring force = kx cos230 = 3kx/4
d2 x 3
 M 2  kx
dt 4
3k
 = =1
4M
3. dE = Idt (dS cos )

2dE 2Idt  dS cos 2   
dP =  dP = 
C C d

dP 2I
dF =  dS cos 2 
dt C
2I cos2 
dFx = dF cos  =
C  dS
2
2F R 2 I
dFx =   2R sin d  cos2  
0 C C
dr P(t=0)
4.   5  3cos 
dt
0 t

 dr 
16
  5  3cos   dt
0
5m/s
P 3m/s
t r
16  5t  3  cos dt - (i) O
0
v x dt  0
t t
3t
  3  5cos dt  0   cos dt 
0 0
5
- (ii)
From (i) & (2)

9t
16 = 5t 
5
t = 5 sec.
5
5. For entering without jerk v2 = 0 = 2rad/s v2
Using work energy theorem on sleeve after v1

Top View
entering in the frame of rod.
W spring + W centrifugal = K
1 1 1
 k2  m2 2  0  mv 12  v12  8
2 2 2
1

Now K  m v12  v 22  6
2

6. For minimum time person should use maximum friction for speeding up half the time and slowing
down with maximum friction in next half time because he has finally to be stopped as stated in the
question.
7. Let us work in the ground frame for A and for B work in T
the frame of A.
4 mg A
4 5
mg  T '  ma1 (i)
5
3 mg
4 T1 a1 5
T ' ma1  mg (ii)
5
T
From (i) & (ii)
4 ma1
T = 0  a1  g 4 mg
5 5
3 mg
 In ground frame motion of B will be free fall. 5
8. F =  Av2
6
Chemistry PART – II
SECTION – A
1. From virial equation of state is

B C
Z  1   2  ......
V V
B  RT 
Z H2   1  = 0.998  pv  RT, v  P 
V  
Z  CO2   0.927
 H2 approaches ideal behaviour.
Molar volume
PV = ZRT
ZRT .998  0.0821 250
VH2    0.205 L
P 100
Similarly
ZRT 0.927  0.821 250
VCO2    0.190 L
P 100
Thus molar volume of H2 is more then that of CO2.
2. B and C are acidic buffer

D is basic buffer.
ln
3. pH = pKa + log
H ln
ln 
1
(a) If    then H ln  ln 
H ln 10
Solution is colourless
pH = pKa – 1.
ln 
(b) If    10
H ln
 ln  H ln
Thus solution is pink.
pKa + 1
(c) is also correct.
4. (A) IF4 sp3d2 hybridisation and square planer structure (2- lone pairs)
(B) POCl3 sp3 hybridised and has no lone pairs.
(C) XeF4 sp3d2 hybridisation and square planer structure (2- lone pairs)
(D) XeO2F2 sp3d hybridisation and 2 bond and (1 – lone pair)
5. Radial probability increases as r increases and reaches a maximum value when r = ao and then
o
falls, when r > 1 A radial probability is very small.
7
6. 

NaHC 2O 4    2
 Na  H  C2O 4
It has one H+  NaOH = M
C2O42  2CO2  2e
M M
Equivalent weight = 

no. of e lost 2
 dN 
7.    N
 dt 
dN
  1.4  107 particle / min
dt
 = disintegration constant
N = No. of particles in 0.1 mg 239Pu = 0.1  10–3 g
0.1 103 0.1 103
N= mole  Na atom
239 239
0.1 10 3
1.4  107 =    6.023  1023
239
 = 5.558  10–11 min–1
0.693
t50% =

t87.5% = 3  t50 %
= 3  1.2468  1010
= 3.7404  1010 min
8. Salt in NH4NO2
NH4NO2  N2  2H2O
NO2  H  HNO2

3HNO2 
 2NO  HNO3  H2 O
2NO  O2  2NO2 Brown 
2KI + 2HNO2 + H2SO4  I2 + 2NO + K2SO4 + 2H2O
I2 + Starch  Blue colour
and NO2 is not a paramagnetic
3HNO2  H2O + HNO3 + 2NO
Fe2   SO24  NO  Fe NO   SO 4
Brown ring
5NO2  2MnO4  6H  5NO3  2Mn2  3H2O
colourless
3NO2  Cr2O72  8H 
 3NO3  2Cr 3   4H2O
8
9. (A) Amides are more stable acid derivative than ester.
O O O
C O + NH2 CH3 C
NH2 CH3
Ph Br Ph Br
O Br
O
Ph C NH CH3 Ph C NH2 CH3

O O
(B)
O OH OH
Br
+
C NH CH3 Ph C NH CH3 Ph C N CH3
Ph
O O O H
H
+
H
OH
Ph C N CH3
O
10. OC2H5
Br
 C H OH
2 5
    
O O
O O
Br
O  O  2 5 C H OH
 
O O OC2H5
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SECTION-B
1. O
C CH3 O
CH3
OH
 Ph C CH C Ph
Geometrical Isomers
NH  OH

2

 Ph C N OH
CH3
Geometrical Isomers
O OH O
C OH
 H3C C CH2 C CH3
H3C CH3
CH3
Gives iodoform test Single aldol
O
NH2OH D2O
  H3C C N OH  
D3C C CD3
OD
CH3
Single oxime
CH3

OH
 
O OH O
Racemic mixture
O

OH
  More than one aldol
NH  OH
2
 More than one oxime

O
NaOD

D O
 Gains more than 4 units of molar mass
2
2.
O
H3C Unequal distribution of S-character
CH3 Bond angle C-O-C > 109°28'
Both O-C bond are equivalent

NH3  unequal distribution of S- character
Bond angle H – N – H < 109°28’
All N – H bond equivalent
PBr4  Equal distribution of S – character
Bond angle Br – P – Br = 109°28’
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All P - Br bonds are equivalents

O
O O
Xe
O O
O
Equal distribution of S-character
Bond angle O – Xe – O = 90°
All Xe - O bonds are equivalent.
SECTION-C
1. Secondary amine form sulphonamides that do not dissolve in KOH.

H
H
CH3 CH3 N
N N CH3
H
H
N N
N CH3
H H
2. If dianion is hydride donor the rate law is

2 2
R  k H2CO  OH 
Hence, reaction is overall 4th order.

3. NH4 is oxidised to N2 and HNO3 is reduced to NO2.

2NH4  6NO3  4H  N2  6NO2  6H2O
6 5 0 4
for two N tom

2 moles of NH4 = 6 moles NO3
1 mole  NH4 2 SO4 = 6 moles of HNO3
4. H CH2Br
H H
H2O2
 HBr  excess   BrH 2C
H
+ H
H
CH2 Br CH2 Br
CH2Br CH2Br
Achiral Chiral (d + l)
5. H2SnCl6 (chlorostannic acid).
11
4
6. Electronic configuration of Mn  CN6  is
xx xx xx xx xx xx
d2sp3
7. O O
B2O5 4 has

B O B
O
O
8. Br Br HO OH O


  
Br Br HO OH
 X  Y Z O
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Mathematics PART – III
SECTION – A
 t2 t 
1. Parametric co-ordinates of y2 = x are  ,  ,  t  R 
 4 2
10
3. Number of way as of choosing 5 distinct digits from {0, 1, …, 9} is C5.
Required number of ways = 10C5  4! – (numbers starting with ‘0’) = 10C5  4! – 3!  9C4
B and C are numerically same
 ln x 
 x 
   x  1 
2  x 
4.  ln x  e dx
ln x
x
 x 
2 x
  1  2x  ln x  e dx
 ln x ln x    x  ln x  
 2 x x  e x dx   e x    x 2  c
    
x e  1  ln x  2x  
e 
  
fx  
 f   x  
5. tanx curve and x2 concave up graph whereas log x and sin x are concave down functions.
sin  cos 2
6.  cot    ….. (1)
cos  sin  cos 
cos 2 sin2 1  cos3 
  ….. (2)
cos  sin  cos2  cos2   sin  
cos3 sin3 1  cos 4 
    ….. (3)
cos  sin  cos  cos3   sin  
2 3


cosn sin  n  1  cos  n  1  
    .....  n 
cos sin  cos  cosn  
n 1 n
sin  
 sin  sin 2 sin3 sinn 
Adding (1), (2), (3) ,….., (n), we get cot       ..... 
 cos  2 3
cos  cos  cosn  
1 cos n  1 
=
cosn  sin 
 p = 1, q = (n + 1), r = 1, s = n
7. Parabola is (y – 2)2 = 4(x – 1), directrix is x = 0 circle is (x + 3)2 + (y – 4)2 = 1
2 1
8. Equation of tangent to y = – x is x = my – ,m>0
4m
1
 x – my + =0
4m
Since this line is tangent to x2 + (y – 2)2 = 4
1
m=
4 5
Hence, equation of tangent is y = 45x + 20.
1
Case II: equation of tangent to y = x 2 is x = my + ,m>0
4m
13
This line is tangent to x2 + (y – 2)2 = 4

1
m=
4 3
Equation of tangent is y = 43x – 12.
2 2 x x 2  x x
9. y = 4sin x + 3cos x – 24sin – 24cos = 3 + sin x – 24  sin  cos 
2 2  2 2
 x x
Let  sin  cos  = t
 2 2
 y = t4 – 2t2 – 24t + 4 = f(t)
2
 f(t) = 4(t – 2)(t + 2t + 3) < 0

Since, 0  x  1t 2
2
 f(t) is decreasing function for 1  t  2 ymin = 4(1 – 6 2 ) and ymax = –21
 sin x, x0

10. f(x) =  0, x0
 2
 tan x
 x2 , 1  x  0
Hence, lim f  x   0 and lim f  x   1 .
x 0 x 0
SECTION – B
abc
1. Given  32 , where A, B and C are respectively (a, 0, 0), (0, b, 0), (0, 0, c)
6
a b c
(A) Centroid of tetrahedron is  , , 
4 4 4
 a = 4, b = 4, c = 4
  = 3
a b c
(B) Equidistant point (, , ) =  , , 
 2 2 2
  = 24
x y z
(C) The equation of plane is    1
a b c
 1 1 1 
 a 
 Foot of perpendicular from the origin is (, , ) is  , b , c 
 1 1 1 
 2  2  2 
 a a a 
1 1 1
  t
a b c
1 2 2 2 –1  2  2   2  2  2   2  2  2   2
t  t = ( +  +  ) and a  , b  , c 
a2   
2 2 2 3
abc = 6  32  ( +  +  ) = 192
(D) Let P be (, , ), then PA  PB

( – a) + ( – b) +  = 0, PB  PC
 + ( – b) + ( – c) = 0
14
a b c
  
1 1 1
  
( + 2 + 2)3 = (192)  (8)
2
2. (A) Given B = (I + A)(I – A)–1

Now BT = ((I – A)–1)T(I + A)T
1
BT  (I  A)T  (I  A)T i.e., BT  (I  A T )1(I  A T )
BT  (I  A)1(I  A) ( A T   A)
BBT  I or det(B) = 1
(B) {sin{x}} = 0 x = –1
sin(1 + x) –1 < x < 0
0 x=0
–1 0
(1  x  2  x  1)dx [1  x  2  x  1]dx
(C)  (1  
x  2  x  1)(1  x  2  x  1) 2[1  x  2]
1 1 ( x  2  1) x 1 x2
 x  dx   x  1   dx
2 2 x 1 2 2 x 1
x2
 ax  b x  1  c  dx
x 1
1 1
 a ,b  1,c  
2 2
1
a 2
 1 = 1 = 5
1 2
c
(D) A vector parallel to line of intersection of given planes is
ˆi ˆj kˆ
2 1 3  10iˆ  5ˆj  5kˆ
1 2 4
Hence, 10(a – 3) + 5(6 – 12) + 5(4 – 2) = 0  a = 5
SECTION – C
2 x2 x 4 x6
1. e x /2
 1  
2 2.4 2.4.6
Now notice that g(t) = e
 t /2
2
2
Also f(x) = xf(x) + 1 (now multiply with e  x /2
)
2 2 2
 e  x /2
f  x   e  x /2
 xf  x    e  x /2
x
 f  x     e  dt
2  t 2 /2
 e x /2
15
x
f x   t /2 dt
2
  e
g x  0
2.  |p(1)| = |p(–1)| = 1, so 1 + a + b and 1 – a + b lie on unit circle. Similarly |p(i)| = |p(–i)| = 1

So –1 + ia + b and –1 – ia + b lie on the unit circle.
Hence, their mid-points 1 + b, –1 + b will lie inside the unit circle but they are 2 units apart
Hence, b = 0
Now 1 + a and 1 – a lie on unit circle, but their mid-point 1 also lie on unit circle hence they must
coincide
a=0
3. a, b, c, d must be integers
 (k – a)(k – b)(k – c)(k – d) = 4, hence (k – a), (k – b), (k – c), (k – d) all divides 4, so they must
belong to {–4, –2, –1, 1, 2, 4}. As they are all distinct, so at most two of them have absolute value
1. Hence none can have absolute value 4 or their product be at least 8
Hence, no are –2, –1, 1, 2
 Their sum = 0
 4k = a + b + c + d
4. Using differentiation we get min AB = 27f 2() (treating f() as constant)

Now min value of 27f 2() is 27  (8)
sin A sinB sinC

5.   
a b c
a
  b c a
Now let b c  a  x 0
c  a b  y 0
a b c z0
sin A 1 y z  1 x z  1 x y 
  sinB  sinC  sin A
=         
2 x x  2y y  2 z z
1 y x 
     1 (Using A.M.  G.M.)
2 x y 
Hence, equality holds if x = y and similarly for others
 Min value is 3
OA  
6.   cot   
r  4 2
A

Let, tan  t
2  

1 t 2 4 2

1 t t O

 17  3
 tan  2
2 2
a + b + c = 17 + 3 + 2 = 22
16
a  c  cos   b 2 sin    a  c  3
7. cos  
a  b  c2 2  6
2 2
In order that cos  is independent of 

a + c = 0, b = 0
3 
cos    
2 6
8. Again, all faces sum to 18. If x, y, z are the vertices next to one, then the remaining vertices are
17 – x – y, 17 – y – z, 17 – x – z, x + y + z – 16. Now it remains to test possibilities. Note that we
must have x + y + z > 17
Let x < y < z
3, 7, 8 does not work, 4, 6, 8 works, 5, 6, 7, does not work, 5, 6, 8 works, 5, 7, 8 does not work
6, 7, 8 works
So 3  2 = 6

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AITS-CRT-IV (Paper-1)-PCM (Sol)-JEE(Advanced)/16

ANSWERS, HINTS & SOLUTIONS

CONCEPT RECAPITULATION TEST – IV

Q. No. PHYSICS CHEMISTRY MATHEMATICS

4. Conservation of angular momentum

5. (A) Time when ball move 40 m in horizontal direction = 40/20 = 2 sec

8. i1 = 30, i2 = 90, A = 60

3. dE = Idt (dS cos )

From (i) & (2)

5. For entering without jerk v2 = 0 = 2rad/s v2

Using work energy theorem on sleeve after v1

7. Let us work in the ground frame for A and for B work in T

1. From virial equation of state is

2. B and C are acidic buffer

falls, when r > 1 A radial probability is very small.

NO2  H  HNO2

9. (A) Amides are more stable acid derivative than ester.

Ph C NH CH3 Ph C NH2 CH3

All P - Br bonds are equivalents

1. Secondary amine form sulphonamides that do not dissolve in KOH.

2. If dianion is hydride donor the rate law is

5. H2SnCl6 (chlorostannic acid).

B2O5 4 has

Mathematics PART – III

7. Parabola is (y – 2)2 = 4(x – 1), directrix is x = 0 circle is (x + 3)2 + (y – 4)2 = 1

This line is tangent to x2 + (y – 2)2 = 4

(D) Let P be (, , ), then PA  PB

2. (A) Given B = (I + A)(I – A)–1

2.  |p(1)| = |p(–1)| = 1, so 1 + a + b and 1 – a + b lie on unit circle. Similarly |p(i)| = |p(–i)| = 1

4. Using differentiation we get min AB = 27f 2() (treating f() as constant)

sin A sinB sinC

In order that cos  is independent of 

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