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Chemistry Practice MCQs Set 1
Chemistry Practice MCQs Set 1
1
Assertion (A): Acetic acid is more acidic than 3
Which of the given reactions will yield amine as a
phenol
product with less number of carbon than the reactant?
ion
A.
1. Both A and R are correct and R is the correct
explanation of A
B.
2
Match List I with List II
List I List II
Structural Formula Name
A.
C.
I. Catechol
B.
D.
II. Resorcinol
C.
1. A only
4. C only
D.
4
Given below are two statements
Choose the correct answer from the options given 3. Statement I is correct but Statement II is incorrect
below:
4. Statement I is incorrect but Statement II is correct
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Chemistry Practice Contact Number: 9667591930 /
5
Statement I: The lattice enthalpy of NaCl(g) is 788 9
Assertion A: Carbon dioxide gas above its critical
kJ mol-1
temperature is called carbon dioxide vapor
Statement II: 788 kJ of energy is required to separate Reason R: A gas below the critical temperature can be
liquefied by applying pressure
6
Given below are two statements
10
Match List I with List II
Statement I: Silicones are surrounded by non-polar alkyl List I List II
groups, thus water repelling in nature
Statement II: The starting materials for the Crystal system Examples
manufacturing of silicones are alkyl or aryl substituted A. Cubic I. KNO3
silicon chlorides
B. Tetragonal II. Na2SO4.10H2O
1. Both Statement I and Statement II are correct
7
Assertion (A): [Ti(H2O)6]Cl3 on heating, removes 1. A-IV, B-I, C-II, D-III
Reason (R): In the absence of ligand, crystal field 3. A-III, B-I, C-IV, D-II
splitting does not occur and hence the substance is 4. A-III, B-IV, C-I, D-II
colorless
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Chemistry Practice Contact Number: 9667591930 /
12
Given below are two statements
15
Which of the following molecules/species have the
Statement I: The mass of a gas dissolved in a given mass same bond order?
2−
2+
2−
13
Match the chemical composition in List I with its
name in List II
16
Assertion (A): Among halogens, chlorine has the
List I
List II
highest negative electron gain enthalpy value.
Chemical Composition Reagent Reason (R): The ionic radius of Cl- is 184 pm.
A. Benzenesulphonyl chloride I. Tollen's reagent 1. Both A and R are correct and R is the correct
explanation of A
allotrope of carbon.
below:
C. Tollen's test
D. Lucas test
1. A only
2. A and B only
3. A and C only
4. B and C only
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Chemistry Practice Contact Number: 9667591930 /
18
Which of the following statements are incorrect? 22
Match List I with List II
A. Frequency of radiation emitted by a body goes from List I
List II
C. Optical isomerism is a very rare phenomenon in C. Boyle's Law III. V/n = Constant
octahedral complexes involving bidentate ligands.
D. Avagadro's Law IV. V/T = Constant
D. In NH3 and H2O molecules, both the central metal
below:
23
Match List I with List II
List I
List II
19
Statement I: Expansion of gas against external Types of solids Examples
pressure (Pext ≠ 0) is called free expansion.
A. Molecular Solids I. MgO
Statement II: No work is done during the expansion of B. Ionic Solids II. SiC
an ideal gas when the process is reversible only.
C. Metallic Solids III. CCl4
1. Both statement I and statement II are true
D. Covalent Solids IV. Ag
2. Both statement I and statement II are false
20
Statement I: Spontaneous process is an irreversible 3. A - (IV); B - (II); C - (III); D - (I)
of all process
21
Match List I with List II 2. Both A and R are correct but R is not the correct
List I
List II
explanation of A
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Chemistry Practice Contact Number: 9667591930 /
25
Given below are two statements:
29
Which of the following statements are correct?
Statement I: Dissociation is the process of separation of A. In diborane, each boron atom uses sp2 hybrids for
ions in the water already existing as such in the solid bonding.
solution.
In light of the above statements, choose the most D. Vitamin B12 contains cobalt.
26
Consider the following structures:
30
Given below are two statements:
Choose the correct option for the structure(s) which are Statement II: Oxides like CO, NO and N2O are neutral
resonating structures of phenol.
oxides.
27
For the following molecules/intermediates/species:
31
Statement I: A process or change is said to be
A - BH3; B - SiH4; C - PCl3; D - :CH2; E - NH3
reversible, if a change is brought out in such a way that
Select the correct option for electrophile(s).
the process could at any point be reversed by a finite
1. A, B, C and D only
change.
28
Given below are two statements:
2. Both statement I and statement II are false
Statement I: Both carbon and silicon atoms belong to 3. Statement I is correct but statement II is false
group 14, both CO2 and SiO2 are gases and linear 4. Statement I is incorrect but statement II is true
molecules.
2. Both statement I and statement II are false Reason R: Arrhenius equation confirms that the higher
3. Statement I is correct but statement II is false
the value of activation energy faster will be the rate of a
4. Statement I is incorrect but statement II is true
reaction.
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Chemistry Practice Contact Number: 9667591930 /
33
For a zero-order reaction, the rate constant is 34
K =
[R]0 −[R]
Match List I with List II
t
35
Which of the following species is/are Lewis acid?
A. BCl3
B. BF3
C. Mg2+
D. OH-
3. E. Co3+
3. B only
4.
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Chemistry Practice Contact Number: 9667591930 /
36
Identify the reaction(s) which do not give n-propyl 38
Assertion A: Heavier elements of group 15 do not
benzene as a major product:
form pπ − pπ bonds.
explanation of A
39
Assertion (A): Melting point of gallium is lesser
than aluminum
D.
40
Match the model/theory in List I with their related
concept given in List II.
List I List II
A. Thomson I. Work function
2. A and B only
Choose the correct answer from the options given below
3. C and D only
:
4. D only
A B C D
1. I IV II III
2. II IV I III
37
Assertion A: Bromobenzene reacts with sodium 3. III II IV I
methoxide at room temperature to give anisole 4. III IV II I
Reason R: Sodium methoxide is a base
explanation of A
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Chemistry Practice Contact Number: 9667591930 /
41
Which of the following statements are not correct?
45
Statement I: Equilibrium can be established for a
A. BeSO4 and MgSO4 are insoluble in water
chemical reaction only
of the reactants
referred as spectroscopy
1. B and E only
2. B, C and E only
3. A and D only
46
For the given examples of non-polar molecular
4. B and D only
solids
A. Ar
B. HCl
C. SO2
42
Given below are two statements
D. C (Diamond)
Statement II: Werner on the basis of physical Choose the correct answer from the options given
experiments showed optical and electrical differences below:
43
Assertion (A): At high altitudes, the atmospheric 1. Both A and R are correct and R is the correct
pressure is low
explanation of A
Reason (R): Liquids at high altitudes boil at higher 2. Both A and R are correct but R is not the correct
temperatures in comparison to that at sea level
explanation of A
1. Both A and R are correct and R is the correct 3. A is correct but R is not correct
explanation of A
4. A is not correct but R is correct
explanation of A
44
Given below are two statements:
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Chemistry Practice Contact Number: 9667591930 /
48
Which of the following compounds are aromatic 49
Which of the following elements have similar/close
alcohol ?
electronegativity value at the Pauling scale?
A. A. Si
B. Ge
C. Sn
D. Pb
E. C
1. A and B only
2. A, B, and C only
4. A, and E only
50
Assertion (A): On bringing the two nuclei closer, it
results in a sudden increase in energy and stabilization of
the molecules
C.
1. Both A and R are correct and R is the correct
explanation of A
D.
51
Given below is the probability density graph of an
orbital.
E.
1. 1s
2. 2s
3. 2p
below:
1. A, C and E only
2. B, C and E only
3. D and E only
4. E only
Page: 9
Chemistry Practice Contact Number: 9667591930 /
52
Assertion (A): CCl4 is insoluble in water while 55
The correct graph for the Arrhenius equation is:
2.
53
Statement I: Displacement redox reactions fit into
metal displacement and non-metal displacement
54
Which of the following statements are correct?
below:
4.
1. A and B only
2. B and C only
3. A and D only
4. A and C only
56
Statement I: The value of the equilibrium constant
is dependent on the initial concentration of reactant and
products
Page: 10
Chemistry Practice Contact Number: 9667591930 /
57
Statement I: Glass is an extremely viscous liquid
61
Which of the following statements are correct-
Statement II: Viscosity of liquid decreases as the A. BCl3 exists as a monomer whereas AlCl3 is
temperature rises
dimerized through halogen bridging
lubricant in machines
below:
2. A and D only
3. A and E only
4. D and C only
Assertion A: Hypophosphorous acid is a good
62
59
Match List I with List II
reducing agent and reduces AgNO3 to metallic silver
Column I
II 2. Both A and R are correct but R is not the correct
A. Number of radial nodes for the 3p orbitals I. 0 explanation of A
II. 9
having dipole moment 4. A is not correct but R is correct
below:
1. Both A and R are correct and R is the correct
1. A-II, B-III, C-I, D-IV
explanation of A
60
Given below are two statements
thereafter, a small increase in covalent radius is observed Reason (R): Halogens except fluorine have d-orbitals
from silicon to germanium
and thus can expend their octets
Statement II: A considerable difference in the values of 1. Both A and R are correct and R is the correct
electronegativity from silicon to lead is observed
explanation of A
Page: 11
Chemistry Practice Contact Number: 9667591930 /
65
Assertion (A): The people living at high altitudes or 68
Match Terms with Symbols
climbers have a high concentration of oxygen in the Term Symbol
blood and tissues
A. Resistance I. κ
Reason (R): At high altitudes, the partial pressure of
B. Specific resistance II. R
oxygen is less than that of the ground level
explanation of A
Choose the correct answer from the options given
3. A is correct but R is not correct
below:
66
Match Crystal system with Axial angles 4. A-II, B-I, C-III, D-IV
69
Match List I with List II
B. Trigonal II. α = β = γ = 90
o
List I List II
C. Hexagonal III. α ≠ β ≠ γ ≠ 90
o
A. Ionic I. NH3.BF3
D. Triclinic IV. α = β = γ ≠ 90
o
67
Match List I with List II 3. A - (III); B - (II); C - (IV); D - (I)
A. ΔH = q I. P = 0
ext
B. Free 70
Match List I with List II
II. Heat
expansion
List I List II
C. Path
III. At constant pressure A. sp3d I. BrF5
function
D. B. dsp2 II. PF5
IV. Infinitely slow process which proceeds
Reversible
through a series of equilibrium states C. sp3d2 III. [PtCl4]2-
process
below:
Choose the correct answer from the options given
1. A-I, B-III, C-II, D-IV
below:
Page: 12
Chemistry Practice Contact Number: 9667591930 /
71
Assertion (A): In the given equation Phosphorus is 74
Match List I with List II
undergoing oxidation as well as reduction.
List II
P + 3OH + 3H O → P H + 3H P O
List
Types of
− −
Reactions
4 2 3 2
2
2. Both A and R are correct but R is not the correct II. FeCl3 + 3H2O → Fe(OH)3(sol) +
B. Reduction
explanation of A
3HCl
3. A is correct but R is not correct
III. SO2 + 2H2S → 3S(sol) + 2H2O C. Double
4. A is not correct but R is correct
decomposition
→ Al O (s) + 2Cr(s) 2 3
B.
Decomposition II. 2KClO (s) −−−→ 2KCl(s) + 3O (g)
3 2
reactions
C. Non-metal III.
Δ
displacement CH4 (g) + 2O2 (g) −−−→ CO2 (g) + 2H2 O(l)
D. Metal IV.
Δ
displacement 2F e(s) + 3H2 O(l) −−−→ F e2 O3 (s) + 3H2 (g)
73
Match List I with List II
List I List II
Different regions of the spectrum Frequencies
I. Radiofrequency A. 106 Hz
II. Microwave B. 1013 Hz
III. Ultraviolet region C. 1010 Hz
IV. Infra-red region D. 1016 Hz
Page: 13
75
Which of the following graph is incorrect?
76
The correct structure of the repeat unit of neoprene
1. is
1.
2.
2. 3.
4.
3.
77
Terylene is prepared by the condensation of
Ethylene glycol with
1. benzene-1,2-dicarboxylic acid
2. benzene-1,3-dicarboxylic acid
3. benzene-1,4-dicarboxylic acid
4. benzoic acid
4.
Page: 14
Chemistry Practice Contact Number: 9667591930 /
78
The product (major) formed in the given organic 81
The compound given below is called as a
reaction:
1. Catechol
2. Resorcinol
A is-
3. Hydroquinone
1. 4. Cresol
82
For the given organic reaction:
2.
1.
3.
4.
2.
79
Identify the most basic compound in the given
options
1. N-Methyl aniline
2. Phenylmethanamine
3.
3. Ethanamine
4. N,N-Dimethylaniline
80
Which one of the following does NOT give positive
Fehling's test?
4.
1. Ethanal
2. Butanal
3. Benzaldehyde
4. Cyclopentanecarbaldehyde
Page: 15
Chemistry Practice Contact Number: 9667591930 /
83
Which among the following methyl halides has the 85
Number of sigma (σ) and pi (π) bonds present in
highest dipole moment?
the given molecule, respectively, are
1. CH − F
2. CH − Cl
3. CH − Br
4. CH − I
84
The correct structure of DDT is
1.
2. 86
The stationary and mobile phases used in paper
chromatography are mainly
87
The number of hydrogen atoms bonds to 1° , 2°,
1. 18, 4, 0
2. 18, 6, 0
3. 20, 6, 2
4.
4. 18, 4, 2
88
In the following reaction:
1. 0.23
2. 5.85
3. 4.35
4. 5.18
Page: 16
Chemistry Practice Contact Number: 9667591930 /
89
Match List I with List II
94
Identify A and B in the following reaction
Δ Δ
H3 BO3 −−−−→ A−
→ B
3 2 3
3. A = B O , B = H BO
4. A = BH , B = H BO
4. Orthorhombic
90
Identify the Incorrect statement/condition for
96
Which one of the following chemical reactions does
hybridization
1. The orbitals present in the valence shell of the atom NOT occur in a blast furnace during the extraction of
are hybridized
iron?
2 3 3 4 2
3 4 2 3 2
hybridization
4. F eO + C → F e + CO
participate in hybridization
97
Which one of the given hydrides of group 15
elements has the lowest boiling point?
91
1. N H
3
2
3
4. SbH
2 2
LiCl. Y H O.
1. 2 and 8
2. 6 and 2
98
Choose the correct option for M n 2 O7 , CrO and
3
3. 2 and 2
from the following
V2 O 5
4. 8 and 8
1. M n O , CrO and V O are acidic
2 7 3 2 5
3 2 7 2 5
2 5 3 2 7
92
The alkali metals react with liquid ammonia and 4. M n O , CrO and V O are basic
2 7 3 2 5
1. Imide
2. Amide 99
Given
3. Amine A
X2 (g) → X(g) → X
B
−
(g) → X
C
−
(aq)
4. Azide
When
Δdiss H
⊖
dissociation enthalpy; Δsub H - sublimation enthalpy
−
⊖
− lonisation enthalpy; Δ H − electron gain enthalp
93
The common name of compounds and their formula
⊖ ⊖
Δie H eg
1. Quick lime- CaO
Select the correct option from the following
2. Slaked lime- Ca(OH )
2 1. A = Δ H , B = Δ H , C = Δ H
diss
⊖
eg
⊖
hyd
⊖
sub
⊖
ie
⊖
hyd
⊖
4. Soda Ash- N a CO . H O
diss
⊖
eg
⊖
latt
⊖
sub
⊖
eg
⊖
hyd
⊖
Page: 17
Chemistry Practice Contact Number: 9667591930 /
100
The correct electronic configuration of Xe is
1. [Ar]4d10 2
5s 5p
6
2. [Kr]3d 10
4s 4p
2 6
3. [Kr]4d 10
5s 5p
2 6
4. [Ar]3d10
4s 4p
2 6
Page: 18