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Dark Raman Resonances Due To Ramsey Inte
Dark Raman Resonances Due To Ramsey Inte
Dark Raman Resonances Due To Ramsey Inte
I. INTRODUCTION fine levels of the ground state, interact with atoms in Na 关9兴
and Cs 关10兴 atomic beams. Ramsey fringes due to ground-
In coherent population trapping 共CPT兲, laser radiation, ap- state coherences with ⌬mF = 2 were observed in atomic beam
plied to a ⌳ scheme, places atoms in a nonabsorbing or dark of Ca atoms 关11兴. The observation of Ramsey fringes using
state when two light fields are in Raman resonance with the nonlinear Faraday rotation spectroscopy 共NLFR兲 in the Rb
splitting between two lower states 关1,2兴. This process is very atomic beam were given in 关12兴. Experiments 关9–12兴 pre-
efficient because of simultaneous coherent superposition of sented considerably narrower line shapes of EIT and NLFR
the ground states into an absorbing or bright state which is resonances when compared to nonseparated applied pump
strongly coupled to the excited state of the ⌳ scheme 关3–6兴. and probe beam excitations.
CPT is observed in fluorescence as a fluorescence dip. Nar- In several works, Ramsey methods were used on beams in
row gain in laser transmission or electromagnetically in- Raman resonance to excite alkali-metal atoms, contained in a
duced transparency 共EIT兲 can be observed due to the exis- gas cell and mixed with a buffer gas. Linearly polarized
tence of the “dark” state. probe beam, counterpropagating vs spatially displaced pump
In this paper, we study EIT resonances in a vacuum vapor laser beam in sodium vapor, monitors precession of orienta-
Rb cell when we apply Ramsey method 关7兴 of separated tion in atoms pumped by the circularly polarized pump laser
excitation regions. We show that such separation of fields light 关13兴. The manifestation of Ramsey interference effect
plays an important role in line shapes and linewidths of EIT. of radio-frequency Zeeman transitions in atomic vapor due
In the original Ramsey method, long-lived atomic polariza- to collisional velocity diffusion was shown by Buhr and
tion between ground-state hyperfine levels is induced by us- Mlynek 关14,15兴. These experiments apply the Ramsey reso-
nance idea in the domain where atoms with CPT alter both
ing microwaves. The first field creates coherent superposition
their position and velocity. It was shown that multiple colli-
between two levels. In the region between the two fields,
sions between buffer gas atoms and alkali-metal atoms lead
coherence acquires a phase shift which depends on both the to diffusion of alkali-metal atoms back to the laser beam,
frequency of hyperfine splitting and the time of flight. The which leads to diffusion-induced Ramsey narrowing of EIT
absorption of the microwave field in the second interaction 关16,17兴. Temporal Ramsey fringes due to scattering of de-
region is modulated if the phase of the coherence is changed, layed probe beam by coherently prepared Rb atoms were
for example, by changing the detuning of the microwaves in observed in Ref. 关18兴, while Ramsey fringes due to Zeeman
respect to the atomic frequency. Temporal instead of spatial coherence in Rb atoms for temporally and spatially separated
separation of microwave Ramsey pulses allows application laser beams were shown in Ref. 关19兴. High-contrast, sub-
of Ramsey methods to atomic clocks in buffered alkali-metal kHz, Ramsey fringes through Raman resonant beams were
gas cells 关8兴. In our work, we use modified Ramsey method observed using circularly polarized light and double ⌳
in vacuum Rb cell, by applying pump optical photons to scheme in Cs vapor with buffer gas 关20兴. Temporal Ramsey
create alignment in the ground-state hyperfine level in a Rb fringes due to multiple atom reflections from coated walls of
atom, followed by the pair of probe photons to detect in- the Rb cell were measured using both pump and probe
duced alignment. beams, spatially overlapped and separated 关21兴.
Modified Ramsey methods were performed, in several Excitations from the Ramsey method using beams with
cases, on thermal atomic beams. Spatially separated pump Raman resonance in buffered gas cells have found important
and probe laser beams, in Raman resonance with two hyper- applications, particularly for CPT based frequency standards
and atomic clocks, either active 关22,23兴 or passive 关24兴. The
aim of this paper is to further study Ramsey effects through
*zoran.grujic@phy.bg.ac.yu Raman resonance in vacuum gas cells, i.e., to study the effect
Fg=2
m=2
m=1
m=0
Fg=1 m=-2
m=-1
Fg=2
FIG. 1. 共a兲 Schematic of atomic energy level diagram for 87Rb D1 line ground and excited levels, 共b兲 the energy level diagram for
magnetic sublevels of the Fg = 2 → Fe = 1 transition, and 共c兲 pump and probe laser beam radial profiles used in the theoretical model. In 共a兲
and 共b兲 solid lines represent laser light coupling energy levels and dotted lines show the deexcitation paths from excited levels.
of the temporal evolution of coherent superposition on the ground-state hyperfine level. Total probe fluorescence was
shape of EIT resonance. Similar studies in vacuum cells were calculated after averaging over atom velocity components
briefly done in Ref. 关19兴. In our work, we use two-photon parallel and perpendicular to the laser beam. Our work is
Raman transitions between Zeeman sublevels of the Fg = 2 relevant to some applications of the CPT, particularly for
ground-state hyperfine level. Both pump and probe beams atomic frequency standards based on CPT, either active
are tuned to the Fg = 2 → Fe = 1 transition in 87Rb and probe 关22,23兴 or passive standards 关24兴. The Ramsey method with
beam transmission is monitored while axial magnetic field is Raman resonance type excitation approach has advantages
scanned around zero. Experimentally, we put the probe beam over the standard Ramsey method for atomic frequency stan-
inside the central region of hollow pump beam. The role of dards, since it eliminates need for large microwave resona-
the pump in this setup is similar to that of an antireflection tors.
wall coating, and to that of buffer gas collisions in the vapor
cell with buffer gas. This setup allows enhanced interaction
of the atomic coherence with the probe beam in comparison II. THEORY
with separated laser beams 关19兴. This experimental geometry
is similar to the geometry used in Ref. 关25兴, where the sub- We used density matrix formalism to analyze the dynam-
Doppler feature was observed in the transmission of the hol- ics of the interaction between Rb atoms and spatially sepa-
low probe, through the very thin 共10 m兲 cell, while the rated pump and probe laser beams. The temporal evolution
pump beam is placed in the probe center. of the density matrix elements for the excited and the ground
The results of our experiment are compared to the results state populations and coherences 共̺eie j , ̺gig j兲 and for optical
of time-dependent optical Bloch equations for density matrix coherence 共̺eig j兲 is obtained from time-dependent optical
elements for atoms in the pump, in the dark, and in the probe Bloch equations for the open Fg = 2 → Fe = 1 transition in
87
region. All the levels interacting with laser light are taken Rb. Figures 1共a兲 and 1共b兲 show Rb atomic level diagrams
into account, as well as population losses to the other with levels coupled and optically pumped by laser light.
ប k=−2
共̺
˜ e g E+g e − E−e g ̺
i k k j i k
˜ g e 兲 − 2⌫L̺e e 兺 具Jg储erជ储Je典2共2F⬘g + 1兲共2Jg + 1兲
k j i j
F ⬘
g
Jg Je 1
Fe F⬘g Ig
再 冎 2
,
˜˙ e g = ̺
̺ i j
˜ e g i关 − 共e − g 兲兴 +
i j i j
i
ប
冉兺 1
k=−1
̺eiekE−ekg j −
2
兺 E−e g ̺g g
k=−2
i k k j
冊 − ⌫L̺eie j 兺 具Jg储erជ储Je典2共2Fg⬘ + 1兲共2Jg + 1兲
Fg⬘
再 Jg Je
Fe Fg⬘ Ig
1
冎 2
ប k=−1
共̺
˜ g e E−e g − E+g e ̺
i k k j i k k j
J J 1
˜ e g 兲 + 2⌫L具Jg储erជ储Je典2共2Fg + 1兲共2Fe + 1兲共2Jg + 1兲 g e
Fe Fg Ig
再 冎 2
冉 冊冉 冊
1
Fe 1 Fg Fe 1 Fg
⫻ 兺 ̺e
q=−1
i+qe j+q j+q −q −j i+q −q −i
, 共1兲
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where
1
zx
E+aia j = − aia j−1E−1+ − aia j1E+1+ − aia j0ei E0z ,
2
1 zx
E−aia j = − aia j−1E−1− − aia j1E+1− − aia j0e−i E0z ,
2
yx yx
E0x + iei E0y E0x + ie−i E0y
E−1+ = , E−1− = ,
2 冑2 2 冑2
yx yx
− E0x + iei E0y − E0x + ie−i E0y
E+1+ = , E+1− = , 共2兲
2 冑2 2 冑2
aia jq is the matrix dipole element, and បei and បgi are the
energies of Zeeman sublevels. Fast oscillations at the laser
frequency in Eq. 共1兲 were eliminated by common substitu-
˜ e g e−it. The summation Fg⬘ is over ground states
tion ̺eig j = ̺ i j
Fg = 1 , 2. E0x and E0y are x, y components of the laser’s elec-
tric vector, orthogonal to the beam propagation direction B=290mG
along the z axis.
Eជ = eជ x cos共t兲E0x + eជ y cos共t + yx兲E0y + eជ z cos共t + zx兲E0z .
共3兲
The identity
再 冎
2
Jg Je 1 1
兺 共2F⬘g + 1兲 Fe F⬘g Ig
=
2Je + 1
共4兲 FIG. 2. 共Color online兲 Calculated dependence of spontaneous
Fg⬘ emission and of ground state coherence between Zeeman sublevels
as a function of radial position of an atom 共as atom passes through
relates ⌫L in Eq. 共1兲 to the emission rate ⌫
the pump beam, the “dark region,” and the probe region兲 for differ-
2Jg + 1 ent values of B. First column: Spontaneous emission from the ex-
⌫ = 2⌫L具Jg储erជ储Je典2 . 共5兲 cited Fe = 2 hyperfine level. Second column: the real 共solid line兲 and
2Je + 1 imaginary 共dashed line兲 parts of Zeeman coherence induced be-
tween mF = 0 and mF = −2 Zeeman sublevels of Fg = 2. Results are
Here 具Jg储erជ储Je典2 is reduced matrix element of the dipole op-
given for the magnetic field values of 0, 50, 170, and 290 mG, for
erator between the ground and excited states 关26兴.
four rows top to bottom and average pump and probe powers of
As schematically given in Fig. 1共c兲, the probe laser beam 2 mW and 20 W, respectively. Polarizations of the pump and
is in the axis of the hollow pump beam. Both the pump and probe beam are linear and parallel to each other. The results are for
probe beams have the same frequency . Their radial inten- the atom velocity of 260 m / s and its trajectory is along the probe
sity profiles are modeled by beam diameter. The distances which atoms travel through the pump,
E共r兲 =
Erf冉 r − r1
a共r2 − r1兲
冊 冉
− Erf
r − r2
a共r2 − r1兲
,
冊 共6兲
“dark” and probe regions are 3.5, 1.7, 1.5 mm, respectively.
until the atom exits the probe region. The density of the
2 rubidium vapor is low enough, so we can ignore relaxation
of coherence due to the collision processes.
where r1, r2, and a are suitable parameters.
The atom fluorescence is proportional to total excited-
In order to make numerical integration faster, the transi-
state population
tion from the region without the laser light to the region with
light fields is described by the error function, Eq. 共6兲. Exter-
⌸e共t,B, vជ 兲 = 兺 ̺eiei共t,B, vជ 兲, 共7兲
nal magnetic field B, along the beam propagation, splits the i
Zeeman sublevels by the amount 2BgFB, where B is the
Bohr magneton and gF is the gyromagnetic factor of the where vជ is atom velocity vector.
level. We assume that each collision with the wall resets the Figure 2 shows the dependence of the atomic fluorescence
state of an atom, therefore, atoms entering the pump beam 共left column兲 and the coherence between Zeeman sublevels
have equal population of Zeeman sublevels in the ground- mF = 0 and mF = −2 of the Fg = 2 共right column兲 on the atom
state hyperfine levels. Numerical integration is carried out location for magnetic field B: 0, 50, 170, and 290 mG. Po-
063816-3
GRUJIĆ et al. PHYSICAL REVIEW A 78, 063816 共2008兲
larizations of the pump and probe beam are linear and par- VNDF
OI BS
allel to each other. As schematically indicated by shaded ar- ECDL M
eas, the atom enters and crosses the pump region, traverses
the “dark region” where not illuminated by either of laser P
fields, and then enters the probe region. Results in Fig. 2 are DDAVLL
BE
for the atom velocity of v = 260 m / s and its trajectory is
along the probe beam diameter. Curves presenting ⌬m I I
D
= ⫾ 2 ground state coherence are real 共solid lines兲 and imagi- M
nary 共dashed lines兲 part of the matrix elements ̺gig j. Only for λ/2 P I
B = 0, during the flight of atoms through the excitation zone, cell walls
the excited state population relaxes to zero and the coherence Helmholtz’s
coils dark region
reaches its steady state value. The atom is pumped either into pump
probe d=1,5mm
the dark state or to the Fg = 1 hyperfine level. For B ⫽ 0, the Digital Trigger Signal
generator
dark state is not ideal. The atom can be excited and then oscilloscope
pumped back again either into the dark state or into un-
coupled Fg = 1 hyperfine level. Hence, it is necessary to deal FIG. 3. Experimental setup. ECDL: external cavity diode laser,
with time-dependent optical Bloch equations not only to take OI: optical isolator, DDAVLL: Doppler free dichroic atomic laser
into account the real radial profiles of the pump and probe lock, BS: beam splitter, I: iris, P: polarizer, VNDF: variable neutral-
beams, but also to achieve a proper description of this open density filter, BE: beam expander, M: mirrors, / 2: retardation
atomic system. plate, D: photodiode detector.
Motion of atoms in vacuum Rb cell is faster than the
relaxation rates of the ground state coherence and the coher- laser beam, determines the Doppler shift in the laser fre-
ence varies as atoms traverse the pump laser beam. This is in quency seen by an atom:
contrast to buffer gas cells where much slower motion of
atoms allows the atomic coherence to be instantaneously ad- ⌼共B兲 = 兺 兩vជ 兩Ie共B兲Wb共T,兩vជ 兩兲, 共9兲
justed at each part of the laser beam 关16兴. While in the “dark vជ
region,” the phase of the dark state oscillates, which causes where 兩vជ 兩 accounts for atom flux through the laser beam. In
oscillation from dark to bright state. The frequency of the Eq. 共9兲
evolution is equal to the separation between Zeeman sublev-
els, splitted by the 2gFB. The frequency of oscillations in-
creases while the amplitudes of modulation decreases with B.
Wb共T, v兲 = 4 冉 冊
M
2kT
3/2
v2e−M v
2/2kT
共10兲
In the absence of collisions, the damping rate of the oscilla-
tions is zero. For each value of B, the phase shift of the is the Maxwell-Boltzmann distribution, k Boltzmann con-
atomic coherence at the entrance of the probe region depends stant, T is the temperature of rubidium vapor, and M is the
on the atom transit time, which in turn depends on the atom mass of a 87Rb atom. We have found that the contribution to
velocity and the direction of the atom propagation. Interfer- the total fluorescence ⌼共B兲 comes from atoms with small vz.
ence occurs when the electric field of the probe beam, phase The range of velocities vz contributing to the fluorescence
coherent to the pump beam, interacts with an atom. If the increases with the laser beam intensity. Even for the highest
two oscillators are in phase, the probe beam transmission intensities, laser detuning as seen by the atom with vz is
increases, otherwise decreases. In the cell, the atoms move much smaller then the separation between the hyperfine lev-
with different velocities due to the Maxwell-Boltzmann dis- els of the excited 2 P1/2 state. This justifies why in Eq. 共1兲 we
tribution and travel at different angles in respect to the laser did not include the Fe = 2 hyperfine level of the excited state.
beam. Thus, the atoms for the same B acquire different
phases at the entrance to the probe beam. This results in the
III. EXPERIMENTAL SETUP
lowering of the amplitude or in the washing out of the Ram-
sey fringes in the probe transmission. The laser light is generated by an external cavity diode
Total fluorescence from an atom due to excitation by the laser 共ECDL兲 and locked to the D1 transition in 87Rb using
probe beam is the doppler free dichroic atomic laser lock 共DDAVLL兲 关27兴
technique 共see Fig. 3兲. The laser beam is split into two beams
Ie共B, vជ 兲 = 冕
0
tp
⌸e共t,B, vជ 兲dt, 共8兲 using a nonpolarizing beam splitter. The intensities of the
two beams are adjusted by variable neutral-density filters.
The diameter of one of the beams 共the pump beam兲 is en-
where t p is the atom transit time through the probe beam. larged to ⬃25 mm and the beam is sent through the iris of
This time is determined by the atom trajectory in the probe, 12 mm in diameter. The polarization of the pump beam is
i.e., and by velocity component perpendicular to the laser determined by the linear polarizer. The linear polarization of
beam vx. To calculate the total fluorescence ⌼共B兲 we aver- the probe beam and its orientation in respect to the linear
aged Ie共B , vជ 兲 over atom trajectories, i.e., over incident angles polarization of the pump beam is determined by both the
of an atom on the probe beam and over different atom ve- linear polarizer and a / 2 retardation plate. The two beams
locities 共vជ summation兲. vz, velocity component parallel with are combined using a 1-in. mirror with a hole in its center
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DARK RAMAN RESONANCES DUE TO RAMSEY … PHYSICAL REVIEW A 78, 063816 共2008兲
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GRUJIĆ et al. PHYSICAL REVIEW A 78, 063816 共2008兲
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