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Renewable Energy 180 (2021) 637e657

Contents lists available at ScienceDirect

Renewable Energy
journal homepage: www.elsevier.com/locate/renene

Experimental investigation on the dynamic thermal performance of


the parallel solar-assisted air-source heat pump latent heat thermal
energy storage system
Xin Jin , Huihui Zhang , Gongsheng Huang , Alvin CK. Lai *
Department of Architecture and Civil Engineering, City University of Hong Kong, Tat Chee Ave, Kowloon, Hong Kong

a r t i c l e i n f o a b s t r a c t

Article history: In this study, a dual-source solar-heat pump latent heat thermal energy storage system for hot-water
Received 17 December 2020 supply was proposed to take advantage of renewable energy sources. An experimental setup mainly
Received in revised form consisting of a solar heat collector with a gross area of 2 m2 and an air-source heat pump with a
10 August 2021
maximum capacity of 2 kW was established to evaluate the adaptability of the phase-change material to
Accepted 18 August 2021
the solar-heat pump and the feasibility of the heating system. A comparative study was carried out to
Available online 26 August 2021
investigate the effects of the operation modes on the system thermal performance and explore optimal
operating parameters. Compared to the single heating mode, the overall efficiency of the system was
Keywords:
Solar-heat pump
enhanced by about 57.5% under the combined heating mode due to the introduction of solar energy. The
Latent heat thermal energy storage coefficient of performance of the heat pump significantly increased from 2.09 to 2.60 when the flow rate
Phase-change material increased from 0.010 L/s to 0.038 L/s. However, an increase in the flow rate could not significantly
Dynamic thermal performance improve the overall efficiency of the entire heating system due to the higher power consumption of the
Energy efficiency pump. The storage unit exhibits a great storage density of about 211.13 MJ/m3 with a volume saving rate
of 21%.
© 2021 Published by Elsevier Ltd.

1. Introduction solar energy, the heat pump (HP) deployment is an effective solu-
tion to supply heat during weak solar intensity periods. As a
Building sectors occupied about 50% of the total energy con- renewable energy harvest supplier, the air to water heat pump
sumption and 30% of the carbon dioxide generation in the devel- (AWHP) can be widely utilized for hot water production in the
oped countries [1]. The building energy consumption will keep building sector due to its environmentally friendly characteristic
growing by nearly 1.5% per year from 2012 to 2040 [2]. Thereinto, and high efficiency [9]. The solar heat collector (SHC) and the
the heating loads, including space heating and domestic hot water, AWHP collect heat from renewable sources and deliver it to the
account for a large percentage of the total building energy profile thermal energy storage (TES) tank or the end-users through the
and are highly covered by fossil fuels [3e5]. To reduce this large heat transfer fluid (HTF) [10]. The TES unit is designed to balance
amount of non-renewable energy consumption, solar thermal en- the mismatch between the supply and the demand [11]. Besides,
ergy application has rapidly grown in the heating supply market. It combining the HP with the TES unit can avoid the frequent on/off
is reported that one solar water heater can indirectly reduce over 50 cycles of the HP during the peak consumption period.
tons of greenhouse gas emissions during a 20-year lifetime [6]. To The latent heat thermal energy storage (LHTES) is a promising
fix the volatile heat generation of the solar water heater, dual- TES technique due to the high energy storage density and nearly
source heating equipment integrated with the storage technique isothermal phase-transition temperature of the phase-change
has been introduced [7,8]. In response to the highly intermittent material (PCM) [12]. These advantages of the PCM can efficiently
reduce the storage tank volume or increase the storage capacity in
comparison with the sensible TES devices. To be a suitable PCM
used in the heating system, properties should be possessed: (1)
* Corresponding author.
E-mail addresses: cindyjin2-c@my.cityu.edu.hk (X. Jin), hhzhang6-c@my.cityu. phase-change temperature within the operation demand; (2) high
edu.hk (H. Zhang), gongsheng.huang@cityu.edu.hk (G. Huang), alvinlai@cityu.edu. phase-change enthalpy per volume; and (3) large storage density.
hk (A.CK. Lai).

https://doi.org/10.1016/j.renene.2021.08.067
0960-1481/© 2021 Published by Elsevier Ltd.
X. Jin, H. Zhang, G. Huang et al. Renewable Energy 180 (2021) 637e657

Nomenclature Abbreviation
AWHP air to water heat pump
A area (m2) COP coefficient of performance
Cp specific heat capacity (kJ/kg$K) CPCM composite phase-change material
D storage density (MJ/m3) HP heat pump
f solar fraction HTF heat transfer fluid
H enthalpy (kJ/kg) LHTES latent heat thermal energy storage
I solar irradiation intensity (kW/m2) PCM phase-change material
J daily solar radiation (kJ/m2$d) SATKU sodium acetate trihydrate-potassium chloride-urea
m mass (kg) SHC solar heat collector
Q thermal energy (kWh) SHP solar-heat pump
t time (s) TES thermal energy storage
T temperature ( C)
U uncertainty Subscripts
V volume (m3) a average
V_ volume flow rate (m3/s) d daily
_
W power consumption (kW) e end
i inlet
Greek symbols l liquid
h efficiency m melting
f volume saving rate o outlet
u PCM fraction s solid
r density (kg/m3) st start
sys system

Due to the maximum temperature limitation of the AWHP and the as a promising hot water producer concerning the HP pressure,
heat requirement of end-users, the recommended melting tem- input power, and stored/released thermal energy of the LHTES unit.
perature of the selected PCM is within the range of 45e48  C [13]. Bayomy et al. numerically predicted the thermal performance of a
Among the existing PCMs developed for the AWHP, sodium acetate domestic hot water LHTES tank (melting point: 36.4  C) operating
trihydrate-potassium chloride-urea (SATKU) composite phase- under the source temperature of 50  C by quantifying the heat
change material (CPCM) shows the desired melting point and a storage efficiency and the outlet water temperature [20]. The re-
relatively larger latent heat of fusion. However, the actual perfor- sults revealed that the storage efficiency increased with the greater
mance of the HP LHTES system containing the SATKU CPCM as the end-user demand. Kumar and Mylsamy experimentally evaluated
potential storage medium has not been investigated yet. the thermal performance of the SHC integrated with different
Some promising studies have been reported about the thermal PCMs, referring to energy efficiency, exergy efficiency, and the
performance of the LHTES system. Zhang et al. conducted the discharging water temperature [21]. In comparison with the sen-
optimization of the discharging performance of an LHTES unit sible storage unit with the same volume, the hot water duration of
based on the bionic design method [14]. The fractal tree structure the LHTES tank was extended.
led to a faster solidification rate of the storage unit. Li et al. It is summarized from previous studies that the thermal per-
numerically studied the impact of the charging flow rate on the formance of the heating system highly depends on the design and
charging completion time of the AWHP PCM storage system [15]. operating parameters. However, the investigations mainly focus on
With the fixed stored thermal energy demand, the charging the single latent heat exchanger rather than the coupled heating
completion time decreased with the increase of the water flow rate. system or remain at the constant heat-source temperature level.
Lin et al. studied the charging and discharging performance of the Limited research has been carried out regarding the integration of
multi-flow channel latent heat exchanger at different working fluid the PCM with both the HP and SHC. The feasibility of applying the
flow rates [16]. Under the nearly constant inlet temperature, the latent heat storage medium in the solar-heat pump (SHP) heating
higher flow rate induced an increment in the average heat transfer system has seldom been conducted. Likewise, the performance of
power and a decrement in the total energy. Wu et al. experimen- the dual-source water heater coupled with the LHTES unit in terms
tally investigated the heat exchange characteristic of a PCM unit of the dynamic thermal behavior and the efficiency of energy uti-
operating as a condenser of the AWHP [17]. Under the constant lization has not been evaluated yet. Hence, the impacts of the PCM
source temperature, the main factors influencing the discharging integration and the operating conditions on the dynamic thermal
performance of the heat exchanger are the pipeline configuration, performance of the SHP heating system need to be systematically
the inlet HTF flow rate, and the phase-change temperature. Zou investigated.
et al. experimentally compared the performance between the To reduce the reliance on fossil fuels, it is significant to combine
AWHP combined with an LHTES tank and the conventional water the SHC and the HP with the LHTES technique and develop an SHP
heater in conjunction with a sensible TES tank [18]. Even though LHTES system for heat supply. In this study, to investigate the
the gross volume of the LHTES tank was increased, the heat storage feasibility of integrating the LHTES technique with SHP, an exper-
was improved by 14%, and the corresponding coefficient of per- imental setup of the SHP heating system containing the SATKU as
formance (COP) of the HP was enhanced. Long et al. developed an the latent heat storage medium was built up. The experimental
AWHP heating system using paraffin (melting point: 56.03  C) as investigation was conducted to evaluate the compatibility of the
the latent heat storage medium to take advantage of the off-peak PCM to the heating devices. As the thermal performance of the
electricity strategy [19]. The system showed a good performance system highly relies on the operating conditions, a comparative

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X. Jin, H. Zhang, G. Huang et al. Renewable Energy 180 (2021) 637e657

study was carried out to assess the impacts of the flow rate and The system configurations were then determined based on the
supply water temperature on the thermal characteristics of the above estimations and the product specifications. The detailed in-
dual-source heating system. Moreover, the system performance formation of the main compositions of the experimental test rig is
regarding energy efficiency, power consumption, and temperature listed in Table 1.
variation under different operation modes was compared. The The flow rate range of the solar circulation loop was determined
optimal operating parameters that result in a higher energy- based on the following equation:
efficient potential of the heat collection system were then
analyzed and discussed. V_ SHC ¼ V_ per unit ASHC (5)

where V_ per unit is the volume flow rate of the working fluid corre-
2. Material and methods
sponding to the per-unit aperture area of the collector, and the
empirical value is usually set to be 15e20 mL/(s∙m2) [23].
2.1. System configuration
The flow rate range of the air-source HP circulation loop was
estimated as follows:
A test stand was established to evaluate the practical thermal
performance of the SHP LHTES system containing a novel PCM as 
the latent heat storage medium. The schematic diagram of the V_ HP ¼ Q_ Cp;HTF rHTF DT (6)
system prototype, mainly including an SHC LHTES circuit and an HP
LHTES circuit, is shown in Fig. 1. The test rig primarily contains a flat where DT is the water temperature rise by the HP unit during
plate collector, an AWHP, an LHTES unit, a buffer water tank, water heating, assumed at 5.0e8.0 K.
pumps, and flowmeters. The SHP LHTES module was designed to Based on the above estimations and the practical operation
produce domestic hot water for a single unit, in which a typical manual of the heating device provided by the manufacturer, the
daily hot water consumption was projected to be 50 L. With a larger flow rate value ranging from 0.010 L/s to 0.038 L/s was selected in
hot water demand, the module size could be enlarged in double, or the experiment. To conduct the comparative measurement, the
several system modules could be jointed in series or parallel con- system was tested in an environment-controlled chamber, taking
nections. The initial temperature of the water source was equal to advantage of its controllable and repetitive operating conditions.
20  C. Regarding the indoor experimental test, the following assumptions
The design collecting area of the solar water heating system was were made [28]: (a) ambient environment kept consistent during
decided according to the following equation [22]: the test, (b) isolation was considered stable at the initial setting, (c)
 the HTF uniformly distributed in its flow direction. The operation
A ¼ Vd Cp;HTF rHTF ðTe  Tst Þf Ja ha ð1  hloss Þ (1)
principles of each mode are described in the following sections.
where Vd is the design daily hot water consumption, and f is the
solar fraction, recommended to be 30%e80%. rHTF and Cp;HTF are the 2.2. Solar-heat pump latent heat thermal energy storage system
density and specific heat of HTF, respectively. Ja is corresponding to test
the annual average daily solar radiation on the collector surface of
the local site. ha is the annual average efficiency of the collector, 2.2.1. Solar heat collector latent heat thermal energy storage mode
usually set to be 45%e50%. hloss is the heat loss rate of the collector test
system, and the empirical value is set at 15%e30%. In the SHC LHTES mode, the tungsten-halogen lamp was used as
The design heat production of the air-source HP unit was the solar simulator due to its resembling infrared spectral distri-
calculated as follows: bution to sunlight and the low price [24,25]. Solar simulators with a
. maximum power of 1 kW each were installed parallel to the SHC.
Q_ ¼ KVd Cp;HTF rHTF ðTe  Tst Þð1  f Þ t (2) During the charging process, the solar simulator array was kept
running to provide irradiance for the SHC. The average irradiance
where K is the safety factor, assumed at 1.0e1.05, and t is the design received by the SHC was approximately 0.83 kW/m2, following the
operation time. test conditions recommended and outlined in studies [24e27].
The volume of the LHTES unit was estimated by the formula Meanwhile, the circulating HTF was pumped to the SHC and then
given below: reversely flowed back to the LHTES unit to transfer the thermal
energy to the storage medium continuously. During the discharging

Q
VLHTES ¼ h i (3)
ð1  uÞCp;HTF rHTF ðTe  Tst Þ þ urPCM Cp;s ðTm  Tst Þ þ Cp;l ðTe  Tm Þ þ Hm

where V and u are the unit volume and the PCM volume fraction, process, the tungsten halogen lamps were turned off, and the main
respectively. rPCM and Hm are the density and the phase-change water was delivered to the LHTES unit for extracting the stored
enthalpy of the latent heat storage medium, respectively. thermal energy.
The amount of the latent heat storage medium was computed
by:
2.2.2. Heat pump latent heat thermal energy storage mode test
mPCM ¼ uVLHTES rPCM (4) A conventional AWHP was considered as the second heat source
that could work during the low-radiation periods. The low-grade
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X. Jin, H. Zhang, G. Huang et al. Renewable Energy 180 (2021) 637e657

Fig. 1. (a) The picture of the solar-heat pump (SHP) latent heat thermal energy storage (LHTES) system test rig and (b) the schematic diagram of the system configuration.

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X. Jin, H. Zhang, G. Huang et al. Renewable Energy 180 (2021) 637e657

Table 1
Information on the main components of the SHP LHTES system.

Equipment Information

Solar heat collector (SHC) Manufacturer Dongguan Tegu New Energy Technology Co., Ltd.
Type Flat plate collector
Gross area 2.0 m2
Heat pump (HP) Manufacturer P.A.Hilton Ltd.
Type Air to water heat pump (AWHP)
Refrigerant Tetrafluoro ethane, CH2FCF3 (R134a).
Heating capacity 2 kW
COP 2e4
Maximum load 0.5 kW
Condenser Flat plate water-cooled condenser
Evaporator Continuous tube-externally finned-copper/aluminum galvanized steel construction
Latent heat thermal energy storage (LHTES) unit Manufacturer Hailing Yanan Hardware Store
Type Shell and tube heat exchanger
Solar simulator Manufacturer Shanghai Tingmei electronic commerce Co., Ltd.
Type QVF13
Water pump Manufacturer Flojet Co., Ltd.
Type PT416916
Frequency converter Manufacturer Xuzhou Rlpe Automation Control Equipment Co., Ltd.
Type AT2-0.75
Insulation layer Manufacturer Xiamen Lianyou Network Technology Co., Ltd.
Type Nitrile butadiene rubber

thermal energy from the ambient environment was absorbed by measurement was adopted. Four thermocouples were fixed at the
the evaporator and then released to the liquid stream through the entrances and exits of both the condenser and SHC, respectively, to
condenser. The charging process was kept driving until the high- monitor the temperature fluctuation of the coming and exiting HTF
pressure protection mechanism of the HP was activated. After- of the heating equipment during the charging process. The power
ward, the discharging loop was started by regulating the three-way consumption profiles of the AWHP and the water pump were log-
valve. Similar to the SHC LHTES mode, the city water was then ged through the power quality analyzer during the operation
introduced to the LHTES heat exchanger. period. The temperature distribution of the LHTES tank was
continuously recorded via the probes during the endothermic and
2.2.3. Solar-heat pump latent heat thermal energy storage mode exothermic processes. The average temperature of the PCM in three
test tubes located at different radius was selected to represent the
The dual-source heating system is a hybrid apparatus in which overall temperature evolution of the latent heat storage medium.
the heat can be collected from both the solar source and the at- Four thermocouples were inserted in the multilayers of the PCM in
mosphere. In this combined operation mode, the dual-source each cylindrical tube, as plotted in Fig. 3. Meanwhile, the temper-
heating equipment was connected in parallel. The operating pa- ature variation of the working fluid surrounding the PCM tubes at
rameters and test conditions were identical to those of the above- the same height level was simultaneously monitored via the ther-
mentioned single heating modes. The circulating working fluid mal probes. Data profiles were obtained through the data acquisi-
was heated by the SHC and the HP simultaneously and then flowed tion recorders at intervals of 30 s. The flow rate of HTF was
to the storage unit for heat exchange. The fluid worked as a high- monitored through the variable area flowmeter and adjusted by the
temperature heat source and rejected the heat to the storage me- frequency converter. The parameters and accuracies of the main
dium. The unit outlet liquid stream further flowed back to the fabricated devices are tabulated in Table 2.
heating devices to achieve a complete working cycle. During the
charging period, both the solar simulator and the compressor were
kept running. The charging process maintained activating until the
over-load cut-out of the HP occurred.

2.3. Latent heat thermal energy storage unit 2.4. Data processing for the solar-heat pump latent heat thermal
energy storage system test
The schematic diagrams of the LHTES tank and the built-in
stainless-steel tube for PCM are shown in Fig. 2. The vertically The total accumulated thermal energy delivered by the LHTES
designed shell and tube type heat exchanger owns good effec- unit was estimated as [16]:
tiveness and can be easily manufactured [29]. The SATKU CPCM was
prepared by the melt-blending method, and further details are tðe ,
given elsewhere [13]. The PCM was fully melted to the liquid state  
QLHTES ¼ V_ HTF rHTF Cp;HTF TLHTES;o  TLHTES;i dt 3600 (7)
by heating in the thermostat and then slowly poured into the tailor-
made tube, as shown in Fig. 2(a). The heating and cooling cycles tst
were performed for the PCM tubes, and the PCM was continuously
added to the tube to ensure the trapped air in the PCM disappeared. where V_ HTF is the volume flow rate of HTF. TLHTES;i and TLHTES;o are
About 9 kg PCMs were encapsulated in eighteen tubes, which were the coming and exiting temperatures of the LHTES unit, respec-
evenly integrated into the thermal storage unit. The unit was tively. tst and te are the time corresponding to the start and end of
assembled by the nitrile butadiene rubber insulation layer to the procedure, respectively.
reduce the heat loss. The total accumulated thermal energy produced by the SHC,
To capture a transient heat exchange process, a real-time QSHC , was computed as:
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X. Jin, H. Zhang, G. Huang et al. Renewable Energy 180 (2021) 637e657

Fig. 2. (a) The picture of the LHTES unit prototype and the schematic diagrams of the (b) phase-change material (PCM) tube and (c) the LHTES unit.

642
X. Jin, H. Zhang, G. Huang et al. Renewable Energy 180 (2021) 637e657

The thermal energy efficiency of the SHC, hSHC , was calculated


using:
 
V_ HTF rHTF Cp;HTF TSHC;o  TSHC;i
hSHC ¼ (10)
ASHC I

where A is the total effective area of the SHC, and I is the solar
irradiation intensity.
The total accumulated thermal energy transferred to the liquid
stream flowing through the HP, QHP , was expressed as:

tðe ,
 
QHP ¼ V_ HTF rHTF Cp;HTF THP;o  THP;i dt 3600 (11)
tst

where THP;i and THP;o are the HTF temperature of the HP at the inlet
and outlet, respectively.
The average heat exchange power of the HP, Q_ , was given by: HP

tðe
1  
Q_ HP ¼ V_ HTF rHTF Cp;HTF THP;o  THP;i dt (12)
ðte  tst Þ
tst
Fig. 3. Location of measured points in the LHTES unit.
The COP of the HP was obtained by:
 
V_ HTF rHTF Cp;HTF THP;o  THP;i
COP ¼ (13)
W_ HP
tðe ,
  _ HP is the electric power consumed by the HP.
QSHC ¼ V_ HTF rHTF Cp;HTF TSHC;o  TSHC;i dt 3600 (8) where W
tst
The efficiency of the HP LHTES system, hHP;sys , was determined
by the following equation:
where TSHC;i and TSHC;o are coming and exiting HTF temperatures of  
the SHC, respectively. V_ HTF rHTF Cp;HTF THP;o  THP;i
hHP;sys ¼ (14)
The average heat exchange power of the SHC, Q_ , was ob- SHC W _ þW _ pump
HP
tained by:
where W_ pump is the power profile of the circulating pump.
tðe The overall efficiency of the SHP LHTES system, hSHP;sys , was
1  
Q_ SHC ¼ V_ HTF rHTF Cp;HTF TSHC;o  TSHC;i dt (9) determined by the following equation:
ðte  tst Þ
tst

   
V_ HTF rHTF Cp;HTF TSHC;o  TSHC;i þ V_ HTF rHTF Cp;HTF THP;o  THP;i
hSHP;sys ¼ _ P _ (15)
W þ W
HP pump

Table 2
Detailed parameters of other fabricated devices.

Instruments Manufacturer Type Accuracy

Power quality analyzer Fluke Co., Ltd. 43B ±2.0%


Temperature recorder Lutron Electronic Enterprise Co., Ltd. BTM-4208SD ±0.1%
Precision hygrometer Lutron Electronic Enterprise Co., Ltd. HT-3027SD ±0.4%
Flowmeter MPB Industries Ltd. 1200 ±2.0%
Solar power meter Lutron Electronic Enterprise Co., Ltd. SPM-1116SD ±5.0%
Thermocouple Shanghai Yulai Instruments & Apparatuses Co., Ltd. K-type ±0.4%

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X. Jin, H. Zhang, G. Huang et al. Renewable Energy 180 (2021) 637e657

Fig. 4. Temperature evolution of the water with different charging flow rates: (a) 0.038 L/s, (b) 0.030 L/s, (c) 0.020 L/s, and (d) 0.010 L/s.

Fig. 5. Temperature evolution of the PCM with different charging flow rates: (a) 0.038 L/s, (b) 0.030 L/s, (c) 0.020 L/s, and (d) 0.010 L/s.

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X. Jin, H. Zhang, G. Huang et al. Renewable Energy 180 (2021) 637e657

3. Results and discussions

A prototype of the SHP water heating system combined with the


LHTES technique was established in the present study. A series of
experimental tests were conducted to investigate the compatibility
of the PCM to the SHP water heater and evaluate the impacts of the
operating conditions on the dynamic thermal performance of the
system. The system thermal behavior under different heating
modes was characterized through the energy charging and dis-
charging processes. The optimal operating parameters were further
analyzed by the system performance comparison related to the
storage medium temperature evolution, the overall efficiency, the
thermal output, the recovered energy, and the power consumption
among different scenarios. The important results of the experi-
mental investigation are presented in the following sections.

3.1. The thermal energy performance of the solar heat collector


latent heat thermal energy storage mode

Fig. 7. Total accumulated charging energy and average power of the SHC with different
3.1.1. Water and phase-change material temperature variation in flow rates.
the charging process
The water temperature variation of each layer of the LHTES unit
at the given charging flow rates of 0.010 L/s, 0.020 L/s, 0.030 L/s, and can be divided into three stages: (1) sensible pre-heating stage, (2)
0.038 L/s under the single SHC heating mode is illustrated in Fig. 4. latent heating stage, and (3) sensible super-heating stage. The PCM
The SHC produced heat by absorbing the simulant light source temperature grew rapidly at the first stage, in which only the
during the charging process. The heat was then collected by the sensible heat of the solid phase was stored. After reaching the onset
HTF running in tubes attached to the plate, resulting in an incre- melting temperature of the PCM (47.3  C), an endothermic platform
ment of the HTF temperature. It can be seen that the stratification appeared in each temperature curve, indicating that the phase-
phenomenon existed within the storage tank for all flow rates. A change process was started. The charging energy was then absor-
clearer distinction between each layer was found in the scenarios bed and mainly stored as the latent heat thermal energy of the
flow rate lower than 0.020 L/s. The rate of increase in temperature storage medium. As a result, the temperature rising rate became
of the upper test point rose as the flow rate decreased, while it relatively lower during the solid-liquid phase-change period. The
showed a reverse trend for the water located at the bottom layer. third stage took place when the temperature rose to the end
For the flow rate of 0.010 L/s, the highest temperature of the upper melting point. At the final stage, the PCM temperature grew faster
layer could reach up to 65.7  C. However, the final temperature of again and stored the thermal energy in the sensible heat of the
the bottom layer was only 58.9  C. The largest temperature differ- liquid phase. It can be observed that the top layer of the PCM took
ence between the upper and bottom layers was 18.4 K, while the the least time to reach both the onset melting point and the end
corresponding variation was 4.2 K for the flow rate of 0.038 L/s. It melting point among all testing layers. This phenomenon may be
was observed that the lower flow rate of HTF facilitated the strat- driven by the larger temperature gap between the storage medium
ification phenomenon. and the environment at the unit top layer and the buoyancy effect
Fig. 5 illustrates the temperature distribution of the PCM varying [30]. In contrast, the bottom layer underwent the longest phase-
with different charging flow rates. The charging process of the PCM change duration due to the lower environmental medium
temperature.
The temperature driving potential between the LHTES medium
and the HTF significantly affects the heat transfer performance [31].
The temperature difference between the PCM and the water in the
top layer maintained a higher level at the flow rate of 0.010 L/s,
which accelerated the heat absorption of the heated PCM and led to
a faster temperature growth for the upper part of the PCM. The final
temperatures of the PCM in the upper layer were 65  C and 62  C,
concerning the flow rates of 0.010 L/s and 0.038 L/s, respectively.
The temperature difference between each layer became larger as
the HTF flow rate decreased. This may be attributed to the more
obvious stratification phenomenon of the unit working with a
lower flow rate. Therefore, the temperature-increasing rate of the
PCM at the bottom layer for the flow rate of 0.010 L/s was much
lower than other groups. It can be found that the bottom PCM
reached a maximum temperature of 55  C for the flow rate of
0.038 L/s, while only 50  C was observed for the flow rate of 0.010 L/
s. It indicates that the higher flow rates mitigate the stratifications
of both the PCM and the water.

Fig. 6. The efficiency of the SHC with different flow rates against time.

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X. Jin, H. Zhang, G. Huang et al. Renewable Energy 180 (2021) 637e657

Fig. 8. Temperature evolution of the PCM with different discharging flow rates: (a) 0.038 L/s, (b) 0.030 L/s, (c) 0.020 L/s, and (d) 0.010 L/s.

3.1.2. Instantaneous efficiency and charging energy in the charging of around 47  C, illustrating that the crystallization of the PCM
process occurred. It can be found that the exothermic plateau of the PCM in
The efficiency versus time profiles of the SHC working with the upper layer was wider than that of the bottom layer. The
different flow rates are depicted in Fig. 6. The instantaneous effi- accelerated solidification of the bottom PCM results from the larger
ciency decreased with time due to the source temperature varia- temperature gap between the latent heat storage medium and the
tion. The higher supply water temperature may induce a decrease environment. The late response of the upper layer was more
in the efficiency of the heating device. The efficiency of the SHC was obvious for the flow rate of 0.010 L/s. This, in turn, the PCM in the
slightly enhanced as the working fluid flow rate increased within upper layer displayed a more stable exothermic platform and a
the investigation range. The variation became smaller since the longer constant-temperature period of about 30 min. Moreover, the
flow rate increased to 0.020 L/s. The SHC outlet temperature with crystallization process took place faster with a higher discharging
the lower flow rate was much larger than that of the higher flow flow rate. This may refer to the accelerated heat transfer and the
rate because of the longer residence of the HTF in the SHC. How- increasing mass of the inlet city water at the higher flow rate [16].
ever, the HTF was exposed to the radiation for a longer time. It thus Besides, it can be seen that the endothermic process took much
triggered more convection and radiation heat loss to the ambient longer than the exothermic one since the discharging temperature
environment, which may result in a decrease in the efficiency of the difference is larger than the charging temperature difference [35].
SHC [32,33]. Fig. 7 shows the accumulated thermal energy and the Fig. 9 depicts the outlet HTF temperature profiles of the LHTES
average power collected from the SHC at different charging flow unit with various discharging flow rates. It is observed that the
rates. The heat produced by the SHC was observed to slightly rise temperature of the drain water from the LHTES unit gradually
with the flow rate increase may due to the increasing convective decreased with time. All temperature curves displayed a turning
heat transfer coefficient between the finned heat exchanger and the point at around 45  C, after which the inclination rate of the tem-
HTF and less heat loss [34]. perature curve showed a decreasing trend. The PCM solidified at a
nearly constant temperature and released the stored latent heat to
3.1.3. Phase-change material and water temperature variation in the inlet city water [36]. At the higher flow rate, the discharging
the discharging process period became shorter. The valid periods of the outlet water
Fig. 8 shows the PCM temperature variation, varying with the exceeded 40 min and 110 min for the flow rates of 0.038 L/s and
HTF flow rate during the discharging period. At the first cooling 0.010 L/s, respectively.
stage, the PCM temperature rapidly decreased to release the stored
sensible thermal energy. Then, the temperature gradient suddenly 3.1.4. Discharging energy in the discharging process
reduced, and an exothermic platform appeared at the turning point The accumulated thermal energy and the average power
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Fig. 9. Temperature evolution of the outlet water with different discharging flow rates: (a) 0.038 L/s, (b) 0.030 L/s, (c) 0.020 L/s, and (d) 0.010 L/s.

thermal energy could not be inadequately supplied to the main


water at the higher flow rate may owing to the large thermal
resistance of the storage medium [16].

3.2. The thermal energy performance of the heat pump latent heat
thermal energy storage mode

3.2.1. Water and phase-change material temperature variation in


the charging process
The temperature evolutions of the water in the scenarios
working with different charging flow rates under the single HP
heating mode are shown in Fig. 11. The profiles showed a similar
trend with the temperature curves presented in Fig. 4. The strati-
fication phenomenon became more apparent as the charging flow
rate decreased. At the early stage, a higher temperature rising rate
of the top testing point was observed for the lower HTF flow rate
groups of 0.010 L/s and 0.020 L/s due to the higher temperature at
the condenser outlet. However, the duration was prolonged for the
Fig. 10. Total accumulated discharging energy and average power of the LHTES unit bottom point to reach the same target value at the lower flow rate.
with different flow rates. In addition, the HP compressor was automatically switched off as
the condenser pressure rose above approximately 1700 kN m2
gauge. The lower HTF flow rate led to the overloaded compressor,
released from the LHTES unit are shown in Fig. 10. The cumulative thus accelerating the high-pressure cut-out of the HP.
recovered energy of the LHTES unit lay within the range of Fig. 12 presents the PCM temperature variation during the
1.81 kWh to 1.94 kWh. The average released power revealed an charging process, differing from the inlet HTF flow rates. It was
increasing tendency as the flow rate increased, ranging from observed that the upper part of the PCM took less time to accom-
0.76 kW to 1.46 kW. The increment results in the faster heat ex- plish the phase-change process due to the stratification phenom-
change with a higher discharging flow rate. However, a reversed enon. Besides, the higher HTF flow rate resulted in a larger liquid
tendency was observed in the total discharging energy. The stored fraction of the PCM. Due to the early thermal cut-out, the PCM
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Fig. 11. Temperature evolution of the water with different charging flow rates: (a) 0.038 L/s, (b) 0.030 L/s, (c) 0.020 L/s, and (d) 0.010 L/s.

Fig. 12. Temperature evolution of the PCM with different charging flow rates: (a) 0.038 L/s, (b) 0.030 L/s, (c) 0.020 L/s, and (d) 0.010 L/s.

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Fig. 13. (a) The COP, (b) the power consumption of the HP, (c) the efficiency, and (d) the power consumption of the HP LHTES system with different flow rates against time.

PCM was mainly worked as the sensible heat at the lower flow rate
of 0.010 L/s.

3.2.2. Instantaneous efficiency and charging energy in the charging


process
Fig. 13(a) and (b) depict the instantaneous COP and the power
consumption of the HP versus time with different flow rates. As
observed, the instantaneous COP got the peak value initially and
then decreased by about 40% at the end of the heating process. The
COP exhibited a decreasing trend due to the growth of the HP inlet
HTF temperature [37e39]. Also, the COP of the HP reduced with the
decrease in the HTF flow rate. The average COP at the HTF flow rates
of 0.010 L/s and 0.038 L/s were recorded as 2.09 and 2.60, respec-
tively. On the contrary, the power drawn by the HP rose with the
increasing inlet temperature, as well as with the decreasing flow
rate. The overall efficiency variation with the flow rate showed the
same trend as that of the COP. The average efficiency of the HP
LHTES system working at the HTF flow rates of 0.010 L/s and
0.038 L/s were 1.97 and 2.27, respectively. However, the total power
Fig. 14. Total accumulative charging energy and average power of the HP with
different flow rates. consumed by the HP heating system decreased first and then
increased with the increase in the flow rate. Therefore, the effi-
ciency increment caused by the higher flow rate became slight
could not complete the phase transition when the HTF flow rate compared to that of the COP due to the increasing total power
was lower than 0.030 L/s. As observed, the maximum PCM tem- consumption of the system at higher flow rate levels.
perature in the bottom part reached about 52  C at the flow rate of Fig. 14 presents the accumulative charging energy and average
0.038 L/s. In contrast, it was limited to 42  C at the flow rate of power of the HP working at different flow rates. The accumulated
0.010 L/s. Only the PCM located at the first test point position could charging energy transferred to the HTF increased as the flow rate
reach the super-heating stage before the high-pressure cut-out at increased, which may be caused by the appreciable growth of the
the flow rates of 0.020 L/s and 0.030 L/s. The charging phase of the heat transfer ability and less heat loss. The average heat exchange
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Fig. 15. Temperature evolution of the PCM with different discharging flow rates: (a) 0.038 L/s, (b) 0.030 L/s, (c) 0.020 L/s, and (d) 0.010 L/s.

power of the HP was enhanced by about 0.16 kW, with the charging discharged with the flow rates of 0.038 L/s and 0.020 L/s, respec-
flow rate varying from 0.010 L/s to 0.038 L/s. It can also be seen that tively. The turning point in the temperature curves of the dis-
the cases charging at the flow rate of 0.010 L/s to 0.020 L/s might charging water occurred within the range of 40  Ce50  C.
not satisfy a large thermal energy demand within the single heating
operation. The HP needs to restart for accomplishing the same heat 3.2.4. Discharging energy in the discharging process
storage, which results in the frequent switch of the equipment. The recovered energy and the average power of each discharg-
Therefore, the operation problems related to the HP repeated start- ing test for the HP LHTES mode are presented in Fig. 17. It can be
stops might emerge when the operating flow rate is low. found that the average heat exchange power of the LHTES unit went
up as the discharging flow rate increased. This is related to the fact
3.2.3. Phase-change material and water temperature variation in that the heat transfer was accelerated with the higher flow rate of
the discharging process the working fluid. However, the cumulative recovered energy was
Fig. 15 depicts the temperature variation of the PCM differing decreased as the flow rate increased may due to the large thermal
from flow rates during the discharging process. The slope of all resistance laid in the PCM.
temperature curves was observed to decrease at the inflection
point of about 47e50  C, at which the PCM was beginning to so- 3.3. The thermal energy performance of the solar-heat pump latent
lidify. After releasing the latent heat, the PCM temperature heat thermal energy storage mode
decreased rapidly again as only the sensible heat was transferred to
the incoming HTF at the final cooling stage. The PCM at the upper 3.3.1. Water and phase-change material temperature variation in
layer displayed a more stable exothermic platform, which exceeded the charging process
20 min at the discharging flow rate of 0.020 L/s. The constant The water temperature of the LHTES unit varying with different
temperature period was relatively shorter for the PCM at the bot- flow rates under the SHP operation mode is compared in Fig. 18. The
tom layer. In addition, the higher flow rate is effective in shortening temperature evolution curves showed a similar tendency as the
the discharging time of the PCM. The discharging process running single charging mode. Nevertheless, the temperature rising rate
with a higher flow rate of 0.038 L/s was completed around 20 min under the combined heating mode was significantly higher than
earlier than that of the scenario working with a lower flow rate of the single heating mode. Compared to the SHC heating mode, the
0.020 L/s. time taken for the average temperature to increase to 50  C was
The temperature evolution of the drain water from the LHTES declined by about 63.2% at the flow rate of 0.038 L/s under the SHP
unit is shown in Fig. 16. As the flow rate increased, the outlet water heating mode. The stratification phenomenon existed under all
temperature decreased more rapidly. The effective duration of the flow rate scenarios, and the temperature difference between
outlet water was approximately 30 min and 48 min after being different layers became smaller since the flow rate increased. As
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Fig. 16. Temperature evolution of the outlet water with different discharging flow rates: (a) 0.038 L/s, (b) 0.030 L/s, (c) 0.020 L/s, and (d) 0.010 L/s.

showed an inflection point of about 47  C, at which the PCM started


to melt. The PCM temperature measured at the top testing point
increased faster for all scenarios due to the larger heating driving
force and the density gradients [40]. In addition, the temperature of
the storage medium at the tube bottom increased faster at higher
flow rates. A more uniform temperature distribution along the tube
direction was observed at the flow rate of 0.038 L/s. This indicates
that the stratification phenomenon was aggravated when charging
by the lower flow rate. Compared to the single heating mode, the
PCM temperature grew faster under the dual-source heating mode.
The duration taken for the bottom storage medium to reach the
phase-change stage was reduced by about 51.6% at the charging
flow rate of 0.020 L/s. The liquid sensible-heat charging period was
not exhibited in each test point owing to the relatively inadequate
charging. The charging performance might be limited by the heat
transfer resistance of the LHTES unit, which was mainly caused by
the PCM [16,41,42]. Due to the lower heat transfer ability of the
LHTES unit, the heat absorbing was insufficient before the system
shut down. To achieve enhanced charging energy, the heat transfer
Fig. 17. Total accumulated discharging energy and average power of the LHTES unit efficiency of the LHTES tank still requires further improvement.
with different flow rates.
3.3.2. Instantaneous efficiency and charging energy in the charging
process
can be observed, the high-pressure cut-out was advanced due to The instantaneous efficiency profiles of each heating device and
the rapid temperature increment compared to the single HP heat- the entire dual-source heating system are presented in Fig. 20. Due
ing mode. to the rapid increase of the inlet HTF temperature, the decreasing
The temperature evolution of the latent heat storage medium, rate of the SHC efficiency and the HP COP became larger in com-
differing from various flow rates under the combined heating parison with the single heating mode. The time taken for the same
mode, is shown in Fig. 19. The temperature increased quickly in the efficiency drop was shortened to around 50% when switching to the
sensible heat charging stage, and the growth rate became lower dual-source heating mode. Like the single HP heating mode, an
during the latent heat charging stage. The temperature curves improvement in the HP COP was found by increasing the flow rate
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Fig. 18. Temperature evolution of the water with different charging flow rates: (a) 0.038 L/s, (b) 0.030 L/s, (c) 0.020 L/s, and (d) 0.010 L/s.

under the combined heating mode. The average COP was enhanced storage medium during the discharging process. The same trend
by about 16.5% as the flow rate increased from 0.010 L/s to 0.038 L/s. was observed in all discharging profiles of the PCM. The exothermic
The average overall efficiency of the dual-source heating system platform ranged from about 50  C to 45  C to release the latent heat.
was enlarged by about 57.5% compared to that of the single HP The liquid phase exothermic process was not discovered in the
heating mode at the flow rate of 0.038 L/s due to the introduction of bottom test points due to the inadequate heat charging. The tem-
solar thermal energy. However, the overall efficiency of the SHP perature gradient became larger after the latent heat release. The
system was slightly varied with the flow rate due to the power crystallization of the storage medium was shortened as the flow
consumption difference. rate increased. The heat release duration was reduced by about
As shown in Fig. 21(a), the power consumption of the HP under 57.1% as the flow rate increased from 0.010 L/s to 0.038 L/s.
the SHP heating mode followed the same pattern with the single HP The drain water temperature profiles of the LHTES unit during
heating mode; it increased as the supply water temperature the discharging process are depicted in Fig. 24. The discharging
increased. The growth rate was significantly enlarged in compari- temperature evolution under the combined mode showed a similar
son with the single heating mode. The average system power rose trend as the single mode. A turning point at about 45  C was
by about 6.4% compared to the single HP operation mode at the exhibited in all outlet water temperature curves, after which the
flow rate of 0.038 L/s. The power consumption of the HP showed an temperature variation became slow due to the large phase-change
increasing trend with the lower flow rate. On the contrary, the total enthalpy of the latent heat storage medium. PCMs with favorable
power evolution of the dual-source heating system against the flow thermal properties could delay the rapid temperature decrease of
rate presented an opposite tendency. Within the same operation the LHTES unit. The drain water temperature was maintained at a
time, the system power consumptions were reduced by around relatively higher level for a longer period at the lower flow rate. The
4.4% and 4.0% as the flow rate decreased from 0.038 L/s to 0.020 L/s approximate constant temperature period under the discharging
and 0.010 L/s, respectively. The total accumulative heat produced by flow rate of 0.010 L/s was also prolonged to about four times longer
the SHP system showed an increasing trend with the higher flow than 0.038 L/s.
rate, as depicted in Fig. 22. The charging energy ranged from
1.01 kWh to 1.66 kWh for the flow rates of 0.01 L/s to 0.038 L/s. The 3.3.4. Discharging energy in the discharging process
average power supplied by the SHP was enhanced by around 6.1% The recovered energy of the LHTES unit in the discharging
as the flow rate increased from 0.01 L/s to 0.038 L/s. process is shown in Fig. 25. The average power was enhanced by
about 115% when the discharging flow rate increased from 0.010 L/s
3.3.3. Phase-change material and water temperature variation in to 0.038 L/s. However, it can be observed that the lower the flow
the discharging process rate, the greater the energy released to the liquid stream. The
Fig. 23 presents the temperature variation of the latent heat released energy was decreased by about 7.9% as the flow rate
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Fig. 19. Temperature evolution of the PCM with different charging flow rates: (a) 0.038 L/s, (b) 0.030 L/s, (c) 0.020 L/s, and (d) 0.010 L/s.

increased to the maximum value. space occupation of the unit decreases with the higher storage
In addition to the thermal performance of the heating system, density, corresponding to a larger volume saving rate. About 21% of
the volume of the LHTES unit also required consideration. space could be saved by adopting SATKU as the latent heat storage
Regarding the limitation of building area in the high-density dis- medium, which results in a compact heat storage unit for flexible
trict, the storage system shall be well designed to avoid occupying installation.
too much space as well as imposing excessive loading on the
building structure. The corresponding volume saving rate (f) can 3.4. Uncertainty analysis
be estimated by the following equation [43]:
The uncertainty assessments of the efficiency of the SHC and the
VNo PCM  VPCM COP of the HP were conducted to evaluate the assurance of the
f¼  100% (16) experiment in this study. The efficiency and COP uncertainties are
VNo PCM
related to the accuracy of each independent variable in their cal-
Table 3 lists the volume storage density of the LHTES unit and its culations. The corresponding information of each measured vari-
corresponding volume saving rate. Only the sensible heat would be able is listed in Table 2. The differentiations of the specific heat
stored in the water, leading to significant growth in the volume of capacity, the gross area of the SHC, and the density of the working
the unit without PCM. The volume storage density of the unit was fluid were neglected in the calculation [45]. The uncertainties in the
effectively increased to around 211.13 MJ/m3, 25.97% larger than efficiency of the SHC (UhSHC ) and the COP of the HP (UCOP ) were
that of water. To achieve the desired thermal capacity, the entire given by the following equations [46]:

vffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffi
u0 12 !2 
u   
u v h vhSHC 2 vhSHC vhSHC 2
UhSHC ¼ ±t@Um_ HTF SHC A þ UT þ U TSHC;i þ U I (16)
vm_ HTF SHC;o
vTSHC;o vTSHC;i vI

vffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffi
u0 12 0 12
u  2 !2
u vCOP vCOP vCOP vCOP
B C
UCOP ¼ ±u
t@Um_ HTF _ A þ UT þ UTHP;i þ @UW_ HP
_ HP A
(17)
vmHTF HP;o
vTHP;o vTHP;i vW

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X. Jin, H. Zhang, G. Huang et al. Renewable Energy 180 (2021) 637e657

Fig. 21. (a) The power consumption of the HP and (b) the power consumption of the
SHP LHTES system with different flow rates against time.

where U is the error of each variable.


The maximum errors were ±0.03 and ± 0.11 for the efficiency
and COP, respectively. The maximal relative uncertainties in
determining the efficiency of the SHC and the COP of the HP in this
study were 5.4% and 3.0%, respectively.

4. Conclusion

This study evaluated the compatibility of the SATKU to the SHP


and the dynamic thermal behavior of the dual-source heating
system. In addition, comparative experiments were performed to
explore the effects of the operating parameters and operation
modes on the system performance. The findings are summarized as

Fig. 20. (a) The efficiency of the SHC, (b) the COP of the HP, and (c) the overall effi-
ciency of the SHP LHTES system with different flow rates against time.

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X. Jin, H. Zhang, G. Huang et al. Renewable Energy 180 (2021) 637e657

 The average COP of the HP increased from 2.09 to 2.60, as the


HTF flow rate increased from 0.010 L/s to 0.038 L/s. Besides, the
average power drawn by the HP decreased with a higher flow
rate.
 Compared to the single heating mode, the temperature-rising
rate of the heating system became larger under the combined
heating mode. The average efficiency of the coupled SHP system
was improved by around 57.5% compared to the single HP
heating mode at the flow rate of 0.038 L/s because of the
introduction of solar thermal energy. Nevertheless, the power
consumption of the entire heating system was slightly increased
due to the larger pump consumption relative to the higher flow
rate.
 The volume storage density of the LHTES unit was about
211.13 MJ/m3, 25.97% larger than that of the sensible heat stor-
age medium. As a result, the space occupation could be reduced
by about 21% in comparison with the sensible TES tank.

The experimental test rig of the SHP LHTES system was estab-
Fig. 22. Total accumulative charging energy and average power of the SHP system with
different flow rates.
lished in this study, providing theoretical references for coupling
the LHTES technology to the low-carbon heating system. The test
results revealed the potential to implement the SHP heating system
follows: for hot water production and presented the impacts of the charging
modes and operating conditions on the system thermal behavior,
 The phase-change area of the SATKU was adapted to the which deliver the design guideline of the novel heating supplier. To
working condition of the SHP. The latent heat storage medium further systematically investigate the system performance, an
could achieve the phase-change stage under each operation experimentally validated numerical model characterizing the dy-
mode at the inflection point of about 47  C. namic performance of the system should be established as future
work. The practical application of the SHP LHTES system

Fig. 23. Temperature evolution of the PCM with different discharging flow rates: (a) 0.038 L/s, (b) 0.030 L/s, (c) 0.020 L/s, and (d) 0.010 L/s.

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X. Jin, H. Zhang, G. Huang et al. Renewable Energy 180 (2021) 637e657

Fig. 24. Temperature evolution of the outlet water with different discharging flow rates: (a) 0.038 L/s, (b) 0.030 L/s, (c) 0.020 L/s, and (d) 0.010 L/s.

the economic and energy-saving benefits of the proposed heating


system, future work in terms of the optimal control framework for
the heating system should also be developed.

CRediT authorship contribution statement

Xin Jin: Conceptualization, Writing e original draft, Investiga-


tion. Huihui Zhang: Methodology. Gongsheng Huang: Writing e
review & editing. Alvin CK. Lai: Supervision, Methodology,
Investigation.

Declaration of competing interest

The authors declare that they have no known competing


financial interests or personal relationships that could have
appeared to influence the work reported in this paper.

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