—_ : Se NTERNATIONAL INDIAN SCHOOL - JEDDAH y) HALF YEARLY EXAM (2022-23) Max Marks: 70 Time: 3 Hours Printed Pages: 10 Class XID SUBJECT: Chemistry General Instructions: Read the following instructions carefully. a) There are 35 questions in this question paper with internal choice. 4) SECTION A consists of 18 multiple-choice questions carrying 1 mark each, ¢) SECTION B consists of 7 very short answer questions carrying 2 marks each. 4) SECTION C consists of 5 short answer questions carrying 3 marks each. ¢) SECTION D consists of 2 case- based questions carrying 4 marks each. f) SECTION E consists of 3 Jong answer questions carrying 5 marks each. g) All questions are compulsory. ‘f) Use of log tables and calculators is not allowed SECTION A The following questions are multiple-choice questions with one correct answer. Each question carries 1 mark. There is no internal choice in this section. 1. Which of the following condition is not satisfied by an ideal solution? (2) AHmixing = 0 (b) AVinixing = 0 (c) Raoult’s Law is obeyed (d) Formation of an azeotropic mixture 2. If limiting molar conductivity of Ca** and CF are 119.0 and 76.3 § cm? mol", then the value of limiting molar conductivity of CaCl, will be Page 1 of 10the compound which contains all the four 1° » 2°, 3° and 4° carbon atoms is (a)2, 3-dimethyl pentane (b) 3-chloro-2, 3-dimethylpentane (©) 2,3, 4-trimethylpentane (d) 3, 3-dimethylpentane 9. Which of the following possesses highest melting point? (8) Chlorobenzene (b) m-dichlorobenzene (©) o-dichlorobenzene (d) p-dichlorobenzene 10. Ethyl alcohol is obtained when ethyl chloride is boiled with (a) alcoholic KOH (8) aqueous KOH (c) water (d) aqueous KMn04 11. The correct order of boiling points for primary (1°), Secondary (2°) and Tertiery (3°) alcohols is (a) 2°> 12> 3° (p) 3°>2°>1° ()1°>2°>3° (dy 2° > 32> 1° 12. Dehydration of alcohol to ethers is catalyzed by %4) cone. HyS0, at 413 K (b) Hot NaOH ~~ (¢) Hot HBr (4) Hot HNO; 13. Strength of acidity is in order: OH OH OH OH INO, CH, NO, NO, T 0 i i (a) I>I>I>IV (b) UI>IV>1>0 ()I>IV>I>n @IV>m>I>0 14. Acetone reacts with Grignard reagent to form a) 3° alcohol (b) 2° alcohol (g) ether (d) no reaction Page 3 of 10,(@) 195.3 S om? mol" (§) 271.6 S cm? mol" (0) 43.3 S cm’ mol (d) 314.3 S cm’ mol" 3. What will be the fraction of molecules having energy equal to or greater than activation energy, Ea? (@K ()A (¢) Ae ERT (a) eet 4. Which among the following is a false statement? (a) Rate of zero order reaction is independent of initial concentration of reactant. (b) Half life of a third order reaction is inversely proportional to square of initial concentration of the reactant. (¢) Molecularity of a reaction may be zero or fraction. (d) For a first order reaction, ty2=0.699K 5. For a chemical reaction AB, it is found that the rate of reaction doubles when the concentration of A is increased two times. The order of reaction is (a) Two @®) One (c) Half (a) Zero 5. In a reaction, X — Y, the concentration of X decreases from 0.50 M to 0.38 M in 10 nin. What is the rate of reaction in Ms" during this interval? #210" (b) 4 x 10? 2» 107 (d) 1 x 10? 7. TUPAC name of (CHs)3CCI ‘a) 3-Chlorobutane (0) 2-Chloro-2-methylpropane ‘c) t-butyl chloride @ n-butyl chloride Page 2 ofnts labeled as Assertion (A) and Reason ® an alcohol of comparable molecular mass, an 15. Given below are two stateme Assertion (A): An ether is more volatile th Reason (R): Ethers are polar in nature. Select the most appropriate answer from the options given below: a. Both A and R are true and R is the correct explanation of A b. Both A and R are true but R is not the correct explanation of A. c. A is true but R is false. d. Ais false but R is true. 16. Given below are two statements labeled as Assertion (A) and Reason (R) Assertion: In electrolysis, the quantity of electricity needed for depositing 1 mole of silver is different from that required for 1 mole of copper. Reason: The molecular weights of silver and copper are different Select the most appropriate answer from the options given below: @. Both A and R are true and R is the correct explanation of A b. Both A and R are true but R is not the correct explanation of A. c. Ais true but R is false. d. A is false but R is true. 17. Given below are two statements labeled as Assertion (A) and Reason (R) Assertion : Order and molecularity are same. Reason : Order is determined experimentally and molecularity is the sum of the stoichiometric coefficient of rate determining elementary step. Select the most appropriate answer from the options given below: a. Both A and R are true and R is the correct explanation of A b. Both A and R are true but R is not the correct explanation of A. Page 4 of 1“ c. Ais true but R is false, 4. Ais false but R is true, 18. Given below are two statements labeled as Assertion (A) and Reason (R) Assertion: Molarity of a solution in liquid state changes with temperature. Reason: The volume of a solution changes with change in temperature. Select the most appropriate answer from the options given below: ¥. Both A and R are true and R is the correct explanation of A b. Both A and R are true but R is not the correct explanation of A. c. A is true but R is false. d. A is false but R is true. SECTION B This section contains 7 questions with intemal choice in two questions. The following questions are very short answer type and carry 2 marks each. 19. Explain the following behaviours : (i) Alcohols are more soluble in water than the hydrocarbons of comparable molecular masses. (ii) Ortho-nitrophenol is more acidic than ortho-methoxyphenol OR (i) Write the product formed when p-nitro chlorobenzene is heated with aqueous NaOH at 443 K followed by acidification, (ii) Compare the acidity of phenol with the product formed in the above reaction. 20. How would you differentiate between SN, and SN; mechanisms of substitution reactions? Give one example of each. Page 5 of 10OR / which one is more reactive towards (®) Out of (CH,);C-Br, and CH C H2C H,C H,-Br, SN; and why? = action? Gi) Why allylic and benzylic halides are more stable towards SNi re: 21. Although chlorine is an electron-withdrawing group, yet a in electrophilic aromatic substitution reactions. Explain why is it so? t is ortho- and para-directing 22. Distinguish between order of the reactions and molecularity? 23. How does the temperature change affect the rate of a reaction? How can this effect the rate constant of the reaction quantitatively? 5 2 24. The molar conductivity of a 1.5 M solution of an electrolyte is found to be 138.9 S em mol". Calculate the conductivity of this solution. 25. Define the following with examples: (i) Azeotrope (ii) Isotonic solutions SECTION C This section contains 5 questions with internal choice in two questions. The following questions are short answer type and carry 3 marks each. 26. How would you convert the following: (i) Phenol to benzoquinone (ii) Propanone to 2-methylpropan-2-ol (iii) Propene to propan-2-ol 27. Give reasons: (i) C—Cl bond length in chlorobenzene is shorter than C — Cl bond length in CH3 — Cl. (ii) The dipole moment of chlorobenzene is lower than that of cyclohexyl chloride. (iii) Grignard reagents should be prepared under anhydrous conditions, Page 6 of 10yi The rate of a reaction becomes four times when the temperature changes from 293 K to 13 K. Calculate the energy of activation (Ea) of the reaction assuming that it does not hange with temperature. [R= 8.314 JK" mol", log 4 = 0.6021 ] OR For a decomposition reacti ion, the values of k at two different temperatures are given below: k1=2.15 « 10°L mot! 5" at 650K k2=2.39 x 107L mol! s" at 700K Calculate the value of activation energy for this reaction. Gog 11.11 = 1.046) (R=8.314 1K mot") 29. Conductivity of 2.5 x 10M methanoic acid is 5.25 x 10° § om’! Calculate its molar conductivity and degree of dissociation, Given : 1°") = 349.5 Scm? mol" and 4°(HCOO) = 50.5 Sem? mol". 30. Calculate the mass of compound (molar mass = 256 g mol") to be dissolved in 75 g of benzene to lower its freezing point by 0.48 K (K;= 5.12 K kg mol") OR A solution prepared by dissolving 1.25 g of oil of winter green (methyl salicylate) in 99.0 g of benzene has a boiling point of 80.31°C. Determine the molar mass of this compound. (BP. of pure benzene = 80.10°C and Ky for benzene = 2.53°C kg mol") SECTION D The following questions are case-based questions. Each question has an internal choice and carries 4 (1+1+2) marks each. Read the passage carefully and answer the questions that follow. 31. A solution which obeys Raoult's law strictly is called an ideal solution, while a solution which shows deviations from Raoult's law is called a non-ideal solution or real solution, Suppose the molecules of the solvent and solute are represented by A and B respectively, and let gA-B, gA-A and gB-B are the attractive forces between A-B, A-A and BB : respectively. An ideal solution of the components A and B is defined as the solution in Page 7 of 10A-B are of the same ‘ the components : rea Fi in the pure components AA and B: . ts A and B is defined as the solution in ‘a 5 A-B are of the different the component: in the pure components A-A and B-B. which the intermolecular interactions bet : magnitude as the intermolecular interaction: Similarly, a non- ideal solution of the compon' which the intermolecular interactions between i magnitude as the intermolecular interactions found i Answer the following questions: a) Give one example of an ideal solution. b) Write two characteristics of non-ideal solution. sulting solution increases, what type c) On mixing liquid A and liquid B, volume of the re of deviation from Raoult's law is shown by this solution and why? OR Which type of deviation will be shown by a solution, if gA-B >gA-A and gB-B a¢ 32. All chemical reactions involve interaction of atoms and molecules. A large number of atoms/molecules are present in a few gram of any chemical compound varying with their atomic/molecular masses. To handle such large number conveniently, the mole concept was introduced. Alll electrochemical cell reactions are also based on mole concept. For example, a 4.0 molar aqueous solution of NaCl is prepared and 500 mL of this solution is electrolysed. This leads to the evolution of chlorine gas at one of the electrode. The amount of products formed can be calculated by using mole concept. a) In electrolysis of aqueous NaCI solution when Pt electrode is taken, then which gas is liberated at cathode? b) In the electrolytes, what is the number of moles of electrons involved. c) What is the total charge (coulomb) required for complete electrolysis of the above solution. OR Calculate the mass of Chlorine gas liberated by the complete electrolysis of the above solution. (At. Mass of Cl-atom = 35.5 u) Page 8 of 3SECTION E y- following questions are long answer type and carry 5 marks each. Two questions frave an internal choice. 33. Write the products of the following reactions: @ CH; CH, -CH = CH, + HCl > Gi) (CH3),CHCH,OH 22%, ii) H+ HBr — H H (iv) (CHC = C(CH:), > CHz—-CH=CH2z oO + HBr fest, @) OR A compound is formed by the substitution of two chlorine atoms for two hydrogen atoms in propane. Write the structures of the isomers possible. Give the IUPAC name of the isomer which can form enantiomers. 34. (a) Define molar conductivity of a substance and describe how for weak and strong electrolytes, molar conductivity changes with concentration of solute. How is such change explained? (b) A voltaic cell is set up at 25°C with the following half cells: Ag* (0.001 M) | Ag and Cu™* (0.10 M) | Cu. ingae ‘What would be the voltage of this cell? (E°ceu = 0.46 V) OR (a) State the relationship amongst cell constant of a cell, resistance of the solution in the cell and conductivity of the solution. How is molar conductivity of a solute related to conductivity of its solution? Page 9 of 10(b) A voltaic cell is set up at 25°C with the following half-cells : ‘Al | AL* (0.001 M) and Ni | Ni** (0.50 M) A Wetgo Calculate the cell voltage. [E"(N*/Ni) =-0.25V, EB? (AP*/Al) =-1.66V] 104 wxo7 35. (a) 1.0 g of anon-electrolyte solute dissolved in 50 g of benzene lowered the freezing point of benzene by 0.40 K. The freezing point depression constant of benzene is 5.12 K kg mol". Find the molar mass of the solute. (b) What is the significance of Henry’s law constant, KH? (c) What leads to anoxia? Jobe bbibbbiooiiociiiiobiioiscionks Page 10 of 10