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  • Lesson 7 Unit 03

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    Vince Estebes
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    This document contains the answers to 3 chemistry questions. 1) The emf of a galvanic cell containing Cd anode and H2 cathode is calculated to be 0.3765 V. 2) The emf of a galvanic cell containing Mg anode and Ni cathode is calculated to be initially 2.12 V and after a change in concentrations to be 2.10 V. 3) A redox reaction involving MnO2, H+, Br- is given and the pH calculated to be 1.28 when the cell is at equilibrium.

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    This document contains the answers to 3 chemistry questions. 1) The emf of a galvanic cell containing Cd anode and H2 cathode is calculated to be 0.3765 V. 2) The emf of a galvanic cell containing Mg anode and Ni cathode is calculated to be initially 2.12 V and after a change in concentrations to be 2.10 V. 3) A redox reaction involving MnO2, H+, Br- is given and the pH calculated to be 1.28 when the cell is at equilibrium.

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    16 views3 pages

    Lesson 7 Unit 03

    Uploaded by

    Vince Estebes
    This document contains the answers to 3 chemistry questions. 1) The emf of a galvanic cell containing Cd anode and H2 cathode is calculated to be 0.3765 V. 2) The emf of a galvanic cell containing Mg anode and Ni cathode is calculated to be initially 2.12 V and after a change in concentrations to be 2.10 V. 3) A redox reaction involving MnO2, H+, Br- is given and the pH calculated to be 1.28 when the cell is at equilibrium.

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    of 3

    ESTEBES, VINCENT JAMES L.

    BSCE 1 – 4

    ANSWERS:

    1. 𝑨𝒏𝒐𝒅𝒆: 𝑪𝒅 ⟶ 𝐂𝒅𝟐+ + 𝟐𝒆− 𝑬°𝒂𝒏 = 𝟎. 𝟒𝟎 𝑽


    𝑪𝒂𝒕𝒉𝒐𝒅𝒆: 𝟐𝑯+ + 𝟐𝒆− ⟶ 𝐻2 𝑬°𝒄𝒂𝒕 = 𝟎. 𝟎𝟎𝑽

    𝑬°𝒄𝒆𝒍𝒍 = 𝑬°𝒄𝒂𝒕 − 𝑬°𝒂𝒏


    𝑬°𝒄𝒆𝒍𝒍 = 𝟎. 𝟎𝟎 𝑽 − (−𝟎. 𝟒𝟎 𝑽)
    𝑬°𝒄𝒆𝒍𝒍 = 𝟎. 𝟒𝟎 𝑽

    𝟎. 𝟎𝟓𝟗𝟐 𝑽 [𝑪𝒅𝟐+ ] × 𝑷𝑯𝟐


    𝑬𝒄𝒆𝒍𝒍 = 𝑬°𝒄𝒆𝒍𝒍 − 𝒍𝒐𝒈
    𝟐 (𝑯+ )𝟐

    𝟎. 𝟎𝟓𝟗𝟐 𝑽 𝟎. 𝟐𝟎 × 𝟎. 𝟖𝟎
    𝑬𝒄𝒆𝒍𝒍 = 𝟎. 𝟒𝟎 𝑽 − 𝒍𝒐𝒈
    𝟐 (𝟎. 𝟏𝟔)𝟐

    𝟎. 𝟎𝟓𝟗𝟐 𝑽
    𝑬𝒄𝒆𝒍𝒍 = 𝟎. 𝟒𝟎 𝑽 − 𝒍𝒐𝒈 𝟔. 𝟐𝟓
    𝟐

    𝑬𝒄𝒆𝒍𝒍 = 𝟎. 𝟒𝟎 𝑽 − 𝟎. 𝟎𝟐𝟑𝟓 𝑽
    𝑬𝒄𝒆𝒍𝒍 = 𝟎. 𝟑𝟕𝟔𝟓 𝑽

    The emf of a galvanic cell is 𝑬𝒄𝒆𝒍𝒍 = 𝟎. 𝟑𝟕𝟔𝟓 𝑽


    2. Initially without any change

    𝟎. 𝟎𝟓𝟗𝟐 𝑽 [𝑴𝒈𝟐+ ]
    𝑬𝒄𝒆𝒍𝒍 = 𝟐. 𝟏𝟏 𝑽 − 𝒍𝒐𝒈
    𝟐 [𝑵𝒊𝟐+ ]
    𝟎. 𝟎𝟓𝟗𝟐 𝑽 𝟎. 𝟒
    𝑬𝒄𝒆𝒍𝒍 = 𝟐. 𝟏𝟏 𝑽 − 𝒍𝒐𝒈 ( )
    𝟐 𝟎. 𝟔

    𝑬𝒄𝒆𝒍𝒍 = 𝟐. 𝟏𝟐 𝑽

    1. 𝑬°𝑴𝒈𝟐+/𝑴𝒈 = −𝟐. 𝟑𝟔 𝑽
    𝑬°𝑵𝒊𝟐+/𝑵𝒊 = −𝟎. 𝟐𝟓 𝑽

    [𝑴𝒈]
    𝑴𝒈 =
    𝟒
    𝟎. 𝟒𝟎
    𝑴𝒈 =
    𝟒
    𝑴𝒈 = 𝟎. 𝟏𝟎 𝑴

    𝑬°𝒄𝒆𝒍𝒍 = 𝑬°𝑵𝒊/𝑵𝒊𝟐+ − 𝑬°𝑴𝒈𝟐+/𝑴𝒈

    𝑬°𝒄𝒆𝒍𝒍 = [−𝟎. 𝟐𝟓 𝑽 − (−𝟐. 𝟑𝟔 𝑽)]


    𝑬°𝒄𝒆𝒍𝒍 = 𝟐. 𝟏𝟏 𝑽

    𝟎. 𝟎𝟓𝟗𝟐 𝑽 [𝑴𝒈𝟐+ ]
    𝑬𝒄𝒆𝒍𝒍 = 𝑬°𝒄𝒆𝒍𝒍 − 𝒍𝒐𝒈
    𝟐 [𝑵𝒊𝟐+ ]
    𝟎. 𝟎𝟓𝟗𝟐 𝑽 𝟎. 𝟏
    𝑬𝒄𝒆𝒍𝒍 = 𝟐. 𝟏𝟏 𝑽 − 𝒍𝒐𝒈 ( )
    𝟐 𝟎. 𝟔
    𝑬𝒄𝒆𝒍𝒍 = 𝟐. 𝟏𝟑 𝑽

    [𝑵𝑰𝟐+ ]
    2. 𝑵𝑰𝟐+ =
    𝟑
    𝟎. 𝟔𝟎
    𝑵𝑰𝟐+ =
    𝟑
    𝑵𝑰𝟐+ = 𝟎. 𝟐𝟎 𝑴

    𝟎. 𝟎𝟓𝟗𝟐 𝑽 [𝑴𝒈𝟐+ ]
    𝑬𝒄𝒆𝒍𝒍 = 𝑬°𝒄𝒆𝒍𝒍 − 𝒍𝒐𝒈
    𝟐 [𝑵𝒊𝟐+ ]
    𝟎. 𝟎𝟓𝟗𝟐 𝑽 𝟎. 𝟒
    𝑬𝒄𝒆𝒍𝒍 = 𝟐. 𝟏𝟏 𝑽 − 𝒍𝒐𝒈 ( )
    𝟐 𝟎. 𝟐
    𝑬𝒄𝒆𝒍𝒍 = 𝟐. 𝟏𝟎 𝑽
    3. 𝑴𝒏𝑶𝟐 (𝒔) + 𝟒𝑯+ (𝒂𝒒) + 𝟐𝑩𝒓− (𝒂𝒒) ⟶ 𝐌𝒏𝟐+ (𝒂𝒒) + 𝑩𝒓𝟐 (𝒍) + 𝟐𝑯𝟐 𝑶(𝒍)

    𝑶𝒙𝒊𝒅𝒂𝒕𝒊𝒐𝒏 𝒉𝒂𝒍𝒇: 𝟐𝑩𝒓− (𝒂𝒒) ⟶ 𝐁𝒓𝟐 (𝒍) 𝑬 = −𝟏. 𝟎𝟕𝟕 𝑽


    𝑹𝒆𝒅𝒖𝒄𝒕𝒊𝒐𝒏 𝒉𝒂𝒍𝒇: 𝑴𝒏𝑶𝟐 (𝒔) ⟶ 𝐌𝒏𝟐+ (𝒂𝒒) 𝑬 = 𝟏. 𝟐𝟗𝟗 𝑽

    𝑬°𝒄𝒆𝒍𝒍 = 𝑬°𝒐𝒙𝒊𝒅𝒂𝒕𝒊𝒐𝒏 + 𝑬°𝒓𝒆𝒅𝒖𝒄𝒕𝒊𝒐𝒏


    𝑬°𝒄𝒆𝒍𝒍 = 𝟏. 𝟐𝟗𝟗 𝑽 + (−𝟏. 𝟎𝟕𝟕 𝑽)
    𝑬°𝒄𝒆𝒍𝒍 = 𝟎. 𝟏𝟓𝟕 𝑽

    𝟎. 𝟎𝟐𝟓𝟕 𝑽
    𝑬𝒄𝒆𝒍𝒍 = 𝑬°𝒄𝒆𝒍𝒍 − 𝐥𝐧𝑸
    𝒏
    𝟎. 𝟎𝟐𝟓𝟕 𝑽 [𝒏|𝒏𝟐 ]
    𝑬𝒄𝒆𝒍𝒍 = 𝑬°𝒄𝒆𝒍𝒍 − 𝒍𝒏
    𝒏 [𝑩𝒓]𝟐 [𝑯𝟏 ]𝟒

    𝒔𝒖𝒃𝒔𝒕𝒊𝒕𝒖𝒕𝒆:
    𝒏=𝟐
    𝑬=𝟎
    𝑩𝒓− = 𝟏
    𝑴𝒏𝟐+ = 𝟏

    𝒘𝒆 𝒈𝒆𝒕 [𝑯+ ] = 𝟎. 𝟎𝟓𝟐 𝑴


    𝑻𝒉𝒖𝒔, 𝒑𝑯 = −𝒍𝒐𝒈[𝑯+ ]

    𝒑𝑯 = 𝟏. 𝟐𝟖

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