Professional Documents
Culture Documents
Index
Index
❖ CERTIFICATE 2
❖ ACKNOWLEDGEMENT 3
❖ OBJECTIVE OF PROJECT 5
❖ INDRODUCTION 6-7
❖APPLICATION 9
❖THEORY 10-11
❖EXPERIMENT 1 12-14
❖EXPERIMENT 2 15-16
❖EXPERIMENT 3 17-18
❖CONCLUSION 18
❖BIBLIOGRAPHY 19
Objective of the Project
5. Inter-molecular forces :-
The stronger the forces keeping the molecules
together in the liquid or solid state the more energy
that must be input in order to evaporate them.
Application
When clothes are hung on a laundry line, even
though the ambient temperature is below the
boiling point water, water evaporates. This is
accelerated by factors such as low humidity, heat
(from the sun) and wind. In a clothes dryer hot air is
blown through the clothes, allowing water to
evaporates very rapidly.
Theory
Evaporation is the process whereby atoms or
molecules in a liquid state (or solid state if the
substance sublimes) gain sufficient energy to enter
the gaseous state. The thermal motion of a
molecule must be sufficient to overcome the
surface tension of the liquid in order for it to
evaporate, that is, its kinetic energy must exceed
the work function of cohesion at the surface.
Evaporation therefore proceeds more quickly at
higher temperature and in liquids with lower
surface tension. Since only a small proportion of the
molecules are located near the surface and are
moving in the proper direction to escape at any
given instant, the rate of evaporation is limited.
Also, as the faster moving molecules escape, the
remaining molecules have lower average kinetic
energy, and the temperature of the liquid thus
decreases. If the evaporation takes place in a closed
vessel, the escaping molecules accumulate as a
vapor above the liquid. Many of the molecules
return to the liquid, with returning molecules
becoming more frequent as the density and
pressure of the vapor increases. When the process
of escape and return reaches equilibrium, the vapor
is said to be “saturated,” and no further change in
either vapor pressure and density or liquid
temperature will occur.
EXPERIMENT 1
AIM :-
To compare the rate of evaporation of water,
acetone and diethyl ether
Materials required:-
China dish, Pipette, Beaker, Weighing balance
Measuring flask, Acetone, Distilled water, Diethyl
ether, Watch
PROCEDURE:-
1. Take three china dishes.
2. Pipette out 10 ml To compare the rate of
evaporation of water, acetone and diethyl ether.
each sample.
3. Dish A-Acetone
Dish B-Water
Dish C-Diethyl ether
4. Record the weights before beginning the
experiment.
5. Leave the three dishes undisturbed for ½ an hr
and wait patiently.
6. Record the weights of the samples after the
given time.
7. Compare the prior and present observations.
OBSERVATION
LIQUIDS WEIGHT WEIGHT OF WEIGHT OF WEIGHT OF
OF DISH (DISH+SUBSTANCE)BEFORE (DISH+SUBSTANCE)AFTER SUBSTANCE
EVAPORATION EVAPORATION EVAPORATES
Water 50 60 59.8 0.2
(gm)
Acetone 50 57 55.5 2.3
(gm)
Diethyl 50 58 54.3 2.67
ether
(gm)
Inference and conclusion: –
The rate of evaporation of the given three liquids is
in order :- Diethyl Ether>Acetone>Water
Reason: –
Water has extensive hydrogen bonding in between
oxygen atom of one molecule and hydrogen atom
of another molecule. But this is absent in the case
of acetone.
EXPERIMENT II
Aim:-
To study the effect of surface area on the rate of
evaporation of Diethyl ether.
Requirements :-
Three Petri dishes of diameter 2.5 cm,5 cm, and 10
cm with covers ,10 ml pipette and stopwatch.
Procedure :-
1. Clean and dry the petri dishes and mark them as
A,B,C.
2. Pipette out 10 ml of Diethyl ether in each of the
petri dishes A,B and C cover them immediately.
3. Uncover all the three petri dishes simultaneously
and start the stopwatch.
4. Note the time when diethyl ether evaporates
completely from each petri dish.
OBSERVATION
Petri dish Mark Diameter of Petridish Time taken for Complete
Evaporation.
11 min 45 sec
A.
2.5
8 min 45 sec
B.
5.0
6 min 30 sec
C.
7.5
Result :-
It will be observed that maximum evaporation
occurs in petridish with largest diameter followed
by smaller.
EXPERIMENT III
Aim:-
To study the effect of temperature on the rate of
evaporation of acetone.
Requirement:-
Two petridishes of 5 cm diameter each ,stop watch,
10ml pipette, thermometer and thermostat.
Procedure :-
1. Wash and clean, dry the petridishes and marks
them as A and B.
2. Pipette out 10 ml of acetone to each of petridish
A and B and cover them.
3. Put one petri dish at room temperature and to
the heat for some time.
4. Note the reading.
OBSERVATION
Petri dishes mark Time (sec) Temperature (c) Volume taken (ml Evaporated
volume (ml)
A.
10 30 10 10
B.
20 40 10 10
Results :-
The order of evaporation of acetone in two petri
dishes as given.
Room temperature < Heating.
CONCLUSION
➢ Water has extensive hydrogen bonding in
between oxygen atom of one molecule and
hydrogen atom of another molecule. But this is
absent in the case of acetone .
Diethyl Ether>Acetone>Water
BIBLIOGRAPHY
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