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Stem Genchem2 q1w2
Stem Genchem2 q1w2
GENERAL CHEMISTRY 2
SELF-LEARNING PACKAGE
Quarter 1 | Week 2
SHS—General Chemistry 2
Competency/ies: Describe the difference in structure of crystalline and amorphous solids
(STEM_GC11IMFIIIa-c-104)
Interpret the phase diagram of water and carbon dioxide (STEM_GC11IMFIIIa-c-107)
Determine and explain the heating and cooling curve of a substance
(STEM_GC11IMFIIIa-c-109)
General Chemistry 2 – SHS
Self-Learning Package
Intermolecular Forces of Liquids and Solids
First Edition, 2020
SHS—General Chemistry 2
Competency/ies: Describe the difference in structure of crystalline and amorphous solids
(STEM_GC11IMFIIIa-c-104)
Interpret the phase diagram of water and carbon dioxide (STEM_GC11IMFIIIa-c-107)
Determine and explain the heating and cooling curve of a substance
(STEM_GC11IMFIIIa-c-109)
Introductory Message
Welcome!
The Self-Learning Package for Senior High School is a developed to guide you
our dear learners to meet the standards set by the K to 12 Curriculum.
The Self-Learning Package is developed to help you, dear learner, in your needs
to continue learning even if you are not in school. This learning material aims to
primarily provide you with meaningful and engaging activities for independent
learning. Being an active learner, carefully read and understand to follow the
instructions given.
REMEMBER ….
To answer the given exercises, questions and assessment, USE your Activity
Notebook or Answer Sheet. When you are DONE, wait for the teacher/volunteer to
collect your activity notebook/ answer sheet.
SHS—General Chemistry 2
Competency/ies: Describe the difference in structure of crystalline and amorphous solids
(STEM_GC11IMFIIIa-c-104)
Interpret the phase diagram of water and carbon dioxide (STEM_GC11IMFIIIa-c-107)
Determine and explain the heating and cooling curve of a substance
(STEM_GC11IMFIIIa-c-109)
SELF-LEARNING PACKAGE IN
GENERAL CHEMISTRY 2
Intermolecular Forces of Liquids
and Solids
Learning Competency:
Describe the difference in structure of crystalline and amorphous solids
(STEM_GC11IMFIIIa-c-104)
Interpret the phase diagram of water and carbon dioxide ( STEM_GC11IMFIIIa-c-107)
Determine and explain the heating and cooling curve of a substance
(STEM_GC11IMFIIIa-c-109)
Lesson 1: Solids and their Properties
Ready to Launch!
When you look around you, solids are everywhere. A solid is a state of
matter characterized by particles arranged in such a way that their shape and
volume are relatively stable. Solids are formed when the forces holding atoms
or molecules together are stronger than the energy moving them apart.
In today’s lesson, you are going to explore more about solid, its types
and classifications based on the attrac-
tive forces between them.
Activity
Direction: Observe and identify the common features and properties of
each group of materials listed below. Record your observation.
Group A. salt, sugar, alum (tawas)
Group B. rubber band, plastic, glass
Analysis
Direction: Based on your observation in the group of materials above
answer the following questions in a one whole sheet of pad
paper.
1. What are the two types of solids?
2. What features/properties can be used to distinguish
these two types of solids?
Abstraction and Generalization
• Solids can be categorized into two groups: the crystalline solids and the
amorphous solids.
• The differences in properties of these two groups of solids arise from the
presence or absence of long range order of arrangements of the particles in
the solids.
Difference between crystalline and amorphous solids:
Arrangement of particles
• The components of a solid can be arranged in two general ways: they can
form a regular repeating three-dimensional structure called a crystal lat-
tice, thus producing a crystalline solid, or they can aggregate with no par-
ticular long range order, and form an amorphous solid (from the Greek
ámorphos, meaning “shapeless”).
• Crystalline solids are arranged in fixed geometric patterns or lattices.
Examples of crystalline solids are ice and sodium chloride (NaCl), copper
sulfate (CuSO4), diamond, graphite, and sugar (C12H22O11). The ordered
arrangement of their units maximizes the space they occupy and are
essentially incompressible.
• Amorphous solids have a random orientation of particles. Examples of
amorphous solids are glass, plastic, coal, and rubber. They are considered
super-cooled liquids where molecules are arranged in a random manner
similar to the liquid state.
Explanation of properties:
• High melting point – a large amount of energy is needed to melt the crystal
since the forces of attraction to be broken are numerous and extend
throughout the crystal.
• Dense – atoms are packed closely together. Metals exhibit close-packing
structures, a most economical way by which atoms utilize space.
• Electrical conductivity – then delocalized electrons move throughout the
crystal.
Figure 6. Copper is a
metallic solid.
2. IONIC CRYSTALS
• Ionic crystals are made of ions (cations and anions). These ions form strong
electrostatic interactions that hold the crystal lattice together. The electro-
static attractions are numerous and extend throughout the crystal since
each ion is surrounded by several ions of opposite charge, making ionic
crystals hard and of high melting points.
• The figure below shows a model of NaCl crystal, where one Na+ ion is sur-
rounded by six Cl-ions, and a Cl- ion is likewise surrounded by six Na+
ions.
Table 2: Observe Property and Inference about the Structure of Ionic Crystals
3. MOLECULAR CRYSTALS
• Molecular crystals are made of atoms, such as in noble gases, or mole-
cules, such as in sugar, C12H22O11,iodine, I2, and naphthalene, C10H8. The
atoms or molecules are held together by a mix of hydrogen bonding/dipole-
dipole and dispersion forces, and these are the attractive forces that are
broken when the crystal melts. Hence, most molecular crystals have rela-
tively low melting points.
Table 3: Observe Property and Inference about the Structure of Molecular
Crystals
• The valence electrons of the atoms in the crystal are all used to form cova-
lent bonds. Because there are no delocalized electrons, covalent network
solids do not conduct electricity.
• Covalent bonds are the only type of attractive force between atoms in the
network solid. Rearranging or breaking of covalent bonds requires large
amounts of energy; therefore, covalent network solids have high melting
points. Covalent bonds are extremely strong, so covalent network solids
are very hard. Generally, these solids are insoluble in water due to the dif-
ficulty of solvating very large molecules. Diamond is the hardest material
known, while cubic boron nitride (BN) is the second-hardest. Silicon car-
bide (SiC) is very structurally complex and has at least 70 crystalline
forms.
Reflect
Uric acid is a chemical created when the body breaks down sub-
stances called purines, which are found in some foods. Purines show up when
cells die and get taken apart. Most of the uric acid leaves your body when you
pee, and some when you poop.
If you have high levels of uric acid, it can be a sign of disease such as
gout. Watch out for foods that are high in purines
such as tuna, sardines, high fat foods, organ meats
and sugary foods.
Direction: Choose one crystal you usually use or see at home or in your
neighborhood. Read about the crystal and write a four-six para
graph essay by answering the following questions. Cite your
sources following the APA format . Do this in a short bond
paper. Refer to the rubric on the next page for scoring.
1. How is the crystal formed?
2. Is it beneficial or harmful to man or both? Discuss how it is
beneficial or harmful to man.
3. If it is something harmful, what can be done to avoid its
formation? If it is something beneficial, how can its formation
be promoted?
Rubric
https://sites.google.com/a/une.edu/hgeo/home/2-the-middle-east/tuesdayfebruary23/middle-east-project/rubric
Ready to Launch!
Direction: Find and circle all of the words that are hidden in the grid.
The words may be hidden in any direction. Define phase diagram using
the words found. Write the answer in your answer sheet.
V T R M A T T E R E N E R G Y T O O
C R I T I C A L P O I N T A S E D E
G O L D H W L A E D I A G R A M U V
O P O K O H E S E R U S S E R P T Y
O A V O P A A Z O A N M T L P E S E
D V E P T H A V A L S S I K L R R R
D A Y S P F P C I M I N E M A A Q U
A B O E E I P Q G K L D P O T T P S
Y B U E O S U C A T D O G L E U O S
H M E L T I N G C U R V E E B R N E
E C H M D H A P P Y S M I L E E M R
L E I O L A B C D E F H I J J K L P
O A L O H A M A N V C R I T I C A L
Solid
A E Liquid
G Gas
C H Critical point
Triple point
Solid gas
E Solid liquid
B
Liquid gas
D
Analysis
Direction: Using the phase diagram above, answer the following ques-
tions below. Write your answer in a one whole sheet of pad paper.
1. What is a phase diagram?
2.What are the three areas of a phase diagram?
3. What does each line in a phase diagram
represents?
Abstraction and Generalization
• A phase diagram is a graphical representation of the physical states of a
substance under different conditions of temperature and pressure. It gives
the possible combinations of pressure and temperature at which certain
physical state or states a substance would be observed. Each substance
has its own phase diagram. A typical phase diagram is shown below;
• There is only one difference between the phase diagram for water and the
other phase diagrams discussed. The solid-liquid equilibrium line (the
melting point curve) slopes backwards rather than forwards.
• For water, the melting point gets lower at higher pressures. This is be-
cause solid ice is less dense than liquid water. This phenomenon is caused
by the crystal structure of the solid phase. In the solid forms of water
and some other substances, the molecules crystallize in a lattice with
greater average space between molecules, thus resulting in a solid occupy-
ing a larger volume and consequently with a lower density than the liquid.
When it melts, the liquid water formed occupies a smaller volume.
• An increase in pressure will move the above equilibrium to the side with
the smaller volume. Liquid water is produced. To make the liquid water
freeze again at this higher pressure, the temperature should be
reduced. Higher pressures mean lower melting (freezing) points.
• The only thing specia about this phase diagram is the position of the triple
point, which is well above atmospheric pressure. It is impossible to gt any
liquid carbon dioxide at pressures less than 5.2 atm.
• Between A & B, the material is a solid. The heat supplied to the material is used
to increase the kinetic energy of the molecules and the temperature rises.
• Between B & C, the solid is melting. Heat is still being supplied to the
material but the temperature does not change. Heat energy is not being
changed into kinetic energy. Instead, the heat is used to change
the arrangement of the molecules.
• At point C, all of the material has been changed to liquid.
• Between C & D, the heat supplied is again used to increase kinetic energy of the
molecules and the temperature of the liquid starts to rise.
• Between C & D, the liquid is heated until it starts to boil.
• Between D & E, the liquid is still being heated but the extra heat energy does not
change the temperature (kinetic energy) of the molecules. The heat energy is used
to change the arrangement of the
molecules to form a gas.
• At point E, all of the liquid has been changed into gas.
• Between E & F, the gas is heated and the heat energy increases the kinetic energy
of molecules once more, so the temperature of the gas increases.
When a system contains only one phase (solid, liquid, or gas), the temperature
will increase when it receives energy. The rate of temperature increase will be de-
pendent on the heat capacity of the phase in the system.
When the heat capacity is large, the temperature increases slowly, because much
energy is required to increase its temperature by one degree. Thus, the slopes of
temperature increase for the solid, liquid, and gases are different.
• The figure below shows the heating curve of water. To calculate the total energy
change for such a process, all the steps should be included.
Lesson 2
Try This
Answer Key
Lesson 2
Keep This in Mind Assess Your Learning
Expected Answer
Application