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Well Services and OneStim

QHSE Standard 18: Chemical


Product Management
Reference: InTouch ID# 3313694
Version: 4.5
Release Date: 09-Mar-2020

EDMS UID: 0000079558

Produced: 09-Mar-2020 17:12:58


Owner: WS InTouch Manager

Private IPC,Well
standard,18,eighteen,h
com munication,
Ser vices,Safety,QHSE,
chemical
azcom,hazhaz
ar dous,
ar d,

Copyright © 2020 Schlumberger, Unpublished Work. All rights reserved.


WS QHSE Standard 18 / Legal Information

Legal Information

Copyright © 2020 Schlumberger, Unpublished Work. All rights reserved.

This work contains the confidential and proprietary trade secrets of Schlumberger
and may not be copied or stored in an information retrieval system, transferred,
used, distributed, translated or retransmitted in any form or by any means,
electronic or mechanical, in whole or in part, without the express written
permission of the copyright owner.

Trademarks & Service marks


WS InTouch Manager\\InTouch ID# 3313694\4.5\Release Date:09-Mar-2020\EDMS UID: 0000079558\Produced: 09-Mar-2020 17:12:58

Schlumberger, the Schlumberger logotype, and other words or symbols used


to identify the products and services described herein are either trademarks,
trade names or service marks of Schlumberger and its licensors, or are the
property of their respective owners. These marks may not be copied, imitated
or used, in whole or in part, without the express prior written permission of
Schlumberger. In addition, covers, page headers, custom graphics, icons, and
other design elements may be service marks, trademarks, and/or trade dress
of Schlumberger, and may not be copied, imitated, or used, in whole or in part,
without the express prior written permission of Schlumberger.

A complete list of Schlumberger marks may be viewed at the Schlumberger


Oilfield Services Marks page: http://markslist.slb.com

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WS QHSE Standard 18 / Document Control

Document Control
Owner: WS InTouch Manager

Reviewer: InTouch

Approver: Armando Ballesteros, WS InTouch Manager

Contact Information
Name: WS InTouch Manager
LDAP Alias: InTouchSupport.com

Revision History
WS InTouch Manager\\InTouch ID# 3313694\4.5\Release Date:09-Mar-2020\EDMS UID: 0000079558\Produced: 09-Mar-2020 17:12:58

Version Date Description Prepared by

4.5 09-Mar-2020 Updated QADB references to new Chemicals Author: Candra Sutama, Ahmed
Quality Management System (C-QMS); in Tawil, Ambuj Johri; TechCom:
section 18.8.3.1, added chemicals to list not Blanca Vijil
requiring exemption that are used in spacer,
cement slurry or lost-circulation treatment
fluid; changed reference to SPCC plan to
Spill Preparedness and Response Procedure
(SPRP); in section 18.10.2, updated text to
reference Global Regulatory Compliance
website.

4.4 15-May-2019 Updated to correlate with release of WS QHSE Author: Armando Ballesteros;
Standard 18 Guideline 01: Product Shelf-Life TechCom: Blanca Vijil
Extension and to include OneStim.

4.3 13-Aug-2018 Add reference to Haz-Tag content to section Author: Juan Amado; TechCom:
18.12. Update section 18.8.5 product Blanca Vijil
obsolescence decision-maker from Chemistry
Portfolio manager to sub-Product Line Domain
Head.

4.2 04-Jun-2018 Fixed formatting of list in section “Operations Author: Jeff Beckel; TechCom:
planning center and category group.” Shobha Raghavan

4.1 10-Nov-2017 Updated to align with the new way to work Author: Jeff Beckel; TechCom:
(NWW). Changed Area to Geomarket, Shobha Raghavan
Segment to Product Line, Area Chemicals
Sourcing manager to Geomarket Chemicals
Supply manager, and Area Operations Support
manager to Well Services OI manager.

4.0 18-Aug-2017 Edited to upgrade and enhance operational Author: Jeff Beckel; TechCom:
safety. 1. Added the section Operations Shobha Raghavan
planning center and category group 2. Added
the section Technology Lifecycle Management
3. Added the section Exempted common
chemicals 4. Added the section Product
repackaging 5. Removed section Handling
flammable liquids 6. Removed the Glossary.

3.3 18-May-2017 Updated the Chemical Regulatory Compliance Author: Jeff Beckel; TechCom:
web site link to https://slb-chemicals.slb.com. Shobha Raghavan

3.2 03-Mar-2017 Section 18.10, changed the SDS for Well Author: Arya B Christiawan,
Services chemicals source location and TechCom: Shobha Raghavan
updated the website.

Private
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WS QHSE Standard 18 / Document Control

Version Date Description Prepared by

3.1 13-Sep-2016 Add chemical transfer hose requirements to Author: Stephan Harris;
Section 18.17. TechCom, John Schneider

3.0 13-Jul-2016 Revise table 18-1 for samples to client or 3rd Author: Sebastien Peyle;
party lab, revise Section 18.8.3 for D031, TechCom, John Schneider
D020, and D151 exemption

2.9 29-Apr-2016 Revise 18.17, clamp-on, quarter-turn or similar Author: Stephan Harris;
connection (e.g. Camloc) is now defined in TechCom, John Schneider
WS Standard 04

2.8 29-Mar-2016 Revise 18.8, 18.8.1-4 for requirements of Author: J.Hayes, A.Christiawan,
suppliers. Add new section 18.8.5 Product M.Nikolaev; TechCom, John
obsolescence. Update Responsibilites Schneider
sections and add OPC based on OI
Transformation
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2.7 20-Oct-2015 MSDS changed to SDS. Table 18–1, samples Author: Joe Hayes; TechCom,
to client or lab are governed by the restrictions John Schneider
of the most stringent component, CC1 or CC2.
Removed duplicate sentence in 18.8.3

2.6 19-Nov-2014 Add reference to Stimulation Product Shelf Author: John Schneider
Life Extension, InTouch page 6548795

2.5 16-Jul-2014 Add reference to SRPC Product Shelf Life Author: John Schneider
Extension, InTouch page 6409433

2.4 08-Aug-2013 Add new section 18.8.3 for chemical supplied Author: John Schneider
by client, update confidentiality codes in Table
8-1

2.3 11-Jun-2013 Camlok=>Camlock, COA on all local chemical Author: John Schneider
purchases

2.2 08-Jan-2013 Add PCM gel-gun eductor to the list of Author: John Schneider
approved applications of Camloc connectors

2.1 20-Mar-2012 Assigned responsibilities for PPE use and Author: John Schneider
maintenance. Added section 18.7 Chemical
Hazard Assessment and Risk Control
(C-HARC), Appendix A: Glossary of MSDS
terms

2.0 22-Jul-2011 Renamed. 18.3 Scope, 18.6 Chemical Author: John Schneider
Hazards, 18.7 Approved WS chemical
products revised, added 18.7.1 PLC and CC
codes, 18.7.2 Local chemical purchasing,
18.7.3 Chemical shelf life.

1.46 09-Dec-2010 18.10 Strapping for containers on pallets must Author: John Schneider
be plastic.

1.45 07-Sep-2010 Clarify Scope due to revisions in Standard 30. Author: John Schneider

1.44 11-Aug-2010 Changed link for WS Chemical QA in 18.7 Author: John Schneider

1.43 16-Mar-2010 Minor changes and link fixes in section 18.7, Author: John Schneider
18.9

1.41 25-Sep-2009 Corrected link for Chemical Confidentiality Author: John Schneider
document in Sec 18.7

1.4 27-Mar-2009 Corrected link for B-Procedure, 18.16 for Author: John Schneider
quick-connect use exceptions

1.32 18-Mar-2008 replaced same text of 18.16 Author: John Schneider

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WS QHSE Standard 18 / Document Control

Version Date Description Prepared by

1.21 02-Sep-2008 replaced text of 18.15, deleted driver Author: John Schneider
requirements from 18.19, delete revision
history topic ref

1.2 22-Aug-2007 replaced text of 18.15, deleted driver Author: John Schneider
requirements from 18.19, delete revision
history topic ref

1.1 31-Jan-2007 Safety in title becomes QHSE, minor edits, Author: John Schneider
added 18.19 Acid handling systems

1.0 10-Feb-2005 Converted this standard from Word to XML. Author: Stephen Fishman
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WS QHSE Standard 18 / Foreword

Foreword IPC,Well Services,WS,

New releases of this document supersede any other version. The most current
version of the document is in InTouchSupport.

If you have a printed copy, compare the "Release Date" to the content in InTouch
to be sure you have the most current version.
WS InTouch Manager\\InTouch ID# 3313694\4.5\Release Date:09-Mar-2020\EDMS UID: 0000079558\Produced: 09-Mar-2020 17:12:58

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18-i WS QHSE Standard 18 / Chemical Product Management 18-i

18 Chemical Product Management


18.1 Statement of standard _________________________________________ 18-1
18.2 Objective ______________________________________________________ 18-1
18.3 Scope _________________________________________________________ 18-1
18.4 Exemptions ___________________________________________________ 18-2
18.5 Responsibilities _______________________________________________ 18-2
18.5.1 Line management ___________________________________________ 18-2
18.5.2 Operational Planning Center & Resource Management Center _ 18-3
18.5.3 Sales and technical _________________________________________ 18-3
18.5.4 Job supervisor ______________________________________________ 18-3
18.5.5 All involved employees including those mentioned above ______ 18-4
18.6 Chemical hazards and exposure information __________________ 18-4
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18.7 Chemical Hazard Analysis and Risk Control __________________ 18-6


18.8 Approved Well Services and OneStim chemical products _____ 18-7
18.8.1 Product Confidentiality Codes and Purchasing Level Codes ___ 18-8
18.8.2 Local chemical purchasing _________________________________ 18-10
18.8.3 Chemicals provided by a client or third party _________________ 18-12
18.8.3.1 Exempted common chemicals ___________________________ 18-12
18.8.4 Chemical shelf life _________________________________________ 18-13
18.8.5 Product obsolescence ______________________________________ 18-14
18.9 Product repackaging _________________________________________ 18-14
18.10 Labels ________________________________________________________ 18-14
18.10.1 Chemical identity __________________________________________ 18-15
18.10.2 Hazard warning labels ______________________________________ 18-16
18.11 Safety data sheet (SDS) ______________________________________ 18-16
18.12 Minimum chemical storage requirements _____________________ 18-17
18.12.1 Acid storage _______________________________________________ 18-19
18.13 Fuels _________________________________________________________ 18-19
18.14 Tote tanks ____________________________________________________ 18-20
18.15 Other deliveries ______________________________________________ 18-20
18.16 Shipment of materials ________________________________________ 18-21
18.17 Material safe handling procedures ___________________________ 18-22
18.18 Dry material bulk systems ____________________________________ 18-23
18.19 Liquid bulk systems __________________________________________ 18-24

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18-1 WS QHSE Standard 18 / Chemical Product Management 18-1

18 Chemical Product Management IPC,Well Serv ic es,Safety,QHSE,


communication,
standard,18,eighteen,hazcom,hazardous,
chemical hazard,

18.1 Statement of standard


This standard defines specific rules and procedures that must be followed at all
locations involving Well Services and OneStim operations.
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18.2 Objective
This standard is meant to prevent injuries, service quality and HSE incidents,
environmental incidents, and equipment losses when handling hazardous
materials.

18.3 Scope
This standard identifies the procedures for chemical product management,
chemical hazard communication (HAZCOM), material handling, including
purchase and inventory, and the use or sale of approved Well Services chemical
products at all Well Services and OneStim locations.

The words “material”, ”product”, “chemical”, and “materials handling” refer to


chemicals, fuels, and crude oil used for mixture preparation, including N2/CO2,
cement, other dry bulk materials, and corrosive chemicals, such as acid. These
materials can be supplied by either Schlumberger, clients, or third-party vendors.

This standard also includes requirements for handling and transporting


combustible and flammable fluids in the base or at the wellsite. This standard
includes mixing of combustible and flammable fluids in the yard or in the base,
but not at the wellsite. Refer to Well Services and OneStim QHSE Standard 30:
Pumping Combustible and Flammable Fluids, InTouch ID# 3313709, for mixing
and pumping combustible and flammable fluids at the wellsite.

This standard does not define complete HAZCOM training because of the wide
variety of special requirements in different countries and government agencies.
In some locations, Well Services and OneStim must develop additional training
programs to comply with local regulations.

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18-2 WS QHSE Standard 18 / Chemical Product Management 18-2

Compliance with this standard is the minimum requirement from Schlumberger.


Other rules and regulations from the client or from government agencies must
also be followed so long as they meet, or exceed, Schlumberger minimum
requirements.

18.4 Exemptions
Any deviation from this and any other relevant Schlumberger QHSE Standard
or Well Services/OneStim Standard is by exemption only, as outlined in the
Management of Change and Exemption (Standard 010), InTouch documentation
ID# 3260269, and the Well Services and OneStim Appendix to Schlumberger
Standard S010, InTouch documentation ID# 3999148. Exemptions will be
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approved only if the following conditions are met:

• A complete hazard assessment and risk control is performed, per Hazard


Analysis and Risk Control (Standard 020), InTouch documentation ID#
3757610.
• Appropriate risk mitigation measures are discussed and put in place.
• Proper levels of management notification(s) and approval(s) are completed.

18.5 Responsibilities

18.5.1 Line management


Line management shall

• ensure full compliance with this standard and other relevant Schlumberger
and Well Services or OneStim standards and Do It Right Standard Work
• ensure that development plans are in place for personnel competencies
required to meet Geomarket operational needs
• validate the assignment of personnel, equipment, and materials to ensure
adequate levels to meet job requirement
• ensure personnel have the proper PPE as determined by 18.7: Chemical
Hazard Analysis and Risk Control of this standard that the PPE is supplied in
good condition and that personnel have been properly trained as to how and
when the wearing of the PPE is required
• consult with technical personnel to complete the Chemical Hazard Analysis
and Risk Control (C-HARC)

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18-3 WS QHSE Standard 18 / Chemical Product Management 18-3

• verify that the job requirements do not exceed pressure ratings or


compromise safety.

18.5.2 Operational Planning Center & Resource


Management Center
Operational Planning & Resource Management Center (OPRM) shall
• assign equipment, materials, and competent personnel to ensure adequate
resources to meet the job requirements.
• ensure that assigned personnel are current on all applicable certifications
relevant to the employee's job assignment.
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• Ensure that only Schlumberger approved suppliers are used to supply


chemical, transportation, and other associated equipment, supplies and
services
• Ensure materials are received with a Certificate of Analysis (CoA) and that
the CoA matches the product label, lot number(s) and product purchase
specifications.
• Ensure materials are received with a current SDS and correct shipping
paperwork
• Ensure that material dispatched to location has a loading ticket which
matches with the product label, lot number(s) and quantity.
• Ensure the SDS of material dispatched to location matches with the hazard
placard(s).
• Ensure that materials dispatched to location are not obsolete and are within
shelf life guidelines as defined in this standard

18.5.3 Sales and technical


Sales and technical personnel shall

• ensure that the job requirements do not exceed product or equipment


specifications or compromise safety
• ensure that the proper product is used for the application
• identify incompatibilities between products planned to be used in the job.

18.5.4 Job supervisor


The job supervisor shall

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18-4 WS QHSE Standard 18 / Chemical Product Management 18-4

• verify the factors that contribute to the level of risk in the C-HARC, using
the approach in this standard
• notify line management of changes in the C-HARC and ensure approval by
line management to proceed with the job
• verify that all Schlumberger employees and contractors at the work site are in
compliance with this, and other, safety procedures and standards
• verify, at the wellsite, that all required PPE is in good condition. Instruct
personnel as to when and where the PPE is required. Verify that proper PPE
is worn by personnel at all times as required
• take appropriate action, up to and including stopping the job, if unacceptable
risks exist
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• confirm that the job requirements does not exceed pressure ratings or
compromise safety.

18.5.5 All involved employees including those mentioned


above
All involved employees shall

• perform the job while being alert to changes that increase risk
• understand and comply in full with this and other relevant Well Services,
OneStim, and Schlumberger standards and Do It Right Standard Work
• recognize the SQ and HSE risks associated with the operation and reduce
these risks to as low as reasonably possible
• maintain and use the necessary PPE whenever and wherever required.

18.6 Chemical hazards and exposure information


A chemical is considered to be hazardous if it is a physical, chemical, health, or
environmental hazard.

Physical and chemical hazards include:

• Explosive materials
• Cryogenic liquids (as described in Well Services and OneStim QHSE
Standard 9: Pumping Carbon Dioxide, InTouch ID# 3313683 and Well
Services and OneStim QHSE Standard 11: Pumping Nitrogen, InTouch ID#
3313684)

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18-5 WS QHSE Standard 18 / Chemical Product Management 18-5

• Flammable liquids (as described in Well Services and OneStim QHSE


Standard 30: Pumping Combustible and Flammable Fluids, InTouch
ID#3313709)
• Flammable solids
• Oxidizers (as described in Well Services and OneStim QHSE Standard 17:
Storage and Handling of Oxidizers, InTouch ID# 3313693)
• Pyrophoric or spontaneously ignitable in air
• Water-reactive chemicals
• Corrosive materials such as acid
• Dust explosion
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Hazardous chemicals that pose health threats include:

• Known or suspected carcinogens


• Toxic materials
• Reproductive toxins
• Eye or skin irritants
• Corrosive materials
• Sensitizers
• Chemicals that can damage the liver, kidneys, lungs, nose, skin, eyes, the
blood system, or the other targeted organs.

Health conditions can be either acute or chronic.

• Acute conditions develop quickly and are caused by a single exposure to a


hazardous chemical. Symptoms can occur immediately but, in some cases,
may not be apparent for several days. Examples of acute conditions are eye
irritations caused by exposure to acids, or dizziness caused by exposure
to solvent fumes.
• Chronic conditions develop without warning signs that anything is wrong
until the medical condition has become a significant health threat. Chronic
conditions are caused by continuous or repeated low-level exposure to
hazardous chemicals over an extended period of time. Common medical
problems can include damage to body organs and, possibly, cancer.

Chemicals can enter the body in several ways:

• Eyes

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18-6 WS QHSE Standard 18 / Chemical Product Management 18-6

Eyes can be damaged by most chemicals. Chemicals can enter your eyes
from splashed liquid, dust, or fumes, or by wiping your face. As a minimum,
the eye protection specified in the Safety Data Sheet (SDS) must be worn
when handling any chemical.
• Through the mouth
When handling chemicals, always wash your hands before smoking or
eating. Do not eat or drink anything in the vicinity of chemicals.
• Inhalation
This is a very dangerous form of exposure. Vapors or dust can easily enter
the lungs.
• Through the skin
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Chemicals can enter body tissue by means of absorption.

18.7 Chemical Hazard Analysis and Risk Control


Because of the potential exposure of personnel to hazardous substances, all
chemical handling shall have a specific Chemical Hazard Analysis and Risk
Control (C-HARC) detailing the risks and control measures for each exposure
situation. The C-HARC may be incorporated into the job HARC but must be
identifiable as specific steps in the process. Personal Protective Equipment
(PPE) must be determined based on the following criteria, and the actual
requirement list must be included on the job HARC.

• For activity such as loading and unloading sealed drums, totes, etc. where
there is no requirement to open the chemical container, normal PPE as
required by the location is mandatory, and use of additional PPE is not
required unless identified during the assessment. An example is for moving
drums from truck to warehouse, etc.
• For any activity which requires a container to be opened, a connection made,
contents transferred from one container to another, or transferring a fluid from
one tank into another tank containing the exact same fluid, use of PPE as
required by the SDS is mandatory. This includes all items as detailed in the
SDS. Examples of these activities include opening a drum to take a sample
or hooking a hose onto a tote tank.
• For any activity which requires one substance to be added to another
substance, including to water, perform a C-HARC of the resulting chemical
formulation. This formulation shall determine the final PPE requirement
for that operation. The SDS covering the raw materials does not take into

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18-7 WS QHSE Standard 18 / Chemical Product Management 18-7

account any mixing, therefore additional hazards can arise for which the
PPE for the raw materials is not sufficient or appropriate. The assessment
must include the following information:
– The hazardous properties of the substances being mixed
– The chemical reaction as each substance is added to the mixture
– The hazardous nature at each addition, such as vapors, temperature,
dust, etc.
– How the substance may be hazardous to the workers
– What the expected exposure level might be and how this relates to the
relevant exposure limits
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– What PPE is required during the mixing and pumping sequence for all
employees.

• Where PPE is determined as necessary then the times for wearing it shall be
listed. For example, if and when PPE is required for the mixing of substances
then it shall also be required for those working with the fluids during transfer
and pumping operations, and for personnel in the vicinity where a spill or
leak could reasonably be expected
• All assessments must document the minimum PPE requirements for cleanup
in the event of a spill.

18.8 Approved Well Services and OneStim


chemical products
Well Services and OneStim may only purchase, inventory, use, or sell approved
Well Services and OneStim coded products.

The following requirements apply to all Well Services and OneStim chemical
products:

• Chemical products are assigned Well Services chemical product codes,


and are considered “Approved Well Services Chemical Products” after
successful completion of stages and gates found within the Concurrent
Lifecycle Management (CLM) or Well Services B-coding procedure, InTouch
ID# 4130254, or Third Party Chemical Products Coding Procedure, InTouch
ID# 4570229.
• No employee shall name/code a non-approved product in such a manner that
it creates the appearance of a chemical product approved as a coded Well
Services chemical product.

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18-8 WS QHSE Standard 18 / Chemical Product Management 18-8

• The use, or assumption of responsibility by Well Services or OneStim, of any


non-Well Services-coded products or chemicals pursuant to a client request
may occur only under an exemption as described in the Chemicals provided
by a client or third party section of this Standard.
• Well Services chemical product codes shall be assigned only by the Quality
Assurance function.
• All employees shall protect confidential chemical information by adhering
to the guidelines in Table 18-1: Confidentiality Code Handling for Field
Operations and Table 18-2: Purchasing Level Code for Field Operations.

18.8.1 Product Confidentiality Codes and Purchasing


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Level Codes
Schlumberger assigns Confidentiality Codes (CC) and Purchasing Level Codes
(PLC) to all chemical products based on the level of restriction required to
maintain and protect Schlumberger technology.

CC codes are determined by the level of Confidential Business Information


associated with the product. The codes restrict the type of information which can
be shared both within and outside of Schlumberger. These restrictions, which
may be placed on the product for legal or business reasons, include the release
of chemical composition, supplier information, and test items. The CC level
determines how the product is handled in regards to sales, labeling and samples.

PLC codes are determined by the degree of restriction required for purchasing
chemicals. They indicate the level of control for the sourcing of the product.

CC and PLC levels can be found in the Chemicals Quality Management System
(C-QMS), https://cqms.slb.com. All employees shall protect confidential chemical
information by adhering to the guidelines in Table 18-1 and Table 18-2. Below is
the summary of CC and PLC handling chart for Field Operation.

Table 18-1: Confidentiality Code Handling for Field Operations

CC1 CC2 CC3


1
Direct sales to client Not Allowed Allowed, must follow the requirements Allowed
when sending product to client

Direct sales or loan to Not Allowed Not Allowed Allowed


competitor

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18-9 WS QHSE Standard 18 / Chemical Product Management 18-9

CC1 CC2 CC3

Sample to client or Restricted Restricted Not restricted


2
third-party lab
Location must document on QUEST Location must document on QUEST
management of change and meet management of change and obtain all the
the following requirements prior to following prior to proceeding:
proceeding:
• Procedures and scope of testing
• Procedures and scope of testing must be pre-defined and agreed to
must be pre-defined and agreed to with the client.
with the client.
• Whenever possible, Schlumberger
• Whenever possible, Schlumberger must replicate the tests.
must replicate the tests.
• Approval obtained from:
• Approval obtained from: For WS: GM PSD Manager (GM
For WS: GM PSD Manager (GM PSD Manager consults with product
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PSD Manager consults with product steward, IP, GCRC, supply chain)
steward, IP, GCRC, supply chain) For OneStim: Product Line PSD
For OneStim: Product Line PSD Manager
Manager
• Approval obtained from line
• Approval obtained from line management based on risk level.
management based on risk level.
• Effective agreement1 is in place.
• Effective agreement1 is in place.
• Sample has Schlumberger label &
• Sample has Schlumberger label & SDS only, no supplier marking or
SDS only, no supplier marking or SDS.
SDS.
• Chemical lot number is specified.
• Chemical lot number is specified.
• Blend composition is specified, if
• Blend composition is specified, if applicable.
applicable.

• Confirmation that the sample will be


accompanied by Well Services or
OneStim personnel at all times.

• Confirmation that the sample will


not be left with the client upon
completion of testing.

Sample to competitor Not Allowed Not Allowed Allowed

Sample to Schlumberger Sample has Schlumberger label and SDS Sample has Schlumberger label and SDS Follow Well Services
location only, no supplier marking or SDS, and only, no supplier marking or SDS, and and OneStim QHSE
follow 18.10 Well Services and OneStim follow Well Services and OneStim QHSE Standard 18 labeling
QHSE Standard 18 labeling requirements Standard 18 labeling requirements 18.10 requirements18.10
1
Required to have signed Non-Analysis Agreement and Secrecy Agreement
2
If any mixture, either blend or set cement samples, containing one or more chemicals classified as CC1 or CC2 is sent to a client or third party
lab, then the most stringent restrictions for the chemical composition in the sample (CC1 or CC2) shall apply for the whole mixture or blend. Set
cement samples containing CC1 or CC2 additives that react during the setting process are exempt.

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18-10 WS QHSE Standard 18 / Chemical Product Management 18-10

Table 18-2: Purchasing Level Code for Field Operations

PLC1 PLC2 PLC3


Description Highly restricted, Restricted, must be Non Restricted. The
must be purchased purchased centrally sourcing strategy lies
centrally or or approved by Global with the Global Category
approved by Global Chemical Category. PLC2 Team.
Chemical Category. may be purchased locally,
The sourcing see below. The sourcing
strategy lies with strategy lies with the Global
the Global Category Category Team.
Team.
Purchase Restricted. Must Restricted. Must obtain Allowed and must meet
Locally obtain expert approval from Global requirements in section
approval from Chemical Category and met 18.8.2: Local chemical
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Chemical Sustaining all requirements in section purchasing.1


Manager, and final 18.8.2: Local chemical
approval from purchasing.1
Global Chemical
Category and meet
all requirements in
the Local chemical
purchasing section1
1
Location must document that all locally purchased material meets the technical requirements of the product
specifications as detailed in the C-QMS. The documentation can be either a CoA from the supplier, or where
not available a documented lab test confirming results.

Note
CC1 products are always PLC1.
CC2 product may have PLC1 or PLC2 classification.
CC3 product may have PLC1, PLC2 or PLC3 classification.

18.8.2 Local chemical purchasing


Only approved chemical codes will be added to SWPS and created in
SAP/Lawson for inventory. Non-approved codes must have a valid exemption in
place (see Section 18.8) and will be expensed. The requirements for purchasing
chemicals are:

• All chemical products being purchased locally must meet the Schlumberger
Product Purchase Specifications on C-QMS, https://cqms.slb.com.
• It is the responsibility of the person in charge of local purchasing to provide a
copy of the Schlumberger Product Purchase Specifications to the supplier.

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• The supplier must sign and return a copy of this Product Purchase
Specification and a certificate of analysis (CoA) for the product validating
that the product meets the specification. This constitutes an agreement that
the supplier will only supply product that meets the Schlumberger Product
Purchase Specifications.

Note
The Schlumberger Product Purchase Specifications shall be signed by the
supplier before the first order is placed.

• The signed Schlumberger Product Purchase Specifications shall be made


available with the chemical purchase order and supplied to Schlumberger via
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defined by Quality Assurance Team method of delivery (for example, upload


to the online database, email, etc).
• Schlumberger shall request a Certificate of Analysis (CoA) with every
purchase for every batch/lot of each product. Where the supplier is unable to
supply a CoA, the product must be tested and results recorded in QUEST.
The test must include a product performance test and additional tests as
defined in the Product Purchase Specifications for the product. The CoA
or test results shall show that the product meets Schlumberger Product
Purchase Specifications.
• All cement batches accepted by the location for use must have a documented
CoA which complies with the testing requirements of API10A. Where this is
not available from the supplier a Well Services or OneStim laboratory must
complete the testing and document the results prior to use.
• Any proposal to use a new supplier for an existing product, or to source a
new product from an existing supplier shall be initiated via an InTouch request
from the Geomarket Purchasing and Sourcing Organization, and shall be
approved by the following managers, depending on the Confidentiality and
Purchasing Level Codes of the chemical.
Table 18-3: Local Purchasing Level codes and Approvals Required

Confidentiality/Purchasing Approvals Required for Approvals Required for


Level Codes Well Services OneStim
GM Product Line Manager Product Line PSD Manager
CC1/PLC1 Category Manager for Category Manager for
Chemicals Chemicals
GM Product Line Manager Product Line PSD Manager
CC2/PLC2 Category Manager for Category Manager for
Chemicals Chemicals
OU PSD Manager
OU PSD Manager
CC3/PLC3 Geomarket Sourcing
OU Sourcing Manager
Manager

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• All current approved chemical suppliers do not need to go through


requalification unless it is requested by any of the functions (WS Marketing
and Technology, IP, GRC-C, and Global Chemical Category).

18.8.3 Chemicals provided by a client or third party


The use of non-Well Services coded products or chemicals in Well Services
fluids or system pursuant to a client request may be performed only under an
exemption, unless specified under the Exempted common chemicals section
of this Standard.

The exemption requires prior expert approval from the Client Support Lab
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manager, the Sub-Product Line Domain Manager and from the relevant WS
Marketing and Technology (IP, GRC-C, and Global Chemical Category).
Following these expert approvals, Product Line and Group management must
approve the exemption based on the risk level according to the Well Services
and OneStim Appendix to SLB QHSE S010: Exemptions, InTouch ID# 3999148.

If it is expected that the products or chemicals may be used beyond the


requested duration of the exemption, the location must also submit a B-Code or
TP-code request to the Client Support Lab for review and prioritization with the
HQ Portfolio/technical function.

18.8.3.1 Exempted common chemicals


The following chemicals, when provided by the client or mud company and used
in a spacer, cement slurry, or lost-circulation treatment fluid, do not require an
exemption if the CoA meets the Well Services specifications and the fluid passes
the required Well Services lab tests for the application.

• Barite (D031)
• Bentonite (D020)
• Calcium carbonates (D151)
• Sodium Chloride (D044)
• Potassium Chloride (M117)
• Calcium Chloride (S001/S002)
• bactericide
• diesel (often pumped as base fluid for wash, for gunk plug)
• dye
• hematite.

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For stimulation services, the following chemicals, when provided by the client or
a third-party, do not require an exemption if the CoA meets the Well Services
specifications and the fluid passes the required Well Services lab tests for the
application.
• Sodium Chloride (D044)
• Potassium Chloride (M117)
• Calcium Chloride (S001/S002)
• Diesel (U051)
• Raw Hydrochloric Acid
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18.8.4 Chemical shelf life


A product shelf life is the reasonable time the product would be expected to
perform as intended and is determined by several factors which include the
actual application of use, storage conditions and temperature cycles. Shelf life
is based on the product’s chemistry and how that chemistry is expected to
respond to a variation of conditions such as would be expected in Well Services
and OneStim operations. The shelf life of products is listed on the C-QMS,
https://cqms.slb.com.. Chemicals should be used within their specified shelf life.

The Chemicals Procurement and Sourcing Function shall ensure that products
sold to Schlumberger or its agents are at 75% or more of remaining shelf life as
per the Product Purchased Specification in place at the moment of sale.

In certain circumstances a product may meet the product specification and


perform as intended even after the documented shelf life has been exceeded.
Use of a product that has exceeded its shelf life may be considered in certain
conditions but only when the following process has been applied and completed.

The request to use any product which has exceeded its documented shelf life
must be validated via the respective sub-product line InTouch technical helpdesk.
This expert advice must be requested by submitting an InTouch ticket as per
Well Services and OneStim QHSE Standard 18 Guideline 01 Product Shelf
Life Extension, InTouch ID# 3313694.

InTouch shall not initiate any action until the information required on the guideline
is supplied by the location.

If an exemption is required, line management approval shall then be documented


as per Well Services and OneStim Appendix to SLB Standard 10: Management
of Change (MOC) and Exemptions, InTouch ID# 3999148. No product may be
used until the defined level of line management approval is received in QUEST.

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18.8.5 Product obsolescence


Chemical products can be obsoleted upon decision by the sub-Product Line
Domain Head because of technology, supplier withdrawal, cost of ownership,
market, and regulatory compliance. The obsoleted product list is announced
annually via InTouch. When this obsolescence announcement is released, the
remaining inventory of obsolete product shall not be used and shall be properly
disposed of. An exemption to allow the use of this obsolete product must be
approved by the sub-Product Line Domain Head.
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18.9 Product repackaging


If product is repackaged due to a container having been opened (e.g. a damaged
container or due to a partial container being returned from the wellsite), there is
risk that the product may have become contaminated. Additional QC tests of
the repackaged product shall be conducted prior to dispatch of the products to
the next job.

If product is repackaged, in addition to proper label replacement as defined in


the “Labels” section of this Standard, the following information shall be included
on the container:
• original lot number
• repackaging date
• repackaging location
• the name of the person who repackaged the product

18.10 Labels
All materials that can cause a physical, health, or environmental hazard, as
described in section 18.6: Chemical hazards and exposure information, must
comply with this Well Services and OneStim standard for labels. Products that
must have labels include:

• chemicals supplied by Well Services or OneStim


• chemicals placed in new or replacement containers
• chemicals in the work area including samples and laboratory reagents
• raw materials
• common chemicals, such as solvents, fuels, and coolants

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• consumer retail products in their original container with the original consumer
label are excluded.

The Well Services and OneStim minimum requirements for labels stipulates that
each materials package or container must be clearly marked with:

• The product name as it appears on the SDS. For Schlumberger coded


products, this must include the product code.
• Hazard warnings.
• The name and address of the manufacturer, or the name and address of the
company packaging or distributing the product. Products with SLB labels
must include SLB contact information and products with supplier labels must
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include supplier or distributor contact information.


• Product samples in laboratories must have labels that, at a minimum, show
the chemical name and/or code and appropriate hazard warnings.

Missing or worn labels must be replaced immediately with a new label that meets
Well Services and OneStim requirements. Labels on purchased products must
never be removed or defaced.

Labels can be downloaded from the Global Regulatory Compliance – Chemical


(GRC-C) web site at https://slb-chemicals.slb.com web site.

Well Services and OneStim require its suppliers to apply a


Schlumberger-approved label that meets the BS5609 Marine Immersion Label
Testing Standard and Globally Harmonized System (GHS) requirements. Refer to
Schlumberger Chemical Products Packaging Guidelines, InTouch ID# 6664001.

Labeling Exemption

The only exemption to the minimum label requirements applies to small


containers used for transferring chemicals between two or more containers that
are properly labeled. The chemicals transferred in this manner must be intended
for immediate use by the Well Services or OneStim employee who performs the
transfer. An example of this is transferring paint thinner from a large container to
a smaller one to make it easier to clean paint brushes.

18.10.1 Chemical identity


The product identity of any chemical material must be prominently labeled on
every container in which it is stored. For Schlumberger coded products, the
identity must display the alphanumeric Well Services code and the Schlumberger
product name of the chemical; these must be identical to the identity of the
material in its SDS.

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Example: Inhibitor Aid A153

Additional information is included for Well Services or OneStim products or


materials if it is needed by local government agencies.

18.10.2 Hazard warning labels


All containers must have a warning label that defines the hazards of the product.
The label design, however, is not standardized and may have a different
appearance in many parts the world. This hazard warning label shall match with
the information contained in the SDS for the product.
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GHS hazard warning labels for Well Services chemicals can be obtained from the
Global Regulatory Compliance (GRC-C) website (https://slb-chemicals.slb.com/).
If a specific label is not available at this website, submit an InTouch ticket to the
GRC-C helpdesk, by selecting the "OFS-Shared Services" Product Line, and the
"GRC-C Documentation" desk.

Any additional local regulatory requirements must be followed

18.11 Safety data sheet (SDS)


This standard refers to these sheets as “SDS.” In the USA, they were previously
referred to as MSDS, but now are called SDS at all locations worldwide.

An SDS for any material is the reference document for all information about its
hazards, safety, and handling. All personnel handling hazardous materials must
know where to find the SDS and how to use these sheets. More information
about SDSs can be found in the Glossary of Common SDS Terms, InTouch
ID# 3313694.

An SDS must be available for each hazardous material in the work place. This
requirement includes all hazardous items, whether these are Well Services
chemicals, purchased products, or purchased maintenance materials. Consumer
products in their original container with their original label are not included.

The identity of the material on the container label must match the SDS so the
correct SDS can be found using the material name or code. For local products,
the vendor's SDS must be kept in an SDS file or book arranged by product name
or code. The location Geomarket OPRM Manager is responsible for making sure
that all third-party materials or products have a current SDS on file.

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A current SDS must be available to any person in the workplace who handles
materials or who has exposure to these materials. All SDSs must be stored in
the work areas so they are easy to find.

The only source for the current SDS for Well Services chemicals is the Global
Regulatory Compliance (GRC-C) website (https://slb-chemicals.slb.com/). If a
specific SDS is not available at this website, submit an InTouch ticket to the
GRC-C helpdesk, by selecting the “OFS-Shared Services” Product Line, and the
“GRC-C Documentation” desk. An SDS must always be supplied as a matter of
course for materials purchased from Well Services

When products are purchased from a third-party and then pumped for a client,
the third-party SDS must be available on request.
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A glossary of standard SDS terms is included in Glossary of Common SDS


Terms, InTouch ID# 3313694.

18.12 Minimum chemical storage requirements


At any Schlumberger district or base, all chemicals, except bulk dry chemicals,
shall be stored on concrete pads constructed in a way that provides secondary
containment. This includes all bulk liquid products, such as acids, solvents,
and hydrocarbons.

All secondary containment must have a minimum capacity of 110% of the volume
of the largest container in the storage area.

Bulk tanks containing flammable fluids must be separated from other bulk tanks
by a wall or must be in a separate storage area.

Protect all chemicals in drums, totes, or sacks with a roof or cover.

Fuel storage areas must have a roof for protection from the rain. For details on
fuel storage, refer to Well Services and OneStim QHSE Standard 4: Equipment,
InTouch ID# 3313678.

Note
Underground storage tanks are not permitted.

All bulk cement plants must have a dust collector that functions correctly.

All bulk storage vessels must have signs that display the following information:

• The contents of the container

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• The correct hazard warning labels for the country in which the material is used
• Relevant hazard warning signs, such as FLAMMABLE or NO SMOKING
• A label on each hatch with the alert “CONFINED SPACE PERMIT
REQUIRED.” For details about this issue, refer to Well Services and OneStim
QHSE Standard 12: Permit to Work, InTouch ID# 3313688.

Chemical warehouses must be clean at all times. All spills must be cleaned up
immediately, and disposed of in accordance with local regulations.

Store chemicals in the appropriate containers, as defined by the requirements of


the SDS. Chemicals must be stored separately, by type.
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Well Services product signs must be displayed in front of each product so they
can be seen at the same time as the chemical. The sign must show the Well
Services product code, for example A261, and the symbols for the required PPE.
For more information on the chemicals and the required PPE, refer to HAZ-Tag,
WS and OneStim QHSE Standard 18, InTouch ID# 6155952.

Dry materials in sacks on pallets must not be stacked more than three pallets
high.

Chemicals in steel drums can be stacked on pallets up to four pallets high ONLY
if each pallet is full and ONLY if the drums are banded together.

Chemicals in plastic drums may be stacked on pallets up to two pallets high


ONLY if each pallet is full and ONLY if the drums are banded together. The
maximum height of stacked chemicals in plastic drums varies based on the
strength of the plastic container. Many plastic containers cannot be stacked more
than two pallets high without collapsing the plastic containers on the bottom layer.

Containers of chemicals must be fastened to the pallets beneath them. Where


pallet strapping is used for this purpose, use plastic or webbing-type straps and
not metal ones, which can cause injury when removed.

Each location must have an up-to-date Spill Preparedness and Response


Procedure (SPRP), and this plan must be updated in accordance with
Schlumberger QHSE Standard S008: Environment, InTouch ID# 3605373.

Each location must have an emergency spill kit to manage a chemical spill. The
size of the kit and the amount of equipment is determined by the quantity of
products stored, but each spill kit must contain this equipment:

• Shovels to remove contaminated dirt or chemical absorbent materials


• Bags of absorbent material to soak up chemical or oil spills
• Booms to contain spills to an isolated area

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• Chemical spill drums to contain dirt or absorbent materials


• Soda ash to control HCl spills
If HF acid is used at the location, use calcium carbonate
• New drums to contain leaking drums of chemicals.

18.12.1 Acid storage


Acid storage is defined as any situation where any acid of any concentration
above 7,000 galUS [26.5 m3] is stored in a container for 24 hours or more, being
left attended or unattended.
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Equipment used for acid storage shall be inspected per the requirements of Well
Services and OneStim QHSE Standard 04 Guideline 02: Acid Tank Inspection
and Test, InTouch ID# 3313678.

Equipment used for acid storage shall be installed in a secondary containment


with an acid-resistant lining. This secondary containment shall have a volume
equivalent to 110% of the volume of the largest container in the storage.

Equipment used for acid storage shall be placed on a stable surface that can
support its weight when full.

18.13 Fuels
Do not use gasoline or kerosene as a cleaning fluid.

Do not store gasoline at Well Services or OneStim locations unless the location
is remote from commercial filling stations. To store gasoline, the location must
meet these requirements:

• The HQ WS OPRM Manager or OneStim OPRM Manager, Geomarket


Facility Manager and Geomarket HSE Manager must approve the installation
of a gasoline storage unit.
• The storage and refueling system must meet the specifications for the type
of gasoline.
• The installation must be inspected and approved by local government
agencies.
• If there are no local regulations for storing gasoline, the Geomarket Facility
Manager must arrange for an engineer to certify the design criteria of the
installation.

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Do not store or transport gasoline in drums. Gasoline must be transported


in containers specifically designed to hold gasoline. Gasoline containers
must not be transported in the passenger area of any vehicle, or near radio
communications equipment. Gasoline containers must be securely fastened in
any transport vehicle, and the containers must have danger signs displayed
in accordance with local regulations.

When transporting diesel or kerosene, transport and hazard signs must be


displayed according to local regulations. The minimum requirement is that the
vehicle is clearly marked as a transport of flammable materials.

Fuels for Well Services vessels shall comply with the requirements of Vessels,
Procedure, Fuel Management, InTouch ID# 5271863. If international, regional,
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or local regulations exceed the requirements of this document, they shall be


followed.

18.14 Tote tanks


Tote tanks containing hazardous materials must be stored in a containment area.

Make sure the vent is open before draining or removing materials from a tote
tank. If the vent is not open, a vacuum can be created that will collapse the tank.

Do not use a forklift truck on the side of the tank with the valve assembly.

Each tote tank is designated for a specific type of product. Do not use the tote
tank to carry any other type of product.

18.15 Other deliveries


All bulk materials delivered to Well Services or OneStim bulk facilities must be
controlled by a Well Services or OneStim employee authorized to operate the
facility.

Third-party companies delivering hazardous materials on transport units


equipped with compressors must use their own air supply equipment to unload
products.

All personnel must wear applicable PPE for any product when loading or
unloading at a Well Services or OneStim facility.

Loading and unloading areas must be clearly marked.

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Companies delivering products not made by Well Services or OneStim must also
deliver an SDS for each product. This requirement does not apply to the delivery
of a product already in use at the work site, when a current SDS is available.

18.16 Shipment of materials


When transporting materials within a country, prepare, document, and ship these
materials in compliance with local regulations. Follow international regulations
when materials are expected to cross national borders. The manager at the
originating location is responsible for compliance with these requirements.

Prior to product transfers between two Well Services or OneStim locations, both
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the sending and receiving location shall verify the remaining shelf life of the
products. If the product shelf life is not compliant with the Chemical Shelf Life
section of this Standard, an exemption shall be created by the sending location
and shall be approved by both the sending and receiving location.

Only use drivers deemed competent for driving vehicles transporting hazardous
materials. Training shall include, but is not limited to, local regulatory Hazardous
Materials training, OFS Hazardous Materials Level 2 (or GeoMarket equivalent),
Well Services and OneStim QHSE Standard 18, and Schlumberger driving
certifications for the specific type of vehicle. Only use personnel having been
trained on the local regulatory Hazardous Materials training, OFS Hazardous
Materials Level 2 (or GeoMarket equivalent), and Well Services and OneStim
QHSE Standard 18, to prepare shipping documentation.

Never transport materials that are packaged in leaking or damaged containers.


Make sure the correct method of packaging and transportation is used for the
prevailing weather conditions and anticipated handling methods.

Fasten drums or other containers on pallets to each other with straps, and then
to the pallet. Tightly fasten sacks to the pallet.

Never transport hazardous materials in the driver or passenger area of any Well
Services or OneStim vehicle.

Report any material or chemical spill immediately using the Well Services or
OneStim Emergency Response plan for the relevant Geomarket. All reports
must comply with local reporting regulations.

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18.17 Material safe handling procedures


Wear the minimum eye protection specified in the SDS when handling chemicals
or when chemicals are in use nearby.

Note
If the job you are performing puts you in contact or potential contact with
chemicals, or the vapor, dust, or mist from chemicals, you MUST wear the PPE
indicated on the label/SDS.
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Before handling a chemical, read the label completely and take the necessary
precautions to protect yourself from injury or illness. For answers to most
questions, refer to the SDS or see your supervisor.

Always use or wear all required PPE when opening any chemical container.
Slowly loosen the plug or container cap to release pressure, and keep your face
as far away as possible from the cap or plug.

Ensure the product in the container is in a homogeneous state and that a


representative sample is taken. Ensure the sample container is correctly labeled
with at least the sampling date, location and lot number.

Do not use clamp-on, quarter turn, or similar connections, e.g. Camlock


connections, on any hoses or connections, except as described in the Dry bulk
equipment section of Well Services QHSE Standard 4: Equipment, InTouch
Documentation ID# 3313678.

Never put your head inside a storage tank unless you are wearing an SCBA or
other breathing apparatus. If it is necessary to look inside a tank, do not keep
your face over the opening longer than necessary.

For tank entry, follow the procedures in Well Services QHSE Standard 12:
Permit to Work, InTouch ID# 3313688.

Never use a fire or an open flame to heat chemicals, and make sure there is
adequate ventilation. Use only electrical strip heaters, forced air heaters, or
steam heaters. Loosen plugs and container caps to prevent a pressure increase
inside the container.

Never allow acids to come in contact with galvanized (zinc coated) materials.
Galvanized drum plugs and pipes are not permitted when working with acids
because an explosion can occur when acid and zinc come in contact.

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When using corrosive chemicals or flammable liquids on the job, follow the
minimum safe procedures, which includes flushing all lines with water before
disconnecting the equipment at the end of the job.

Procedures must be defined on any job where two reactive mixtures follow each
other in the delivery or pumping system. This situation can occur through dry
additive feeder kits or in the connection between the precision continuous mixer
(PCM) and the blender. Job procedures must define the process of flushing
through the system to separate these reactive mixtures.

Use portable chemical transfer pumps to move chemicals from containers to


displacement tanks or other tanks. The wetted components of transfer pumps
used to handle chemicals shall be compatible with the types of fluids being
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handled.

Chemical transfer hoses must meet the requirements stated in the Chemical
transfer hoses section of Well Services QHSE Standard 4: Equipment, InTouch
ID# 3313678.

Never use open containers to transfer chemicals if there is an available air


supply, and make sure the pump and its parts are made from materials designed
to handle the chemical being transferred.

If your work clothes become wet with chemicals, remove the clothes immediately
and, if the chemicals have touched the skin, rinse the affected area with water.
Work clothes stained with chemicals must be properly washed before they can
be worn again, but DO NOT wash contaminated work clothes at your home.

The pant cuffs of work clothes must always be worn outside and over the work
boots or chemical boots to prevent chemicals from entering the boots and
causing a chemical burn to feet.

A chemical container can be reused, but only to store the same type of product
that was originally in the container.

All containers must be discarded according to local regulations.

Only use safety knives or knives with locked and protected blades to open sacks.

18.18 Dry material bulk systems


Use only approved dry bulk equipment as defined in Well Services and OneStim
QHSE Standard 4: Equipment, InTouch ID# 3313678.

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Always wear chemical goggles when handling chemicals, when using the batch
blender, when coupling or uncoupling hoses, or when opening tanks or other
containers. Never use low pressure suction hoses as bulk discharge lines.

Protection from silica dust shall follow the requirements of the “Respiratory
protection” section of Well Services and OneStim Standard 13: PPE, InTouch
ID# 6291367.

Never look in the end of a line or hose on any bulk system without ensuring that
there is no pressure in the line. When connecting a bulk system on a job site,
keep the delivery lines or hoses as short as possible to decrease the amount of
dust generated, and prevent the formation of blockages.
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Mark all tanks with their contents and mark all lines to show their function, such
as vent, fill, etc.

Never allow anyone on or directly under bulk tanks when the tanks are under
pressure.

Never permit any vessel, tank, pipe, connection, union, or hatch to be connected,
disconnected, tightened, or worked on while the equipment is under pressure.

When operating a bulk system, monitor the pressure gauge on each tank, but do
not rely solely on the air-compressor unloader system to maintain the correct
pressure.

No welding, smoking, or other ignition sources shall be permitted within 30 ft (10


m) of areas where dust generation from combustible dry materials is occurring.

18.19 Liquid bulk systems


Use only approved liquid bulk equipment as defined in Well Services and
OneStim QHSE Standard 4: Equipment, InTouch ID# 3313678.

Wear the correct type of PPE when handling any hazardous material, and always
wear chemical goggles in any area where chemicals are handled.

When unloading pressurized tank cars or acid storage tanks, do not exceed the
rated working pressure of the tank, and use a regulator and relief valve. Drums
or other non-pressurized chemical containers must NEVER be unloaded using
air pressure.

All tanks must be marked with their contents, and lines must be marked to show
their function, such as vent, fill, etc.

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18-25 WS QHSE Standard 18 / Chemical Product Management 18-25

All electrical equipment in any mixing room near a tank or system containing
flammable liquids must comply with local electrical codes. All electrical
equipment must be explosion-proof and must not be an ignition source.

Flammable and combustible materials, additives, other chemicals, and products


shall be handled per the requirements of the “Transferring flammable fluids from
one container to another” section of Well Services and OneStim QHSE Standard
30: Pumping Combustible and Flammable Fluids, InTouch ID# 3313709.

When working with concentrated liquid calcium chloride or other liquid


concentrate salts, follow these precautions:

• Wear rubber boots and gloves


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• Spills must be cleaned immediately and disposed of properly to avoid having


to designate the area as hazardous
• Mixing rooms must have adequate ventilation to prevent the collection of
fumes

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Copyright © 2020 Schlumberger, Unpublished Work. All rights reserved.

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