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Technical Presentation Report On FFDC
Technical Presentation Report On FFDC
Technology
Department of Chemical Engineering
Saransh Mathur(2001330519006)
Index
Acknowledgment
Abstract
List of tables
Chapter 1: Introduction
Chapter 2: Literature Review
Chapter 3: Flavours
3.1: Flavorants
3.3: Aroma
Chapter 4 : Fragrance
Through this project we came to know about so many things related to the topic
and got my concepts more clear.
We would also like to extend our gratitude to the Head of the department of
Chemical Engineering “DR.Ankita Sharma” for providing us with all the
required facilities.
Last but not the least we would like to thanks my parents who guided , helped
and encouraged us in completely this project.
Saransh Mathur
Abstract
Flavour is an important attribute of food and beverage quality control;
thus it has always been the focus of much research. It is formed by the
combination of taste (attributed to non-volatile compounds), aroma
(related to volatile compounds), and chemesthetic sensations. The
characteristic flavour of food is due to its volatile compounds, thus
many studies have focused on the analysis of these compounds. All
advances in flavour chemistry are due to the development of new
technologies that facilitate and allow the analysis of volatile and non-
volatile compounds in foods or the pattern recognition, as observed in
the E-nose and E-tongue equipment. However, further studies are
required to understand the food flavour, supported by the constant
development of new technologies.
The design of fragrances for laundry products which deliver a
prolonged odour intensity at key consumer touch points is an ongoing
challenge in the fragrance industry. Current fragrance development
practices are based on the combination of perfumery expertise (e.g.
creation of classic and modern odour themes such as Chypre or
Fougère) with technical know-how (e.g. chemical–physical properties
of fragrance ingredients). However, due to the complexity of such
multi-component mixtures this process still requires a significant
number of trial and error cycles throughout the fragrance development
process to achieve the desired odour intensity and character
requirements. To improve the efficiency of the fragrance development
process, we have combined simple, high throughput analytical
methods with psychophysical models, to predict the intensity and
character of fragrances at three key consumer touch points for laundry
products. The predicted results have shown a good agreement with
experimental ones, making this approach useful in the early research
phase for defining the structure/backbone of highly performing
fragrance themes.
Chapter 1:Introduction
ChemSearch Journal 9(2), Alhassan, M., Lawal, A., Nasiru, In most parts of Nigeria, plant
December, 2018 Publication of Y., Suleiman, M., Safiya, A.M. materials whose edible use is
Chemical Society of Nigeria, and Bello, N. Department of not established are regarded
Kano Chapter Chemistry, Sokoto State as waste materials. Available
University, P.M.B. 2134-Birnin materials like lemon grass
Kebbi Road, Sokoto-Nigeria leaves that contain essential
oils can be utilized in the
production of perfumes that
can mask body odours. Lemon
grass extracts obtained using
soxhlet extraction and solvent
extraction were utilized in the
formulation of perfume using
methanol and ethanol as
solvent media. An oil yield of
4.5% and 3.8% were obtained
for solvent extraction and
soxhlet extraction methods
respectively. Physicochemical
properties of the two
formulations revealed that the
essential oil has saponification
value of 21.04mgKOH/g and
the densities of the two
formulations in methanol and
ethanol were 0.768gcm-3 and
0.82gcm-3 at 60o c while the
boiling point for both
formulations was 85o .
International Journal of Miss Diwan Tapoja The work done will focus on
Engineering Research & the study and optimization of
PG Student,
Technology (IJERT) Vol. 3 Issue extraction of ingredient oil
11, November-2014 from lemongrass. This study
investigates the influence of
Desai S. A. operating parameters like
Associate Professor time, size, type of grass on the
extraction of oil. Lemon grass
Chemical Engineering is an important herbal and
Department Chemical aromatic plant and its oil is
Engineering , TKIET, one of the major essential oils
Warananagar, India used in the perfumery and
cosmetic industry. It is widely
used in the scented soaps,
sprays, deodorants, polishes
and medicines. The extracted
oil is rich in Citral A & P. Citral
is the starting material for the
manufacture of vitamin A. In
the present experiment citral
is isolated by Hydro-distillation
of lemon grass, which is used
to make lemongrass tea. The
distillate contains 90 % citral
and 10 % neral, the isomer
about the 2,3-bond. The result
indicates that the wet grass
gives the maximum extract.
The Yield can be raised from
8% to 12% by using Hydro-
distillation and pre heated
water as solvent.
Smell
Smell flavorants, or simply, flavorants, are engineered and composed in similar
ways as with industrial fragrances and fine perfumes. To produce natural
flavors, the flavorant must first be extracted from the source substance. The
methods of extraction can involve solvent extraction, distillation, or using force
to squeeze it out. The extracts are then usually further purified and subsequently
added to food products to flavor them. To begin producing artificial flavors,
flavor manufacturers must either find out the individual naturally occurring
aroma chemicals and mix them appropriately to produce a desired flavor or
create a novel non-toxic artificial compound that gives a specific flavor.
Most artificial flavors are specific and often complex mixtures of singular
naturally occurring flavor compounds combined together to either imitate or
enhance a natural flavor. These mixtures are formulated by flavorist to give a
food product a unique flavor and to maintain flavor consistency between
different product batches or after recipe changes. The list of known flavoring
agents includes thousands of molecular compounds, and the flavor chemist
(flavorist) can often mix these together to produce many of the common flavors.
The compounds used to produce artificial flavors are almost identical to those
that occur naturally, and a natural origin for a substance does not necessarily
imply that it is safe to consume. In fact, artificial flavors are considered
somewhat safer to consume than natural flavors due to the standards of purity
and mixture consistency that are enforced either by the company or by law.
Natural flavors in contrast may contain toxins from their sources while artificial
flavors are typically more pure and are required to undergo more testing before
being sold for consumption.Flavors from food products are usually result of a
combination of natural flavors, which set up the basic smell profile of a food
product while artificial flavors modify the smell to accent it.
Basic tastes
The five basic tastes (sweet, bitter, sour, salty, and umami) are basic elements of
the experience of human flavor and important for the assessment of the
nutritional quality of food by humans and other organisms. The sour and salty
taste, for example, indicate potentially spoiled food, while both the sweet and
umami tastes are indicative of nutritious foods, and the bitter taste serves as a
warning against poison intake. The taste is perceived by receptor cells organized
in groups.
Aroma
The aroma is another component of flavor, and responsible for the so-called
characteristic flavor of food. During chewing, volatile compounds are released
from food and transported from the oral cavity to the pharynx during
swallowing. With the subsequent exhalation, the volatile compounds are swept
by the air that comes from the lungs reaching the olfactory epithelium and
exhaled through the nose. In this process, the sensory perception occurs by the
olfactory epithelium via the retro nasal
Flavour Technology
In addition to seeking new flavor sources, companies are also turning towards
technology. Advances in analytical technology, information management,
molecular biology, chemosensory science and extraction techniques are leading
to new flavors and improved, fresher profiles.
Molecular biology and research in olfaction and taste will advance flavor
science as well. "We have work on taste and smell receptors coming out of
universities like Columbia, Rockefeller University and University of California-
San Diego. Their work has moved us to understand how taste receptors and
molecules interact. An understanding of what happens between molecules in a
flavor composition and what happens between that flavor and the entire system
will hopefully lead to a whole new generation of higher performing flavors and
ingredients," observes Eilerman.
Flavouring Tips
With all of these improvements and advancements, it is still important to keep
fundamental flavoring principles in mind. "It's all about flavor management,"
observes Wampler. "Product development processors should focus on flavor
management, preserving the flavor in their system. This could mean preserving
the natural flavor that is part of the food or optimizing their production by
adding flavors late in the process."
Acids provide tartness in products such as beverages. The choice of acid can
effect flavor perception. Citric and/or malic acid are commonly used with
strawberry flavor; tartaric acid is used with grape flavor. Each acid has its own
impact on the overall flavor of the system. The choice of the correct acid or
blend of acids and the level at which they are used is important to optimize the
flavor impact.
Chapter4:Fragrance
They are part of the products in our everyday life unless we actively avoid
fragranced products.
Alcohols
Aldehydes
Ketones
Esters
Lactones
Scents containing products that are not applied directly to the body, such as
laundry detergents, fabric softeners, room fresheners, and more, are regulated
by the Consumer Product Safety Commission (CPSC).
The CPSC is responsible for creating voluntary standards, issuing and enforcing
mandatory standards, and recalling and potentially banning products that can
cause us harm.
Like the FDA and cosmetic ingredients, products are not required to have
premarket approval before being sold to the public. However, manufacturers are
legally responsible for ensuring product safety, so the CPSC can issue recalls or
ban products containing ingredients known to cause harm.
Are they safe?
Manufacturers cannot sell products that cause harm making fragrances safe for
most individuals.
However, some fragrances might contain ingredients that could cause allergic
reactions including asthma, allergies, migraines, and contact dermatitis in
sensitive populations.
If you have sensitive skin or have other health sensitivities, it's important to
work with your physician to learn your triggers and avoid fragranced products
when needed.
There are reports raising concerns about some fragrance ingredients, especially
phthalate ingredients. Research does not show that exposure to a limited amount
of phthalate ingredients, including fragrance ingredients, will cause harm.
As we have discussed in previous blogs, a hazard is not a risk if people are not
exposed to a hazard at harmful levels. As with most ingredients, the dose makes
the poison. If you’re ingesting, using, or coming into contact with a harmful
phthalate, in large enough qualities an adverse health effect could result.
However, known harmful phthalates are not permitted for use and are not found
in new products or fragrance products.
As with all science, our understanding evolves as scientists and manufacturers
conduct more research. We will continue to monitor academic discourse around
this area and update our content if a significant change occurs.
Classification of Scents
Scents are classified as notes based on their olfactory character. A perfume is
a unique mixture of top, middle, and base notes designed to give a particular
harmony of scents. The following basic groups are listed in order of
decreasing vapour pressure, or volatility.
a) The top notes are those that are detected and fade first
providing freshness to the blend. They are responsible for the
customer's first impression, and hence, in a way, the selling note
of a perfume. They are light scents, lasting 5-10 minutes, and
extracted from plant material such as cardamom seed, basil ,bergamot,
citronella, coriander, eucalyptus, ginger, grapefruit,lemongrass, lemon,
orange, lime, marigold, peppermint, sage,spearmint, tangerine and tea tree.
The more commonly used are those extracted from citrus sources or grasses.
b) The middle notes are those that last for several hours and are the most
prominent within the fragrance. They are usually combinations of spicy, floral
or fruit scents, extracted from ambrete seed, black pepper, carrot seed, cassia,
chamomile,cinnamon, clove, fir, cypress, juniper, marjoram, pine,
rose,rosemary, thyme and yarrow.
c) The base notes give a perfume the depth and last the longest.
They include the extract of plant material such as amyris, anise,
angelica root, clary sage, fennel, geranium, lavender, lavandin,
balsam, cedarwood, frankincense, jasmine, myrrh, patchouli,
rosewood, sandalwood, vetiver and ylang ylang. Musks extracted
from musk deer, musk rats and civet are scents derived from
animal sources.
Essence Oils
Essential oils not extracted via steam or pressure are referred to
as essence oils. Essence oils are derived in a variety of ways from
flowers, barks, leaves, roots or resins.
Concretes: The aromatic plant matter is extracted by organic
solvents such as hydrocarbons. Concretes are more stable and
concentrated than unmodified essential oils.
Resinoids: Oils from natural resins such as frankincense, myrrh,
amber, benzoin, etc. are extracted using hydrocarbon solvents.
Occasionally the ethanol soluble fraction of a resinoid is called
an absolute.
Absolutes: They are obtained by taking the concretes through a
second process of ethanol extraction or liquid carbon dioxide.
With the latter process, the oils produced are of excellent aroma
quality and entirely free of unwanted solvent residues or non-
volatile matter.
The products obtained from all the above methods go through a
final process of solvent removal. These techniques are used
worldwide for higher yield or to obtain products that cannot be
obtained by any other process. They also produce a more true to
natural fragnance. An example of this is the case with jasmine.
Chapter 5:Future Aspects
Changes
1)Growth of natural ingredients based products: The global F&F
market is largely based upon synthetic market with synthetic ingredients
accounting close to 60-65% of the total market. The changing trend in the
global market can be observed from the fact that the market for natural
ingredients is growing at a CAGR of close to 6-7% as compared to synthetic
ingredient market i.e. growing at a slower rate of <1%7. The shift towards
natural ingredients can be attributed to increasing consumer awareness
towards healthy foods and government regulations prohibiting use of certain
synthetic flavors in food production. The global F&F houses have also been
taking steps to strengthen their natural products portfolio.
2)Scaling of Operations: Increasing presence of global F&F power
houses in the country requires the small Indian firms to scale their operations
to match the bargaining power of the bigger players. Medium size firms are
moving towards scaling of operations that would help improve raw material
sourcing efficiency and pricing, as well as improve cost structures by means of
manufacturing efficiencies.
3)Enhanced R&D Spending: The ability to create unique and creative
fragrances, often involve significant research and perfumery skills which is
one of the main differentiating factor between the Indian players and the top
F&F houses. Even though small Indian players have made limited investment
in such skills, it has been observed that medium size to large Indian players are
working towards development of proprietary blends, often using proprietary
constituent ingredients. Some of the activities being taken up by other global
players are
a.Improving fragrance delivery systems using techniques like encapsulation,
sustained release
b.Developing captive aroma chemical ingredients through R&D(e.g.
developed by Givaudan)
c.Long term purchase arrangements with global FMCG player
Chapter 7:Conclusions
We can say that the flavour and fragrances holds a part in our
lives which we may underlook but cannot ignore.
Their development has brought various products which not only
used for self purposes but in medical field as herbal medicines
as well.
Their uses varies and sometimes certain herbs are hard to
develop and which is where we may see more development in
the industries of flavours and fragrances field.
Great advances have been made toward understanding the flavor
chemistry using new technologies and sophisticated equipment.
Today, it is possible to determine not only the compounds
responsible for the flavor profile of food but also those that
effectively contribute to the aroma and those released from food
and beverages in real time, that is, during consumption. In
addition, instruments such as the electronic nose and electronic
tongue have been developed and/or improved to replace the
human.
Essential oils have seen a revival in popularity in the last few
years. They are widely used in the cosmetic industries as a
fragrance and active components.
Moreover, their ability to impart a wide range of unique and
pleasant aromas in cosmetic products and at the same time
acting as bioactive agents (anti-aging, antimicrobial, sun
protection, and whitening) make them prized and highly valued
ingredients in cosmetics and cosmeceutical products.
References
J. Zhang et al.
Volatile flavour components and the mechanisms underlying their production in
golden pompano (Trichinous blochii) fillets subjected to different drying methods:
a comparative study using an electronic nose, an electronic tongue and SDE-GC-
MS
Food Res
(2019)
D. Zhu et al.
Collaborative analysis on difference of apple fruits flavour using electronic nose
and electronic tongue
Sci Hortic
(2020)
J Food Eng
(2019)
G. Arvisenet et al.
Effect of sugar and acid composition, aroma release, and assessment conditions on
aroma enhancement by taste in model wines