CV κ

10.28. a)
CP
dS = dT + V α dP
T
∂S
=
, Buktikan bahwa ∂ P V Tα
( )
C ∂T
( )
∂S
= P
∂P V T ∂P T( )
+ Vα

( )( )( )
∂T
∂P V
∂P
∂V T
∂V
∂T P
= -1

( ∂T∂ P ) =-1∂ P ∂ V
V
( ∂V ) ( ∂T )
T P

−(
∂P )
∂V

( ∂ P ) ∂V
∂T
=
T

V
(∂T ) P

( ∂V∂ P ) = - κ V, ( ∂V∂T ) =α V
T P

−(∂
∂ P )
V

( ∂T
) =
T
∂ P V
(∂
∂ T )
V
P

2
TV α
C P - CV =
κ
CP
( ∂S
∂P ) V
=
T (∂
∂P)
T
T
+ V α
terbukti

CP
b)
CP
dS = dT + V α dP
T
∂S
, buktikan bahwa ∂V
( ) P
=
TV α

C ∂T
( )∂S
= P ( )
∂V P T ∂ V P

( ∂∂VT ) P
=
1
αV
C 1
( )∂S
= P
∂V P T αV terbukti
 ( )
1 ∂V κ CP
− = γ=
c) V ∂ P S γ dimana CV

CP
dS = dT + V α dP
T
Pada S tetap

CP
0= dT − V α dP
T Jika persamaan dibagi dv pada S tetap maka

CP ∂ T
0= ( ) - V α ( ∂V∂ P )
T ∂V S S

C ∂T
Vα (
∂V ) T ( ∂V )
∂P P
=
S S

C ∂T
V ( )
∂P
= P
∂V S Tα ∂V ( ) S

( ∂∂VT ) ( ∂∂VS ) ( ∂T∂ S ) =− 1

S T V

( ∂V ) ∂V ∂ S
∂T
=
−1
S
( ∂S ) (∂T )
T V

−(
∂V )
∂S

( ∂V ) ∂ S
∂T
= T

S
( ∂T )V
( ∂V∂ S ) =( ∂∂ PT ) = ακ
T V

C
( ∂T ) T
∂S
V
= V

α
−
( ∂∂VT ) = C
S
κ
V
= −
T α
CV κ
T
C Tα C
−V ( )
∂P
= P = P =
γ
∂V S Tα C V κ CV κ κ atau

− ( )
1 ∂V
V ∂P S
=
κ
γ