12 13 7 9

8
TIC SIM
209
Standar 11

d 10

5 15 18
3 4 6 9 14
2 7 16 19
22
1 21 24
23
8

8
11 15 7 9
TIC SIM
209
HI-6F-9 sample 19

7 16
5 9 12
4 6 18 23
12 13 14
3 17 20 22
10 21 24

Fig. 1. TIC GC-EI-MS chromatograms from an EPA standard and HI-6F-6 sample (28/2/06 in SOS1000).
Fluoranthene (7) and pyrene (9) are shown in SIM mode (ion 209). Labeled peaks are identified in
Table 1.
 900

HI-3F-1 HI-3F-9 HI-6F-9

600
ng/g-dw

300

IndPyr
Pyr

Chrys+Try

B(e)Pyr

Per
Flu

An

B(a)Pyr

B(ghi)Per
Ace

Phe

Fla

B(b+j)Fla

B(k)Fla

DB(ah)An
Acy

B(a)A
Ret

Fig. 2. PAHs concentration distributions at HI-3F-1 (31/10/05 in CCC1500), HI-3F-9 (28/2/06 in

CCC1500) and HI-6F-9 (28/2/06 in SOS1000). Abbreviations are specified in Table 2.

Table 1
Identified PAHs in sediment filters. Identification numbers, retention times (tR) and ions used in Fig. 1.

Id.number Compound tR compound Ions

1 acenaphtylene 14.70 152, 150
2 acenaphtene 15.36 154, 152
3 fluorene 17.25 166, 165
4 phenanthrene 20.94 178, 152
5 anthracene-d10a 21.04 188, 180
6 anthracene 21.12 178, 152
7 fluoranthene 25.67 202, 200
8 pyrene-d10 b
26.47 212, 106
9 pyrene 26.54 202, 200
10 Retene 27.93 219, 234
11 benzo[a]anthracene-d12a 31.26 240, 120
12 benzo[a]anthracene 31.34 228, 226
13 chrysene+triphenylene 31.50 228, 226
14 benzo[b]fluoranthene-d12a 35.34 264, 132
15 benzo[b o j ]fluoranthene 35.42 252, 126
16 benzo[k]fluoranthene 35.51 252, 126
17 benzo[e]pyrene 36.41 252, 126
18 benzo[a]pyrene 36.59 252, 126
19 perylene-d12b 36.81 264, 132
20 perylene 36.93 252, 126
21 indene[1,2,3-cd]pyrene 41.41 276, 138
22 dibenzo[a,h]anthracene 41.52 278, 139
23 benzo[ghi]perylene-d12a 42.54 288, 142
24 benzo[ghi]perylene 42.68 276, 138
a
surrogate standards
b
internal standards

(A)
 (B)

50
H1-2F-1 H1-6F-1 H1-6F-4

40
Fig. 3. GC-FID chromatogram with identified lipids in HI-6F-4 sample (15/12/05 in SOS1000).
Abbreviations are specified in Table 2.
30
ug/g-dw

20

10

0
C18OH

C20OH

C26OH

C30OH
C23

C25
C22OH
C27
C24OH
C29

D5,22
C31
D5
D0
C28OH
C33
24EtD5
24EtD0

Dino
C32OH
C37:3
C37:2

C38:2Me
C38:3Me
Phytol

C38:2Et
C38:3Et
Fig. 4. Lipid distributions at HI-2F-1 (31/10/05 in CCC1000), HI-6F-1 (31/10/05 in SOS1000) and HI-
6F-4 (15/12/05 in SOS1000). Abbreviations are specified in Table 2.
80000

70000
PCB-30

60000

50000

40000

30000
PCB-52
20000
PCB-28
b-HCH

d-HCH
Pe-CB

g-HCH
HCB

10000

18 20 22 24 26 28
PCB-142

PCB-209

70000
4,4’-DDT

60000
4,4’-DDD

50000

40000
2,4’-DDT
PCB-101

2,4’-DDD

30000
PCB-180

20000
(A)
PCB-138
2,4’-DDE

PCB-118

PCB-153

10000

32 34 36 38 40 42 44 46 48
 Response

(B)
Response

Fig. 5. GC-µECD chromatogram with identified organochlorine compounds in HI-6F-6 sample (15/01/06
in SOS1000). Abbreviations are specified in Table 2.
100
H1-8F-1 H1-6F-1 H1-6F-6
ng/g-dw

10

1
4,4'-DDT
2,4'-DDT
2,4'-DDD

4,4'-DDD
2,4'-DDE
a-HCH

b-HCH

g-HCH

d-HCH

PCB 28

PCB 52

PCB 101

PCB 153

PCB 138
PCB 118

PCB 180
PeCB

4,4´-DDE
HCB
Fig. 6. Organochlorine concentrations at HI-8F-1 (31/10/05 in CCC1900), HI-6F-1 (31/10/05 in
SOS1000) and HI-6F-6 (14/01/06 in SOS1000). Ordinate axis is represented in logarithmic scale.
Abbreviations are specified in Table 2.

PCBs DDTs PeCB and HCB HCHs

1000

800

600
FLUX

400

200

0
30-Oct-05

14-Nov-05

29-Nov-05

14-Dec-05

29-Dec-05

13-Jan-06

28-Jan-06

12-Feb-06

27-Feb-06

14-Mar-06

29-Mar-06

13-Apr-06

days

Fig. 7. Time series distributions of PCBs, DDTs, PeCB and HCB, and HCHs fluxes (ng/m 2·day) in
CCC1000 station.

Table 2
PAHs, lipids and organochlorine compounds identified in sediment filters with its average, range, LOD
and LOQ (ng/g-dw). Lipids are in µg/g-dw; nd, not detected; nq, not quantified.
Abbreviations Compound Average Range LOD LOQ
PAHs
Acy acenaphtylene 8.4 nd-206.8 0.6 1.1
Ace acenaphtene 20.6 nd-142.9 5.7 9.5
Flu fluorene 9.4 nd-131.9 1.3 2.2
Phe phenanthrene 102.6 20.6-572.5 3.1 5.2
An anthracene 23.1 7.1-139.4 2.2 3.7
Fla fluoranthene 106.3 54.9-521.7 0.4 0.7
Pyr pyrene 76.6 32.0-872.5 0.6 0.9
Ret retene 310.5 27.7-1264.4 1.7 2.8
B(a)A benzo[a]anthracene 57.8 23.4-256.9 0.7 1.2
Chrys+Try chrysene+triphenylene 86.5 33.8-266.9 0.8 1.3
B(b+j)Fla benzo[b+j ]fluoranthene 48.2 26.9-114.9 0.3 0.5
B(k)Fla benzo[k]fluoranthene 36.1 19.4-106.9 0.3 0.4
B(e)Pyr benzo[e]pyrene 33.0 18.1-87.7 0.1 0.2
B(a)Pyr benzo[a]pyrene 23.2 11.1-95.6 0.1 0.1
Per perylene 20.2 6.6-39.8 0.1 0.2
IndPyr indene[1,2,3-cd]pyrene 63.0 nd-125.4 0.1 0.2
B(ghi)Per benzo[ghi]perylene 64.6 23.9-158.0 0.6 0.9
DB(ah)An dibenzo[a,h]anthracene 13.3 nd-27.1 0.2 0.4
Lipids
C23 tricosane 0.51 0.10 - 3.22 0.02 0.04
C25 pentacosane 0.54 nq - 4.05 0.08 0.14
C27 heptacosane 1.37 0.38 - 10.46 0.04 0.06
C29 nonacosane 1.64 0.32 - 27.18 0.06 0.10
C31 hentriacontane 2.05 0.44 - 34.02 0.09 0.16
C33 tritriacontane 1.91 0.29 - 18.79 0.04 0.07
C18OH octadecan-1-ol 13.52 2.67 - 160.07 0.11 0.18
C20OH eicosan-1-ol 3.99 0.98 - 37.77 0.10 0.16
C22OH docosan-1-ol 2.90 1.02 - 16.87 0.02 0.03
C24OH tetracosan-1-ol 2.25 0.96 - 10.01 0.02 0.04
C26OH hexacosan-1-ol 1.78 0.76 - 7.39 0.04 0.06
C28OH octacosan-1-ol 1.91 0.51 - 43.49 0.04 0.06
C30OH triacontan-1-ol 2.18 0.29 - 96.10 0.01 0.02
C32OH dotriacontan-1-ol 1.17 0.1 - 59.67 0.06 0.10
Phy (E,7R,11R)-3,7,11,15-tetramethylhexadec-2-en-1-ol (Phytol) 22.44 4.03 - 85.76 0.12 0.21
Δ5,22 cholesta-5,22-dien-3β-ol (22-deshydrocholesterol) 10.36 1.75 - 65.22 0.09 0.15
Δ5 cholest-5-en-3β-ol (cholesterol) 68.33 6.23 - 1172.16 0.10 0.17
Δ0 5α-cholestan-3β-ol (cholestanol) 4.38 0.70 - 50.65 0.02 0.03
24EtΔ5 24-Ethylcholest-5-en-3β-ol (β-sitosterol) 11.76 2.42 - 83.39 0.10 0.17
24EtΔ0 24-Ethylcholestan-3β-ol (β-sitostanol) 5.18 1.04 - 43.01 0.04 0.07
Dino 4α,23,24-trimethyl-5α-cholest-22E-en-3β-ol (Dinosterol) 1.82 0.43 - 6.99 0.04 0.07
C37:3 heptatriaconta-8E,15E,22E-trien-2-one 1.36 0.04 - 9.28 0.01 0.02
C37:2 heptatriaconta-15E,22E-dien-2-one 1.19 0.07 - 6.51 0.01 0.01
C38:3Et octatriaconta-9E,16E,23E-trien-3-one 0.62 0.05 - 3.88 0.02 0.03
C38:3Me octatriaconta-9E,16E,23E-trien-2-one 0.80 0.10 - 3.63 0.06 0.09
C38:2Et octatriaconta-16E,23E-dien-3-one 1.05 0.10 - 6.55 0.01 0.01
C38:2Me octatriaconta-16E,23E-dien-2-one 0.52 nd - 2.61 0.01 0.01
Organochlorine compounds
PeCB pentachlorobenzene 2.1 nd - 7.5 0.3 0.5
a-HCH α-hexachlorocyclohexane 0.3 nd - 1.8 0.2 0.3
HCB hexachlorobenzene 4.3 nd - 14.8 0.5 0.8
b-HCH β-hexachlorocyclohexane 0.2 nd - 3.7 0.3 0.5
g-HCH γ-hexachlorocyclohexane 3.3 nd - 11.4 0.3 0.5
d-HCH δ-hexachlorocyclohexane 0.4 nd - 14.7 0.5 0.9
PCB 28 2,4,4'-trichlorobiphenyl 2.1 nd - 8.4 0.6 1.0
PCB 52 2,2',5,5'-tetrachlorobiphenyl 3.0 nd - 22.0 0.7 1.1
2,4'-DDE 1,1-dichloro-2-(2-chlorophenyl)-2-(4-chlorophenyl)ethylene 0.3 nd - 3.2 0.2 0.4
PCB 101 2,2',4,5,5'-pentachlorobiphenyl 7.9 1.5 - 49.3 0.5 0.9
4,4´-DDE 1,1-dichloro-2,2-bis(4-chlorophenyl)ethylene 1.6 0.8 - 4.1 0.2 0.4
2,4'-DDD 1,1-dichloro-2(2-chlorophenyl)-2(4-chlorophenyl)-ethane 0.9 0.2 - 10.6 0.1 0.1
PCB 118 2,3',4,4',5-pentachlorobiphenyl 5.4 nq - 30.2 0.8 1.3
4,4'-DDD 1,1- dichloro-2,2-bis(4-chloropheny)ethane 6.6 nq - 38.9 1.0 1.7
2,4'-DDT 1,1,1-trichloro-2-(2-chlorophenyl)-2-(4-chlorophenyl)ethane 0.5 nd - 7.8 0.4 0.7
PCB 153 2,2',4,4',5,5'-hexachlorobiphenyl 4.6 1.5 - 19.2 0.5 0.8
4,4'-DDT 1,1,1-trichloro-2,2-bis(4-chlorophenyl)ethane 4.6 1.5 - 84.9 0.9 1.4
PCB 138 2,2',3,4,4',5'-hexachlorobiphenyl 6.4 1.7 - 33.4 0.8 1.4
PCB 180 2,2',3,4,4',5,5'-heptachlorobiphenyl 2.0 nd - 9.8 0.7 1.2