Aits 2223 PT I Jeea TD Paper 2 Sol

FIITJEE
ALL INDIA TEST SERIES

JEE (Advanced)-2023
PART TEST – I
PAPER –2
TEST DATE: 20-11-2022
ANSWERS, HINTS & SOLUTIONS

Physics PART – I
Section – A
1. D
Sol.  = I (about ICOR)
2
 4  1  m 2   N1 ICOR
mg      m   
 5  2  12  2   
COM
6g N2

5

 3g  
 acm   
2 5
mg  N2   maCM  cos  mg acm
3mg  4 
mg  N2   
5 5
13mg
 N2 
25
2. A
Sol.   t    cons tant 
F cos 
N = F sin t F
v
mdv
  Fcos t  N  mg  
dt
N F sin 
0 T
 mdv   F  cos t   sin t   mg dt
0 0 mg
F T

 sin t   cos t 0  mgT
 f = N
 Also T 
2
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AITS-PT-I (Paper-2)-PCM(Sol.)-JEE(Advanced)/2023 2
   
 F  sin   cos     mgT
 2 2 

F 1     mg
2
mg
 F .
2(1   )
3. B
Sol. F.B.D. of rod F1 N1

0  0 (about pivot)
mg f1
 N1  …(i) F2 O
2
mg
F.B.D. of cylinder  N1
 O
C  0  f1
 f1R  f2R y f2
C
f1  f2 …(ii)  mg
(say f) 

Also 0  0 x
N2
N1  mg   N2  N2  N1  mg 
3mg
N2  …(iii)
2
 x 0 (on the cylinder)
F 
f 1  cos    N2 sin 
3mgsin 
 f
2 1  cos  
Also f1 max  f2max  N1  N2 
3mgsin  mg
 f  N1  
2 1  cos   2
3 sin 

1  cos 
4. A
Sol. F.B.D. of block is as shown (  90°) N
N = F sin  + mg cos  Fcos
f = F cos  – mg sin 
for No sliding f  N
1 mgsin +f
Fcos   mgsin   F sin   mgcos  
3
sin  mg  cos  
cos    sin    Fsin + mgcos
3 F  3 
sin 
cos    0 ( no sliding even when F  )
3
tan   3    60
For  > 90°
N  F sin   mgcos 
3 AITS-PT-I (Paper-2)-PCM(Sol.)-JEE(Advanced)/2023
f  mgsin   F cos 
f  N    120
 Range    [60°, 120°]
5. A, B, D
Sol. Applying WET on bead from A to B W N + W F = K
m u
O  F R  x   R  x     v 2  u2  R+x
conservative
2 
P
4Fx Fx
v 2  u2   u0  2 N+F
x
m m
mv 2 v
Also N  F 
R R–x
m 4Fx  m
N  u2   F  u2  u20   F
R m  R 
m m 4Fx
N   2  1 u02  F   2  1 F
R  R  m

N  F  4  2  1  1
  


N  F 1  4 1  2  ˆi
  
6. A, D
Sol. As PA + PB = 10  = Constant Y
The bead will move along the elliptical path in vertical

plane.
Such that 2a = 10  and 2ae = 8  a = 5, b = 3 A B
 Equation of ellipse is x
x2 y2
 1
 5 2  3 2 P
3/2
2
r0  1   y  
  3
at  0, 3  ( y = 0, y = )
y  25
25 
 r0 
3
m 2  3
2T0 cos   mg 
r0
 2g   cos   
 5 T0  
T0
31 mg
T0  . v  2g
30
mg
7. A, C
Sol. Angular momentum of system is conserved about the axis passing through the pivots
 
Li (Just before collision) = L f (Just after collision)
 2 
mv0R =  mR2   5m  R2  
 5 
v0
 
3R
Now, applying conservation of mechanical energy after the collision
1 2  3R
 mR2   5m  R2  2  mgR  5mg
2 5  8
mR2 v2 7mgR
 3  02 
2 9R 8
21R 7g
Also v 0  2gh  h  
8 12R
8. A, D
Sol. For u to be minimum, it just grazes the cylinder at two points
as shown.
From COME
mu2 mv 2 v
  mgh
2 2 
u2  v 2  2gh  
2 2 u0
u  v  2gR 1  cos   h
v
0
2Rsin
sin 2 Rg
Also 2R sin   v 2  v2  …(2)
g cos 
From (1) and (2)
 1 
u2  Rg 2  2cos  
 cos  
d 2 1
For u  min.
d
 
u  0  cos  
2
  = 45
u02  Rg 2  2 2 
Also ucos   v cos 
tan2 0  [3  2 2]
9. A, D
Sol. Just after the jump by the frog. 5v0 (w.r.t. to A)
According to COLM of (A + frog)
(4v 0 – v) m – mv = 0 v = 2v 0 37° K
A B
V
Now consider the motion of blocks in their v0 A C.M. v0

COM frame. m m t=0
At any time t 2K 2K
2k
vBC  vB  v CM  v 0 cos  t  ,  
m
vB  v CM  v 0 cos t
vB  v0  v 0 cos t
Also the frog is in projectile motion from ground frame 3v0
 3v  2v 12v02  6v 0 
R  2 0  0  T  
 g  g g  g 
2v0
R
Also frog land on B
T
Then  0   vB dt  R
0
T
 0  R   v 0  cos t  1 dt
0
v
 0  R  v 0 T  0 sin T

12v 20 6v 20 m  2K 6v 0 
 0    v0 sin  
g g 2K  m g
 
6v02  2
 0  3    .
g  
10. B, C
dm
Sol. F  mg  v 0 also m = y
dt
dy
F  yg  v0 
dt
= yg  v 02
dE
Heat loss per unit time = Fv 0 
dt
d 1 y

 yg  v 20 v 0    y  v 20  yg 
dt  2 2
v 30
ygv 0   v03    ygv 0
2
v 30
 .
2
Section – B
11. 2
Sol. Observing the motion in COM frame. Then system will look like
v/2 v/2
 
v/2
v/2 v/2
Just before the collision Just after the collision

After the collision, ring starts sliding and then starts pure rolling on wedge as shown.
R = 2v (pure rolling)
Applying COAM of ring in centre of mass frame (after the collision) v

about point P on wedge 
2  v 2
mR    mR   mRv   mR  v
 2
P
v v
mR  3mRv   v  
2 6
v
Therefore the velocity of wedge is (in centre of mass frame) when pure rolling starts after the
6
first collision. Then they again collides and ring again starts pure rolling on wedge and velocity of
v nd
wedge is (in centre of mass frame) after 2 collision.
18
The process goes on and there will be infinite collisions and finally wedge comes at rest in centre
of mass frame.
v
 Velocity of wedge = (in ground frame)
2
12. 5  
Sol. v  u  gt
  g
   v u
also s   v ave  t   t
 2  t
  
 v  u  gt …(i)
 u
  2s v
v u  …(ii) s
t
t=0
Squaring and multiplying
     
 v.v  u.u  2u.v  v.v  u.u  2u.v   4g2s2
 
2
s 
100  2u.v 100  2u.v 
4g2
  
s is max. when u.v  0  u  v
100
 smax   5m
2 10 
13. 6
Sol. If it strike again at same point, then the horizontal component of their velocities are same after the
first collision.
v0cos v2

v0 v1
v1
 v0sin 
Just before collision Just after collision

As e = 1
vsep = vapp
v2cos = v0sin
3
 v 2  v 0 tan    40  = 30 m/s
4
2v 2
t0  = 6 sec.
g
14. 9
Sol. Tmax  T1
v
Tmin = T2
mu2
T1  mg  …(1)
l T2 + mg
2
mv l v
T2  mg  …(2)
l
From COME (of pendulum + earth system)
1 1 T
mu2  mv 2  mg(2l)
2 2 l
mg
 u2  v 2  4gl …(3)
T1
T1
also 2 …(4)
T2 u
from (1), (2) (3) and (4)
mg
u  11gl , v  7 gl
 v   9gl ,
mv 2
T  9mg K=9
l
15. 2
Sol.

V0
2R/3
P
V R/3
C.O.M.
Applying COLM
v
mv0  m  2m  v v  0
3
Applying COAM about point P
2R  MR2  v R
mv0     2m 0  mR2 
3  
 2  3
2v
 R  0
3
R
 2
v
16. 3
 3  /2
2v 0 cos   
Sol. T  2  h

 v0
gcos   
 2
t=0
2v    t=T
 0  4cos2    3 
g  2  /2
Also Rsin = V0sin2T /2 Rsin

2v 2
R sin   0  2sin  cos   2 1  cos    3  gcos(/2)
g
As v02  2gh
R
 h
8 cos   2cos   1

h  0 2cos2   cos   0
cos   2cos   1  0
1
cos  
2

 K = 3.
3
2nd Method:



 v0
[90 (/2)]
/2
 
2     90    180
 2
3
  90   90–
2

Now  > 0
 v0
 < 60° /2

max  radian
3 /2
17. 6
Sol. Applying impulse momentum theorem. N
v0/2
3
 Ndt  mv 0 2
30° 30°
 v0 
 Ndt  m  2  v  30°
30° v0
v
 v  0 1  3
2
  f = N
v03/2
Just before the impact
Also v 02  2gH and
2gH 2
 
2gh 1  3   4

1  3  l v
1 h
Also   a
2 3 30° 30°
2
 1 H 1 Just after the impact
h 1    1  
 2 4 2 a = g/2 [1 + 3 ]
H
 6
4h
18. 8
Sol. In equilibrium, the centre of mass of the system must lies on the vertical line passing through
hinge.
 XCM = 0 O
L  2R 
m1  m2  0
2    x
L2 2R
   R 
2  R
 L = 2R m2
m1  2R   m2R
YCM  L
m1  m2 m1
y
 L2  R2    4  L
      4,   2
 L  R 22
  = 8.
Chemistry PART – II
Section – A
19. A
Sol. PCl5  PCl3  g   Cl2  g
Dd
 , n=2
n  1 d
D
1      
d
D
Thus, 1   will linearly increases with increase of   .
 d
20. A
So Ho
Sol. nK  
R R
o
S  8R
21. B
2x 2x 2x  16x
Sol. Change in potential energy     2x     2x 
8 8 8
14x 7x
 
8 4
22. A
2.303 100
Sol. K 298  log
t1/2 50
2.303 100
K 308  log
t1/2 25
K 298 log 2 1
   0.5
K 308 log 4 2
23. A, B
Sol. Possible transition 3  2 and 4  2
36
 3 2 
5R
16
 4 2 
3R
24. A, B, C
Sol. Molecular mass of A 2B4  100
2A  4B
2A  4B  100,  5  given 
2A
A 10
A  10,B  20,   1: 2
B 20
A 2B4  g   A 2  g  2B2  g

1   2
At 10 min. V.D. = 25
Molecular mass = 50
100
50 
1  2
1 1
 %B2  by mole    100  50%
2 2
1
%A 2  by mole    100  25%
4
At t = 20 min.
100
40 
1  2
  0.75
d  A 2B 4  0.5  0.25 0.25
  
dt 10 10
d  A 2  0.75  0.50 0.25
  
dt 10 10
Ratio of rate = 1 : 1
25. A, C, D
Sol. 2HI  H2  I2
At equilibrium 4  2x x  3y x
2N2  6H2  4NH3
At equilibrium 4.25  2y x  3y 4y
Given x = 1.0 M
4y = 0.5 M
5
Using these value K C1 
32
45
K C2  6
5
 32 
K C2   
 125 
26. B, C, D
Sol. SO2  1 p  p 
1 p  d 
SO3  1 p  p 
2  p  d 
XeO 4  4  p  d 
ClO3  2  p  d 
27. A, B, D
Sol.
H
H
C C nodal plane
H
H
Equitorial plane
F F Axial
H F H F
C S C S
H F F
H
F F
Axial plane Equitorial Axial
More stable form due Less stable due to more
to bent rule. nodal repulsion. Its nodal
plane lies in axial. plane lies in equitorial
28. C, D
Sol.  AlCl3 n  has (3C – 4e) bond not (3C – 2e)
B2H6   Two (3C – 2e) bond
H
H H
H H B
B Al
H H
H H H
H
H H
H
B B
B Be
H
H H H H
H
6-(3C-2e) bond 4-(3C-2e) bond
Section – B
29. 5
Sol. x = 9, y = 3, z = 2
In one electron system all orbitals of a shell are degenerate (same energy level). In case of many
electron system different orbitals of a shell are non-degenarate. Hence, in second excited state
only three p-orbitals (2p) are degenerate.
H-atom
1s 2s 2p 3s 3p 3d
n=1 n=2 n=3
H-ion
1s 1s 2s 2p 1s 2s 2p
Ground state 1st excited state 2nd excited state
30. 6

Sol. (i) Borax   NaBO2  B 2 O3

(ii) Borax  NH4 Cl   BN  B2 O3  NaCl  H2 O
(iii) Borax  HCl  H3 BO3
(iv) Borax  H2 O  Na B  OH 4   H3 BO3

(v) 3B2 H6  6NH3   2B3 N3 H6  12H2
THF
(vi) B3 N3 H3 Cl3  3LiBH4   B3 N3H6  3LiCl  3BH3
(vii) LiH  B 2 H6  2LiBH4

sp3
(viii) K 3  AlF6   BF3  3KBF4  AlF3

sp3
Except (vii) and (viii) all options can give sp2 hybridised Boron centre as one of the product.
31. 6
2  
Sol. Lone pair in  TeBr6  , IF2  , SNF3 and  XeF3 are 1, 2, 0 and 3 respectively. Hence, x = 6.
Diamagnetic species are Li2 , C2 , O22 , K 2 O, N2 O 4 , B3 N3 H6 .
Note: Be2 does not exist so we can’t say it is paramagnetic or diamagnetic species.
Hence, y = 6.
xy
 6.
2
32. 4
Sol. In container (I) In container (II)
2SO2  g  O2  g  2SO3  g 
KMnO4 will oxidized only SO2
2x1 x1 0
Moles of O.A. Moles of R.A.
 2x1  2a x1  a 2a
2 5
0.2  4 Moles of SO 2 Total moles nT   3x1  a 

2 5 x1  a 1 x1
Given  a
Mole of  SO2 equilibrium  2 3x1  a 4 3
2
2SO3  g  2SO2  g   O2  g  2a 
  20 
10  2x1 2x1 x1  nT   1  1
y  KP  2
  atm
2x1 = 2  2x1  2a   x1  a   20 
  20    20 
x1  1.0  nT   nT 
2 y 80
 2  1 Value of  4
    x 20
5 5 1
x  KC 2
 mol /  
8 80
 
5
33. 6
Sol. a = 4  i, iv, vi, vii
b = 2  ii, ix
v and viii forms  M.O.
d = 2  iii, x
a2  b2  2d 24
 6
4 4
34. 9
Sol. I, II, III and IV are correct due to bent rule and V is incorrect. Correct order in case of V is
II > III > IV > I = V.
x=4
y=1
2x + y = 9
35. 8
3
 5.8 
Sol. K SP of Mg  OH 2 is    10 3  .4  4  1012
 58 
2
Mg  OH 2  s   Mg  2OH
x  0.01 2x
 x  0.01  4x 2
  4  10 12
4x 2  0.01  4  1012
x  105 mole / 
Mg2  in container II  1.0  105
 
NH4 
 
For basic buffer pOH  pK b  log
 4 
NH OH
pOH  5  log5
= 5.70
OH  2  106
4  1012
Mg2  
  4  1012  1.0 M
1.6  10 20
 Al3     2  103 M
  8  1018
x  105
y  1.0
z  2  103
yz 200
Value of   8.
25x 25
36. 5
Sol. Statement 4, 11 and 12 are incorrect and other statements are correct.
x = 9, y = 3.
Mathematics PART – III
Section – A
37. A
1 tan1 x
Sol. By differentiating, f   x   2
f  x  0
1 x 1 x2
1
f  x   1  tan1 x  2e tan x
38. A
a
  f  x   f  x   dx  g  a 
3
Sol. ; f(x) = 2x + 6x – 8
1
3
f x 1  101 
 g  x   5 dx  2 ln  22 
2
39. D
2
x 2  2x  cot x 
 ex 
Sol.  e  sin x   ln  sin x  dx
2
ex
Let = t   ln  t  dt  t  ln t  1  c
sin x
40. B
Sol. x2 + y2 – ax = 0  x2 + 2xyy – y2 = 0
2xy 2xy
Orthogonal curve : x 2   y2  0 ; y  2
y x  y2
y P
By solving, x 2  y 2 
c
Passing through (1, 1) so x 2 + y2 = 2y
For shortest distance, Q = (1, 0) Q
D = PQ – r = 2  1
41. A, B, D
Sol. f(x) = f(x)(tan x – 1)(tan3 x – tan2 x + 3 tan x + 1)
  
g(x) = tan3 x – tan2 x + 3 tan x + 1 = 0 has exactly one root in x    ,  which lies in
 2 2
  
x   , 0
 4 
   
So, f(x) = 0 at x  and k where k    , 0 
4  4 
42. A, C
Sol. f  x   f 1  x   x y
-1
-1 y = f (x)
(x, f (x))
1
(f(x), x)
y = f(x)
(x, f(x))
x
1
43. A, B
1

Sol. fg = fg + fg by solving g  x   e x  2
g(x) is discontinuous at one point at x = 2
44. B, D
Sol. Graph of y = f(x) 
2
x
–1 0 1
45. A, D
3/ 4
 1  2 cos t 
3 sin t
Sol. f  x   x  2 
dt
0 cos t  2   cos t  2  
 3
 2x ; x0
1
 2
x 3
f  x    x  3u du  f  x     x  ; 0x3
0  3 2
 3
 x2 ; x3

46. B, C
x2  x  1  1  f(x)
Sol.  ,3  x  R 
x2  x  1  3 
Maxima at x = –1 and minima at x = 1 2
x
–1 1


2
Section – B
47. 1
Sol.
 6x f  x   4x 2   2f  x  dx  
2x
dx  
fx
dx  
1
c
  3f  x   2x   x
 f  x 
2 2
 x2  f  x  2
 x2  f  x   2 2
x  f  x
2
Substitute f  x  
4x  3f  x 
48. 2
16  4
 4
Sol.  2 8    x  4 x  4  dx 
3  0 
49. 5
 n  n2  mr
 1  1   n n2 r 1 
Sol. lim    2 2  m  
lim 2   = lim   2 2  2 2
dx 
 r 1  n  r  n2  k 2  m     r 1 n  r 0 n  x
n n
 k 1 
    m   
 
1
 n n  r  tan1 x 2
= lim   2 2 tan1      dx 
n
 r 1 n  r  n   0 1 x2 32
50. 7
 x 2  1  x 2  9  |f(|x|)|
Sol. f x  x  R – {–3, 1}
 x  1  x  3 
Graph of y = |f(|x|)|
Discontinuity at x =  1
Non-differentiable at x = 0, 1, 3
–3 –1 1 3
51. 8
4 4 4  /8
dx dx 1 1
Sol. I     I  2 2
dx  64  2
dx
0 2  sin 4x 0 2  sin 4x 0 4  sin 4x 0 4  sin 4x
 /8 3  /8
2 128 1
I  64  dx ; 3x = t  I   dt
7  cos8x 3  8t 
0 0 7  cos  
3
52. 4
Sol. f(x) = k(x + 1)2(x – 1)2(x – 5)2 + 4  f(2) = 81k + 4 = 85  k = 1
f(x) = (x + 1)2(x – 1)2(x – 5)2 + 4  f(x) = 2(x + 1)(x – 1)(x – 5)(3x2 – 10x – 1)
10  x 2  9  19
    lim  2 
3 x
10  x  5x  6  4
3
53. 4
 1
 
2022 1  x 2022  2021  1 2023 1  x 2023  2021  1

1

x x 1
Sol. lim 2021

x 0 2022 x 2021
 = 2021 = 43  47 number of divisors = 2  2 = 4
54. 2
 y2  3  1
Sol. Area = 2   y  dy 
 4  3
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FIITJEE

ALL INDIA TEST SERIES

ANSWERS, HINTS & SOLUTIONS

The bead will move along the elliptical path in vertical

Now consider the motion of blocks in their v0 A C.M. v0

Also the frog is in projectile motion from ground frame 3v0

Just before the collision Just after the collision

Applying COAM of ring in centre of mass frame (after the collision) v

Just before collision Just after collision

Also Rsin = V0sin2T /2 Rsin

A 2B4  g   A 2  g  2B2  g

n=1 n=2 n=3

Ground state 1st excited state 2nd excited state

Mathematics PART – III

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