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Aits 2223 PT I Jeea TD Paper 2
Aits 2223 PT I Jeea TD Paper 2
MARKING SCHEME
Section – A (Single Correct): Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct option is chosen.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –1 In all other cases.
Section – A (One or More than One Correct): Answer to each question will be evaluated according to the following
marking scheme:
Full Marks : +4 If only (all) the correct option(s) is (are) chosen;
Partial Marks : +3 If all the four options are correct but ONLY three options are chosen;
Partial marks : +2 if three or more options are correct but ONLY two options are chosen and both
of which are correct;
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a
correct option;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –2 In all other cases.
Section – B: Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct integer is entered;
Zero Marks : 0 Question is unanswered;
Negative Marks : –1 In all other cases.
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AITS-PT-I (Paper-2)-PCM-JEE(Advanced)/2023 2
Physics PART – I
mg mg
(A) F (B) F
2 1 1
3mg 2mg
(C) F (D) F
2 1 1
3. A horizontal stick of mass m has its left end attached to a pivot on pivot
the inclined plane while its right end rests on the top of a cylinder m
of same mass m as shown. The coefficient of friction between the
cylinder and both the stick and plane is . Then the smallest value
of for which the system doesn’t slip anywhere is
m
sin 3 sin
(A) (B)
2 cos 1 cos
sin 3 sin
(C) (D)
1 cos 2 cos
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3 AITS-PT-I (Paper-2)-PCM-JEE(Advanced)/2023
31 mg 35
(A) T0 (B) r0
30 3
41 mg 25
(C) T0 (D) r0
40 3
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AITS-PT-I (Paper-2)-PCM-JEE(Advanced)/2023 4
9. The system of two blocks and a frog (each having mass 5v0
m) is placed on a smooth horizontal surface as shown.
Initially the spring is in natural length (0) and all are at 37°
m K
rest. Now the frog jumps with velocity 5 v 0 at an angle of
37 with horizontal w.r.t. the block A and lands directly on A m m B
block B. If R is the horizontal Range of frog in ground 0
frame during the jump. If stiffness of the spring is
2mg2
K , then choose the correct option(s).
288 v 20
12v02 24v 02
(A) R (B) R
g g
12v02 2 6v02 2
(C) 0 1 (D) 0 3
g g
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5 AITS-PT-I (Paper-2)-PCM-JEE(Advanced)/2023
v 02
(A) Force exerted (F) on the end of the rope is yg
2
(B) Force exerted (F) on the end of the rope is yg v 02
v 30
(C) Heat loss per unit time is
2
(D) Heat loss per unit time is v 30
12. A projectile is thrown from ground with velocity 8 m/s. When it is moving with 6 m/s, it is at
maximum separation from the point of projection corresponding to the speed 6 m/s. Then this
maximum separation corresponding to speed 6 m/s is k meter. Find the value of k. (Take g = 10
ms–2)
14. Bob of mass m of simple pendulum is given a velocity from the lower most position in horizontal
T
direction in uniform vertical gravitational field (g) such that max 2 during the subsequent
Tmin
motion. Then the tension in the string when it becomes horizontal is K mg. Find the value of K. (T
represents tension in the string)
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AITS-PT-I (Paper-2)-PCM-JEE(Advanced)/2023 6
15. A bead of mass m is given a velocity along a smooth rigid spiral wire
(mass M = 2m and outer radius R) such that bead slides along the
wire. When bead will reach the center of spiral and sticks to it, at that
moment velocity of bead is v and angular velocity of spiral is .
(Assume that the center of mass of loop lies at its centre and given
that its moment of Inertia about an axis passing through centre and
MR2 R
perpendicular to its plane is I ). Find (Neglect gravity)
2 v
1 H
rough inclined plane is the find .
2 3 4h
(Assume that particle does not jump.)
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7 AITS-PT-I (Paper-2)-PCM-JEE(Advanced)/2023
Chemistry PART – II
19. For the dissociation of PCl5 g the variation of 1 against (D/d) is represented as
(D Vapour density at t = 0, d Vapour density at equilibrium)
(A)
1
D
d
(B)
1
D
d
(C)
1
D
d
(D)
1
D
d
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AITS-PT-I (Paper-2)-PCM-JEE(Advanced)/2023 8
20. For an reaction 2 pentyne 1 pentyne. The temperature dependence of equilibrium constant
8000
is given by nK 8.0 . The value of So at 300 K. is….
T
(A) 4R
(B) 8R
(C) 8000R
R
(D)
8
x
21. An electron in an atom jumps in such a way that its kinetic energy changes from x to . The
8
change in its potential energy will be?
7
(A) x
8
7
(B) x
4
7
(C) x
4
9x
(D)
4
22. The time required for 50% completion of a first order reaction at 298 K is equal to that required for
75% completion of a reaction at 308 K. If the pre-exponential factor for the reaction is
3.5 106 sec 1 in the given temperature range. Find the ratio of K 298 to K 308 .
(A) 0.5
(B) 2
3
(C)
4
3
(D)
2
23. In the emission spectrum of H-atom from energy level ‘n’ to ground state in one or more step and
no line belongs to the Breckett series is observed. The wave length of lines belonging to Balmer
series may be (R = Rydberg constant)
36
(A)
5R
16
(B)
3R
R
(C)
3R
35
(D)
3R
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9 AITS-PT-I (Paper-2)-PCM-JEE(Advanced)/2023
25. A closed rigid container of volume 1 litre, initially contains 4 mole of HI (g) and 4.25 moles of
N2 g at 27o C. When the mixture is heated to 127o C two reversible reactions takes place till
equilibrium is established.
2HI g H2 g I2 g K C1
2N2 g 6H2 g 4NH3 g K C2
At equilibrium the concentration of I2 and NH3 are 1.0 M and 0.5 M respectively. Choose the
correct option
5
(A) K C1
32
16
(B) K C2
125
1
(C) K C1 K C2
25
(D) Conc. of N2 at equilibrium = 4.0 mol/litre
26. How many of the following compounds has more than one p d bond
(A) SO2
(B) SO3
(C) XeO 4
(D) ClO3
27. Which of the following statement(s) is/are true for CH2 = CH2 and CH2 = SF4 (Methyl sulphur
tetrafloride)?
(A) In ethylene nodal plane lies in molecular plane
(B) In methyl sulphur tetrafloride nodal plane lies in axial plane
(C) In methyl sulphur tetrafloride nodal plane lies in equatorial plane
(D) If the nodal plane lies in equatorial plane its stability will be less than if its lies in axial plane
28. How many of the following compounds has more than two (3C – 2e) bond.
(A) AlCl3 n
(B) B2H6
(C) Al BH4 3
(D) Be BH4 2
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AITS-PT-I (Paper-2)-PCM-JEE(Advanced)/2023 10
29. Not considering the electronic spin the degeneracy of the second excited state of H-atom is ‘x’
degeneracy of the second excited state of H is ‘y’. And number of angular node in d 2 2 orbital
x y
x
is ‘z’. Calculate the value of z?
y
2
30. The given reaction how many of them can give sp hybridised boron centre. In case of the
product(s)
(i) Borax
(ii) Borax NH4 Cl
HCl
(iii) Borax
H O
(iv) Borax
2
(v) B 2H6 NH3
THF
(vi) B3 N3 H3 Cl3 LiBH4
(vii) LiH B2 H6
(viii) K 3 AlF6 BF3
31. (i) If the sum of the number of lone pairs of electrons on each central atom in the given species
is/are ‘x’
2
TeBr6 , IF2 , SNF3 and XeF3
(ii) and among the following species the number of diamagnetic spin is/are ‘y’
B 2 , Li2 , C2 , C2 , O22 , O2 , He2 , Be2 , KO2 , K 2 O, N2 O 4 , B 3N3 H6
(Atomic number of Te = 52, Br = 35, Xe = 54, K = 39, I = 127).
xy
Calculate the value of ?
2
32. Equilibrium constant of SO3 g decomposition and formations was calculated by following two
methods
Method (1) Method (2)
2SO3 g 2SO2 g O2 g 2SO2 g O 2 g 2SO3 g
I II
at t = 0, 10 moles of SO3 is added 5 in Initially 2 : 1 molar ratio SO2 and O2 is added
respectively. At the equilibrium total pressure
container. If at equilibrium mixture is titrated with
of mixture 20 atm. Mole % of O2 at equilibrium
0.2 M acidic KMnO4 its volume 4 litre. KC for the
is 25%. KP for the reaction is ‘y’ atm -1.
reaction is ‘x’ (mol/litre)
y
The value of is ?
x
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11 AITS-PT-I (Paper-2)-PCM-JEE(Advanced)/2023
0.01 M Mg(NO3)2
at 25oC
0.35 M NH4Cl + 0.7 M NH4OH
I II
at 25oC
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AITS-PT-I (Paper-2)-PCM-JEE(Advanced)/2023 12
36. Choose the correct and incorrect statement in the following given statements
1. Hydrogen peroxide. In the pure state is non-planar and almost colourless.
2. S 8 s aOH aq. bS2 aq. cS 2 O32 aq dH2 O
The value of a + b is 16.
3. Hydrogen peroxide. In its reaction with KIO4 and NH2 OH respectively is acting reducing
agent and oxidizing agent.
4. MgCl2 .6H2 O on heating give anhydrous MgCl2 .
5. H3 BO3 is mono basic weak Lewis acid.
6. According to MOT B2 and C2 both do not have bond.
7. ‘Be’ cannot be qualitatively confirmed by the flame test.
8. Correct order of density of alkali metals is Li < K < Na < Rb < Cs.
4
9. The silicates in which three oxygen atoms of SiO4 are shared known as sheet silicate.
10. Pb 4 compounds are stronger oxidizing agent than Sn4 compounds.
11. Graphite is better lubricant on the earth than on moon.
12. The hydrolysis of trialkylchlorosilane R3 SiCl yields trialkylchlorosilanol.
If the correct number of statement(s) is/are x and incorrect statement(s) is/are y. Value of
3x y
is….
6
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13 AITS-PT-I (Paper-2)-PCM-JEE(Advanced)/2023
f x f y tan1 x tan1 y
37. If f(x) is a function such that f x y 0 x, y R and f(0) = 1,
1 y2 1 y2
then the function f(x) is
1 –1
(A) 1 tan1 x 2e tan x (B) –(1 + tan x)
1 1
(C) e1 tan x
(D) 1 tan1 x e tan x
38. A function f(x) is such that the area enclosed by |y| = f(x) between x = 1 and x = a (a > 1) is given
4 2 f x
by g(a) = a + 6a – 16a + 9, then the area formed by the curve k x between the lines
g x 5
x = 2 and x = 3 with the x-axis is
1 101 1 131
(A) ln (B) ln
2 22 2 22
1 141 1 101
(C) ln (D) ln
2 12 2 12
x2
39. The value of e 2x cot x x 2 ln sin x cosec x dx is equal to
2 2
(A) e x 2x ln sin x 1 cosec x c (B) e x 2x ln sin x 1 cosec x c
2 2
(C) e x x 2 ln sin x 1 cosec x c (D) e x x 2 ln sin x 1 cosec x c
40. Let C be a curve f(x, y) = 0 passing through (1, 1) such that it is orthogonal to the family of circles
x2 + y2 – ax = 0, where ‘a’ being parameter, then the shortest distance between the curve C and
the parabola x2 = 2y + 1 is
(A) 2 1 (B) 2 1
(C) 3 1 (D) 3 1
41. Let f(x) = (cos2 x)(etan x), x , , then which of the following options is/are true?
2 2
(A) f(x) = 0 has atleast one root in x ,
2 2
(B) y = f(x) has a point of local maxima in x , 0
4
(C) f(x) = 0 has exactly one root in x ,
2 2
x3 6x2 11x 6
(D) lim 1
x x2 3x 2
where ‘’ is the total number of points of maxima and minima of y = f(x)
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AITS-PT-I (Paper-2)-PCM-JEE(Advanced)/2023 14
42. Let f(x) be a function satisfying f(x) > 0, f(x) > 0 x (0, 1) and f(0) = 0, f(1) = 1, then which of
the following options is/are true?
1 1 1 1
(A) f f 1 (B) f 1 f 1 1
2 3 2 3
1 1 1 1 1 1 1 1
(C) f f (D) f f
3 3 3 2 2 2
43. In a question, a student was given to find the derivative of the product of two functions ‘f’ and ‘g’.
x 1
The student by mistake thought (fg) = fg for his question f x and he got the correct
x3
answer. Given that g(1) = e. Which of the following options is/are correct?
(A) g(x) is discontinuous at one point
(B) lim g x 1
x
x3 8
(C) lim 12 where is the number of points of discontinuity of g(x)
x x 2
1 x 2
44. Let f x cos1 2
and g(x) = {f(x)} x R (where {x} denotes fractional part function of x),
1 x
then which of the following options is/are true?
(A) Total number of points where f(x) is not continuous is 2
(B) Total number of points where g(x) is not continuous is 7
(C) f(1) = f(-1) = 1 and g(x) is not differentiable at x = 0
(D) Total number of points where f(x) is not continuous is 3
3 /4
1 2 cos t
45. Let f(x) be a function defined by f x x cos t 3 sin t 2x
dt where x is any
cos t 2 3
0
real number, then which of the following options is/are true?
(A) f(x) is continuous and differentiable everywhere
(B) f(x) is continuous for all x but non-differentiable at two values of x
3
(C) Minimum value of f(x) is for x R
2
3
(D) Minimum value of f(x) is for x R
4
x2 x 1
46. Let the function f : , , be given by f x sin1 log3 2 , then which of
2 2 x x 1
the following options is/are true for f(x)?
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15 AITS-PT-I (Paper-2)-PCM-JEE(Advanced)/2023
16
48. If the area bounded between the curves |x| + y = 4 and x y 2 is sq. units, then the
3
value of is
x 2 1 x 2 9
50. Consider f x , x R – {a, b}, where g(x) is a polynomial of degree 4.
g x
f(x) has a removable type of discontinuity at x = a and x = b. The following three informations are
also known
(i) lim f x (ii) lim f x 4
x x 1
4 3 /8
dx dx 3
51. If , then the value of is
2 sin 4x 8x 16
0 0 7 cos
3
52. Let f(x) be a polynomial of degree 6 such that f(2) = 85 and attains its local minimum value 4 at
points x = –1, x = 1 and x = 5. The local maximum value of f(x) lies at x = and x = .
x2 9
If lim 2 , then the value of [] is (where [.] represents greatest integer function)
x x 5x 6
1
x2022
1 t 2021 1 1
1
53. If the value of lim 2022 dt , then the number of positive divisors of is
x 0 x t
x 2023
m
54. If the area bounded by the curves x 2 = y, x2 = –y and y2 = 4x – 3 is , where m and n are
n
relatively prime positive integer, then |m – n| is
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