2019-DSE CHEM PAPER 1A S.K.H. Tsang Shiu Secondary School F.6 Annual Examination (2018-2019) CHEMISTRY PAPER 1 Time allowed: 2 % hours This paper must be answered in English. GENERAL INSTRUCTIONS. 1. There are TWO sections, A and B, in this Paper. You are advised to finish Section A in about 45 minutes. 2. Section A consists of multiple-choice questions in this question paper, while Section 8 contains conventional questions printed separately in Question-Answer Book B. 3. Answers to Section A should be marked on the Multiple-choice Answer Sheet while answers to Section B should be written in the spaces provided in Question-Answer Book B. The Answer Sheet for Section A and the Question-Answer Book for Section B must be handed in separately at the end of the examination. 4, A Periodic Table is printed on the last page of Question-Answer Book B. Atomic numbers and relative atomic masses of elements can be obtained from the Periodic Table INSTRUCTIONS FOR SECTION A (MULTIPLE-CHOICE QUESTIONS) 1. Read carefully the instructions on the Answer Sheet. 2. When told to open this book, you should check that all the questions are there. Look for the words ‘END OF SECTION A’ after the last question. 3. All questions carry equal marks. 4. ANSWER ALL QUESTIONS. You should use an HB pencil to mark all your answers on the Answer Sheet. Wrong marks must be completely erased. You must mark the answers clearly; otherwise you will lose marks if the answers cannot be captured. 5. You should mark only ONE answer for each question. If you mark more than one answer, you will receive NO MARKS for that question 6 No marks will be deducted for wrong answers. 2018 - 2019 F6 Annual Examination Chemistry Paper 1 Section A 1This section consists of two parts. There are 24 questions in Part | and 12 questions in Part I. Choose the best answer for each question. Candidates may refer to the Periodic Table printed on the LAST page of Questions-Answer Book B. PARTI 1. Octopuses’ blood is blue in colour because their blood consists of a protein that contains A. calcium ions. 8. copper(l) ions. C. chromate ions. D__ permanganate ions. 2. The atomic numbers of elements X and ¥ are both smaller than 20. Elements X and Y belong to Group IV and Vil in the periodic table respectively. Which of the following statements are correct? (1) The melting point of element X is higher than that of element ¥. (2) Both elements X and ¥ are non-metallic. (3) Elements X and ¥ combine to form a covalent compound A. (1) and (2) only B. (1) and (3) only C. (2)and (3) only D. (2), (2) and (3) 3. Which of the following statements concerning calcium and strontium (Sr) are correct? (1) The melting point of strontium is higher than that of cal m. (2) The reactivity of strontium towards water is higher than that of calcium. (3) Both elements are silvery white solids under room temperature and pressure. A. (2) and (2) only B. (1) and (3) only C. (2) and (3) only D. (A),(2) and (3) 2018 ~ 2019 F6 Annual Examination Chemistry Paper 1 Section A 24. Which of the following substances conduct(s) electricity? (1) NHs(aq) (2) Bra(l) (3) SiO2(s) A. (dJonly B. (2) only . (A)and (3) only D. (2)and (3) only 5. Which of the following chemical species are ionic compounds? (1) NH«NOa(s) (2) BFsNHa(s) (3) CH(CH2)::0SO3Na(s) A. (1)and (2) only B. (1) and (3) only C. (2)and (3) only D. (A), (2) and (3) 6. Which of the following methods can be used to distinguish between CuO and Ag.0? (1) heating each of them strongly (2) heating each of them with carbon strongly (3) adding each of them to dilute hydrochloric acid ‘A. (1) and (2) only B. (1) and (3) only C. (2) and (3) only D. (A), (2) and (3) 7. Which of the following statements concerning concentrated potassium hydroxide solution is/are correct? (1) Itusually stores in a brown bottle. (2) It contains hydrogen ions. (3) Itis corrosive. A. (1) only 8B. (2)only C. (1) and (3) only D. (2) and (3) only 2018 - 2019 £6 Annual Examination Chemistry Paper 1 Section A 38 A white solid dissolves in water to form an acidic solution. The solution reacts with aqueous sodium hydroxide on heating to give a gas. The solid is probably ‘A. calcium oxide. B. calcium carbonate. €. ammonium chloride. D sodium chloride, 9. Which of the following substances can be used to distinguish between calcium nitrate solution and lead{(II) nitrate solution? (1) dilute sodium hydro: (2) sodium carbonate solution (3) sodium chloride solution A. (1)and (2) only B. (1) and (3) only C. (2)and (3) only D. (2), (2) and (3) je solution 10. Which of following actions will change the pH of 25.0 cm? of 1.0 M hydrochloric acid? (1) add 25.0 cm? of deionized water to it (2) adda piece of magnesium strip to it (3) add 25.0 cm? of 1.0 M hydrochloric acid to it A. (1)and (2) only B. (1) and (3) only C. (2)and (3) only D. (1), (2) and (3) 11. 40.0 cm? of an aqueous solution contains potassium chloride and potassium dichromate. If the concentrations of potassium ions and potassium chloride are 0.08 mol dm- and 0.05 mol dm-* respectively, what is the concentration, in mol dm”, of dichromate ion in the solution? A. 0.015 B. 0.025 Cc. 0.030 D 0.050 2018 - 2019 F.6 Annual Examination Chemistry Paper 1 Section A 412. 2.03 g of an oxide of metal X of formula XO reacts completely with 42.50 cm? of 1.5 mol dm nitric acid. Metal X most likely is (Relative atomic masses: Fe = 55.8; Cu = 63.5; Ti = 47.9; Sr = 87.6) A fe Bo Gu c Ti D sr 13. A sample of concentrated nitric acid has a density of 1.60 g cm. What is the concentration, in mol dmv, of the sample if it contains 65.5% of nitric acid by mass? 0; N= 14.0; O= 16.0) (Relative atomic masses: H = A. 876 B. 10.4 Cc 166 D 254 14. Which of the following statements concerning natural gas is/are correct? (1) Itis a mixture of gases. (2) It liberates considerable amount of sulphur dioxide upon burning, (3) It contains greenhouse gases. A. (1) only B. (2)only C. (1) and (3) only D. (2) and (3) only 15. The diagram shows the structure of a part of a polymer. HCdHC HC rrrtil -C-C-C-C-C-C~ rrr at HF HF HE Which of the followng is/are correct? (1) The polymer has no sharp melting point. (2) The structural formula of its monomer is CHCI=CHF. (3) The polymer is made up of two kinds of monomers. A. (1)only B. (2) only C. (A)and (3) only D. (2) and (3) only 2018 ~ 2019 F.6 Annual Examination Chemistry Paper 1 Section A 516. The experimental set-up given below helps to analyse the composition of car exhaust gas. car exhaust gas —+ — Ice water liquid X — limewater_—_acidified KMnO.(aq) Which of the following statements are correct? (1) Liquid x turns dry cobalt(t!) chloride paper pink. (2) There is no observable change in \ewater, (3) The acidified KMnO,(aq) changes from purple to colourless. A. (1) and (2) only B. (1) and (3) only C (2)and (3) only D. (1), (2) and (3) 17. Which of the following compounds can form hydrogen bonds among its molecules? (1) NHs (2) Hco;H (3) CHE A. (2) and (2) only B. (1) and (3) only (2) and (3) only D. (1), (2) and (3) 18. Which of the following reactions involve sulphur dioxide that acts as an oxidizing agent? (1) 2H2S(aq) + SO2(g) > 3S(s) + 2H20(!) (2) NaClO(aq) + S02 (g) + H20(!) > NaCl(aq) + H2SO4(aq) (3) 2Mg{s) + SO2(g) > 2Mg0(s) + S(s) A. (1)and (2) only B. (1) and (3) only C. (2)and (3) only D. (1), (2) and (3) 2018 - 2019 F.6 Annual Examination Chemistry Paper 1 Section A 619. iron(I!) sulphate solution 20. 21. The following diagram shows a simple chemical cell YW) salt bridge platinum electrode platinum electrode acidified potassium dichromate Which of the following statements concerning the above chemical cell are correct? (1) The platinum electrodes could be replaced by the graphite electrodes. (2) The colour of the iron(t!) sulphate solution changes from pale green to yellow. (3) Electrons flow from the left electrode to the right electrode in the external circuit. A. (1) and (2) only B. (1)and (3) only C. (2) and (3) only D. (1), (2) and (3) Which of the following processes is/are endothermic? (1) Zns) + CuSO«(aq) > ZnSO«(aq) + Culs) (2) 2H20(|) > 2Ha(g) + O2(g) (3) als) > ha(e) A. (A)only B. (2) only . (Q)and (3) only D. (2) and (3) only Which of the following may give either positive or negative value(s)? (1) The standard enthalpy change of formation (2) The standard enthalpy change of neutralization (3) The standard enthalpy change of reaction A. (1)only B. (2) only . (A)and (3) only D. (2) and (3) only 2018 ~ 2019 F6 Annual Examination Chemistry Paper 1 Section A22. Given that: aH [COx(g)] = -393.5 kJ mol* +f; [H20())] = -286.0 kJ molt aH [NaHCOs\s)] 951.0 kJ mol AH [Na2CO3(s)] = -1131 kJ mol Thermal decomposition for NaHCOs: 2NaHCOs(s) —» Na2CO3(s) + H20(|) + CO2(g) ‘What is the standard enthalpy change of thermal decomposition for NaHCOs(s)? A B. c D 491.5 molt -859.5 ki molt #1403 kJ mol -3713 Ki) mol 23. Which of the following gases are colourless? (1) carbon monoxide (2). sulphur dioxide (3) nitrogen monoxide A B. c D. (1) and (2) only (1) and (3) only (2) and (3) only (2), (2) and (3) 24. Consider the following statements and choose the best answer: Ast statement 2nd statement The atomic number of oxygen is 16. Oxygen has isotopes. A. Both statements are true and the 2nd statement is a correct explanation of the 1st statement. 8. Both statements are true and the 2nd statement is NOT a correct explanation of the 1st statement, C. The Ast statement is false but the 2nd statement is true. D. Both statements are false. 2018 ~ 2019 F.6 Annual Examination Chemistry Paper 1 Section A 8Part Il 25. In the graph below, curve (|) is obtained when adding 10 g of chalk to excess dilute hydrochloric acid. Volume of CO2 / cm? Time /s Which of the following changes made to the reaction would give curve (Il)? A. Use 5 gof chalk. B. Use 10 g of powdered chalk. C. Add 30 cm? of water to the acid before the reaction. D. Heat the reaction mixture. 26. Consider the following compound: HHO ot il H-C=C-C-CH, Which of the following chemical reagents can react with this compound? (1) bromine in organic solvent (2) acidified potassium permanganate solution (3) sodium borohydride solution, NaBHi(aq) A. (1)and (2) only B. (1) and (3) only (2) and (3) only D. (4), (2) and (3) 27. The following chemical equilibrium has been established in a closed vessel keeping at 530K: 2HI(g) = Ha(g) + lag) The volume of the vessel is now halved. Which of the following statements is correct? ‘A. The rate of the forward reaction remains unchanged. B. The value of the equilibrium constant increases, C. The equilibrium position shifts to the right. D. The colour intensity of the reaction mixture increases. 2018 - 2019 F6 Annual Examination Chemistry Paper 1 Section A 928. Which of the following compounds would dissolve in water and give a solution with a pH value greater than 7? (1) sodium oxide (2) zinc oxide (3) dichlorine monoxide A. (i)only B. (2)only (1) and (3) only D. _(2)and (3) only 29. ler the structures of compounds X and Y shown below: oe 7 COOH OH x y Which of the following chemicals can be used to distinguish X and ¥? (1) acidified potassium dichromate solution (2) bromine in organic solvent (3) sodium carbonate solution A. (1) and (2) only B. (1) and (3) only C. (2) and (3) only D. (4), (2) and (3) I conductivities of A and B 30. A and B are compounds of elements in Period 3. The electri are shown below: A a Electrical conductivity in molten state Good Poor Electrical conductivity of the resultant mixture when | <0 eo the compound is added to water co oo What would compounds A and 8 be? Aa 8 A Nacl PeO10 B. AlO3 SiO2 c NaCl SiOz D. PaO10 AlzO3 2018 ~ 2019 F6 Annual Examination Chemistry Paper 1 Section A 1031. 40 cm? of ethane is burnt completely in 300 cm* of oxygen. What is the total volume of gases after the combustion? (All volumes are measured at room temperature and pressure; Molar volume of gases at rt.p. is 24.0 dm* mol) A. 360cm? B. 240.cm? C. 200cm? D. 80cm? 32. Which of the following statements concerning soap are correct? (1) Soap is an ester. (2). Soap is soluble in oil (3). Soap is soluble in water. (2) and (2) only (2) and (3) only (2) and (3) only (2), (2) and (3) po@> 33. Which of the following compounds can be used for synthesizing condensation polymers? (1) CHy=CHCH3 (2) HOCH(CHs)COoH (3) HaNCH2CO2H A. (1)only B. (2) only C. (1) and (3) only D. (2)and (3) only 34, Which of the following statements is INCORRECT? A. Aqueous ions of transition metals are usually coloured. 8. Zincis a transition metal and its ions show variable oxidation states. C. Phosphorus has a lower melting point than sulphur. D. Silicon has a lower melting point than diamond 2018 ~ 2019 F6 Annual Examination Chemistry Paper 1 Section A 1jer the following statements and choose the best answer: Ast statement 2nd statement When hex-d-ene reacts with hydrogen Hex-L-ene undergoes addition reaction bromide, the major product is with hydrogen bromide. 1-bromohexane. A. Both statements are true and the 2nd statement is a correct explanation of the 1st statement. B. Both statements are true but the 2nd statement is NOT a correct explanation of the Ast statement. C. The 1st statement is false but the 2nd statement is true. D. Both statements are false. 36. Consider the following statements and choose the best answer: Ast statement 2nd statement Aluminium has a higher melting point The metallic bonds in aluminium are than sodium. stronger than those in sodium. ‘A. Both statements are true and the 2nd statement is a correct explanation of the 1st statement. B. Both statements are true but the 2nd statement is NOT a correct explanation of the 1st statement. C. The Ast statement is false but the 2nd statement is true. D. Both statements are false. END OF SECTION A 2018 ~ 2019 F6 Annual Examination Chemistry Paper 1 Section A 2