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Allen Chem CPT 17 Nov 2022
Allen Chem CPT 17 Nov 2022
ALLEN CLASS
CAREER INSTITUTE ENTHUSIAST COURSE
KOTA (RAJASTHAN) PRACTICE TEST
CHEMISTRY DATE 17-11-2022
ELECTROCHEMISTRY, SOLUTION & CHEMICAL KINETICS
1. A metal rod is dipped in a solution of its ions. Its electrode potential is independent of
(1) temperature of the solution (2) concentration of the solution
(3) area of the metal exposed (4) nature of the metal
2. The position ofsome metals in the electrochemical series in decreasing Mg > Al> Zn > Cu > Ag. What will
happen if a copper spoon is used to stir a solution of aluminium nitrate?
(1) The spoon will get coated with aluminium. (2) An alloy of copper and aluminium is formed.
(3) The solution becomes blue. (4) No chemical change will take place.
4. A gas X at 1 atrn is bubbled through a solution containing a mixture of 1 M-Y and 1 M -Z" at 25°C. If
the reduction potential of Z > Y > X, then,
(1) Y will oxidize X and not Z (2) Y will oxidize Z and not X
(3) Y will oxidize both X and Z (4) Y will reduce both X and Z
6. The solution of CuSO,4. in which copper rod is immersed. is diluted to 10 times. The reduction electrode
potential
(1) increases by 0.0295 V (2) decreases by 0.0295V
(3) increases by 0.095V (4) decreases by 0.095 V
7. Electrode potential will be more for hydrogen electrode at pH (at the same temperature)
(1) 4 (2) 3 (3) 2 4) 5
8. The standard reduction potentials ofPt | Cr,0,, Cr*3,Pt| MnO, , Mn, Pt|Ce*, Ce* in the presence of
acid are 1.33 V, 1.51 V and 1.61 V, respectively, at 25°C. The decreasing order of oxidizing power is
Cet4 (2) MnO > Cr,0,> Ce+4
(1)Cr,0,> MnO,>
(3) Ce*> MnO, > Cr0, (4)MnO4 > Ce**> Cr,O,2
CHEMISTRY
at 298 K. Ihe electrode potential for the half oi
10. The dissociation constant for
is 1.8 x 10
CH,COOH
0.48; 2.303 RT/F 0 06 -cell
K is (log 2 0.3; log 3
=
= =
13. The corect diagram for the following reaction and E° for tha cell is
14. In an experimental set-up for the measurement of EMF of a half-cell using a reference electrode and a salt
bridge, when the salt bridge is removed, the voltage
(1) remains the same (2) increases to maximum
(3) decreases half the value (4) drops to zero
15. After some time, the voltage of an electrochemical cell becomes zero. This is because
(1) their electrode potential becomes zero.
(2) their reduction potential become equal but have opposite sign.
(3) their reductioni potential become equal and have the same sign.
(4) the ions of the lectrolyte in the salt bridge stop moving.
20. A solution of glucose (CH,0,) is isotonic with 4gof urea (NH,-CO-NH,) per liter of solution. The concentration
of glucose is
(1) 4 g/l (2) 8g/ (3) 12 g/l (4) 14 g/l
CHEMISTRY
-2-
21. In which case van't Hofffactor are equal?
(a) KCI, 50% ionised (b) KSO,,40% ionised (c) FeCl, 30%ionised (d) SnCl, 20% ionised
Code:
(1) (a), (b) (2) (b), (d) (3) (a), (c), (d) (4) (a). (b), c)
22. The osmotic pressure of equimolar solutions of BaCl, NaCl and glucose will be in the order
(1) Glucose > NaCl » BaClh (2) BaCl, NaCl >Glucose
(3) NaCl > BaCl,> Glucose (4) NaCl Glucose> BaClh
23. The van't Hoff factor i for an infinity dilute solution of NaHSO, is:
(1) 1/2 (2) 1/3 (3) 3 (4) 2
24. fP arnd Pare the vapourpressure of a solvent and its solution respectively and N, and N, are the mole fractions
of the solvent and non-volatile solute respectively, then corect relation is:
25. The vapour pressure of pure liquid solvent A is 0,80 atm. When a non-volatile substance Bis added to the
solvent, its vapour pressure drops to 0.60 atm. Mole fraction of the component B in the solution is:
(1) 0.50 (2) 0.25 (3) 0.75 (4) 0.40
Moles of K,So, to be dissolved in 12 mol water to lower its vapour pressure by 10 mmHg at a temperature at
26.
which vapour pressure of pure water is 50 mm is:
(1) 3 mol (2) 2 mol (3) 1 mol (4) 0.5 mol
27. The vapour pressure of a dilute aqueous solution of glucose is 750 mm of mercury at 373 K. The mole fraction
of solute is-
1 1
(1 10 2) 76 35 (4)
28. 1 mol each of following solutes are taken in 5 mol water,
A. NaCl, B. KSO4: C. Na,PO, D. Glucose
will be in order:
Assuming 100% ionisation of the electrolyte, relative decrease in vapour pressure
B <C <D (2)D <C <B <A (3)D < A < B <C (4) Equal
(1)A <
Aluminium phosphate is 100% ionised in 0.01 molal aqueous solution. Hence, AT,/K is:
29.
(2) 0.015 (3) 0.0175 (4) 0.02
(1) 0.01
30. 1.0 molal aqueous solution of an electrolyte X,Y, is 25% ionized. The boiling point of the solution is (K, for H,O
= 0.52 K kg/mol)
(2) 374.04 K (3) 377.12K (4) 373.25K
(1) 375.5 KK
correct
31. Which of the following statement is more
chemical reaction
(1) Catalyst only accelerates the rate of a
can retard the rate
of a chemical reaction
(2) A catalyst
of a reaction
(3) A catalyst can control the speed
A catalyst alters the speed of a
reaction
(4)
be slowed down by the addition of a small amount of acetanilide.
The decomposition of hydrogen peroxide
can
32.
The latter act as -
(2) Promoter
(3) Moderator (4) Poison
(1) Inhibitor
its
Efficiency ofthe catalyst depends
on
33.
(2) Number of free valencies
(1) Molecularweight (4) Amount used
(3) Physical state
CHEMISTRY
34. In the reaction KMnO +H,SO, + HC,O,> products
Mn** ions act as
(1) Positive catalyst (2) Negative catalyst (3) Auto catalyst (4) Enzyme catalyst
35. Platinized asbestos is used as a catalyst in the manufacture of H,SO, It is an example of
(1) Homogeneous catalyst (2) Heterogeneous catalyst
(3) Auto-catalyst (4) Induced catalyst
36.
In(1)the
Fe
ostwald's process for the manufacturing of HINO, the catalyst used is -