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REVIEW PAPER
Muhammad Badar Hayat1,3 | Danish Ali1 | Keitumetse Cathrine Monyake1 | Lana Alagha1 |
2
Niaz Ahmed
1
Department of Mining and Nuclear
Engineering, Missouri University of
Summary
Science and Technology, Rolla, MO 65409, Sun is an inexhaustible source of energy capable of fulfilling all the energy
USA needs of humankind. The energy from the sun can be converted into electricity
2
Department of Electrical and Computer
or used directly. Electricity can be generated from solar energy either directly
Engineering, Missouri University of
Science and Technology, Rolla, MO 65409, using photovoltaic (PV) cells or indirectly using concentrated solar power
USA (CSP) technology. Progress has been made to raise the efficiency of the PV
3
Mining Engineering Department, solar cells that can now reach up to approximately 34.1% in multi‐junction
University of Engineering and
Technology, Lahore, Pakistan
PV cells. Electricity generation from concentrated solar technologies has a
promising future as well, especially the CSP, because of its high capacity, effi-
Correspondence ciency, and energy storage capability. Solar energy also has direct application
Lana Alagha, Associate Professor,
Missouri University of Science and
in agriculture primarily for water treatment and irrigation. Solar energy is
Technology, 288 McNutt Hall, 1400 North being used to power the vehicles and for domestic purposes such as space
Bishop, Rolla, MO 65409, USA. heating and cooking. The most exciting possibility for solar energy is satellite
Email: alaghal@mst.edu
power station that will be transmitting electrical energy from the solar panels
in space to Earth via microwave beams. Solar energy has a bright future
because of the technological advancement in this field and its environment‐
friendly nature. The biggest challenge however facing the solar energy future
is its unavailability all‐round the year, coupled with its high capital cost and
scarcity of the materials for PV cells. These challenges can be met by develop-
ing an efficient energy storage system and developing cheap, efficient, and
abundant PV solar cells.
This article discusses the solar energy system as a whole and provides a com-
prehensive review on the direct and the indirect ways to produce electricity
from solar energy and the direct uses of solar energy. The state‐of‐the‐art pro-
cedures being employed for PV characterization and performance rating have
been summarized. Moreover, the technical, economic, environmental, and
storage‐related challenges are discussed with possible solutions. Furthermore,
a comprehensive list of future potential research directions in the field of direct
and indirect electricity generation from solar energy is proposed.
KEYWORDS
characterization, concentrating solar power, efficient energy storage system, energy crisis,
photovoltaic cells, power tower, solar energy, solar power technologies, Stirling dish system
Int J Energy Res. 2018;1–19. wileyonlinelibrary.com/journal/er © 2018 John Wiley & Sons, Ltd. 1
2 HAYAT ET AL.
conventional cooling systems.7 Purohit, Singh, and as the generation of electric voltage between two elec-
Mamodiya provided a brief general overview of the solar trodes attached to a solid or liquid system caused by shin-
energy system as a whole and discussed the steps required ing a light on the system. Almost all PV cells have a PN
to calculate the size of the solar system.8 Kapumpa and junction across which a photo voltage is applied.15
Virdi provided an overview of the PV cells, factors affect- The economics and efficiency of a solar PV cell
ing their efficiency and methods that have already been depend upon its material. A lot of research has been done
implemented to improve the efficiency.9 Gul, Kotak, and in this area to find out the most efficient and cost‐effec-
Muneer summarized the PV materials, their efficiency, tive material for PV cells. The requirements for ideal solar
and the leading countries in the PV installations along cell material are as follows15,16:
with a brief cost analysis.10 Ameri, Khoram, Min, and
Brabec summarized the major recent developments taken • The material used for manufacturing the solar cells
place in the organic ternary solar cell research based on should have a band gap between 1.1 and 1.7 eV.
various types of sensitizers.11 Ahmad and Tiwari reviewed • The material should have a direct band structure.
all the available solar radiation models.12 Parida, Iniyan, • The material should be readily available and nontoxic.
and Goic reviewed the PV technology by discussing the • The material should be suitable for large reproduction.
different existing materials used for PV cells, its existing • The material should have good PV conversion
performance indicators, and the applications of PV sys- efficiency.
tems.13 Kerschaver and Beaucarne summarized the • The material should have a long‐term stability factor.
modeling and manufacturing advancements of back‐con-
tact solar cells along with discussing its industrial imple- PV cells can be classified into three major genera-
mentation.14 The majority of the aforementioned review tions: first‐generation, second‐generation, and third‐gen-
articles has mainly focused on PV cells and their materials. eration cells. The details are discussed below.
This review paper discusses the solar energy system as
a whole and provides a comprehensive review of all the
possible methods of electricity generation through solar
2.1.1 | First‐generation PV cells
energy. The paper discuses all the technical, economic,
and environmental challenges associated with solar tech- The cells made up of crystalline silicon are called first‐
nology and the ways to overcome those challenges. Fur- generation cells. These cells may be monocrystalline or
thermore, the current paper lists the future research polycrystalline silicon with large grain sizes. They are
directions that are essential for the advancement of this the most dominant type of PV cells in the market. The
technology. In summary, the present review focuses on monocrystalline silicon cells are made of silicon posi-
the following: tive–negative (Si p–n) junctions and have been able to
achieve an efficiency of 25%. The polycrystalline cells
• Direct and indirect ways to produce electricity from are manufactured by melting the silicon and solidifying
solar energy. it to orient crystals in a fixed direction to produce
• State‐of‐the‐art procedures being employed for PV multicrystalline Si, which is then sliced into thin wafers.
performance rating and characterization. The efficiency of the polycrystalline cells is approximately
• Challenges offered by the existing solar technologies. 20.4%. Although the efficiency of polycrystalline silicon
• Possible solutions and potential research opportunities. cells is slightly less than that of monocrystalline cells, this
lack of efficiency is compensated for by their lower pro-
duction costs and the reduced number of defects in the
crystal structure. Furthermore, because of the develop-
2 | GENERATION OF ELECTRICITY ment of ribbon silicon technology, it is envisioned that
U S I N G S O L A R EN E R G Y the production cost of these first‐generation cells will
drop even further.1,17 Significant efforts have been dedi-
Electricity can be generated directly by solar energy cated to improve the capability and the efficiency of the
through PV cells or indirectly by concentrated solar first‐generation cells. Emitter wrap‐through (EWT) cells
power (CSP) as discussed below.5 have been proposed. These cells have laser‐drilled holes
on the front and the back surfaces of the cell to increase
the surface area in order to enhance the absorption of
2.1 | Photovoltaic cells
the solar radiation. This improved cell design has
A system generating an electric current through the PV increased the efficiency of the cells and lowered the over-
effect is called a PV cell. The PV effect can be defined all production cost.18
4 HAYAT ET AL.
In general, first‐generation cells are more efficient at layer is placed between two different electrodes. One of
lower temperatures and require less area for a given unit the electrodes is transparent or semitransparent and
power. However, the main disadvantage of these PV often made up of Indium tin oxide (ITO). The other elec-
cells is that their performance reduces at higher trode is commonly made up of aluminum; however,
temperature. sometimes, other materials like magnesium and gold
are also used.23 The OS organic light absorbing layer con-
sists of a mixture of light‐sensitive conjugated polymers
2.1.2 | Second‐generation PV cells
(such as phthalocyanine) or small molecules and fuller-
Thin‐film cells are considered as the second‐generation ene‐like compounds to absorb light and set their electric-
PV cells. They have lower costs than the first‐generation ity‐generating events in motion.24-26 A typical OS cell
cells because they require less silicon material; however, design is shown in Figure 2. The efficiency of the OS cells
they have a smaller share of the market because of their is around 10%.
lower efficiency. There are different types of thin‐film The DS cells have a reverse concept to light emitting
cells.16 Among these are the amorphous silicon (AS) solar diodes (LEDs). In these cells, light is absorbed by a sensi-
cells where cells are deposited on a substrate support after tizer (ruthenium‐polypyridine dye), which is fixed to the
the decomposition of silane gas in a plasma‐enhanced surface of a wide band semiconductor. At the interface,
chemical reactor. AS cells have the potential to be very charge separation is promoted through the injection of
cost‐effective because of their low usage of material and photo‐induced electrons from the dye into the conduction
the possibility of their roll‐to‐roll production for modules. band of the solid (TiO2). Electrons are then diffuse in the
The major drawback of these AS cells is their low effi- conduction band as a result of electron concentration gra-
ciency (10.1%) and their instability in terms of electrical dient to the charge collector or anode. These cells are
output with time. It has been noted that there efficiency reported to have a solar‐to‐electric conversion efficiency
decreases about 20% if used for too long of a time.17,19 over 10%.27
On the other hand, cadmium telluride (CdTe) solar cells
offer a better efficiency of approximately 17%. CdTe cells
can be manufactured by chemically depositing CdTe
2.1.4 | Comparison of efficiencies of dif-
through evaporation on a substrate. However, the unlim-
ferent PV cells
ited use of these cells is due to the fact that they contain
toxic materials and also due to the limited production of The efficiencies of different terrestrial solar PV cells and
tellurium.17,20 their submodules are summarized in Table 1.28
Copper indium gallium selenide (CIGS) solar cells are The efficiency chart for different solar cells by the US
more efficient than AS and CdTe. CIGS cells are pro- Department of Energy (DOE)‐sponsored National Renew-
duced by the preparation of elements like Cu, In, Ga, able Energy Laboratory (NREL) is shown in Figure 3.
and Se. Efficiency of these cells is 20% at laboratory scale, The highest efficiency is noted for multi‐junction solar
but commercial CIGS modules typically have efficiencies cells that is 34.1%.28 This efficiency is comparable with
between 12% and 14%. Toxicity and the scarcity of the ele- the fossil fuel power plants.29
ments used in these cells are a major challenge.17,20
TABLE 1 Confirmed terrestrial cell and submodule efficiencies measured under the global air mass 1.5 spectrum (1000 W/m2) at 25°C,
regenerated from Green, Emery, Hishikawa, Warta, and Dunlop28
Test Centree
Classificationa Effic.b (%) Areac (cm2) Voc (V) Jsc (mA/cm2) FFd (%) (and date) Description
Silicon
Si (crystalline) 25.0 ± 0.5 4.00 (da) 0.706 42.7f 82.8 Sandia (3/99)g UNSW PERL
Si (multicrystalline) 20.4 ± 0.5 1.002 (ap) 0.664 38.0 80.9 NREL (5/04)g FhG‐ISE
Si (thin‐film transfer) 19.1 ± 0.4 3.983 (ap) 0.650 37.8h 77.6 FhG‐ISE (2/11) ISFH (43‐μm thick)
Si (thin‐film submodule) 10.5 ± 0.3 94.0 (ap) 0.492i 29.7i 72.1 FhG‐ISE (8/07)g CSG solar (1–2 μm
on glass; 20 cells)
III‐V cells
GaAs (thin film) 28.3 ± 0.8 0.9944 (ap) 1.107 29.47j 86.7 NREL (8/11) Alta devices
g
GaAs (multicrystalline) 18.4 ± 0.5 4.011 (t) 0.994 23.2 79.7 NREL (11/95) RTI, Ge substrate
InP (crystalline) 22.1 ± 0.7 4.02 (t) 0.878 29.5 85.4 NREL (4/90)g Spire, epitaxial
Thin‐film chalcogenide
CIGS (cell) 19.6 ± 0.6k 0.996 (ap) 0.713 34.8l 79.2 NREL (4/09) NREL, CIGS on glass
i
CIGS (submodule) 17.4 ± 0.5 15.993 (da) 0.6815 33.84i 75.5 FhG‐ISE (10/11) Solibro, four serial cells
CdTe (cell) 16.7 ± 0.5k 1.032 (ap) 0.845 26.1 75.5 NREL (9/01)g NREL, mesa on glass
Amorphous/nanocrystalline
Si (amorphous) 10.1 ± 0.3m 1.036 (ap) 0.886 16.75f 67.0 NREL (7/09) Oerlikon solar lab,
Neuchatel
Si (nanocrystalline) 10.1 ± 0.2n 1.199 (ap) 0.539 24.4 76.6 JQA (12/97) Kaneka (2 μm on glass)
Photochemical
Dye sensitized 11.0 ± 0.3o 1.007 (da) 0.714 21.93h 70.3 AIST (9/11) Sharp
o i i, l
Dye sensitized (submodule) 9.9 ± 0.4 17.11 (ap) 0.719 19.4 71.4 AIST (8/10) Sony, eight parallel cells
Organic
Organic thin film 10.0 ± 0.3o 1.021 (ap) 0.899 16.75j 66.1 AIST (10/11) Mitsubishi chemical
Organic (submodule) 4.2 ± 0.2o 294.5 (da) 0.714 12.26j 47.7 AIST (9/11) Sumitomo chemical
(10 series cells)
Multi‐junction devices
GaInP/GaInAs/Ge 34.1 ± 1.2 30.17 (t) 2.691 14.7j 86.0 FhG‐ISE (9/09) AZUR (monolithic)
a‐Si/nc‐Si/nc‐Si (thin film) 12.4 ± 0.7p 1.050 (ap) 1.936 8.96h 71.5 NREL (3/11) United solar
q j
a‐Si/nc‐Si (thin‐film cell) 12.3 ± 0.3 0.962(ap) 1.365 12.93 69.4 AIST (7/11) Kaneka
a‐Si/nc‐Si 11.7 ± 0.4n, r
14.23 (ap) 5.462 2.99 71.3 AIST (9/04) Kaneka
(thin‐film submodule)j, l
a
a‐Si, amorphous silicon/hydrogen alloy; CIGS, Cu(In, Ga)Se2.
b
Effic., efficiency.
c
ap, aperture area; da, designated illumination area; (t), total area.
d
FF, fill factor.
e
AIST, Japanese National Institute of Advanced Industrial Science and Technology; FhG‐ISE, Fraunhofer Institut für Solare Energiesysteme; JQA, Japan Qual-
ity Assurance; NREL, National Renewable Energy Laboratory.
f
Spectral response reported in Version 36 of these Tables.
g
Recalibrated from original measurement.
h
Spectral response and current–voltage curve reported in Version 38 of these Tables.
i
Reported on a “per cell” basis.
j
Spectral response and current–voltage curve reported in present version of these Tables.
k
Not measured at an external laboratory.
l
Spectral response reported in Version 37 of these Tables.
m
Light soaked at Oerlikon prior to testing at NREL (1000 h, one sun, 50°C).
n
Measured under IEC 60904–3 Ed. 1: 1989 reference spectrum.
o
Stability not investigated. References 31 and 32 review the stability of similar devices.
p
Light soaked under 100 mW/cm2 white light at 50°C for over 1000 h.
q
Stabilized by manufacturer.
r
Stabilized by 174 h, one sun illumination after 20 h, five sun illumination at a sample temperature of 50°C.
6 HAYAT ET AL.
FIGURE 3 Efficiencies of different generations of solar cells: Courtesy of the National Renewable Energy Laboratory, Golden, Colorado,
2017.29 [Colour figure can be viewed at wileyonlinelibrary.com]
2.1.5 | Trends in electricity production estimations are for high solar radiation areas. In the case
from PV cells of areas with moderate solar irradiations, the PV cost
advantage over fossil fuel powered electricity is expected
Figure 4 shows the increasing trend in the installed
to take place in 2028 and 2046 respectively17 as shown in
capacity for the generation of electricity from PV cells.
Figure 5.
This represents the increased interest in electricity genera-
tion from PV cells worldwide. It is estimated that in case of
industrial applications, leveling of costs between the grid
and PV systems will be achieved by 2022.17 These 2.2 | Concentrated solar power
In CSP or solar thermal technologies, the solar radiations
are concentrated to produce steam or hot air. This steam
PV cumulative installed capacity (GW0)
70
or hot air is then used to generate electricity using a
60
50
40
30
20
10
Year
FIGURE 4 Trend for cumulative installed capacity from FIGURE 5 Evolution of cost of electricity from PV systems over
photovoltaic cells worldwide, with permission of Springer (© the years as compared with conventional grid electricity cost, with
Springer‐Verlag London 2013)17 [Colour figure can be viewed at permission of © Springer‐Verlag London17 [Colour figure can be
wileyonlinelibrary.com] viewed at wileyonlinelibrary.com]
HAYAT ET AL. 7
• Parabolic troughs,
• Power towers,
• Dish/engine systems, and
• Linear Fresnel reflectors.
receiver in Figure 9. The receiver is a long tube that is 2.2.5 | Comparison of CSP technologies
selectively coated with absorbent material known as
black chrome solar absorption cermet. The fluid that is The comparison among different CSP technologies is
water/steam inside the tube transfers the thermal energy given in Table 2. The parabolic trough collector technol-
to a conventional electricity generation system. The flat ogy is currently the most viable options because of its
mirrors used in this type of system are cheaper than the mature technology. However, future solar power tower
parabolic troughs.42 technology seems to be more promising because of its
TABLE 2 Comparison of concentrated solar power technologies regenerated from renewable energy agency40
ET AL.
Typical Capacity
(MW) 10‐300 10‐200 10‐200 0.01‐0.025
Maturity of technology Commercially proven Pilot commercial projects Pilot projects Demonstration projects
Technology development risk Low Medium Medium Medium
Operating temperature (°C) 350‐550 250‐565 390 550‐750
Plant peak efficiency (%) 14‐20 23‐35 18 30
Annual solar‐to‐electricity 10‐16 7‐20 13 12‐25
efficiency (net) (%)
Annual capacity factor (%) 25‐28 (no TES) 29‐43 55 (10 h TES) 22‐24 25‐28
(7 h TES)
Collector concentration 70‐80 suns >1000 suns >60 suns depends on >1300 suns
secondary reflector
Table 2, Continued typical 10‐300 10‐200 10‐200 0.01‐0.025
capacity (MW)
Receiver/absorber Absorber attached to External surface or cavity Fixed absorber, no Absorber attached to
collector, moves with receiver, fixed evacuation secondary collector, moves with
collector, complex design reflector collector
Storage system Indirect two‐tank molten salt Direct two‐tank molten Short‐term pressurized No storage for Stirling
at 380°C (dT = 100 K) or salt at 550°C (dT = 300 K) steam storage (<10 min) dish, chemical storage
direct two‐tank molten salt under development
at 550°C (dT = 300 K)
Hybridization Yes and direct Yes Yes, direct (steam boiler) Not planned
Grid stability Medium to high High (large TES) Medium (back‐up firing Low
(TES or hybridization) possible)
Steam conditions (oC/bar) 380 to 540/100 540/100 to 160 260/50 NA
Maximum slope of solar field (%) <1‐2 <2‐4 <4 10% or more
3
Water requirement (m /MWh) 3 (wet cooling) 0.3 2‐3(wet cooling) 0.25 3 (wet cooling) 0.2 0.05‐0.1 (mirror washing)
(dry cooling) (dry cooling) (dry cooling)
Application type On grid On grid On grid On grid/off grid
Suitability for air cooling Low to good Good Low Best
Storage with molten salt Commercially available Commercially available Possible, but not proven Possible, but not proven
9
10 HAYAT ET AL.
low storage costs, achievable high capacity factor, and the this energy with the help of solar cooking can save the
greater efficiency of the steam cycle.40 environment by saving trees. A solar cooking system
has been established with the energy storage capability.
It consists of flat plate collectors, reflectors, and a work-
3 | DIRECT USES OF SOLAR ing fluid, which usually transfers the heat from the collec-
ENERGY tors for cooking goods Figure 10.48
a receiving antenna on Earth. In this way, the microwave wireless power transmission is still under question. How-
beam can again be converted into electricity on Earth. ever, space transmission systems and wireless transmis-
This satellite system power can be delivered anywhere sion technology are expected to advance to the point of
on Earth.53 contributing to solar power in the future.54
The DC to DC efficiency of the satellite wireless
power transmission system at a frequency of 5.8 Hz is
4 | P V C E L L S/ M O DUL E S
measured to be 45%. This efficiency is the result of the
CHARACTERIZATION
development of highly efficient DC‐RF converters and
rectennas developed for this frequency.
Performance of solar cells can be characterized through
The beam control system based on retro directivity is
current–voltage curves or spectral responsivity‐wave-
yet to be demonstrated. Moreover, because of the huge
length curves. PV power conversion efficiency, under
expenses of space transportation systems and lack of com-
standard reporting conditions (SRC), defined as a ratio
mercial space markets, the financial viability of satellite
of maximum output (electric) to the total irradiance, as
given by Equation 3, is used as the most common perfor-
mance indicator for PV cells.55-62
gives the power rating that is close to the actual and can be
relevant to bulk power generation systems. Energy‐based
rating like integrated power over time in kW to hour is also
being used to characterize the performance of the PV mod-
ules depending upon the type of application. AM/PM
method, a type of energy‐based method, rates the
performance of a PV module in terms of the energy pro-
duced during a standard solar day at a given temperature
and total irradiance.65 Another energy based method
involves measuring the energy delivered by the PV modules
over a set of five days; a hot‐sunny day, a cold‐sunny days, a
hot‐cloudy day, a cold‐cloudy day, and a normal nice
day.63,65-68 Main advantage of these energy‐based rating
methods is that they are more generalized performance
rating methods and thus provide the actual performance
rating for the PV modules while not being site specific.
There are various translation models that can be used
to translate the PV power output from the measured con- FIGURE 12 Generic I–V measurement system configuration.
Regenerated from Hamadani and Dougherty71
ditions to reference conditions in order to compare the
performance of all the PV cells/modules on a single scale.
Some of these are listed below.67,68 VOC is determined by performing a linear regression
using more two or more points around the zero‐current area
on I–V curve. Whereas, ISC is determined by performing a
linear regression/interpolation using more two or more
4.1 | Current–voltage measurements
points around the zero‐voltage area on the I–V curve. Pmax
The current–voltage (I–V) behavior of the solar cell/ is just the maximum power measured for any device, so
module can be measured to determine the maximum basically, it is the highest point on the I–V curve. For
power output (Pmax). The most common setup includes increased accuracy, a higher order polynomial fitting could
a light source (natural or simulated), a surface to place be done around 80% to 85% of Pmax at the PV curve.68-72
the device under test, an external power supply to con-
trol/vary the voltage or current, sensors, a data acquisi-
4.2 | Spectral Responsivity measurements
tion system to measure the current and/or voltage as
the first one is varied via the external power supply. In Spectral responsivity (S[λ]) or quantum efficiency (QE[λ])
order to eliminate the resistance losses while sensing is required to understand the current generation and col-
the voltage, a Kelvin connection needs to be attached lection mechanisms of any PV device. Spectral
to the PV device. Solar simulators can be used to simu- responsivity measurements encompass measuring the
late the natural light in order to ensure the accuracy and photocurrent produced by the incident light of a given
repeatability of I–V characteristics of any PV device. wavelength and power.
Continuous arc, pulsed arc, and filament lamps are the Equation 4 provides relationship/conversion of spectral
most commonly used sources.69,70 The choice of the responsivity to quantum efficiency/yield (electron–hole
source depends upon the application in question and pairs collected per incident photon). Spectral responsivity
the properties required, ie, operating voltage, wattage, is measured as current produced per unit power.
and lifetime.
Figure 12 shows a generic I–V measurement system. qSðλÞ
QEðλÞ ¼ × 100; (4)
Shunt resistor (Rsh) is used to measure the current. For λhc
PV cells, voltage is sensed adjacent to the current Where,
connection; while for PV modules, it is done at the box
containing the current lead connection. Figure 13 shows hc=q ¼ 0:80655 If “ λ ” is in units of “ μm” and“ Sðλ Þ” in unites of Ampere=Watts
a typical I–V curve for a 50‐W PV module. By analyzing
the I–V curve for any PV device, critical parameters The most commonly used systems for measuring the
including open circuit voltage (VOC), short circuit current spectral response of any PV device include the follow-
(ISC), and the maximum power (Pmax) can be ing: filter based, grating monochrometers, and interfer-
determined. ometers.60,61,73-75
HAYAT ET AL. 13
Filter‐based system shown in Figure 14 for measuring grating system, band‐pass filters may have to be used to
the spectral responsivity involves projecting the light suppress modes at longer and/or shorter wavelengths.
from source through the filters (monochrometer) onto Grating‐based systems have a high‐spectral resolution
the PV device under test.59 A pyroelectric radiometer or but low optical throughput as compared with filter‐based
Si detector is used to measure the beam power. Shutter systems.72-74,76
is only required when AC voltmeter is used to measure Typical error sources in the measurement of photo-
the signal. Current to voltage converter measures the current include but are not limited to the following55-76:
photocurrent. Power vs wavelength can be measured in
real time through a reference detector or that data can • Errors related to electrical instruments (I to V con-
be stored in a certain file. verter, AC voltmeter) such as noise, calibration, and
Grating‐based system shown in Figure 15 is used to offsets errors.
measure the spectral responsivity over a wide wavelength • Errors related to PV cell/module such as temperature
range, ie, 400 to 3200 nm. Order‐sorting filters can be bias, white light bias, device sensitivity and response
used to suppress modes at shorter wavelengths. For single time to light.
• Error related to mechanical factors such as vibrations
and movement of optics.
FIGURE 14 Typical filter‐based spectral responsivity FIGURE 15 Typical grating‐based spectral responsivity
measurement system, regenerated from Emery, K. National measurement system, regenerated from Emery, K. National
Renewable Energy Laboratory 201172 [Colour figure can be viewed Renewable Energy Laboratory 201172 [Colour figure can be viewed
at wileyonlinelibrary.com] at wileyonlinelibrary.com]
14 HAYAT ET AL.
Typical error sources in the measurement of light power 5.1 | Technical challenges
includes but are not limited to the following: Among the technical barriers of PV cells are their effi-
ciency that has to improve to be competitive with other
• Errors related to filament or light source as a result of energy sources. The abundant supply of the cell
intensity fluctuation and change in spectrum over age manufacturing materials like CdTe with silicon must be
and time ensured. A hassle‐free metering and billing system has
• Calibration errors related to signal‐to‐noise and cali- to be developed.
bration drift with time. In the case of CSP technologies, heat transferring
• Errors related to stray light when light seen by the fluids having high‐heat capacities must be found, and
detector and not the cell as well as the incomplete thermal losses reduced. In the case of solar water heating,
exclusion of grating orders and pinholes in the filter. the system has to be adopted to meet existing building
• Detectors performance errors such as resolution, sig- codes, safety requirements for appliances, and other stan-
nal‐to‐noise, and time constant errors of pyroelectric dards for widespread application.
detector.
400
5.4.1 | Thermal energy storage
300
The three ways to store the thermal form of solar energy.
200
These include the following: the sensible heat storage,
latent heat storage, and thermochemical storage. In sensi-
100 ble heat storage system, heat energy is stored by changing
the temperature of the storage medium. The common
0 storage media that can be used are water, oil, air, rock
bed, sand, soil, etc.
Latent heat storage is done by changing the phase of
Technology
storage material. Normally the change is between solid
FIGURE 17 Levelized cost for electricity generation by and liquid phase. Typical phase change materials used in
technology (US dollar/kilowatt‐hour), regenerated from Timilsina this system are salt hydrates, polymers, water, etc. The cost
& Kurdgelashvili78 [Colour figure can be viewed at of the phase change materials is very high, which restricts
wileyonlinelibrary.com] the application of phase materials for solar energy storage.
Significant research is needed to assure that low‐grade
TABLE 3 Environmental and socioeconomic indicators of solar energy technologies, regenerated from Tsoutsos et al80
Distributed
Central Solar Distributed Central Photovoltaic Photovoltaic Solar Thermal
Indicator Thermal Solar Thermal Power Generation Power Generation Electricity
CO2 emissions 1.4 kg/kWh or 1.4 kg/kWh or 0.6‐1.0 kg/kWh 0.6‐1.0 kg/kWh Annually 688 t/MW when
savings 840 kg/m2 a 840 kg/m2 a compared with a combined
cycle plant 1.360 t/MW when
combined to a cola fired plant
Production 4000 jobs/a 4000 jobs/a 2‐3000 jobs/a 2‐3000 jobs/a 1 permanent job/MW for
employment operation + 10‐15 jobs/MW
(EU wide) for 12‐18 mo construction
Total employment 12 000 jobs/a 12 000 jobs/a 4‐5000 jobs/a 4‐5000 jobs/a 1000 permanent jobs for 1000 MW
Although, overall solar energy technologies are envi- phase change materials can be practically implemented.
ronmentally friendly, they do have some negative impacts The thermochemical storage of thermal energy is
on the environment. For example, solar thermal heaters done by driving a chemical reaction, the products of
have a visual impact on building esthetics. In case of large which are stored. These products can then later be com-
PV electricity generation systems, a lot of cultivable land bined to release thermal energy.
is occupied. Also, during the manufacturing of these cells, The main challenges facing the thermal energy stor-
toxic and flammable materials are used that can be inju- age systems are their building costs and losses because
rious to health. Solar thermal electricity systems can also of storage. However, a storage efficiency of 90% can be
occupy a lot of land and are very detrimental to the flora achieved. The best strategy for storage is found to be short
and fauna in the area, especially birds. These systems can term, ie, for a few days.81-83
also pollute the local water.80
effective, be environmentally friendly, be highly efficient, • Safe disposal of solar products and making these prod-
be mature, and have long lifetime. Among the many ucts biodegradable should be the goal of future
options are flywheels, capacitors, supercapacitors, fuel research.
cells, lead acid batteries, metal‐air cells, NiCd batteries,
etc. Metal–air batteries, flywheels, capacitors, and super
capacitors are currently considered the electrical energy
7 | C ON C L U S I ON S
storage systems of the future.84
In addition, a lack of implementation‐friendly laws
and skilled labor for solar energy technologies also con- Solar energy can be regarded as the most viable energy
tributes to their limited application.78 source of the future. Electricity generation by solar tech-
nology seems to be very promising. Multi‐junction PV
cells have achieved remarkable efficiencies. The CSP
6 | FUTURE RESEARCH AREA technologies, such as solar power towers offer a reliable
RECOMMENDATIONS source of electricity with the capacity for energy storage.
In addition to electricity generation, solar energy also
The following is our vision on the future potential has a capacity to fulfill the energy needs of essential
research directions in the field of direct and indirect elec- working sectors of society including agriculture, the auto-
tricity generation from solar energy. mobile industry, food preparation industries, water treat-
ment, etc. It has been estimated that by 2032, energy
• The efficiency of PV cells needs to be raised. generation by solar technology will be able to compete
• Research in the field of materials science need to be economically with conventional energy sources. More-
enhanced to find cheaper construction materials for over, the environmentally friendly nature of solar energy
PV cells. makes it the ultimate energy source for humanity.
• Research in the field of mining and metallurgy should Overall, the major findings of this study are summa-
concentrate on exploration, excavation and processing rized as follows:
of materials such as CdTE with silicon. This will ensure
an abundant supply for PV cell manufacturing material. • Electricity can be generated directly or indirectly from
• Research efforts in the field of environment and safety solar energy. PV cells directly generate electric current
are required to minimize the risks associated with the through a PV effect. The economics and efficiency of a
toxic and flammable materials used in the PV cells solar PV cell depend mainly upon its material. PV
through appropriate handling and disposal. cells are usually classified into three major genera-
• In case of solar power tower technologies, exploring tions: first‐, second‐, and third‐generation PV cells
new types of heat transferring fluids having high heat where the first generation is the most dominant type.
capacities is a promising area of research. The efficiency of PV cells can be up to approximately
• Research efforts need to be directed towards reduction 34% in the multijuction devices. CSP technologies use
of thermal losses in solar power technologies. an indirect process to generate electricity from solar
• In the case of solar power towers, efficient energy stor- power where solar radiations are concentrated to pro-
age is a hurdle. The need for a backup heater in the duce hot air that is then used to generate electricity in
solar water heating system adds to the cost and a conventional power cycle. Parabolic troughs power
reduces its economic worth. towers. Dish systems and linear Fresnel reflectors
• A hassle‐free metering and billing system must be are the main CSP technologies in use.
developed. • Solar cells performance can be characterized through
• In case of solar water heating, the system must meet current–voltage (I–V) curves or spectral responsivity‐
the existing building codes, appliances safety stan- wavelength curves. The behavior of I–V curves deter-
dards, and overall industry standards for widespread mines the maximum power output of the solar cell.
application.77 Spectral responsivity explains the behavior of current
• Losses in the storage of thermal energy storage systems generation and collection mechanisms of any PV cell.
need to be addressed to enable long‐term storage. It measures the photocurrent produced by the inci-
• Metal–air batteries, flywheels, capacitors, and super dent light of a given wavelength and power. However,
capacitors are the electrical energy storage systems there are some measurements errors related to the
having promising future.53 However, they need fur- efficiency of the electrical instruments used such as
ther development to meet the ideal standards of a con- I–V converters, voltmeters, cell modules, and detec-
taminant‐free world. tors in addition to other calibration errors.
HAYAT ET AL. 17
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