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JUNE 2019
DOCUMENT CONTROL
Name of Final Environmental Impact Assessment report for proposed
Document expansion project for manufacturing of synthetic organic chemicals by
Deepak Nitrite Ltd., located at Plot No. 4/12, Chemical Complex,
GIDC-Nandesari, District: Vadodara, Gujarat
Document No. EEC/A-207/17-18/EIA-37 Revision 01 Released 20/06/2019
DISCLAIMER:
This report has been prepared by M/s Envisafe Envrionment Consultants for obtainng
Environmental Clearance based as per ToRs issued by SEIAA. Information provided in this
report (unless attributed to references) shall not be copied or used without the written consent of
M/s Envisafe Environment Consultants.
REVISION HISTORY:
Document Control
Page | i
Deepak Nitrite Ltd., GIDC-Nandesari
Environmental Impact Assessment Report
Proposed Expansion for Manufacturing of Synthetic Organic Chemicals
DECLARATION BY EXPERTS
I, hereby, certify that I was a part of the EIA team in the following capacity that
developed this EIA Report.
EIA Coordinator:
Name : Pushpin Shah
Signature & Date : 20/06/2019
I, Pushpin Shah, hereby confirm that the above mentioned experts prepared the EIA
report of “Deepak Nitrite Ltd.”. I also confirm that I shall be fully accountable for any
misleading information mentioned in this statement.
Date : 20/06/2019
Signature :
Designation : CEO/Proprietor
TABLE OF CONTENTS
Document Control i
Declaration of Experts iii
Undertaking by Project Proponent & EIA Consultant vii
Contents xi
List of Tables xvii
List of Figures xix
List of Annexure xxi
List of Abbreviations xxiii
List of Symbols / Notations xxiv
CONTENTS
SR. PAGE
TITLE
NO. NO.
CHAPTER – 1: INTRODUCTION
Table of Contents
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Deepak Nitrite Ltd., GIDC-Nandesari
Environmental Impact Assessment Report
Proposed Expansion for Manufacturing of Synthetic Organic Chemicals
SR. PAGE
TITLE
NO. NO.
2.4 Justification of site selection 2.5
2.5 Product Profile 2.6
2.6 Manufacturing Process 2.10
2.7 Solvent Requirement & Recovery System 2.11
2.8 Material Requirements, Storage & Transportation 2.12
2.8.1. Raw material Requirement 2.12
2.8.2. Handling 2.12
2.8.3. Storage 2.13
2.8.4. Transportation 2.13
2.9 Resource Requirements 2.13
2.9.1. Land 2.13
2.9.2. Machineries & Utilities 2.17
2.9.3. Project Cost 2.18
2.9.4. Power 2.18
2.9.5. Water 2.19
2.9.6. Fuel 2.19
2.9.7. Man Power 2.20
2.10 Project Implementation Schedule 2.20
2.11 Pollution Potential & Management 2.21
2.11.1 Water Pollution 2.21
2.11.2 Air Pollution 2.33
2.11.3 Hazardous Waste 2.37
2.11.4 Noise 2.41
2.12 Regulatory Framework 2.42
2.12.1 General Legal Reuirement 2.42
2.12.2 Permissions under Environmental Statues 2.43
2.12.3 Industry Specific Standards for discharge of liquid effluent 2.43
2.12.4 License from PESO for storage of hazardous chemicals 2.43
2.12.5 Applicability of MAH Unit under MSIHC Rules, 1989 2.43
2.13 Statutory Compliance Of Existing Plant 2.44
2.13.1 Compliance of EC 2.44
2.13.2 Compliance of CTE/CTO 2.44
Table of Contents
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Deepak Nitrite Ltd., GIDC-Nandesari
Environmental Impact Assessment Report
Proposed Expansion for Manufacturing of Synthetic Organic Chemicals
SR. PAGE
TITLE
NO. NO.
2.13.3 Environmental Monitoring & Auditing 2.44
2.13.4 Details of GPCB Notices and Court Case 2.44
2.13.5 Compliance under Factory Act 2.45
2.14 Summary 2.45
Table of Contents
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Deepak Nitrite Ltd., GIDC-Nandesari
Environmental Impact Assessment Report
Proposed Expansion for Manufacturing of Synthetic Organic Chemicals
SR. PAGE
TITLE
NO. NO.
4.3 Prediction of Environmental Impacts 4.4
4.4 Impacts During Construction Phase and Its Mitigative Measures 4.6
4.5 Impacts During Operation Phase and Its Mitigative Measures 4.10
4.5.1 Evaluation of Impacts using Mathematical Model 4.18
Table of Contents
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Deepak Nitrite Ltd., GIDC-Nandesari
Environmental Impact Assessment Report
Proposed Expansion for Manufacturing of Synthetic Organic Chemicals
SR. PAGE
TITLE
NO. NO.
7.6 Risk assessment study 7.19
7.6.1 Modes of Failure 7.22
7.6.2 Maximum Credible Accident/ Catastrophic Failure and Its Mitigation 7.22
Measure
7.6.3 Consequences Analysis 7.24
7.7 Risk Mitigative Measures 7.28
7.8 Onsite Emergency Plan & Disaster Management Plan 7.40
7.8.1 Pre-emergency activity 7.43
7.8.2 Emergency Time Activities 7.46
7.8.3 Post – Emergency Activities 7.47
7.9 Offsite Emergency Plan 7.48
Table of Contents
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Deepak Nitrite Ltd., GIDC-Nandesari
Environmental Impact Assessment Report
Proposed Expansion for Manufacturing of Synthetic Organic Chemicals
SR. PAGE
TITLE
NO. NO.
Table of Contents
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Deepak Nitrite Ltd., GIDC-Nandesari
Environmental Impact Assessment Report
Proposed Expansion for Manufacturing of Synthetic Organic Chemicals
LIST OF TABLES
TABLE PAGE
TITLE
NO. NO.
1.1 Details of Promoters 1.2
1.2 Structure of EIA report 1.5
2.1 Salient features of the project site 2.2
2.2(a) List of Products (Existing as per CC&A) 2.6
2.2(b) List of Products (Scenario after proposed expansion) 2.7
2.2(c) Summary of Products 2.9
2.3 Details of Proposed Additional Products 2.9
2.4 Details of Solvent Requirement & Spent Solvent Generation 2.11
2.5(a) Break-up of Area 2.14
2.5(b) Plant wise built-up area breakup 2.15
2.6 Details of Plant Machineries and Utilities 2.17
2.7 Cost of Project 2.18
2.8 Details of Fuel Requirement 2.19
2.9 Details of Manpower Requirement 2.20
2.10 Product-wise Water Consumption & Wastewater Generation 2.22
2.11 Product-wise Pollution Load 2.24
2.12 Category-wise Water Requirement & Wastewater Generation 2.25
2.13 Summary of water balance after proposed expansion 2.26
2.14 (a) Stage-wise Characteristic Effluent to Proposed MEE 2.29
2.14 (b) Stream-wise Characteristic of Effluent to ETP (Existing Scenario) 2.29
2.14 (c) Stream-wise Characteristic of Effluent to ETP (Scenario after 2.30
proposed expansion)
2.15 Stage-wise characteristic of Effluent to ETP 2.30
2.16 Technical Details of Effluent Treatment Plant 2.31
2.17 Technical Details of Advanced Effluent Treatment Plant 2.31
2.18 Economical and Technical Viability of Effluent Treatment System 2.32
2.19 Details of Flue Gas Stacks 2.34
2.20 Details of Process Gas Generation 2.35
2.21 Details of Process Gas Stack & APCM 2.36
2.22 Details of Hazardous Waste Generation & its management 2.38
Table of Contents
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Deepak Nitrite Ltd., GIDC-Nandesari
Environmental Impact Assessment Report
Proposed Expansion for Manufacturing of Synthetic Organic Chemicals
TABLE PAGE
TITLE
NO. NO.
2.23 Applicable Acts / Rules for Proposed Expansion Project 2.42
3.1 Environmentally Sensitive Receptors 3.2
3.2 Sampling & Monitoring Locations 3.6
3.3 Frequency & Methodology of Environmental Monitoring 3.6
3.4 Land Use Pattern of the Study Area 3.9
3.5 Meteorological Parameters 3.18
3.6 Ambient Air Quality Monitoring Stations 3.20
3.7 Water Sampling Locations 3.24
3.8 Physico-Chemical Characteristics of Water 3.25
3.9 Soil Sampling Locations 3.28
3.10 Physico-Chemical Characteristic of Soil 3.28
3.11 Noise Level Sampling Locations 3.30
3.12 Noise Level in Study Area 3.30
3.13 Enumeration of Flora 3.31
3.14 List of Flora in the study area 3.31
3.15 Enumeration of Fauna 3.35
3.16 List of Fauna in the study area 3.35
3.17 Socio economic profile 3.39
4.1 Prediction of Impacts during Construction Phase 4.4
4.2 Prediction of Impacts during Operation Phase 4.5
4.3 Impacts & Aspect Analysis during Construction Phase 4.6
4.4 Impacts & Aspect Analysis during Operation Phase 4.10
4.5 Details of stack emission due to Proposed Project 4.19
4.6 First Three Highest 24-Hourly Average GLC Values 4.20
4.7 First Highest 24-Hourly Average GLC Values for AAQM Stations 4.20
4.8 Incremental ground level concentration of pollutants 4.21
6.1 Environmental Monitoring Program 6.1
6.2 Responsibilities of EMC 6.5
7.1 Details of hazardous chemicals identified for risk assessment 7.6
7.2 Applicability of license from PESO 7.8
7.3 Monitoring Program for Occupational Health & Safety 7.18
7.4 Atmospheric Condition Assumed 7.25
Table of Contents
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Deepak Nitrite Ltd., GIDC-Nandesari
Environmental Impact Assessment Report
Proposed Expansion for Manufacturing of Synthetic Organic Chemicals
TABLE PAGE
TITLE
NO. NO.
7.5 Summary of MCA Scenarios 7.25
7.6 Risk matrix for emergency management 7.28
7.7 Levels of emergency associated with risk rating 7.28
7.8 Possible Emergency – Spillage (Spill Control Plan) 7.33
7.9 Possible Emergency – Fire 7.34
7.10 Possible Emergency – Toxic Gas Release 7.36
7.11 Details of Fire Extinguishers 7.38
7.12 Details of Fire Hydrants 7.38
7.13 Details of Fire-Water Pumps 7.39
7.14 Details of Provision for Fire-fighting System 7.39
7.15 Responsible key personnel in case of emergency 7.42
7.16 Details of In-charge for specific hazards and emergency 7.42
7.17 Details of off-site emergency contacts 7.48
8.1 Budget Allocation for Various CER Activities 8.2
10.1 Environmental management plan 10.2
10.2 Details of plant species 10.7
10.3 Budget Allocation for Greenbelt Development 10.8
10.4 Photographs of Greenbelt Development 10.8
10.5 Environmental Budget Allocation 10.13
LIST OF FIGURES
FIGURE PAGE
TITLE
NO. NO.
2.1 Site Photographs 2.3
2.2 Location Map of Project Site 2.4
2.3 Layout Plan 2.15
2.4 Water Balance Diagram 2.27
2.5 Schematic Flow Diagram of ETP 2.30
3.1 Map of Study Area showing Impact Zone Distribution and Sampling & 3.5
Monitoring Locations
3.2 Seismic Zone Mapping of Gujarat State 3.8
3.3 Satellite Image of the Study Area 3.10
3.4 Land use / Land Cover Map of the Study Area 3.11
Table of Contents
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Deepak Nitrite Ltd., GIDC-Nandesari
Environmental Impact Assessment Report
Proposed Expansion for Manufacturing of Synthetic Organic Chemicals
FIGURE PAGE
TITLE
NO. NO.
3.5 Wind Rose Diagram 3.16
3.6 Status of PM10 Concentration in Ambient Air 3.18
3.7 Status of PM2.5 Concentration in Ambient Air 3.19
3.8 Status of SO2 Concentration in Ambient Air 3.19
3.9 Status of NO2 Concentration in Ambient Air 3.20
3.10 Status of NH3 Concentration in Ambient Air 3.20
3.11 Status of Cl2 Concentration in Ambient Air 3.21
3.12 Status of HCl Concentration in Ambient Air 3.21
3.13 Status of VOC Concentration in Ambient Air 3.22
3.14 Map of Study Area Showing Population Distribution 3.42
3.14 Map of Study Area showing population literacy rate 3.43
3.15 Map of Study Area showing workers distribution 3.44
4.1 Contour plot showing highest Incremental GLC for PM10 4.23
4.2 Contour plot showing highest Incremental GLC for SO2 4.24
4.3 Contour plot showing highest Incremental GLC for NOx 4.25
4.4 Contour plot showing highest Incremental GLC for NO3 4.26
4.5 Contour plot showing highest Incremental GLC for HCl 4.27
4.6 Contour plot showing highest Incremental GLC for H2S 4.28
6.1 Environmental Management Cell 6.4
7.1 Identification of hazardous areas 7.9
7.2 Risk Assessment Methodology 7.21
7.3 Accidental release of chemical 7.23
7.4 Toxic Threat zone of all chemicals 7.26
7.5 Flammable Threat Zone of all chemicals 7.27
7.6 Threat zone of catastrophic rupture of all chemicals 7.27
7.7 Hierarchy of the emergency team 7.41
8.1 Possible Beneficial Impacts due to Proposed Project 8.6
10.1 Tentative Greenbelt area development 10.9
11.1 Key Infrastructure Map of the Study Area 11.7
Table of Contents
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Deepak Nitrite Ltd., GIDC-Nandesari
Environmental Impact Assessment Report
Proposed Expansion for Manufacturing of Synthetic Organic Chemicals
LIST OF ANNEXURES
ANNEXURE PAGE
TITLE
NO. NO.
Table of Contents
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Deepak Nitrite Ltd., GIDC-Nandesari
Environmental Impact Assessment Report
Proposed Expansion for Manufacturing of Synthetic Organic Chemicals
ANNEXURE PAGE
TITLE
NO. NO.
28. Basic amenities in the study area A-380
29. EHS Policy A-386
30. List of SOPs for EHS A387
31. Characteristic of Hazardous Chemicals A-390
32. MCA Analysis A-397
33. Checklist for Safety Compliance A-486
34. CER Activities A-521
35. CSR Activities of Group A-523
36. Do’s & Don’ts A-527
Table of Contents
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Deepak Nitrite Ltd., GIDC-Nandesari
Environmental Impact Assessment Report
Proposed Expansion for Manufacturing of Synthetic Organic Chemicals
LIST OF ABBREVIATIONS
AAQM : Ambient Air Quality Monitoring
APHA : American Public Health Association
APCM : Air Pollution Control Measure
APTI : Air Pollution Tolerance Index
BDL : Below Detectable Limit
CP : Cleaner Production
CPCB : Central Pollution Control Board
CHWIF : Common Hazardous Waste & Incineration facility
CSR : Corporate Social Responsibility
EAC : Expert Appraisal Committee
EIA : Environmental Impact Assessment
EC : Environment Clearance
EHS : Environment, Health & Safety
EMP : Environment Management Plan
EMS : Environment Management System
EPA : Environmental Protection Act
ETP : Effluent Treatment Plant
DMP : Disaster Management Plan
GLC : Ground Level Concentration
GOI : Government of India
GPCB : Gujarat Pollution Control Board
HAZOP : Hazard & Operability Study
IMD : Indian Metrological Data
IS : Indian Standard
ISCST : Industrial Source Complex Short term
ISO : International Standard Organization
LOC : Level of concern
MOC : Material Of Construction
MoEF : Ministry of Environment & Forest
MSL : Mean Sea Level
MSDS : Material Safety Data Sheets
NH : National Highway
Table of Contents
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Deepak Nitrite Ltd., GIDC-Nandesari
Environmental Impact Assessment Report
Proposed Expansion for Manufacturing of Synthetic Organic Chemicals
Table of Contents
Page | xxiv
COPY OF TOR ISSUED BY
SEIAA, GUJARAT
TOR COMPLIANCE
Deepak Nitrite Ltd., GIDC-Nandesari
Environmental Impact Assessment Report
Proposed Expansion for Manufacturing of Synthetic Organic Chemicals
5. Details with respect to justification for The unit is established on land admeasuring
proposed expansion (1) To address total area of 1,10,600 m2 in Nandesari GIDC
proportionate availability of space for estate. The proposed expansion will be
production plant. (2) To address carried out in 29,031 m2 of undeveloped
proportionate availability of storage area land as well as vertical expansion in 33,999
TOR
TOR Points Compliance Status
No.
for raw materials, finished goods, utilities m2 area within the existing premises. Total
and goods carrier movement within built-up area of the process plant will
premises. (3) To address proportionate increase from 36,897 m2 to 70,896 m2 after
captive/common infrastructure available to expansion.
accommodate additional load due to
proposed expansion. (4) Environment Details of adequacy for proportionate
impact and its mitigation measures for availability of land is elaborated in Section
common/ captive infrastructure due to 2.9.1, Chapter 2.
proposed production.
B GENERIC TOR
1. A tabular chart with index for point-wise Prefix to the EIA report.
compliance of below mentioned TORs.
2. Executive summary of the project – giving Refer Chapter 11 – Summary and
a prima facie idea of the objectives of the conclusion which is brief compilation of EIA
proposal, use of resources, justification, report with its important aspects.
etc. In addition, it should provide a
compilation of EIA report, including EMP
and the post-project monitoring plan in
brief.
3. Justification for selecting the proposed Proposed products being manufactured by
product and unit size. Deepak Nitrite Ltd. are widely used in
pharmaceuticals, specialty chemicals and
food industries. Also, proposed expansion
project will be setup in existing unit located
in notified industrial estate of GIDC-
Nandesari. For details, refer Section 2.2, 2.4
& 2.5 of Chapter 2.
4. Land requirement for the project including The unit is established on land admeasuring
its break up for various purposes, its total area of 1,10,600 m2 in Nandesari GIDC
availability and optimization. estate. The proposed expansion will be
carried out in 29,031 m2 of undeveloped
land as well as vertical expansion in 33,999
m2 area within the existing premises. Total
built-up area of the process plant will
increase from 36,897 m2 to 70,896 m2 after
expansion.
5. Land possession documents. Copy of NA The existing plant is located at Plot No.
order showing permission to use the 4/12, Chemical Complex, GIDC-Nandesari
project land for industrial purpose. If in Vadodara District of Gujarat State. Plot
located in GIDC, copy of plot holding allotment from GIDC is attached as
certificate obtained from GIDC Authority. Annexure 7.
TOR
TOR Points Compliance Status
No.
6. Location of the project site and nearest The project site is located in the notified
habitats with distances from the project industrial area and surrounded by industrial
site to be demarcated on a toposheet (1: units in all the directions. The nearest
50000 scale). human settlement from the site is Dadheda
village located at distance of 690 m from the
project site. Details of the same are given in
Section 3.2.1, Table 3.1, Chapter 3.
7. Topography details of the project area. Topographical details of the project area are
given in Section 3.3, Chapter 3.
9. In case of project located outside notified Not applicable. It is an existing unit located
area: Legal Undertaking stating that unit is in notified industrial estate of GIDC-
complying the three conditions [i.e. water Nandesari.
consumption less than 25 M3/day; Fuel
consumption less than 25 TPD; and not
covered in the category of MAH units as
per the Management, Storage, Import of
Hazardous Chemical Rules (MSIHC
Rules), 1989] as per the amendment to
EIA Notification, 2006 vide SO 1599 (E)
dated 25/06/2014.
10. Present land use pattern of the study area Out of study area, 65.67% of total land area
shall be given based on satellite imagery. is occupied by agricultural fields like crop
lands and fallow lands. Total area of 16.68
% is covered as a built-up land, of which
land cover of 7.90% is for the industrial
purposes, 4.37% as human settlement.
Waste land covers 14.58% and about
3.07% of land is occupied as water body of
total study area.
11. Layout plan of the factory premises clearly Layout plan of the factory premise is given
demarcating various units within the plant. in Chapter 2, Section 2.9.1, Figure 2.3. It is
Provision of separate entry & exit and enclosed in Annexure 7 of the EIA report.
adequate margin all-round the periphery
for unobstructed easy movement of the
emergency vehicle / fire tenders without
reversing back. Mark the same in the
TOR
TOR Points Compliance Status
No.
plant layout.
12. Technical details of the plant/s along with Technical details of the plant are given in
details on best available technologies Section 2.5 to 2.11, Chapter 2.
(BAT), proposed technology and reasons
for selecting the same. Details of the selected technologies and
reason for selecting best available
technologies are given in Chapter 5
13. Product spectrum (Proposed products Refer Section 2.5, Table 2.2 (a) & (b) of
along with production Capacity) and Chapter 2 for details of products along with
processes. production capacities.
14. Chemical name of each proposed product Chemical names of each products along
to be manufactured. Details on end use of with CAS no and end-use of each is given in
each product. (Provide CAS number of all Section 2.5, Table 2.2 of Chapter 2.
the products & raw materials. In case of
Dyes, CI number).
15. Details on raw materials, source and Refer Section 2.8, Chapter 2, Annexure 4,
storage within the premises Annexure 6 of EIA report for details of raw
material requirement, its storage, handling
and source.
17. Details on strategy for the implementation Refer Chapter 10, Section 10.5 for
of cleaner production activities. implementation of cleaner production
activities.
18. Assessment of source of the water supply Presently, the water requirement of the unit
with adequacy of the same to meet with is met by GIDC supply and the same source
TOR
TOR Points Compliance Status
No.
the requirements for the project. will be utilized for proposed expansion. The
Permission obtained from the concern total fresh water requirement for the existing
authority for supply of raw water. plant is 3,256 KLD which will increase up to
3,500 KLD after proposed expansion. For
details refer Section 2.9.5, Chapter 2.
19. Undertaking stating that no bore well shall Undertaking for no borewell is attached as
be dug within the premises (If project is Annexure 5.
located within the Industrial estate).
20. Details on water balance including After proposed expansion, total effluent
quantity of effluent generated, recycled & generation will increase from 1,151 KLD to
reused. 2,156 KLD. Effluent will be segregated into
high COD/TDS and low COD/TDS stream.
Details of methods to be adopted for the Details on Water conservation are given in
water conservation. Section 10.5.2, Chapter 10.
21. Efforts to minimize effluent discharge and There will not be any additional discharge
to maintain quality of receiving water into CETP from the propose expansion
body. project. Unit will maintain zero liquid
TOR
TOR Points Compliance Status
No.
22. Explore the possibilities for Zero Liquid discharge for proposed expansion project.
Discharge (ZLD) option for the proposed For details refer Section 2.11.1, Chapter 2.
project.
TOR
TOR Points Compliance Status
No.
CF
v. Copies of XGN generated Inspection
reports with analysis reports of the
water/Air/Hazardous samples
collected by GPCB (Last 2 year).
Copies of instructions issued by
GPCB in last 2 year and point wise
compliance thereof.
vi. Copies of Show-cause notices,
closure notices etc. served by the
GPCB and its compliance
vii. Recommendations and suggestions
of the last two Environment Audit
reports of CETP and its compliance
report.
viii. Common Facility Up gradation
scheme, if any.
27. In case of Zero Liquid Discharge (ZLD): Not Applicable.
TOR
TOR Points Compliance Status
No.
adequacy of the proposed boiler to supply
steam for evaporation in addition to the
steam required for the process etc.
Techno economic viability of the
evaporation system. Control measures
proposed for the evaporation system in
order to avoid/reduce gaseous
emission/VOC from evaporation of
industrial effluent containing solvents &
other chemicals.
30. Details of the treatability and feasibility of Not Applicable. Unit will not use spray dryer
wastewater to be disposed off by means for effluent treatment.
of spray dryer and its impact on
environment and Human Health
31. Undertaking stating that a separate Unit will provide separate electric meter for
electric meter will be provided for the ETP & Evaporator. Undertaking for the
waste water treatment system viz. ETP, same is enclosed in Annexure 5.
RO, MEE, Spray dryer etc. (Whichever is
applicable)
32. Economical and technical viability of the Refer Section 2.11.1.2 of Chapter 2, for
effluent treatment system economic and technical viability of effluent
treatment system.
33. Plans for management, collection and Refer Chapter 2, Section 2.11.1 and 2.11.3
disposal of waste streams to be generated for management of disposal of waste
from spillage, leakages, vessel washing, streams generated.
used container washing etc.
Measures proposed for preventing effluent Refer Chapter 10, Section 10.3
discharge during unforeseen
circumstances.
34. Action plan for reuse of waste streams like Refer Table 2.22, Section 2.11.3, Chapter 2
Spent acids, Poly Aluminium Chloride etc.
within premises to convert into valuable
products instead of sending outside to
actual end-users.
35. Adequacy of the proposed EMS with Adequacy report of the proposed EMS is
respect to pollution load envisaged in enclosed as Annexure 10.
terms of Air, Water and hazardous waste.
TOR
TOR Points Compliance Status
No.
36. One season Site-specific micro- The site-specific micrometeorological data
meteorological data using temperature, has been collected continuously during the
relative humidity, hourly wind speed and study period by installing automatic
direction and rainfall should be weather station near project site. For
incorporated. details refer Section 3.3.5 of Chapter 3.
38. One complete season base line ambient Ambient air quality has been conducted at 5
air quality data (except monsoon season) locations including project site (1 in upwind,
to be given along with the dates of 2 in downwind and 1 in cross wind
monitoring. The parameters to be covered directions) on consideration of pre-dominant
shall be in accordance with the revised wind direction. For details refer Table 3.6,
National Ambient Air Quality Standards Figure 3.6 to 3.13 in Section 3.3.6 of
(NAAQS) as well as project specific Chapter 3.
parameters like NH3, HCl, CL2, HBr, VOC
etc. Locations of the monitoring stations
should be so decided so as to take into
consideration the pre-dominant downwind
direction, population zone and sensitive
receptors. There should be at least one
monitoring station in the upwind direction.
There should be at least one monitoring
station in the pre dominant downwind
direction at a location where maximum
ground level concentration is likely to
occur.
39. Modeling indicating the likely impact on The maximum 24-hourly average ground
ambient air quality due to proposed level concentration for pollutant due to
activities. The details of model used and proposed project calculated using
input parameters used for modeling mathematical model (ISCST3) PM10, SO2,
should be provided. The air quality NO2, NH3, HCl and H2S are 2.452 Pg/m3,
contours may be shown on location map 4.481 Pg/m3, 0.810 Pg/m3, 1.045 Pg/m3 ,
clearly indicating the location of sensitive 0.299 Pg/m3 and 0.274 Pg/m3 respectively
TOR
TOR Points Compliance Status
No.
receptors, if any, and the habitation. The which is negligible even for the worst-case
wind rose showing pre-dominant wind scenario. Moreover, this will occur at a
direction should also be indicated on the distance of maximum 100 meters from the
map. Impact due to vehicular movement source, which falls within the GIDC
shall also be included into the prediction industrial estate only where there is no
using suitable model. Results of Air existence of permanent habitat. For details,
dispersion modeling should be refer Chapter 4, Section 4.5.1.
superimposed on satellite Image /
geographical area map.
40. Base line status of the noise environment, Noise level monitoring was carried out at 5
impact of noise on present environment locations on 24 hourly bases during study
due to the project and proposed measures period. For details refer Table 3.11 & 3.12 in
for noise reduction including engineering Section 3.3.9 of Chapter 3.
controls.
For details on proposed measures for noise
reduction refer Section 4.5 Chapter 4.
42. Provision of CEMS (Continuous Emission Unit has provided online continuous
Monitoring System) emission monitoring system for steam
boiler. Refer Section 6.3, Chapter 6.
43. Action plan for odour control to be Refer Section 4.5 of Chapter 4
submitted.
TOR
TOR Points Compliance Status
No.
Movement) Rules 2016. CPCB guidelines Section 2.11.3 of Chapter 2.
in respect of specific treatment, such as
solar evaporation, incineration, etc., need
to be followed.
45. How the manual handling of the Refer Section 2.11.3 of Chapter 2, to avoid
hazardous wastes will be minimized. manual handling of hazardous waste.
46. Management of by-products which fall There will not be any generation of by-
under the purview of Hazardous and product from the existing as well as
Other Wastes (Management and proposed expansion project which falls
Transboundary Movement) Rules 2016 as under Hazardous and Other Wastes
per the said rules and necessary (Management & Transboundary Movement)
permissions from the concern authority. Rules, 2016.
47. Membership of Common Environmental Unit has obtained membership from BEIL
Infrastructure like TSDF, Common for disposal of hazardous waste. Copy of
Incineration Facility (CHWIF) etc. membership and LOI from Common
Environment Infrastructure for disposal of
additional hazardous waste is enclosed as
Annexure 13.
48. Name and quantity of each type of Unit will require various solvents for
solvents to be used for proposed manufacturing of various products. There
production. Details of in-house solvent will be generation of spent / mix solvent
recovery system including mass balance, during the manufacturing process. It will be
solvent loss, recovery efficiency (% separated and sent for offsite distillation to
recovery), feasibility of reusing the authorized recyclers or sold to authorized
recovered solvents etc. for each type of end-users having permission under rule 9 of
solvent. “Hazardous and Other Wastes
(Management & Transboundary Movement)
Rules, 2016. Details of solvent requirement
and spent/mix solvent generation are given
in Table 2.4, Section 2.7, Chapter 2.
TOR
TOR Points Compliance Status
No.
for implementation and monitoring of Chapter 6, Section 6.5, Figure 6.1, Table
EMP. 6.2
The EMP should also include the concept Chapter 10, Section 10.5
of waste minimization,
recycle/reuse/recover techniques, energy
conservation, and natural resource
conservation.
Total capital cost and recurring Chapter 10, Section 10.6, Table 10.5
cost/annum earmarked for environment
pollution control measures.
51. Details of in-house monitoring capabilities For details, refer Table 6.1. in refer Section
and the recognized agencies if proposed 6.2 of Chapter 6
for conducting monitoring
52. Permission from PESO, Nagpur for Unit has obtained license from PESO for
storage of solvents, other toxic chemicals, onsite storage of Hydrogen Gas, Chlorine
if any. Gas, NH3 gas, SO2 gas and various
chemicals under Petroleum Class A, B & C
under the Petroleum Act, 1934 and Static &
Mobile Pressure Vessel (U) Rules, 1981.
Copies of licenses obtained from PESO are
enclosed as Annexure 14. Unit will obtain
license for other hazardous chemicals as
listed in Table 7.2, Section 7.3.1, Chapter 7
before commissioning of the expansion.
53. Occupational health impacts on the Details on occupational health hazard from
workers and mitigation measures proposed expansion is given in Section 7.4
proposed to avoid the human health of Chapter 7.
hazards along with the personal protective
equipment to be provided. Provision of
industrial hygienist and monitoring of the
occupational injury to workers as well as For details refer Section 7.4 & 7.5, Chapter
impact on the workers. Plan for periodic 7
medical checkup of the workers exposed.
Details of work place ambient air quality
monitoring plan as per Gujarat Factories
Rules.
54. Details on volatile organic compounds Details on occupational health hazard from
(VOCs) from the plant operations and proposed expansion is given in Section 7.4
occupational safety and health protection of Chapter 7.
measures. Proposal for Leak Detection
and Repair (LDAR) program as per the Refer Table 6.1. in refer Section 6.2,
TOR
TOR Points Compliance Status
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CPCB guidelines. Section 6.3 of Chapter 6 for LDAR program
55. Risk assessment including prediction of Detailed risk assessment study is carried
the worst-case scenario and maximum out based on worst case maximum credible
credible accident scenarios should be accident scenarios. For details, refer
carried out. The worst-case scenario Section 7.6.3 of Chapter 7. Refer Annexure
should take into account the maximum 32 for details of MCA.
inventory of storage at site at any point of
time. The risk contours should be plotted
on the plant layout map clearly showing
which of the facilities would be affected in
case of an accident taking place.
Based on the same, proposed safeguard Refer Section 7.8 & 7.9 of Chapter 7 for
measures including On-Site / Off-Site details on on-site / off-site emergency plan.
Emergency Plan should be provided.
56. MSDS of all the products and raw Refer Part 3 of EIA report for MSDS of all
materials. products and raw materials.
58. Details of quantity of each hazardous For details on storage and handling of
chemical (including solvents) to be stored, hazardous chemicals refer Table 7.1 in
Material of Construction (MoC) of major Section 7.3.1 of Chapter 7.
hazardous chemical storage tanks, dyke
details, threshold storage quantity as per
schedules of the Manufacture, Storage &
Import of Hazardous Chemicals Rules of Refer Section 7.3 of Chapter 7 for details to
major hazardous chemicals, size of the avoid manual handling of hazardous
biggest storage tank to be provided for chemicals.
each raw material & product etc. How the
manual handling of the hazardous
chemicals will be minimized?
59. Details of the separate isolated storage Refer Figure 7.1, Section 7.3.1, Chapter 7
area for flammable chemicals. Details of for details on separate isolated storage of
flame proof electrical fittings, DCP hazardous chemicals.
extinguishers and other safety measures
proposed. Detailed fire control plan for Refer section 7.7(I), Chapter 7 for details on
flammable substances and processes fire-fighting system.
showing hydrant pipeline network,
provision of DG Sets, fire pumps, jockey
TOR
TOR Points Compliance Status
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pump, toxic gas detectors etc.
60. Submit checklist in the form of Do’s & Refer Chapter 10, Section 10.7, Annexure
Don’ts of preventive maintenance, 36 for checklist in the form of Do’s and
strengthening of HSE, manufacturing Dont’s.
utility staff for safety related measures.
61. Specify safety precautions to be taken Refer Chapter 7, Section 7.3.1 for specific
for Chemical storage, process, handling safety precautions for storage and handling
& transportation hazard. of hazardous chemicals as well as safety
precautions for manufacturing process and
allied operations.
62. Details on workers training before Refer Section 7.8.1 (A), Chapter 7 for
engaging work, periodical in-house, details on workers training.
outside etc.
63. Details of various SOPs to be prepared. The list of various SOPs to be prepared is
given in Section 6.4, Annexure 30, Chapter
6.
64. Details on safety audit to be carried out Safety audit is carried out annually by the
and their compliance status. unit. Refer Table 7.2 in section 7.5 of
Chapter 7.
65. Specific safety measures to be taken for Specific safety measures to be taken for
general Public living in the vicinity. general public are given in Section 7.8.1
(N), Chapter 7.
67. Detection and monitoring of VOC’s / Refer Section 7.5, Table 7.3 of Chapter 7.
gases.
68. Detailed five-year greenbelt development To maintain the ecological balance, unit has
program including annual budget, developed green belt in area of 28,724 m2
planning schedule, species, width of which will be expanded up to 36,500 m2
plantations, number of trees to be planted, (33% of total plot area) within the project
area under green belt development [with premises.
map], budgetary outlay etc. along with
commitment of the management to carry The unit will plant about additional 400 trees
out the tree plantation activities outside will be within one year from commissioning
the premises at appropriate places in the of the plant.
nearby areas and elsewhere.
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69. Action plan for the greenbelt development For details refer Chapter 10, Section 10.4.
– species, width of plantations, planning
schedule, etc., in accordance to CPCB
published guidelines.
71. (a) Does the company have a well laid Chapter 6, Section 6.4, 6.5
down Environment Policy approved by its
Board of Directors? If so, it may be
detailed in the EIA report. (b). Does the
Environment Policy prescribe for standard
operating process / procedures to bring
into focus any infringement / deviation /
violation of the environmental or forest
norms / conditions? If so, it may be
detailed in the EIA.
72. What is the hierarchical system or Refer Section 6.4 – 6.5 of Chapter 6, for
administrative order of the company to details of Environmental management cell.
deal with the environmental issues and for
ensuring compliance with the EC
conditions. Details of this system may be
given.
73. Does the company have a system of Refer Section 6.5 – 6.6 of Chapter 6
reporting of non-compliances / violations
of environmental norms to the Board of
Directors of the company and / or
shareholders or stakeholders at large?
This reporting mechanism should be
detailed in the EIA Report.
TOR
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No.
75. Certificate of accreditation issued by the Refer Chapter 12
NABET, QCI to the environmental
consultant should be incorporated in the
EIA Report.
80. In case of Expansion of the project: Refer section 2.12 & 2.13, Chapter 2 for
regulatory framework and compliance of the
existing unit.
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then after for prevention of pollution. point-wise compliance of these instructions
to GPCB in timely manner. Copies of the
inspection report generated from GPCB-
XGN are enclosed in Annexure 22.
f) Environmental audit reports for last 3 Environmental audit of the unit is carried out
years and compliance of its annually by GPCB appointed Schedule-II
recommendations/Suggestions. auditors. Acknowledgement copy of
(Include latest audit report and its submission of last environmental audit
compliance.) report for the period of April 2018 to March
2019 is enclosed as Annexure 21.
TOR
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No.
11013/5/2010-IA.II (I) dated
25/11/2016 regarding lifting of
moratorium on the consideration of
projects for environmental clearance.
(B) Compliance of direction under section
18 (1) (b) of the Water (Prevention and
Control of Pollution) act, 1974 issued
by CPCB dated 31/03/2016 regarding
compliance of CETP.
a) Action initiated by GPCB, if any,
against proposed unit regarding non-
compliance of prescribed standards
under the various environmental laws.
b) Performance of CETP with respect to
current hydraulic load & prescribed
standards with No Objection
Certificate of CETP regarding
incorporation of the proposed unit for
acceptance of waste water.
c) Performance of TSDF site with
respect to current load & prescribed
standards with No Objection
Certificate of TSDF site regarding
incorporation of the proposed unit for
acceptance of hazardous waste to the
common infrastructure.
d) Copies of quarterly action report
taken for the above points submitted
to the CPCB.
e) Report of GPCB which have
conducted monitoring as per the said
direction by CPCB dated 31/03/2016.
INTRODUCTION
Deepak Nitrite Ltd., GIDC-Nandesari
Environmental Impact Assessment Report
Proposed Expansion for Manufacturing of Synthetic Organic Chemicals
CHAPTER – 1 INTRODUCTION
1.1 PREFACE
The report is an Environmental Impact Assessment (EIA) report for the proposed
expansion in manufacturing of existing inorganic chemicals & synthetic organic
chemicals and addition of various other synthetic organic chemicals by M/s. Deepak
Nitrite Ltd. The aim of EIA study is to assess the impacts of proposed industrial activity
on environment for planning suitable mitigation measures and to capitalize on beneficial
impacts of proposed project.
The unit has obtained Environmental Clearance (EC) from State Level Environment
Impact Assessment Authority (SEIAA), Gujarat for their existing plant on 12/09/2012.
Presently, unit holds Consolidated Consent & Authorization (CC&A) issued by GPCB
vide order no. AWH-87712 dated 29/05/2017 which is valid up to 31/03/2024.
Now, the unit proposes to expand manufacturing of some of the existing inorganic
chemicals up to 45,880 TPM and synthetic organic chemicals up to 22,004 TPM. In
addition to this, unit proposes to manufacture various other synthetic organic chemicals
with production capacity of 510 TPM. Thus, total production capacity of the unit will be
68,394 TPM after proposed expansion. Also, unit proposes to expand Captive Power
Plant (Gas based Generator Set) capacity up to 10 MW. The proposed project is
covered under Category 5(f)-B as per new EIA Notification of Ministry of Environment,
Forest & Climate Change (MoEF&CC), dated 14/09/2006 and subsequent
amendments. Therefore, unit requires obtaining Environmental Clearance from State
Impact Assessment Authority (SEIAA).
Hence, the unit had applied for prior Environmental Clearance (ToR) to State Level
Expert Appraisal Committee (SEAC), Gujarat on 07/09/2018. ToR has been issued by
State Level Environment Impact Assessment Authority (SEIAA) vide letter no. SEIAA/
[[
Chapter-1: Introduction
Page | 1.1
Deepak Nitrite Ltd., GIDC-Nandesari
Environmental Impact Assessment Report
Proposed Expansion for Manufacturing of Synthetic Organic Chemicals
Chapter-1: Introduction
Page | 1.2
Deepak Nitrite Ltd., GIDC-Nandesari
Environmental Impact Assessment Report
Proposed Expansion for Manufacturing of Synthetic Organic Chemicals
Thus, by using EIA tool both environmental and economic benefits can be achieved,
such as reduced cost & time of project design & implementation, avoided
treatment/clean-up costs, impacts of laws and regulations, etc.
Chapter-1: Introduction
Page | 1.3
Deepak Nitrite Ltd., GIDC-Nandesari
Environmental Impact Assessment Report
Proposed Expansion for Manufacturing of Synthetic Organic Chemicals
9 To assess the prevailing environmental status within the study area around the
project site.
9 To evaluate performance of the existing plant with respect to compliance of existing
environmental statutes & consents.
9 To critically analyze the various activity of the proposed project and identify potential
source of environmental pollution.
9 To identify and assess significant impacts of proposed project on environmental
components through matrix method.
9 To suggest preventive and mitigation measures to minimize or avoid the adverse
impacts on the environment and to maximize the beneficial impacts.
9 To prepare Environmental Management Plan (EMP) and delineate post-project
environmental monitoring program to be pursued by the industries.
9 To prepare an EIA Study report and utilize it for applicable statutory clearances for
proposed project and/or any other management purpose.
Thus, the present EIA study will help the proponent in their planning of effective control
measures to avoid or minimize the likely adverse impacts on environment due to their
proposed project activities.
The present report of the EIA study for the proposed unit for the manufacturing of
synthetic organic chemicals has been prepared as per the structure given in Table 1.2.
[[
Chapter-1: Introduction
Page | 1.4
Deepak Nitrite Ltd., GIDC-Nandesari
Environmental Impact Assessment Report
Proposed Expansion for Manufacturing of Synthetic Organic Chemicals
[[
Chapter-1: Introduction
Page | 1.5
Deepak Nitrite Ltd., GIDC-Nandesari
Environmental Impact Assessment Report
Proposed Expansion for Manufacturing of Synthetic Organic Chemicals
Sr.
EIA Structure Contents
No.
7. Additional Studies Risk and Safety Management
o Hazard Identification
o Details of hazardous chemicals and Safety
measures for transportation, loading/unloading,
Storage/handling etc.
o Safety measures for the manufacturing process
and allied operations
o Occupational Health & Safety Management
o Monitoring program for EHS
o Risk assessment study and mitigation measures
o Fire fighting system and emergency
management
o Onsite / Offsite Emergency Plan
8. Project Benefits Employment opportunity and Corporate
environmental responsibility (CER)
Socio-economic development and Improvements
in the physical & social infrastructure
Employment & Other tangible benefits
9. Environmental Cost If suggested, at the scoping stage (Not applicable
Benefit Analysis in this case)
10. Environmental Environmental Management Plan for various
Management Plan project Activities
Illustration of greenbelt development plan and
application of cleaner production technology
Budgetary allocation for environment protection
11. Summary & Salient features of the project covering project
Conclusion description, location, mitigation measures, costing
etc.
Overall conclusion for the proposed project
12. Disclosure of Details of the EIA consultants, experts &
Consultants Engaged Laboratory engaged.
[[
Chapter-1: Introduction
Page | 1.6
CHAPTER 2
PROJECT
DESCRIPTION
Deepak Nitrite Ltd., GIDC-Nandesari
Environmental Impact Assessment Report
Proposed Expansion for Manufacturing of Synthetic Organic Chemicals
2.1 BACKGROUND
M/s. Deepak Nitrite Ltd., a responsible care logo holding company, has an existing unit
located at Plot No. 4/12, Chemical Complex at Nandesari notified industrial estate of
GIDC in Vadodara District of Gujarat State and involved in manufacturing of various
inorganic chemicals @ 17,480 TPM, synthetic organic chemicals @ 8,406 TPM and
Captive Power Plant (Gas based Generator Set) of 4.8 MW capacity.
The unit has obtained Environmental Clearance (EC) from State Level Environment
Impact Assessment Authority (SEIAA), Gujarat for their existing plant on 12/09/2012.
Copy of EC letter is enclosed as Annexure 1. Presently, unit holds Consolidated
Consent & Authorization (CC&A) issued by GPCB vide order no. AWH-87712 dated
29/05/2017 which is valid up to 31/03/2024. Copy of CC&A is enclosed as Annexure 2.
Now, the unit proposes to expand manufacturing of some of the existing inorganic
chemicals up to 45,880 TPM and synthetic organic chemicals up to 22,004 TPM. In
addition to this, unit proposes to manufacture various other synthetic organic chemicals
with production capacity of 510 TPM. Thus, total production capacity of the unit will be
68,394 TPM after proposed expansion. Also, unit proposes to expand Captive Power
Plant (Gas based Generator Set) capacity up to 10 MW. The proposed project is
covered under Category 5(f)-B as per new EIA Notification of Ministry of Environment,
Forest & Climate Change (MoEF&CC), dated 14/09/2006 and subsequent
amendments. Therefore, unit requires obtaining Environmental Clearance from State
Impact Assessment Authority (SEIAA).
The Nitrite division at Nandesari in Gujarat is India's largest producer of Sodium Nitrite
and Sodium Nitrate, manufactured by the ammonia oxidation process. Sodium Nitrite is
marketed as a merchant product and also constitutes the basic building block for value-
added products. The Sodium Nitrate is mainly used by the Glass industry.
Based on informal survey of the market with potential customers and various trades, the
company has found there is a huge demand in the pharmaceuticals, specialty chemicals
and food industries for range of proposed products to be manufactured. Also, some of
the products will be used captively in manufacturing of various chemicals at other group
units located across India.
Site photograph of the existing plant are given in Figure 2.1. Location map of the
project site is given in Figure 2.2. The salient features of the projects are described in
Table 2.1.
Main Gate
Prod. Capacity,
Name of Products
Code. TPM
E19 Derivatives of Resorcinol-1,3 CHD, 4 HC OR Alkyl Phenol 30
E20 Alkyl Phenols 50
E21 Resorcinol OR Alkyl Phenols 20
E22 Para Nitro Toluene Sulphonic Acid (Pntosa) OR Lubricity Improvers 400
E23 Lubricity Improvers -
E24 Mono Chloro Benzene (MCB) OR Dichloro Benzene 1,200
E25 Di Chloro Benzene (DCB) 180
E26 Nitro Chloro Benzene (NCB) Or 2 Ethyl Hexyl Nitrate 1,200
E27 2 Ethyl Hexyl Nitrate (EHN) 600
E28 Nitro Toluene (NT) 1,700
E29 Nitro Ortho Xylene/ Nitro Meta Xylene OR 2 Ethyl Hexyl Nitrate 720
E30 Nitro Cumene Or 2 Ethyl Hexyl Nitrate 600
E31 Nitro Cresol Formulation 12
E32 Toluidene OR
E33 Xylidene OR
1,000
E34 Cumidine OR
E35 Dichloro Aniline
E36 Di-Butyl Para Phenyl Diamine (DBPPDA) OR
100
E37 N-(1-Ethyl propyl)-3,4-Xylidine (4NAX)
E38 Methyl Chloro Propionate (MCP) 50
Total (E9 to E38) 8,406
Total (Exiting) 25,886
E39 Captive Power Plant (Gas Based Generator Set) 4.8 MW
Prod. Capacity,
Name of Products
Code. TPM
E13 Acetoxime 18
E14 Acetal Oxime 20
E15 Hydoxyl Amine Base (HA Base) 6
E16 Methyl ethyl ketoxime (MEKO) 20
E17 Ethoxyl Amine Base (EA base) 30
E18 SMIA (2 Methoxyimino-2 Furyle Acetic acid Ammonium salt) 30
E19 Derivatives of Resorcinol-1,3 CHD, 4 HC 30
E20 Alkyl Phenols 100
E21 Resorcinol 20
E22 Para Nitro Toluene Sulphonic acid (PNToSA) 400
E23 Lubricity Improvers 1,000
E24 Mono Chloro benzene (MCB) 1,200
E25 Di chloro benzene (DCB) 1,230
E26 Nitro Chloro Benzene (NCB) 1,200
E27 2 Ethyl Hexyl Nitrate (EHN) 3,120
E28 Nitro Toluene (NT) 5,000
E29 Nitro Xylene (ortho, meta, para) 1,000
E30 Nitro Cumene 600
E31 *Nitro Cresol Intermediate 2,000
E32 Toluidene 1,000
E33 Xylidene 1,000
E34 Cumidine 1,000
E35 Dichloro Aniline 1,000
E36 Di-butyl Para Phenyl Diamine (DBPPDA) 100
E37 N-(1-Ethyl propyl)-3,4-Xylidine (4NAX) 100
E38 Methyl chloro propionate (MCP) 50
Total (E9 to E38) 22,004
Total (after proposed expansion) 67,884
E39 Captive Power Plant (Gas based generator Set) 10 MW
*Generated along with Nitro Toluene
ª Proposed Products
[Synthetic Organic Chemicals (Sr. No. P1 to P26) – EC applicable]
P1 6-Aminopurine (Adenine) &/OR 100
P2 3-Nitro Acetophenone (3NAP) &/OR
P3 3-Amino Acetophenone (3AAP) &/OR
P4 3-Hydroxy Acetophenone (3HAP) &/OR
P5 2,3-Xylenol &/OR
P6 2,4-Xylenol &/OR
P7 2,5-Xylenol &/OR
P8 Phenyl Hydrazine Base
P9 1,2,4 Triazinone (Metribuzin Intermediate) &/OR 100
P10 Dichloropinacolone &/OR
P11 Thiocarbohydrazide (TCH)
5-amino-3-cyano-1(2,6-dichloro-4-trifluromethylphenyl) pyrazole 100
P12
[Fipronil Intermediate]
Prod. Capacity,
Name of Products
Code. TPM
P13 Benzotrifluoride (BTF) &/OR 100
P14 3-Amino Benzotrifluoride (3-ABTF) &/OR
P15 3-(Trifluoromethyl)Acetophenone (TFMAP) &/OR
P16 m-Hydroxy Benzotrifluoride (MHBTF)
Dibenzo[b,f][1,4]thiazepine-11(10H)-one (DBTZ) [Quetiapine &/OR 100
P17
Intermediate]
P18 Guanine &/OR
P19 Aciclovir &/OR
P20 (R)-9-[2-Phosphonomethoxy) propyl]adenine (Tenofovir) [PMPA] &/OR
2-Chloromethyl-3,5-Dimethyl-4-methoxy pyridine hydrochloride &/OR
P21
(Omeprazole Chloro Int.)
P22 2,3,5-trimethyl-4-nitropyridine N-oxide (Omeprazole Nitro Int.) &/OR
P23 3-Ethyl Tryptophol (Etodolac Intermediate) &/OR
P24 S-Alcohol (Duloxetine Intermediate) &/OR
P25 2-Methyl-3-Amino Benzotrifluoride (MTA)
P26 R&D Products (Synthetic Organic Chemicals) 10
Total (Proposed: P1 to P26) 510
Grand total after proposed Expansion 68,394
P17 Dibenzo[b,f][1,4]thiazepine-11(10H)-one
3159-07-7 Pharma Intermediate
(DBTZ) [Quetiapine Intermediate]
P18 Guanine 73-40-5 Pharma Intermediate
Requirement Generation
Sr. Prod. Product Group as Spent
Name of Solvent Total,
No. Code. Wise, Max, Solvent,
TPM TPM
TPM TPM
P12 73.53 73.53
P15 129.69 129.69
P17 447.00
P21 314.00
484.29
P22 216.00
P24 484.29
IPA, DMF, Methanol, Toluene,
16 P20 2,419.00 2,419.00 2,419.00 3,031.00
MDC, Acetone
Acetic anhydride, Acetic Acid,
17 Methanol, Toluene, Ethyl P19 4,290.00 4,290.00 4,290.00 6,759.00
Acetate
Total (Max.) -- -- 23,379.39 24,505.50
2.8.2. Handling
All the raw materials, finished products and fuel are handled as per the standard
practice in the closed systems. Also, all the pipes and equipment are kept cleaned to
avoid any blockage and deposits. Pressure tests (leak tests) are carried out before
every startup. Hydro test of tank/ systems is carried out periodically. All the process and
storage equipment used for the handling of these chemicals are also maintained
properly to avoid any leakage or spillage of the chemical. Also, all storage tanks,
transfer lines, valves, fittings and every joint are inspected by third party periodically.
Drum trolley are used for safe handling and transfer of hazardous chemicals drums from
one place to another place in the plant area. The same practice will be kept continued
for the proposed expansion.
Coal is crushed in a crusher with dust extraction system and conveyed to boiler feeder
through covered belt conveyers in closed loop system. Water sprinkling is ensured to
avoid fugitive emission of coal dust.
Chapter-2: Project Description
Page | 2.12
Deepak Nitrite Ltd., GIDC-Nandesari
Environmental Impact Assessment Report
Proposed Expansion for Manufacturing of Synthetic Organic Chemicals
2.8.3. Storage
The unit has provided adequate and proper storage facilities for all the raw materials,
finished products and fuel. All the raw materials are stored in designated storage area in
tightly closed containers/tanks. The same practice will be adopted for the expansion
project also. Also, additional space of about 5,575 m2. for storage of chemicals will be
created by rented ware house facilities. Copy of agreement with rented warehouse is
enclosed as Annexure 5. Details of storage and handling of existing and proposed
products and raw materials like physical form, type of storage, size of storage
containment, maximum storage capacity, hazardous characteristic and threshold
storage quantity are given in Annexure 6. Coal is stored in isolated shed area having
RCC flooring and covered roof. The same practice will be adopted for the expansion
project also.
2.8.4. Transportation
Most of the raw materials required for the existing product are sourced locally, because
of the existence / development of the chemical industries and chemical markets at
Ankleshwar, Jhagadia and Dahej. Some of the raw materials will be transported through
pipeline supply from nearby industries. This reduces both the cost of raw material
transportation and the associated risk. Finished products are sold to domestic /
international market by convenient mode of transportation. The proposed expansion
products and raw materials transportation are in line with the existing one. Details of
transportation for each of the raw materials and products are given in Annexure 6.
2.9.1. Land
The unit is established on land admeasuring total area of 1,10,600 m2 in Nandesari
GIDC estate. Out of total land available, unit has developed greenbelt in 28,724 m2
area which will be expanded up to 36,500 m2 (33%) area within the existing premise.
The proposed expansion will be carried out in 29,031 m2 of undeveloped land as well
as vertical expansion in 33,999 m2 area within the existing premises. Total built-up area
of the process plant will increase from 36,897 m2 to 70,896 m2 after expansion. The
detailed break-up of the land is given in Table 2.5(a) and plant wise built up area break-up
in Table 2.5(b). Layout plan of the unit is given in Figure 2.3. Plot allotment along with
layout plan is attached as Annexure 7. Also, unit proposes to rent warehouse with
about 5,575 m2 area for additional storage of raw materials. Copy of rent agreement of
warehouse is enclosed as Annexure 5. Also, unit has developed greenbelt in 500 m2
area outside plant premises at Deepak Medical Foundation and in 500 m2 in nearby
villages.
1 Products E1 to E5 16,100 16,600 32,700 G+2 3,765.0 3,800.0 7,565.0 11,295.0 11,400.0 22,695.0
2 Products E7 to E18 1,324 9,710 11,034 G+3 2,686.0 3,297.0 5,983.0 8,058.0 9,891.0 17,949.0
Products E19, E21 to
3 450 1,000 1,450 G+3 275.5 -- 275.5 826.5 1,080.0 1,906.5
E23
4 Products E24, E25 1,380 1,050 2,430 G+3 734.0 285.0 1,019.0 2,936.0 1,140.0 4,076.0
Products E6, E26,
5 4,832 7,968 12,800 G+3 2,743.0 594.0 3,337.0 10,972.0 2,376.0 13,348.0
E28 to E31
6 Product E27 600 2,520 3,120 G+2 229.5 1,100.0 1,329.5 688.5 3,300.0 3,988.5
Product E20, E32 to
7 1,200 3,150 4,350 G+2 707.0 924.0 1,631.0 2,121.0 2,772.0 4,893.0
E38
Total Capacity (Existing) 25,886 41,998 67,884 -- 11,140.0 10,000.0 21,140.0 36,897.0 31,959.0 68,856.0
Total Capacity (Proposed) 25,886 510 510 -- -- 3,200.0 3,200.0 36,897.0 2,040.0 38,937.0
Grand Total 25,886 42,508 68,394 -- 11,140.0 13,200.0 24,340.0 36,897.0 33,999.0 70,896.0
MS 12 0.72 m2 to 210 m2
4 Condenser Graphite 16 3.8 m2 to 24.9 m2
SS304 3 3.9 m2,1 m2
Glass 4 4 m2
5 Nitrator SS316 L 4 460 L to 660 L
SS 50 2 m3/hr to 10 m3/hr
HL 2 2 m3/hr
6 Filter
MS 19 12 m3/hr, 15 m3/hr
PP recessed Plate 4 3 m3/hr
7 Dryer IS-226 2 440 Kg
IS-226 GRST 40 7 10 KL to 48 KL
MSGL 3 8 KL, 6.3 KL
8 Crystallizers
SS304 8 75 KL, 12 KL
MS 1 12 KL
9 Centrifuge SS316 6 7,000 kg/hr
Sr.
Item MOC/Type Qty. Size/Capacity
No
10 Cooling Tower -- 5 13,500 TR
ª Proposed
Glass lined 18 5 KL to 8 KL
MS 12 3 KL to 10 KL
1 Reactors
HDPE 2 3 KL, 5 KL
SS 28 1 KL to 18 KL
2 Distillation set SS/MS 8 8 KL, 12 KL
3 Absorption Column SS/MS 6 800 mm, 1,000 mm Dia.
4 Crystallizer -- 8 12 KL to 20 KL
5 Dryers -- 18 200 Kg, 400 kg
6 Centrifuge -- 12 24", 36"
7 Sparkler filter -- 12 2 KL, 3 KL
8 Nutsche Filter -- 9 6 KL, 8 KL
9 Condensers -- 46 5 m2 to 60 m2
10 Chillers -- 5 50 TR to 250 TR
11 Cooling Towers -- 4 3,000 TR
12 Blowers -- 6 500 CFM to 1,500 CFM
2.9.4. Power
At present, the total connected load of power is 7,000 KW which is procured from
Madhya Gujarat Vij Company Ltd. (MGVCL). It will increase up to 10,000 KW after
proposed expansion. In addition to this, unit has installed 2 Nos. of DG Sets of 625 kVA
each and CPP (Gas based Generator Set) of 4.8 MW as captive source of power and is
used in case of main power failure or inconsistent power supply from MGVCL. Capacity
of CPP (Gas based Generator Set) after proposed expansion will increase up to 10
MW.
2.9.5. Water
Presently, the water requirement of the unit is met by GIDC supply and the same
source will be utilized for proposed expansion. The total fresh water requirement for
the existing plant is 3,256 KLD which will increase up to 3,500 KLD after proposed
expansion. Since the entire water requirement will be fulfilled from GIDC water supply,
unit will not dig any bore-well for groundwater withdrawal and undertaking for the same
is attached in Annexure 8. Copy of letter from GIDC for water supply is enclosed as
Annexure 9.
2.9.6. Fuel
Presently, R-LNG is used as fuel for existing CPP (Gas based Generator Set) (4.8 MW)
and steam boilers @ 2,095 SCM/hr. R-LNG requirement will increase up to 4,200
SCM/Day since unit proposes expand capacity of CPP (GG Set) upto 10 MW for the
proposed expansion project. Coal requirement as a fuel for existing steam boiler (28
TPH) is @ 2,700 TPM which will increase upto 6,000 TPM after installation of additional
steam boiler (40 TPH) for proposed expansion. Furnace Oil and LDO requirement for
the existing plant is 2,350 Lit/hr and 45 Lit/hr respectively. Diesel requirement for
existing DG sets (2 Nos. x 625 kVA) is 260 Lit/hr which will increase upto 390 Lit/hr
after installation of additional DG Set (625 kVA). Details of fuel requirement are given in
Table 2.8.
Table 2.8: Details of Fuel Requirement
% Sulfur
Calorific
Daily Requirement
Kcal/Kg
Carbon
% Ash
Value,
Sr. Type of
%
Utility
No Fuel
Existing Additional Total
Steam
Boilers & 2,095 2,105 4,200
1 R-LNG 10,084 - - 66.00
CPP SCM/hr SCM/hr SCM/Hr
(GG Sets)
% Sulfur
Calorific
Daily Requirement
Kcal/Kg
Carbon
% Ash
Value,
Sr. Type of
%
Utility
No Fuel
Existing Additional Total
5 Diesel DG Sets 260 Lit/hr 130 Lit/hr 390 Lit/hr 9,500 1.00 0.25 77-87
Administration 39 2 41
Production & allied services 470 35 505
Stores & Dispatch 24 2 26
Others 5 - 5
Total 538 39 577
The project activities will commence after receipt of Environmental Clearance from
SEIAA and CTE from GPCB. The expected start date of the expansion activity is from
mid-October 2019 and the completion of all these activities will take about 4 months,
which is expected to be in operative phase in end of January 2020. Tentative project
implementation schedule with respect to various activities is given as follows.
Presently, the fresh water requirement for various domestic, gardening & industrial
activities is 3,256 KLD which will increase up to 3,500 KLD after proposed expansion.
At present, effluent generation from existing industrial activities is 1,151 KLD, which will
increase up to 2,156 KLD after proposed expansion.
Product wise water consumption and wastewater generation is given in Table 2.10,
whereas the product wise pollution load is given in Table 2.11. Category wise water
consumption and wastewater generation is given in Table 2.12 and summary of water
balance after proposed expansion is given at Table 2.13. The water balance diagram is
given in Figure 2.4.
Wastewater Condensate
Water Consumption
Product Generation Water
Stream
Code Lit. / Kg Lit. / Kg Lit. / Kg
KLD KLD KLD
of Prod. of Prod. of Prod.
Total (Process) - Max - 238.74 - 267.79
Total (APCM) - Max - 6.90 - -
P9 Process 14.63 56.29 24.56 94.47 - -
P10 APCE 1.68 6.46 - - - -
P11 Process 1.11 4.27 1.59 6.11 - -
P11 APCE 4.76 18.32 - - - -
P12 Process 0.74 2.83 6.11 23.49 - -
P12 APCE 23.13 88.98 - - - -
Total (Process) - Max - 59.11 - 117.96
Total (APCM) - Max - 107.29 - -
Process - - 0.08 0.33 - -
P13
APCE 5.83 22.44 - - - -
P14 Process 0.32 1.23 0.84 3.22 - -
P15 Process 3.29 12.66 6.04 23.22 - -
P16 Process 8.84 34.00 7.64 29.37 - -
Total (Process) - Max - 34.00 - 29.37
Total (APCM) - Max - 22.44 - -
P17 Process 26.89 103.42 36.88 141.85 - -
P18 Process 21.00 80.77 39.06 150.23 - -
P19 Process 70.72 272.00 47.05 180.96 - -
P20 Process 12.00 46.15 17.49 67.27 - -
P21 Process 33.74 129.77 73.27 281.81 - -
P22 Process 6.40 24.62 10.37 39.88 - -
P23 Process 2.43 9.35 20.69 79.58 - -
P24 Process 1.43 5.49 23.76 91.37 - -
P25 Process 3.63 13.96 6.43 24.74 - -
Total (Process) - Max - 272.00 - 281.81 - -
P26 Process -- 17.50 -- 18.55 - -
All Reactors -- 0.50 -- 0.50
Total Process 782.81 -- 838.91 -- 260.78
Total APCE 189.82 -- 1.00 -- --
Total (Process + APCE) 972.63 -- 839.91 -- 260.78
Direct Re-use of
260.78 -- -- -- –
Condensate Water
Total Water Requirement /
711.85 -- 839.91 -- --
Wastewater Generation
Hy.
COD, COD TDS, TDS Specific
Prod. Code Load,
mg/L Load, kg mg/L Load, kg Parameters, mg/L
KLD
P17 141.85 5,500 780.15 1,50,000 21,276.92 --
P18 150.23 3,500 525.81 2,000 300.46 --
P19 180.96 11,500 2,081.06 400 72.38 --
P20 67.27 59,000 3,968.88 1,644 110.59 --
P21 281.81 1,200 338.17 53 14.94 --
P22 39.88 1,202 47.94 7 0.28 --
P23 79.58 1,203 95.73 16 1.27 --
P24 91.37 30,000 2,741.21 300 27.41 --
P25 24.74 1,209 29.92 1 0.02 --
Total / Average
(Proposed - 281.81 14,084 3,968.88 75,502 21,276.92 --
Group Max)
Total / Avg.(High
Concentrated 667.56 29,700 19,825.93 83,435 1,403.46 --
Stream)
3,330
Chemical
Loss from Evap. & Drift
Process 850 190 610 758 1,645 Loss 25 10
(386) (1,699)
Dust
Process APCE – DM Plant Cooling Washing APCE –
Suppression Flue Gas
Process Gas 470 Evap.&
1,236 Gases &
handling 704
Loss
Scrub
High Low Media: 95 284 Boiler
(420) 27
Conc. Conc.
Stream Stream
Industrial
Stripper Wastewater
668 140 1,321 Generation: 2,156
896
RO ETP
MEE: 946 Condensate 284
896 1,321
RO Reject
138
758
Salt to TSDF
(50) Discharge through As per H&OW(M&TM) Rules
RO Permeate: 758 Effluent Conveyance CAPTIVE CONSUMPTION:
Sodium Nitrite Soln (17%): 12 Legend:
Channel managed by x Reused Water
Vadodara Enviro x Effluent to Stripper/MEE
SALE TO AUTH. END-USERS
Channel Ltd. (VECL) x Direct Re-use
Ammonia Soln (17%): 8
NaHS Soln (28%): 29 x Hazardous Waste
HCl Soln (30%): 235
Note: All quantities are expressed in KLD
After proposed expansion, total effluent generation will increase from 1,151 KLD to
2,156 KLD. Effluent will be segregated into high COD/TDS and low COD/TDS stream.
Unit proposes install stripper and MEE units for treatment of high concentrated effluent.
High COD/TDS stream from manufacturing process @668 KLD will be sent to proposed
stripper followed by MEE. Stripper outlet @668 KLD along with effluent from DM-Reject
@140 KLD and RO Reject @138 KLD will be sent to MEE. Hence, total hydraulic load
of MEE will be 946 KLD. Condensate from MEE @896 KLD will be sent to RO.
Permeate from RO @758 KLD will be re-used in cooling tower makeup.
Low COD/TDS stream from Process, APCE, Boiler, Cooling and Washing @ 1,321 KLD
will be sent to ETP having primary and tertiary treatment along with hydrodynamic
cavitation treatment units. Treated effluent from ETP @ 1,321 KLD will be discharged
into VECL as per current practices and hence there will be no additional discharge to
the CETP of VECL. Hence, there will not be any negative impact on effluent
conveyance channel of VECL. The stream wise characteristics of Effluent streams are
given in Table 2.14 (a, b & c) and stage wise characteristic of effluent stream in ETP
are given in Table 2.15 (a).
(b & c), upgradation in existing ETP will not be required. Hence, treatability &
feasibility study for the proposed scenario is also not required.
Technical details of ETP, Stripper, MEE & RO are given in Table 2.16 & Table 2.17
respectively.
Domestic sewage @170 KLD will be treated in STP and treated sewage will be re-used
in greenbelt development @130 KLD and domestic flushing @40 KLD.
Stripper Outlet
High COD/TDS
Consideration
Consideration
(Feed to MEE)
(Feed to MEE)
(Feed to MEE)
Composite to
RO Permeate
Condensate
Process to
DM Reject
RO Reject
for Reuse
(Stripper)
Stripper
(to RO)
Design
Design
(MEE)
MEE
MEE
Sr. Waste-water
Unit
No. Stream
Hydraulic
1 KLD 668 800 668 140 138 946 1,100 896 758
Flow Rate
2 pH - 6.0-8.0 6.0-8.0 6.0-7.0 7.5-8.5 6.5-7.5 6.5-8.5 6.0-8.0 6.0-8.0 6.5-7.0
3 TDS (max.) mg/L 83,500 1,00,000 83,500 1,500 3,500 59,700 60,000 625 100
4 COD (max.) mg/L 30,000 40,000 5,000 20 800 3,650 4,000 170 50
5 BOD (max.) mg/L 10,000 12,000 1,500 6 350 1,110 1,200 70 17
Secondary
Discharge
Discharge
Outlet for
Primary
Tertiary
Influent
Norms
Outlet
Outlet
VECL
Sr.
Parameters Unit
No.
Unit has provide flow meter at inlet & outlet of ETP for proper effluent treatment and
disposal and the same practice will be followed after proposed expansion. In addition to
this, relevant guidelines and directions given by GPCB are followed from time to time.
Table 2.18: Capital and Recurring Cost of the effluent treatment system
Operating Cost
Cost (Rs. Lakhs/
cost (Rs. Lakhs/
Total Recurring
Hydraulic Load
Capacity (KLD)
(Rs. Lakhs/Month)
Maintenance
(Rs. in Lacs)
Capital cost
Installed
Month)
Month)
Consumabl
Chemical &
Sr.
(KLD)
Manpower
Electricity
Steam,
No Unit
.
e
The capital cost of the entire project (Existing + Expansion) is Rs 269.88 Crore,
whereas total capital investment required for effluent handling, treatment and disposal
system is Rs. 13 Crore. It comes to 4.82% of the total project cost and hence it seems
to be economically viable and will not affect the overall project cost.
The recurring cost for the effluent handling, treatment and disposal system as narrated
in the Table 2.18 will be Rs. 88 Lakh per month. Now, considering the total installed
capacity of the proposed project 42,508 TPM, it would cost Rs. 0.21 per kg of product.
Average market value of the products being manufactured is Rs. 5000 per kg, effluent
treatment and handling cost will be very negligible (0.004%). Also, considering quantity
of effluent to be treated @2,156 KLD, it would cost 0.16 Rs/Liter of effluent. Thus, the
cost for operating proposed ETP is justifiable compared to market value of product.
from the proposed expansion. Unit will provide adequate scrubbing system (water/ alkali
scrubbers) to control emission of process gas into atmosphere. Details of process gas
generation is given in Table 2.20. Details of process gas stack are given in Table 2.21.
Type of
Height
Sr. Emission &
Stack Attached to & Dia. APCM Management of Output
No. Permissible
(m)
limit
Reactor of Thio 10 & H2S < 45 NaHS Solution – Sell to
3 Caustic Scrubber
carbohydrazide 0.15 mg/Nm3 authorized end-users
NOx < 3 NOx absorption
4 Reactor of Sodium 31 & kg/ton in tower with NaOH
Nitrite / Nitrate 0.45 HNO3 as Scrubbing Sodium Nitrite Solution –
produced media. Captive Consumption for
NOx absorption manufacturing of
5 31 & HNO3 < 15 tower with NaOH Sodium Nitrite
Reactor of SMIA
0.45 mg/Nm3 as Scrubbing
media.
Fumes &
Reactor of Nitrosyl 10 & Vapors Bleed liquor to ETP for
6 Acid Scrubber
Sulfuric Acid 0.15 (SO2 < 40 treatment
mg/Nm3)
Fumes &
Vapors
Reactor of 2 Ethyl 10 & (SO2 < 40 Bleed liquor to ETP for
7 Caustic Scrubber
Hexyl Nitrate 0.15 mg/Nm3, treatment
NOx < 25
mg/Nm3)
Reactor of Mono 15 & HCl < 20 Dil. HCl Solution - Sell to
8 Water Scrubber
Chloro Benzene 0.15 mg/Nm3 authorized end-users
Fuming Chamber-
9 10 & -
Laboratory (5 for - -
0.15
R&D)
Fumes &
10 & Vapors Bleed liquor to ETP for
10 MAHCl Plant Water Scrubber
0.15 (HCl < 20 treatment
mg/Nm3)
There will be increase in hazardous waste generation from proposed expansion. Unit
will obtain membership from various CHWIF/TSDF/Co-Processing facilities for
additional quantity of hazardous waste generated. Details of hazardous waste
generation, handling & Management are given in Table 2.22.
Process waste
Mfg. of Prod. Sch-1
(Inorganic - Iron - 1,440 MT 1,440 MT
P17 35.3
Sludge)
Mfg. of Existing
Process waste Prods. & Prod. Sch - 1 3,840
3,545 MT 7,385 MT
(Organic) P3, P12, P24 35.3 MT
and P26
Mfg. of Prod. Sch - 1 Collection, Storage,
Tar waste 900 MT - 900 MT Transportation and
E21 1.2
Disposal by *Co-
Mfg. of Prod. Sch - 1
Spent Carbon 360 MT 485 MT 845 MT Processing OR
P1,P18,P26,E12 36.2
incineration at #CHWIF
Distillation Mfg. of various Sch - 1
- 1,370 MT 1,370 MT
Residue Products 36.2
Mfg. of Prod. Sch - 2 240 5,760
Cresol 6,000MT
E28 A27 MT MT
Collection, Storage and
sent for off-site
Spent / Mix Mfg. of various Sch - 1 2,94,100 2,94,100 distillation OR Sell to
-
Solvent Products 28.6 MT MT authorized end-users
having permission under
Rule 9
Mfg. of Prod.
Hydrochloric Sch - 2 18,000 555 18,555
P15 and existing
Acid B15 MT MT MT
products Disposal by selling to
Sulfuric acid (70 Mfg. of Products Sch - 2 19,800 45,120 64,920 authorized end-users
to 80%) E27,E28,E29 B15 MT MT MT having permission under
Mfg. of Prod Rule 9
Spent Acid Sch - 2 24,770 24,770
P2,P7,P14,P25, -
(Mix) B15 MT MT
P26
The unit has provided designated area of 225 m2 having impervious floor, roof cover
system and leachate collection system in the existing plant for storage of hazardous
waste. It will be expanded upto 580 m 2 after proposed expansion. Unit has obtained
membership of NECL/RSPL/BEIL/GSPL/SEPPL/GGEPIL for the final disposal of
hazardous waste from their existing unit waste and will obtain permission for additional
quantity of hazardous waste from CHWIF/TSDF/Co-processing facilities like
J.K.Lakshmi Cement Ltd., Sanghi Industries Ltd. etc. Copies of memberships and MoU
of the same are enclosed as Annexure 13. Unit will procure LOI and agreement for sale
of hazardous waste to authorized end-users having permission under Rule 9 before
commissioning of the project.
The unit has adopted appropriate procedure for handling of hazardous waste as
described below;
9 Provision of hazardous waste storage within premises having impervious flooring,
roof cover and leachate collection facility.
9 ETP sludge and inorganic process waste generated are collected in HDPE
9 bags/drums after complete sun drying and the bags are sealed or tightly closed.
9 Off specification drugs / expired date products are stored in HDPE bags/drums and
are sealed or tightly closed.
9 Tightly closed HDPE bags/drums are labeled as “ETP Sludge /Hazardous waste”
and transferred through trolley to the respective storage area.
9 Process waste i.e. organic residue and spent carbon generated will be collected in
drums. The tightly closed drums are labeled as “Organic Hazardous Waste” and
then transferred to the respective storage area with the help of trolleys.
9 Suitable PPE are provided to all the workers handling the hazardous waste.
9 Collected different types of hazardous wastes are disposed of at CHWIF / TSDF /
Co-processing regularly according to their hazardous characteristics.
The existing practice of handling and management of hazardous waste will be adopted
for expansion phase also. Discarded containers are sold to scrap vendors after
decontamination. The unit will develop procedure for decontamination of discarded
container. Dedicated area will be allocated near ETP for the decontamination having
impervious flooring, suitable drainage line and three side covered wall. Adequate facility
with pressure pump and treated effluent line will be established for proper washing and
decontamination.
There will be generation of garbage @150 Ton/Month in the form of dead leaves,
grass, waste papers, plastic and other municipal waste etc. It will be disposed off in
accordance with Solid Waste Management Rules, 2016
2.11.4. Noise
The only source of noise generation may be from the DG Set & GG Set, which will be
kept as stand-by and no other source of noise and vibration in the proposed unit
except plant machineries. Adequate precautions taken for abatement of noise
pollution are elaborated in Section 4.4 of Chapter 4 of this report.
The proposed project is for expansion in the existing products as well as addition of
new products falling under synthetic organic chemicals and covered under category
5(f)-B of EIA Notification of MoEF&CC. Therefore, it requires obtaining EC from SEIAA,
Gujarat, CTE/NOC & CTO/CCA for expansion from GPCB. The unit already complies
with all necessary legal / legislative requirements.
Environmental audit of the unit is carried out annually by GPCB appointed Schedule-II
auditors. Acknowledgement copy of submission of last environmental audit report for
the period of April 2018 to March 2019 along with the summary of suggestions received
from environmental audit and its compliance are enclosed as Annexure 21.
Unit had received various written instructions during inspection of GPCB officials in the
past. Unit had submitted point-wise compliance of these instructions to GPCB in timely
manner. Copies of the inspection report generated from GPCB-XGN are enclosed in
Annexure 22.
There is no case pending against unit in any court of law for the violation under any of
the environmental legislation.
2.14 SUMMARY
The proposed expansion is being carried out within existing plant located in notified
industrial estate of Nandesari, where all basic infrastructural facilities are available
including water supply and power supply. Unit proposes to expand manufacturing of
some of the existing inorganic chemicals upto 45,880 TPM and synthetic organic
chemicals upto 22,004 TPM. In addition to this, unit proposes to manufacture various
other synthetic organic chemicals with production capacity of 510 TPM. Thus, total
production capacity of the unit will be 68,394 TPM after proposed expansion. Also, unit
proposes to expand Captive Power Plant (Gas based Generator Set) capacity up to 10
MW. Raw materials will be available from the nearby developed industrial area / estates
of Jhagadia, Ankleshwar & Dahej.
Total industrial effluent generation will increase upto 2,156 KLD after proposed
expansion. It will be segregated into high COD/TDS and low COD/TDS stream. High
COD/TDS stream from manufacturing process @668 KLD will be sent to proposed
stripper followed by MEE. Stripper outlet @668 KLD along with effluent from DM-Reject
@140 KLD and RO Reject @138 KLD will be sent to MEE. Hence, total hydraulic load
of MEE will be 946 KLD. Condensate from MEE @896 KLD will be sent to RO.
Permeate from RO @758 KLD will be re-used in cooling tower makeup.
Low COD/TDS stream from Process, APCE, Boiler, Cooling and Washing @ 1,321
KLD will be sent to ETP having primary and tertiary treatment along with hydrodynamic
cavitation treatment units. Treated effluent from ETP @ 1,321 KLD will be discharged
into VECL as per current practices. There will be no additional discharge of treated
effluent outside plant premise. Hence, there will not be any negative impact on effluent
conveyance channel of VECL.
There is flue gas generation from existing boilers, thermic fluid heaters, furnaces and
GG Set. Since R-LNG/FO is used as fuel in the existing boilers & CPP (GG Set), APCM
is not required. The unit has provided stack of adequate height to existing steam boilers
and DG sets for proper dispersion of flue gas as per CPCB guidelines. For, Coal Fired
Boiler-GT 5992 (28 TPH), unit has provided Electro Static Precipitator (ESP) followed
by Water scrubber as an APCM. Unit will install Electro Static Precipitator (ESP)
followed by Water scrubber for proposed steam boiler (40 TPH). Unit will install
additional GG Set & waste heat boiler. Since, R-LNG will be used as fuel in GG, APCM
will not be required. However, stack of adequate height will be provided. Unit proposes
to install additional DG Set (625 kVA) which will be kept stand-by and stack of adequate
height will be installed for proposed DG Set There are process gas generation from the
existing plant in the form of NOx, NH3, SO2, PM, and Cl2. Unit has provided adequate
scrubbing system (water / acid / alkali scrubbers) to control emission of process gas
into atmosphere. There will be generation of NOx, NH3, HCl, and H2S from the proposed
expansion. Unit will provide adequate scrubbing system (water / alkali scrubbers) to
control emission of process gas into atmosphere.
Hazardous and solid wastes anticipated to be generated from the production activities
will be handled as per H&OW (M&TM) Rules, 2016. Unit has obtained membership of
NECL/RSPL/BEIL/GSPL/SEPPL/GGEPIL for the final disposal of hazardous waste for
safe disposal of existing hazardous waste and will obtain permission for additional
quantity of hazardous waste from CHWIF/TSDF/Co-processing facilities.
BASELINE
ENVIRONMENTAL
STATUS
Deepak Nitrite Ltd., GIDC-Nandesari
Environmental Impact Assessment Report
Proposed Expansion for Manufacturing of Synthetic Organic Chemicals
Existing Environmental condition of the study area (area of influence around the project
site) in general, and within the project site has been described in this chapter.
3.1 PROLOGUE
The baseline status of environmental quality in the vicinity of project site serves as the
basis for identification, prediction and evaluation of impacts. Knowledge of baseline
environmental status of the study area is useful tool for impact assessment; process of
assessing and predicting the environmental consequences of the significant actions.
This depicts direct adverse changes caused by the action and its effect on the physical
condition of the biota including flora, fauna and human being, socio-economic
conditions, current use of land and resources, physical and cultural heritage properties
and biophysical surroundings.
Core Zone (Host and Proximate Area where the proposed activities are to be
commenced) - This area is the closest to the activity where the background quality
of environmental and human health is always at high risk. This involves risks due to
steady state, transient and accidental release of hazardous chemicals, release and
dispersion of gaseous pollutants from stack, propagation of noise, increased traffic
congestion and social stress.
Based on the modeling and analysis the maximum ground level concentration of air
pollutants due to stack emission and maximum threat due to accidental release of
hazardous chemicals will occur within 1 km. Considering these aspects, immediate
vicinity of the plant that is around 1 km radius is taken as factual core zone.
Buffer zone (Moderately affected area)- Being a little away from the activity, the
discharge pollutants need time lag to be transported to this area and gets
attenuated/diluted to a considerable extent. However, the associated risk shall be
real during brake-down, failure or upset conditions, and simultaneously with adverse
meteorological and hydrological factors. Also, covering varied land cover around the
project site, which could be affected from proposed project, is considered as factual
buffer zone at a distance from 1 km to 5 km around the project site.
Unaffected Zone- This area shall be at a minimum risk of serious damage to life,
health and property. Here the impact becomes small enough to become
imperceptible and/or inconsequent and/or insignificant and normal life activities shall
prevail without any disturbances due to the activity. Distance away from the 5 km to
10 km to the buffer zone is the factually unaffected zone in this case.
While generating the baseline status of physical and biological environmental of the
study area, the concept of impact zone has been considered. The Impact zone
selection is based on preliminary screening. For environmental attribute, several
primary and secondary data has been collected and used for the assessment of
impacts.
Figure 3.1: Map of Study Area showing Impact Zone Distribution and Sampling &
Monitoring Locations
*A-Ambient Air, N-Noise, GW-Ground water, SW-Surface Water, PW-Pipe Water, S-Soil
Sampling
Monitoring Source Frequency of Analysis
Attributes Method /
/ Location Monitoring Method
Instrument
Ambient Air 5 Locations 24 hourly twice a As per Annexure 26
Quality week throughout
the study period
B. Noise 5 Locations Once, 24 hourly As per Annexure 26
C. Water
Ground Water Grab samples Once As per Annexure 26
from 4 locations
Surface Water Grab sample from
4 location
Pipe Water Grab sample from
(GIDC Water 1 location
supply)
D. Soil Quality 5 locations Once As per Annexure 26
E. Land Use - Satellite Image: Once Arc GIS software and Computer
Land Cover (Landsat ETM + Aided Data Analysis with field
Thermal MSS) survey for ground checks and
ground truth verification
F. Ecological Data through Once Field survey Computer
Data primary survey & Aided Data
verification with Compilation
secondary data
G. Socio- Primary survey & Once Compilation of data from Census
economic data from Census of India-2011and Computer Aided
Data of India-2011 Data Analysis with field survey
3.3.2 Seismology
The study area falls in Zone III as per IS 1893 (Part-I):2002, which is referred as
Moderate Damage Risk Zone. The area is liable to earthquakes of Modified Mercalli
Intensity Scale VII. The chart showing the seismic zoning map of state Gujarat is given
in Figure 3.2.
Figure 3.2: Seismic zone mapping of Gujarat state
The satellite image/data has been processed using ERDAS Imagine software
supported with ground checks and ground truth verification by experts. Area and
distance calculations have been carried out using GIS software after geo-referencing
the interpreted data with the help of topographical maps. Satellite image of the study
area is given in Figure 3.3 and Land use / Land cover map of study area is given in
Figure 3.4.
Classification of land use / land cover is given in Table 3.4. Data illustrate that 65.67%
of total land area is occupied by agricultural fields like crop lands and fallow lands
(cropland that is not seeded or a season; it may or may not be ploughed. The land may
be cultivated or chemically treated for control of weeds and other pests or may be left
unaltered.). As the soil type is mainly clay type in nature, it facilitates cultivation of
various crops like Groundnut, Tuvar, Chana, Danger, Jowar, Ghanv, Bajri, Cotton and
Sugarcane etc.
Total area of 16.68 % is covered as a built-up land, of which land cover of 7.90% is for
the industrial purposes, 4.37% as human settlement. Waste land covers 14.58% and
about 3.07% of land is occupied as water body of total study area.
Figure 3.4: Land use / Land Cover Map of the Study Area
3.3.4 Meteorology
Meteorology is the interdisciplinary scientific study of the atmosphere and is important
tool in studying environmental phenomena like pollutant dispersion. When the EIA
study is planned for any project meteorological data are very important and shall be
collected through the entire period of the baseline study. Typically for EIA,
micrometeorological data is required to collect as these data are essential to formulate
the pollutant dispersion models. Besides, it also helps in understanding the current
trend in climatologically variable as well as prevailing ambient air quality issues and
forecasting. Details of the various meteorological parameters analyzed during the study
with their importance in EIA are presented in subsequent Table 3.5. Information about
these parameters is taken from “Climatological Normals 1981-2010” issued by The
Additional Director General of Meteorology, IMD, Pune.
The climate of the district is characterized by a hot summer and general dryness except
during the monsoon season. The year may be divided into four seasons. The cold
season is from December to February followed by summer season from March to June,
southwest monsoon season from June to September and post monsoon season during
October and November.
Sr.
Parameters Measurement Method Importance
No.
Wind vane with
Wind
4. magnetic hall effect Determines downward geometry
Direction
sensor
Tipping Bucket sensor Rainwater scrubs the atmospheric pollutants
5. Rainfall with magnet & reed and pollutes surface and groundwater.
switch
Passive Cloud Cover
6. Cloud Cover It influences stability conditions and
Detector – PCCD
determines the dispersion&/or dilution rate of
7. Solar Pyranometer type
pollutant.
Radiation sensor
Determined from Determines plume spread associated with
Atmospheric surface observations on turbulent motions in the atmosphere
8. Stability wind speed, cloud
Condition cover and solar
radiations
3.3.4.1. Temperature
Summer season comprises March, April, May and till mid of June months. Mean daily
maximum temperature during season remains between 36.6 to 40.7 °C while mean
daily minimum temperatures remains between 16.6 to 26.1 °C. May is the hottest
month of the season with highest maximum temperature ever recorded at 46.7°C.
Temperature remains normal during monsoon and post monsoon. It ranges mean
maximum between 32.6 to 37.2 °C and mean minimum temperature between 24.1 to
27.1 °C. Winter season comprises December, January and February months. During
the season mean maximum temperatures remains between 30.1 to 32.4 °C and mean
minimum temperatures remain between 10.8 to 12.7 °C.
3.3.4.2. Humidity
Most humid conditions are found in the monsoons, followed by post-monsoons, winter
and summer in that order. Mornings are more humid than evenings and humidity
ranges from a high of 68-89% in monsoon mornings to a low of 21-29% in summer
evenings. During post-monsoon season, in morning humidity remains between 68-76%
and in the evening it remains between 48-52%.
3.3.4.3. Cloudiness
During the southwest monsoon months, the skies are usually heavily clouded or
overcast. Cloudiness decreases during the post monsoon months. In the rest of the
year the skies are mostly clear or lightly clouded.
3.3.4.5. Rainfall
The average annual rainfall observed during the period was to be 841.8 mm.
Distribution of rainfall by season is 6.1 mm in winter (December, January, February),
8.8 mm in summer (March, April, May), 783.1 mm in monsoons (June, July, August,
September) and 43.8 mm in post-monsoons (October - November).
3.3.5 Micrometeorology
The site-specific micrometeorological data has been collected continuously during
the study period by installing automatic weather station at project site.
The parameters for which data has been collected are temperature, relative
humidity, wind speed, wind direction, rainfall, solar radiation and barometric pressure.
Site specific micrometeorological data collected during study period is given in the
following table. Wind rose diagram is shown as Figure 3.5.
Recently, Government has also put forwards some findings regarding the critical issues
of air quality & critical level of pollution in many part of India. Further, Government
through its concern department is continuously trying to improve the environmental
quality of the Indian regions. The findings have also noted that the issues of
contamination of air have been arising in the region experiencing more industrial
development. Hence, while studying the probable impacts of any industrial project,
establishment of state of air quality in project area has become very important aspect of
EIA study.
With such purpose, ambient air quality monitoring was conducted for the EIA study at 5
locations as given in Table 3.6. Ambient air quality monitoring stations were selected
based on historical wind data of the region i.e. one in upwind direction, two in downwind
direction and two in cross wind direction from project site. AAQ monitoring was carried
out for PM2.5, PM10, SO2, NO2, NH3, Cl2, HCl & VOC. Methodology adopted for
conducting AAQ monitoring and analysis is given in Annexure 26. AAQ monitoring
results obtained during the entire study are given in Annexure 27.
Summary of ambient air quality monitoring results is given in Figure 3.6 to Figure 3.13
as follows.
Figure 3.6: Status of PM10 concentration in ambient air
Concentration of HCl was within the norms specified by GPCB at project site and was
below detectable limit at other locations. H2S in ambient air was below detectable limit
at all the monitoring locations and VOC was observed at project site only.
3.3.7 Hydrology
The importance of water can’t be overstated when it comes to life on Earth. Over 70%
of the Earth is covered in water and without water there simply is no life. With
increasing industrialization & modernization in lifestyle, issue of water crisis either
quality &/or quantity of water is being critical day by day. The main source of such crisis
is found to be the activities requiring huge quantity of freshwater and generating huge
quantity of wastewater. Hence, while studying the probable impacts of industrial project,
it is very important to determine the existing status of water quality & quantity. The
water resource for such investigations can be groundwater or surface water or both
depending upon the water specific planning of the proposed project.
River Mahi which is a perennial river and a major source of surface water for Vadodara
District. Topographically the study area is flat terrain having gentle slope towards river
Mahi. The climate of the study area is Arid. Average long term annual rainfall for 45
years from is around 930 mm. There is sufficient groundwater available in the area. The
CGWA/CGWB has not considered this area to be under threatened area. The ground
water depth observed in study area is about 40-60 meter below GL The general ground
slope is towards Mahi River on either Banks. Considering the proximity to the river, the
soil is expected to get sloughed below the ground level frequently considering the flow
pattern through shallow canyons formed in alluvial formation. Though there is a high
dam upstream reasonable sloughing is expected with one more river flowing though not
perennial within the study area.
In general, water environment is widely divided into two categories in terms of water
sources:
1. Surface water: Rivers, Ponds, Drains, Canals etc.
2. Groundwater: Accumulation in deeper strata of ground
Total 9 water samples have been collected from the Seven locations once during the
study period. Out of these, 4 ground water, 1 pipe water (GIDC Supply), and 4 surface
water samples have been collected. The details of sampling locations are given in
Table 3.7. Methodology adopted for sampling and analysis are given in Annexure 26.
The outcome of the study of water quality is given in Table 3.8. Analysis results of
water sampling are given in Annexure 27.
Co-ordinates
Code
GIDC
S1 Project Site PW 22°24'43.9"N 73°05'30.6"E 26-Nov-18
Supply
GW2 22°25'52.5"N 73°07'35.3"E 26-Nov-18 Borewell
S2 Sankarda Village
SW2 22°25'43.9"N 73°07'33.1"E 26-Nov-18 Pond
Source: Sampling & Analysis carried out by NABL accredited laboratory of Envisafe Environment Consultants
Soil quality can indicate the current as well as future issues related with the water,
ecology and life in the particular region. Thus, it is clearly visible that soil contamination
may result in eventuality in form of contamination of water, ecological destruction, loss
of productivity, food crisis and so threat to life. The major source of contamination is
liquid and solid wastes from industries as well as overuse of fertilizers & pesticide.
Thus, to determine the exact impacts of any proposed project, it is very essential to
determine the existing status of soil quality and existing stress through a study of soil
quality assessment. Based on different types of land use classification soil samples
were collected from five locations of study area once in study period. Details of
sampling locations are given in Table 3.9. Methodology adopted for sampling and
analysis of soil quality is given in Annexure 26. The analysis data of soil samples is
given in Table 3.10. Analysis results of soil sampling are given in Annexure 27.
x Bulk density of soil samples was in range of 1.125 gm/cm3 to 1.402 gm/cm3, which
will have no significant effects on root growth.
x pH of the soil samples ranged from 6.98 to 7.37, which indicates ideal range for
growth of crop.
x The Electrical conductivity of the samples varied from 397 to 765 µs/cm, which
indicates, no salinity ingress in the study area.
x The organic matter in the soil ranged from 2.3% to 3.6%. The result range signifies
that the soil is being maintained in an optimal desired range.
x The concentration of available Nitrogen, Phosphorous and Potassium in the soil
samples signifies that the soil of the area is less fertile.
Thus, for EIA study it is very necessary to study the prevailing noise level during the
day & night time in the project area, as the noise from the proposed activities together
with the existing noise level may result in many issues related with human health as
well as social layout & quality. Considering this, the noise level monitoring at five
selected locations on 24 hourly basis was conducted once during the study period.
Details of sampling locations are given in Table 3.11. The outcomes of the study are
presented in Table 3.12.
The monitored noise levels were compared with the standards prescribed by
MoEF&CC which indicates that the noise levels at all the locations were found well
within the limit for day & night time.
3.3.10.1. Flora
During the survey, a total of 154 plant species belonging to139 genera and 70 families
were noted in the study area; including 74 tree species, 20 shrubs, 45 herbs, 11
climbers, creepers and lianas, and 4 crop plants. Most of the species are of common
occurrence. Enumeration of Flora &list of plant species are given in Table 3.13 & 3.14
respectively.
3.3.10.2. Fauna
During the survey, a total of 89 species belonging to 82 genera and 57 families were
noted in the study area; including 55 avifauna species, 6 mammals, 7 reptiles and 21
insects & others. Most of the species are of common occurrence. Enumeration of fauna
and list of fauna observed during study period are given in Table 3.15 & 3.16
respectively.
IUCN Status/
Migratory Status/
S. No. Common Name Scientific Name Family
Schedule as per
Wildlife Protection
12. Pond heron Ardeolagrayii LC/ R / IV
13. Cattle egret Bulbucus ibis LC/ R/ IV
14. Little egret Egrettagarzetta LC/ R/ IV
15. Median Egret Mesophoyxintermedia LC/ R
16. Red wattled lapwing Vanellusindicus Charadriidaea LC/ R
17. Painted Stork Mycterialeucocephala Ciconiidae NT/RM
18. Tailor bird Orthotomussutorius LC/ R
Cisticolidae
19. Ashy prinia Priniasocialis LC/ R
20. Blue rock pigeon Columba livia LC/ R
21. Laughing Dove Spilopeliasenegalensis LC/ R/ IV
22. Eurasian Collard Dove
Streptopeliadecaocto Columbidae LC/ R/ IV
23. Red Turtle-dove Streptopeliatranquebari LC/ R
ca
24. Jungle Crow Corvus macrorhynchos LC/ R
Corvidae
25. Common crow Corvussplendens LC/ R/ V
26. Crow- pheasant Centropussinensis LC/ R
Cuculidae
27. Indian koel Eudynamysscolopaceus LC/ R
28. Black drongo Dicrurus macrocercus Discruidae LC/ R/ IV
29. Indian silverbill Lonchuramalabarica Estrildidae LC/ R
30. Wire tailed Swallow Hirundosmithii Hirundinidae LC/ R
31. Bronze-winged Jacana Metopidius indicus Jacanidae LC/ R
32. Jungle babbler Turdoidesstriatus Leiothrichidae LC/ R/ IV
33. Coppersmith barbet Megalaimahaemacepha LC/ R/ IV
Megalaimidae
la
34. Green bee- eater Meropsorientalis Meropidae LC/ R
35. Indian robin Saxicoloidesfulicatus LC/ R
Muscicapidae
36. Oriental Magpie robin Copsychussaularis LC/ R
37. Purple sunbird Nectarinia asiatica Nectariniidae LC/ R
38. Little cormorant Microcarboniger Phalacrocoracidae LC/ R/ IV
39. Grey francolin Francolinus LC/ R
Phasianidae
pondicerianus
40. Little Grebe Tachybaptus ruficollis Podicipedidae LC/R
41. Rose ringed parakeet Psittaculakrameri Psittaculidae LC/ R/ IV
42. Red vented bulbul Pycnonotuscafer LC/ R/ IV
Pycnonotidae
43. White-eared bulbul Pycnonotus leucotis LC/ R/ IV
44. White-breasted Amaurornisphoenicurus LC/ R
waterhen
45. Indian Moorhen Gallinula chloropus Rallidae LC/R
46. Grey Headed Porphyrio poliocephalus R
Swamphen
47. Blank-winged stilt Himantopushimantopus Recurvirostridae LC/ R/ IV
48. Common sandpiper Actitishypoleucos LC/ M/ IV
Scolopacidae
49. Wood Sandpiper Tringa glareola LC/ M
50. Bank myna Acridotheresginginianus LC/ R/ IV
51. Common myna Acridotherestristis Sturnidae LC/ R/ IV
52. Brahminy Starling Sturnuspagodarum LC/R
53. Common Woodshrike Tephrodornis LC/R
Tephrodornithidae
pondicerianus
54. Red-naped Ibis Pseudibispapillosa LC/ R/ IV
Threskiornithidae
55. Oriental White Ibis Threskiornismelanoceph NT/RM/ IV
IUCN Status/
Migratory Status/
S. No. Common Name Scientific Name Family
Schedule as per
Wildlife Protection
alus
x Mammals
1. Blue bull Boselaphustragocamelu LC/ III
Bovidae
s
2. Jackal Canisaureus Canidae LC/ II
3. Hanuman Langur Simia entellus Cercopithecidae LC/II
4. Jungle cat Felischaus Felidae LC/ II
5. Common mongoose Herpestesedwardsi Herpestidae LC/ IV
6. Indian Hare Lepusnigricollis Leporidae LC/ IV
x Reptiles
1. Garden lizard Calotesversicolar Agamidae -
2. Red sand Boa Eryxjohnii Boidae IV
3. Indian Rat Snake Ptyas mucosa II
Colubridae
4. Checkered Keel back Xenochrophispiscator II
5. Common cobra Najanaja Elapidae II
6. Indian Flapshell Turtle Lissemyspunctata Trionychidae I
7. Common Indian Varanusbengalensis Varanidae I
Monitor Lizard
x Insects And Others
1. Honey bee Apisdorsata -
Apidae
2. Honey bee Apisflorea -
3. Mosquito Anopheles sp. Culicidae -
4. Black ant Camponotuscompressu -
s Formicidae
5. Red ant Oecophyllasmaragdina -
6. Water strider Gerrislacustris Gerridae -
7. Field cricket Gryllusbimaculatus -
Gryllidae
8. House cricket Gryllusdomecticus -
9. Skimmer dragonfly Orthetrum sp. Libellulidae -
10. Forget-me-not Catochrysops strabo -
Lycaenidae
11. Tailless Lineblue Prosotas dubiosa -
12. Beetle Mylabris sp. Meloidae -
13. House fly Muscadomestica Muscidae -
14. Plain tiger Danauschrysippus Nymphalidae -
15. Pioneer Belenois aurota -
16. Common emigrant Catopsilia pomona -
Pieridae
17. Small Salmon Arab Colotis amata -
18. Common Jezebel Delias eucharis -
19. Termite Macrotermessp. Termitidae -
20. Pigmy locust Acridium sp. Tetrigidae -
21. Grasshopper Conocephalus sp. Tettigoniidae -
R = Resident; M = Migrant; RM = Resident Migrant; LC = Least Concerned; NT = Near Threatened
Source: Primary data collected during study period
Population Density,
(person Per sqkm)
Total Literates
Total Workers
Sr. No.
Name of
Village
Occupational
Population Distribution Literacy Profile
Population Density,
(person Per sqkm)
Total Literates
Total Workers
Sr. No.
Name of
Village
GSFC
35 Complex INA 321 725 3,037 946 2,341 77.08 865 28.48
(INA)
Karachiya
36 96 1,589 7,736 8,058 5,423 70.10 2,715 35.10
(CT)
37 Dhanora 374 675 3,573 955 2,068 57.88 1,168 32.69
38 Dasharath 927 2,129 10,630 1,147 6,953 65.41 3,503 32.95
39 Dumad 1,268 1,090 5,147 406 3,063 59.51 2,334 45.35
Petro-
Chemical
40 405 1,731 7,338 1,812 5,729 78.07 2,148 29.27
Complex INA
(INA
41 Anagadh 1,137 2,560 13,531 1,190 7,782 57.51 4,824 35.65
42 Ranoli (CT) 692 2,360 11,057 1,598 7,791 70.46 3,633 32.86
43 Ajod 406 488 2,393 590 1,803 75.34 880 36.77
44 Sisva 418 473 4,475 1,070 3,605 80.56 1,632 36.47
Nandesari
45 206 645 2,814 1,366 2,011 71.46 829 29.46
INA (INA)
Nandesari
46 785 1,553 7,270 926 5,092 70.04 2,935 40.37
(CT)
47 Padmala 696 1,067 5,113 735 3,357 65.66 1,829 35.77
48 Asoj 1,094 797 3,634 332 2,269 62.44 1,234 33.96
Fajalpur
49 614 745 4,004 652 2,527 63.11 1,957 48.88
(Sankarda)
50 Sokhda 1,180 2,295 12,348 1,046 8,136 65.89 5,359 43.40
51 Sankarda 734 1,161 6,449 878 4,205 65.20 2,147 33.29
52 Rayaka 595 326 1,720 289 1,063 61.80 807 46.92
Vasna-
53 499 665 3,450 691 2,137 61.94 1,478 42.84
Kotariya
54 Dodka 770 458 2,977 387 1,535 51.56 1,194 40.11
55 Kunpad 525 576 2,792 531 1,391 49.82 1,373 49.18
56 Manjusar 1,406 986 4,978 354 2,977 59.80 2,070 41.58
57 Moksi 1,195 1,173 5,768 483 3,157 54.73 2,178 37.76
SAVLI
Poicha
58 769 638 3,184 414 1,946 61.12 1,284 40.33
(Raniya)
59 Raniya 680 594 3,093 455 1,833 59.26 1,251 40.45
60 Khandi 111 306 1,542 1,394 865 56.10 773 50.13
61 Jalampura 176 147 723 411 411 56.85 480 66.39
Total / Average 58,652 3,66,092 17,42,861 1,120 13,08,069 66.70 5,87,738 41.86
Minimum 96 147 723 289 411 49.82 480 28.48
Maximum 17,387 3,03,130 14,11,228 8,117 10,84,280 80.56 4,53,557 66.39
Source: Census of India-2011; For Area: Census of India-2001
3.3.11.2. Literacy
An understanding of education and literacy profile in the region is relevant in order to
understand weather better jobs due to the proposed project could utilize the existing
human resource in the area. The literacy rate ranges from 49.82% (Kunpad) to 80.56%
(Sisva) for the 61 villages and the overall literacy rate in the study area is 66.7%, which
shows that literacy rate in the study area is moderate. The details of literates and
literacy rate in the study area are presented in Table 3.17 and the chromatic map
showing population literacy rate is given below as Figure 3.15.
As per the 2001 census, almost all villages are having drinking water and electricity.
Certain villages are having primary schools, primary health centres, bus facility for
transportation but for the higher education, banking facilities, railway etc almost all
villagers have to travel 5-10 kms up to nearest town. Details of basic amenities
available in the study area are given in Annexure 28.
ANTICIPATED
ENVIRONMENTAL
IMPACTS &
MITIGATION
MEASURES
Deepak Nitrite Ltd., GIDC-Nandesari
Environmental Impact Assessment Report
Proposed Expansion for Manufacturing of Synthetic Organic Chemicals
4.1 INTRODUCTION
Impact identification and prediction is a way of ‘mapping’ the environmental
consequences of the significant aspects of the project and its alternatives. The
identification of environmental impacts has been made by correlating the relationship
between project activity and environmental parameters. Several techniques and
methodologies are in vogue for predicting anticipated impacts due to projects on natural
and social aspects of the environment. These predictions are superimposed over the
baseline (pre-project) status of the environment to derive the ultimate scenario of
environmental conditions. These conditions are then subsequently evaluated for
acceptability by screening them against standards. Based on results of prediction and
evaluation, pollution abatement and control measures in order to mitigate the adverse
impacts on the environment are delineated in an Environmental Management Plan for
theconstructionphaseas well as operational phase of the proposed project.
Air Environment
x Ambient air quality
x Sources of emission and its quantity
x Emission control measures / technology
Chapter-4: Anticipated Environmental Impacts
& Mitigation Measures
Page | 4.1
[[
Construction Phase
Construction of proposed expansion project will be within the existing industrial premise.
All the impacts due to following activities during construction phase will be short term
and limited up to plot area.
9 Site cleaning
9 Leveling and road laying
9 Earthwork comprising of excavation, grading, trenching
9 Transportation of construction materials
9 Civil work
9 Mechanical erection
9 Employment
9 Domestic activities by workers
9 Greenbelt development
Operation Phase:
Each individual activity listed has its own impact on each environmental parameter. After
commissioning of the proposed project, operation phase will have permanent (long
term) impact due to said activities.
9 Raw material, product storage and fuel handling and transportation
9 Manufacturing process & utility operations (consumption of resources & emission of
liquid effluent, flue & process gas, generation of solid/hazardous waste and Noise)
9 Employment
9 Green Belt Development
9 Infrastructure development &CSR activities
The proposed expansion project activities will be within industrial premise and looking to
the project site, magnitude of project and pollution potential, impacts have been
predicted for following two classifications;
1. Positive or Negative
2. Short term or Long term
3. Significant or insignificant or moderate
Economic
Health &
Water
Noise
Land
Safety
Socio
Air
Activity
Parameter
Ecology
Economic
Health &
Water
Noise
Land
Safety
Socio
Air
Activity
(-ve) (-ve)
Mechanical erection – – – – –
ST ST
(-ve) (-ve) (+ve)
Employment – – – –
ST ST ST
(+ve) (+ve) (+ve) (+ve) (+ve) (+ve) (+ve)
Greenbelt development
LT LT LT LT LT LT LT
Note:(+ve): Positive Impact; (-ve): Negative Impact; ST: Short Term; LT: Long Term
Ecology
Economic
Health &
Water
Noise
Land
Safety
Socio
Air
Activity
Evaluation &
Attribute Aspects Impact Mitigation Measures EMP Scope
Impact Zone
x Moderate x Installation of water meter and effectiveness
record keeping of water consumption
Water Domestic Sewage x Disposal of x Negative, x Avoid choking of septic tank / soak x Regular inspection of septic
Quality generation sewage x Short term pit tank /soak pit for sewage
(untreated) x Insignificant x Prevent contamination of storm disposal
water drain with sewage disposal x Supervision of mitigation
measures to ensure its
effectiveness
Land / Removal of top soil x Loss of top soil x Negative, x Topsoil removed during construction x Planning and
Soil as a part of x Short term will be collected and stored in commencement of green
Quality construction activity x Insignificant covered and isolated area for its belt / area development
x Confined to project replenishing and reuse for green belt along with construction
site development phase
Noise Generation of noise x Hearing defects in x Negative, x Avoid construction activities during x For effective
and vibration due to workers / x Short term night time implementation, these shall
operation / working employees x Moderate and direct x Periodical servicing and lubrication be made part of contract
of construction working with the x Confined to project of moving parts of machineries for conditions
machineries site and vicinity reducing tear and wear x Training to be imparted to
machineries
x Disturbance to x Provision of PPEs (ear muffs, ear workers for use of PPEs
local population plug) to workers working with and motivate them to use
machineries generating loud noise the same
Ecology Site cleaning, x Nuisance to local x Negative, x Expert horticulturist will be deployed x Planning and
excavation flora and fauna x Short term to take care of green belt commencement of green
x Confined to project development planning to enhance belt / area development
site the native species population along with construction
phase
Occupati Working at height, x Chances of x Negative, x Impart adequate training to workers / x Preparation and
onal construction of accidents to x Short term labours working on site implementation of safe work
Health building, use of lift workers / labours x Confined to project x Make them aware about risks procedures
&Safety and elevators site involved x Training to be imparted to
x Provision of required PPEs for the workers for use of PPEs
Chapter-4: Anticipated Environmental Impacts
& Mitigation Measures
Page | 4.7
[[
Evaluation &
Attribute Aspects Impact Mitigation Measures EMP Scope
Impact Zone
related work and motivate them to use
the same
x Supervision of mitigation
measures to ensure its
effectiveness
Socio- Labour force x Employment x Positive, - x Ensure employment to local
economic requirement opportunity to local x Short term people as per requirement
people x Quantifiable
x Local residents in
the vicinity
Transportation of Materials
Air Transportation as x Local ambient air x Negative, x All transportation vehicles will be x Keeping minimum
Quality well as loading / quality x Short term suitably covered with tarpaulin & inventory/stock of sand and
unloading of deterioration due x Moderate overloading of the vehicles will be other such dispersible
construction to increased x Transportation route avoided. material at site
vehicular traffic x PUC certified vehicles will be used to x Transport contract to the
materials,
avoid the exhaust emission. agencies having properly
equipment and maintained & PUC certified
machineries vehicles to avoid the
exhaust emission
Noise Transportation as x Disturbance to x Negative, x Vehicular movement will be
well as loading / local population x Short term preferred during day time
unloading of x Moderate
construction x Transportation route
materials,
equipment and
machineries
Occupati Traffic movement x Chances of x Negative, x To avoid unnecessary speeding of
onal accidents to local x Short term vehicles on road as well as inside
Health & people x Moderate the premises.
Chapter-4: Anticipated Environmental Impacts
& Mitigation Measures
Page | 4.8
Deepak Nitrite Ltd., GIDC-Nandesari
Environmental Impact Assessment Report
Proposed Expansion for Manufacturing of Synthetic Organic Chemicals
Evaluation &
Attribute Aspects Impact Mitigation Measures EMP Scope
Impact Zone
Safety x Transportation route
Socio- Contract to x Chances of x Negative, x Ensure contract to local
economic transport agencies contract to local x Short term agency / people as per
people x Moderate requirement
x Transportation route
Installation of plant equipment and machineries
Water Installation, testing x Water x Negative, x Possible reuse of water will be made x Optimal usage of water
Quantity and commissioning consumption for x Short term during equipment and machineries
of plant equipment hydraulic testing of x Insignificant testing
and machineries machineries
Noise Installation, testing x Chances of x Negative, x Provision of PPEs (ear muffs, ear x Provision of acoustic
and commissioning hearing defects to x Short term plug) to workers working with enclosures and vibrating
of plant equipment workers engaged x Insignificant machineries generating loud noise absorbance pads
and machineries in activity (short term and x Information to nearby community
x Disturbance to temporary in nature) heads about plant commencement
local people x Confined to project
site
Occupat- Installation, testing Chances of x Negative, - -
ional and commissioning accidents to x Short term
Health & of plant equipment workers / x Insignificant
and machineries employees / x Confined to project
Safety
personnel working site
Socio- Unskilled, Semis Opportunities of x Positive, - x Employment opportunities
economic skilled and Skilled employment x Short term to local people
Work force generation for local
requirement people / agencies
Evaluation &
Attribute Aspects Impact Mitigation EMP Scope
Impact Zone
Water x Washing of x Unplanned use of x Negative x Proper care to be taken to avoid x Unplanned washing to be
Quantity leakage / spillage water x Short term chemicals leakages / spillages diverted to effluent treatment
& Water due to material x Insignificant (as its x Storage area will have impervious system
Quality handling rare situation) flooring and dyke wall / garland x SOPs for Contingency /
drains to ensure no water resources Emergency measures to be
contamination in place to handle the
x Storm water drains to be separate leakages / spillages
from garland drains to avoid
contamination of storm water runoff
Land / x Leakage / spillage x Contamination of x Negative x Storage area will have impervious x SOPs for Contingency /
Soil due to material soil due to x Short term flooring and dyke wall / garland Emergency measures to be
quality handling leakages / x Confined to project drains to ensure no land in place to handle the
spillages of site / affected land contamination leakages / spillages
chemicals patch x Supervision by experts /
EHS head
Occupati- x Material handling x Accidents x Negative x Provision of necessary safety x Preparation of onsite
onal and storage involving workers x Short term measures (i.e. safety showers and emergency plan and
health & x Spillages / x Plant area and fire extinguishers) for storage area awareness of the same to
Safety leakages of immediate x Provision of PPEs to workers to avoid employees / workers
chemicals leading surrounding any kind of accident x Periodical safety audit of the
to emergency x Training to workers for safe handling plant for ensuring
within in plant of chemicals effectiveness of safety
premises x Training to workers for handling measures proposed /
emergency situations and application implemented
of safety measures x Periodical mock drills for
x Availability of first aid kits and ensuring effectiveness of
necessary medical provision in plant training to works
premises at prominent locations x Supervision by experts /
EHS head
x Agreement / contract with
local medical services
Evaluation &
Attribute Aspects Impact Mitigation EMP Scope
Impact Zone
Socio x Material handling x Spillages / x Negative x Preparation of offsite
economic and storage leakages of x Short term emergency plan and
chemicals leading x Significant awareness of the same to
to emergencyin x Project site and local people around the
the vicinity of the vicinity plant site
plant site x Public addressal system in
case of emergency
Manufacturing Activities and Operations of Utilities
Air Quality x Fuel consumption x Deterioration of x Negative x Process operations to be done as per x SOPs for effective operation
and Flue gas ambient air quality x Short term established SOPs of production plant of APCM and maintaining
generation due to x Effect on x Significant x Provision of APCM with proper logbook for the same
operation of respiratory system x Project site and design such as emissions are within x Work zone monitoring for
Boilers, Thermic / health of local vicinity stipulated norms of GPCB / CPCB VOC emissions for detection
Fluid Heaters & people in vicinity x Installation of VOC gas detectors and of fugitive emissions
GG sets. of the plant site LDAR system x Regular monitoring of
x Process gas where maximum x Usage of PPEs Ambient air quality as well
generation due to GLC occur as stack emissions as per
operation of Env monitoring plan
reaction vessels
Water x Consumption of x As the source of x Negative x Installation of flow meters at strategic x Monitoring of proper working
Quantity fresh water for water supply is x Short term locations to ensure proper recording of flow meters
industrial from GIDC, no x Moderate of water consumption x Verification of records of
operation impact on ground x Project site and x Reuse of treated effluent for Cooling water consumption and
water resources vicinity Makeup. reuse of treated effluent
x Water auditing to reduce
wastage of water
Water x Wastewater x Contamination of x Negative x Installation of Stripper followed by x Preparation of SOPs for
Quality generation due to ground water x Short term MEE followed by RO, overhauling of effluent handling, treatment
industrial sources due to x Moderate existing ETP consisting of primary and disposal
operation improper x Project site and tertiary treatment units. x Preparation of SOPs for ETP
treatment & x Proper handling of effluent to avoid operation and maintenance
Chapter-4: Anticipated Environmental Impacts
& Mitigation Measures
Page | 4.12
Deepak Nitrite Ltd., GIDC-Nandesari
Environmental Impact Assessment Report
Proposed Expansion for Manufacturing of Synthetic Organic Chemicals
Evaluation &
Attribute Aspects Impact Mitigation EMP Scope
Impact Zone
handling leakages x Regular monitoring of
x Efficient working of ETP, MEE & RO wastewater quality as per
x ETP area should have impervious Env monitoring plan
pucca flooring with garland drains to x Keep wall gate completely
prevent groundwater contamination closed at storm water
x Construction of wall gate at final drainage other than
outlet of storm water to prevent any monsoon to prevent any
discharge of contaminated storm discharge of effluent/wash-
water. water in unforeseen
situation.
x Check storm water for any
chemical contamination
before discharge, if it is
found contaminated, re-
direct to ETP for further
treatment.
Noise x Noise generation x Hearing defects to x Negative x Proper foundation, alignment and x Ensure effectiveness of
due to plant workers x Short term installation of rubber padding as well implementation of preventive
operations x Moderate acoustic enclosures for noise and maintenance schedule for
x Project site and vibration generating equipments and equipments and machineries
vicinity machineries x Regular monitoring of noise
x Preparation and implementation of levels with plant area as well
preventive maintenance schedule for factory premises as per Env
equipments and machineries monitoring plan
x Provision of PPEs to workers x Supervision by experts /
x Isolation of high noise generating EHS head
machineries
x “Work permit system” for restricted
entry to high noise generating areas
Occupati- x Industrial x Chances of x Negative x Impart adequate training to workers / x Preparation and
onal operation accidents to x Short term employees implementation of safe work
Evaluation &
Attribute Aspects Impact Mitigation EMP Scope
Impact Zone
Health & workers / x Moderate x Make them aware about risks procedures
Safety employees x Production plant involved with process x Training to be imparted to
area and x Provision of required PPEs for the workers for use of PPEs and
surroundings related work motivate them to use the
x Local people in same
vicinity x Supervision of mitigation
measures to ensure its
effectiveness.
x Agreement / contract with
local medical services
Socio- x Work force x Employment x Positive - x Ensure employment to local
economic requirement x Long term
opportunities for people as per requirement
during operative x Moderate
local community
phase x Local people in
vicinity
Management of effluent, hazardous wastes and gaseous emissions
Air Quality x Flue gas and x Deterioration of x Negative x Regular inspection and maintenance x SOPs for effective operation
process gas ambient air quality x Short term of APCM, utilities as well as reaction of APCM and maintaining
emissions x Effect on x Moderate vessels as per preventive logbook for the same
respiratory system x Project site and maintenance schedule x Work zone monitoring for
/ health of local vicinity VOC emissions for detection
people in vicinity of fugitive emissions
of the plant site x Regular monitoring of
where maximum Ambient air quality as well
GLC occur as stack emissions as per
Env monitoring plan
Water x Storage, handling, x Contamination x Negative x Preventing leakage / spillage of x SOPs to execute proper
Quality reuse and due to spillage of x Short term effluent and hazardous wastes to treatment and safe handling
disposal of liquid effluent and x Moderate avoid ground water contamination of effluent
effluent and hazardous wastes x Quantifiable x Ensure impervious flooring in ETP x Record keeping of effluent
hazardous wastes x Disposal sink and hazardous waste storage areas reuse quantity and quality
Chapter-4: Anticipated Environmental Impacts
& Mitigation Measures
Page | 4.14
Deepak Nitrite Ltd., GIDC-Nandesari
Environmental Impact Assessment Report
Proposed Expansion for Manufacturing of Synthetic Organic Chemicals
Evaluation &
Attribute Aspects Impact Mitigation EMP Scope
Impact Zone
vicinity
Land / x Storage, handling x Contamination x Negative x Preventing leakage / spillage of x SOPs to execute safe
Soil and disposal of due to spillage of x Short term effluent and hazardous wastes to handling and transportation
quality liquid effluent and effluent and x Moderate avoid land / soil contamination of hazardous wastes
hazardous wastes hazardous wastes x Confined to project x Adopting manifest system for x Record keeping of
site / affected land transport and disposal of hazardous hazardous waste disposal
patch waste
Occupati- x Storage, handling x Detrimental x Negative x Avoid manual handling of effluent x Ensuring of use of PPEs by
onal and disposal of (Acute/chronic) x Short term and hazardous waste workers
Health & liquid effluent and effect on worker’s x Moderate x Handling of hazardous wastes within x Supervision of mitigation
Safety hazardous wastes health due to x Confined to project premises through trolleys and measures to ensure its
exposure to site handcarts effectiveness.
effluent and x Persons involved in effluent handling x Agreement / contract with
hazardous waste and hazardous waste storage should local medical services
as well as be aware about risks involved and
gaseous SOPs to follow for safe work
emissions x Use of PPEs to avoid exposure
x Transportation of wastes to be done
in environmentally sound manner
Ecology x Storage, handling x Adverse effect on x Negative x Preventing leakage / spillage of x SOPs to execute safe
and disposal of floral species x Short term effluent and hazardous wastes to handling of effluent
liquid effluent and grown as part of x Moderate avoid land / soil contamination x SOPs to execute safe
hazardous wastes green belt x Confined to project x Prevention of any gaseous emissions handling and transportation
x Gaseous development site without proper APCM operation of hazardous wastes
emissions x SOPs for effective operation
of APCM
Green belt Development
Air Quality x Development and x Improvement in x Positive x Plantation of species having high x Type of species to be
maintenance of local ambient air x Long term tolerance to Air pollutants selected such as Air
green belt quality x Moderate x No. of species to be decided as per pollutant tolerant
Chapter-4: Anticipated Environmental Impacts
& Mitigation Measures
Page | 4.15
[[
Evaluation &
Attribute Aspects Impact Mitigation EMP Scope
Impact Zone
x Absorption of x Confined to project GDCR x Supervision of horticulturist
specific pollutants site x Type of species to be planted in x Survival rate of plants to be
consolation with horticulturist monitored
depending on surrounding and native
species
Water x Development and x Use of water for x Insignificant x Use of water sprinklers and drip x Type of species to be
Quantity maintenance of green belt irrigation system selected such as less water
green belt development intensive
x Supervision of horticulturist
x Use of collected and stored
rain water
x Survival rate of plants to be
monitored
Noise x Development and x Attenuation of x Positive --- x Supervision of horticulturist
maintenance of noise levels due to x Long term x Survival rate of plants to be
green belt green belt at x Moderate monitored
periphery of plant x Acceptable
premises x Confined to project
site
Land / x Development and x Improvement in x Positive x Ensure use of organic manure x Type of species to be
Soil maintenance of soil quality due to x Long term selected according to type of
Quality green belt plantation activity x Moderate soil
x Improvement in x Acceptable x Supervision of horticulturist
water holding x Confined to project x Survival rate of plants to be
capacity of soil site monitored
x Reduction in soil
erosion
x Degradation of
land/soil quality
due to excessive
use of fertilizers
Chapter-4: Anticipated Environmental Impacts
& Mitigation Measures
Page | 4.16
Deepak Nitrite Ltd., GIDC-Nandesari
Environmental Impact Assessment Report
Proposed Expansion for Manufacturing of Synthetic Organic Chemicals
Evaluation &
Attribute Aspects Impact Mitigation EMP Scope
Impact Zone
Ecology x Development and x Benefit to local x Positive -- x Supervision of horticulturist
maintenance of flora and fauna x Long term x Survival rate of plants to be
green belt x Aesthetic x Significant monitored
beautification of x Beneficial
plant site
CER Activities
Socio- x Generation of x Generation of job x Positive x Allocation of fund for CER activities x Priority shall be given to
economic direct and indirect opportunities for x Long term local people based on their
employment local people x Significant educational qualification and
x Infrastructural x Enhancement of x Beneficial skills
development / basic x Confined to project x Review of fund utilization
improvement in infrastructure and site vicinity
local area amenities
x Upliftment of
Socio-economic
status of the
people
The likely impacts on air have been studied based on following assumptions,
1. Maximum possible computed emission at full capacity utilization
2. All the sources of emission form proposed expansion project are in simultaneous
operation
3. PM10 emission would be 50% of the total PM emission for the Steam Boiler, and
100% for DG Set & GG Set.
The following methodology is adopted for the prediction based on above model.
1. Input Parameters
The input parameters for the preparation of mathematical model consist of
micrometeorological data and potential of the air pollutants. The details of all the input
parameters are discussed here below.
x Micrometeorological Data
Micrometeorological data viz. ambient temperature, Relative Humidity, wind speed,
wind direction, Cloud Cover, Rainfall, Radiation etc. required for the mathematical
modeling were collected for the site and the details of which are discussed and
elaborated in Section 3.3.5 of Chapter - 3 in earlier part of this report.
x Potential of the Air Pollutants
The probable sources of air pollution are flue gas emission and process gas emission.
The details of stack emissions viz, physical stack height, inner diameter of the stack at
exit, gas exit temperature, gas exit velocity, quantity of pollutant discharge etc. have
been considered and taken for the processing of mathematical model. The details of
stack emissions likely to occur due to proposed expansion are given in Table 4.5 for
flue gas and process gas emissions.
Process
Process
Process
Process
Process
Process
Process
Process
Process
Stack-1
Stack-2
Stack-3
Stack-4
Stack-5
Stack-6
Stack-7
Stack-8
Stack-9
G.G. Boiler Set
Source Attached To Units
Set (40 (625
TPH) kVA)
Stack / Release Height m 30 54 10 10 15 10 31 31 10 10 15 10
Stack Inside Diameter m 1 2.35 0.35 0.15 0.15 0.15 0.45 0.45 0.15 0.15 0.15 0.15
Cross Sectional Area of
m2 0.7854 4.3374 0.0962 0.0177 0.0177 0.0177 0.1590 0.1590 0.0177 0.0177 0.0177 0.0177
Stack
Gas Exit Temperature °C 100 125 100 30 30 30 30 30 30 30 30 30
Gas Exit Velocity m/sec 5.0 6.0 5.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0 2.0
Gas Exit Flow Rate m3/sec 3.9270 26.0242 0.4811 0.0353 0.0353 0.0353 0.3181 0.3181 0.0353 0.0353 0.0353 0.0353
Nm3/Se
3.1374 19.4854 0.3843 0.0348 0.0348 0.0348 0.3128 0.3128 0.0348 0.0348 0.0348 0.0348
c
Base Elevation from MSL m 41.0 41.0 41.0 41.0 41.0 41.0 41.0 41.0 41.0 41.0 41.0 41.0
Concentration of Pollutant Discharge
a) Particulate Matter 50.0 150.0 100.0 - - - - - - - - -
Particulate Matter (PM10) 50.0 75.0 100.0 - - - - - - - - -
b) SO2 78.4 261.2 169.8 - - - - - 40.0 40.0 - -
c) NO2 mg/Nm3 9.4 18.8 28.2 - - - 25.0 25.0 - 25.0 - -
d) NH3 - - - 175.0 - - - - - - - -
e) HCl - - - - 20.0 - - - 20.0 - 20.0 20.0
f) H2S - - - - - 45.0 - - - - - -
Quantity of Pollutant Discharge
a) Particulate Matter 0.1569 2.9228 0.0384 - - - - - - - - -
Particulate Matter (PM10) 0.1569 1.4614 0.0384 - - - - - - - - -
b) SO2 0.2459 5.0900 0.0653 - - - - - 0.0014 0.0014 - -
c) NO2 gm/sec 0.0295 0.3659 0.0108 - - - 0.0078 0.0078 - 0.0009 - -
d) NH3 - - - 0.0061 - - - - - - - -
e) HCl - - - - 0.0007 - - - 0.0007 - 0.0007 0.0007
f) H2S - - - - - 0.0016 - - - - - -
Location
Location
Location
Location
Location
Location
Conc.
Conc.
Conc.
Conc.
Conc.
Conc.
0.1 km @ 0.1 km @ 0.1 km @ 0.1 km @ 0.1 km @ 0.299 0.1 km @ 0.274
1st 2.452 4.481 0.810 1.045
292.5° 292.5° 292.5° 360° 180° 360°
0.1 km @ 0.1 km @ 0.2 km @ 0.1 km @ 0.1 km @ 0.294 0.1 km @ 0.226
2nd 315° 2.246 315° 4.204 247.5° 0.773 0.860
247.5° 247.5° 247.5°
0.2 km @ 0.2 km @ 0.2 km @ 0.1 km @ 0.1 km @ 0.276 0.1 km @ 0.221
3rd 247.5° 1.905 247.5° 3.486 247.5° 0.667 0.843
247.5° 247.5° 247.5°
Note: Concentration for all the parameters is expressed in μg/m 3
Table 4.7: First Highest 24-Hourly Average GLC Values for AAQM Stations
Aerial Concentration, μg/m3
Location Distance
St. Station
w.r.t from
Code Name PM10 SO2 NOx NH3 HCl H2S
Project Site project
site, m
Project
S1 -- -- Nil Nil Nil Nil Nil Nil
Site
Sankarda 60°/ ENE /
S2 3,779 0.290 0.571 0.098 0.031 0.012 0.008
Village Upwind
Anagad 205° / SSW /
S3 3,939 0.615 1.789 0.169 0.027 0.011 0.007
Village Downwind
Kanvadi 235° / SW /
S4 4,046 0.498 1.158 0.156 0.043 0.015 0.011
Village Downwind
Vasad 326° / NW /
S5 5,237 0.384 1.015 0.109 0.013 0.005 0.004
Village Crosswind
Isopleths diagram showing 1st highest 24 hourly average GLCs contour plots for the
PM10, SO2, NO2, NH3, HCl and H2S for the proposed expansion project are given in
Figure 4.1 to Figure 4.6 respectively.
OBSERVATIONS
ª The maximum 24-hourly average ground level concentration for pollutant due to
proposed project calculated using mathematical model (ISCST3) for PM10, SO2, NO2,
NH3, HCl and H2S are 2.452 Pg/m3, 4.481 Pg/m3, 0.810 Pg/m3, 1.045 Pg/m3 , 0.299
Pg/m3 and 0.274 Pg/m3 respectively which is negligible even for the worst-case
scenario. Moreover, this will occur at a distance of maximum 100 meters from the
source, which falls within the GIDC industrial estate only where there is no existence
of permanent habitat.
ª The incremental ground level concentration of all the pollutants at all the ambient air
monitoring locations is very negligible and practically nil as shown in Table 4.7 and
therefore there will not be any impact on the air quality of surrounding villages due to
the proposed expansion project.
ª It is revealed that all the parametersare well within the NAAQS after consideration of
incremental concentration due to proposed project as shown in Table 4.8.
Concentration
Station Name of
Parameters
Code Station Baseline Incremental Resultant
Figure 4.1: Contour plot showing highest Incremental GLC for PM10
Figure 4.2: Contour plot showing highest Incremental GLC for SO2
Figure 4.3: Contour plot showing highest Incremental GLC for NOx
Figure 4.4: Contour plot showing highest Incremental GLC for NH3
Figure 4.5: Contour plot showing highest Incremental GLC for HCl
Figure 4.6: Contour plot showing highest Incremental GLC for H2S
ANALYSIS OF
ALTERNATIVES
(TECHNOLOGY& SITE)
Deepak Nitrite Ltd., GIDC-Nandesari
Environmental Impact Assessment Report
Proposed Expansion for Manufacturing of Synthetic Organic Chemicals
Proposed
Particulars Alternatives
Technology
will be discharged into VECL as per
current practices. There will be no
additional discharge of treated effluent
outside plant premise.
ENVIRONMENTAL
MONITORING
PROGRAM
Deepak Nitrite Ltd., GIDC-Nandesari
Environmental Impact Assessment Report
Proposed Expansion for Manufacturing of Synthetic Organic Chemicals
6.1 PREAMBLE
The post project environmental monitoring program serves as the key tool to keep track
on performance of mitigation measures implemented & pollution control technologies
installed to prevent impacts associated with various operations of the project.
Thus, environmental monitoring is the effective observation of site conditions and work
activities; and identification of potential non-compliance situations and initiation of
corrective or remedial actions. Monitoring is as important as that of control of pollution,
since the efficiency of control measures can only be determined by monitoring.
Sr.
Components Locations Parameters Frequency
No.
Steam Boilers,
Thermic Fluid Heaters,
5. Flue gas stack PM, SO2, NOx Monthly
CPP (GG Sets), D.G.
Sets
APCM of All SO2, NOx, NH3, HCl, Cl2, H2S
6. Process vent Monthly
Reactors
PM10, PM2.5, SO2, NOx, NH3,
2 within the premise
HCl, Cl2, H2S, VOC and as
7. Ambient Air (1 in upwind and 1 in Monthly
specified by GPCB through
downwind)
consent
Hazardous Chemical Sludge from
8. General parameters Twice in a year
Waste ETP / MEE Salt
All prominent locations
9. Noise Noise levels Quarterly
within the premises
10. Soil 1 within premises As per norms Once in a year
Greenbelt Within the premises
11. Plant growth and survival rate Periodic
development and in plant vicinity
Online continuous emission monitoring system is provided for coal fired steam boiler.
Adequate scrubbing system (water / acid / alkali scrubbers) is provided for control of
NOx, NH3, SO2, and Cl2 emission from manufacturing process and the same will be
provided for the proposed expansion project. There will be generation of NOx, NH3, HCl
and H2S from the proposed expansion. Unit will provide adequate scrubbing system
(water/ alkali scrubbers) to control emission of process gas from proposed expansion
project. For detection of fugitive emission from raw material storage, material handling,
manufacturing process, continuous monitoring system with audio visual alarm will be
installed and LDAR program will be implemented effectively to control fugitive emission,
if any.
Apart from EHS policy, there will be different SOPs related to EHS of the unit, which will
be implemented and reviewed periodically. The list of SOPs related to EHS is given at
Annexure 30. Employees will be made aware about the relevant SOPs in their working
area at the time of recruitment and whenever the SOPs will be amended.
Organogram of EMC is given in Figure 6.1. Unit has assigned responsibility to officers
from various disciplines and cadres to perform and co-ordinate the activities concerned
with management and implementation of environmental control measures.
UNIT HEAD
ASSISTANT MANAGER
CHEMIST / SUPERVISOR
OPERATORS
HELPERS
Corporate Environment Head and Unit head will be responsible for total environmental
management. Overall activities to be performed by EMC are presented below and
details of responsibilities to be given to each officer of the EMC are given in Table 6.2.
parameters and causes are identified in case of non-conformity with the permissible
limits.
ADDITIONAL
STUDIES
Deepak Nitrite Ltd., GIDC-Nandesari
Environmental Impact Assessment Report
Proposed Expansion for Manufacturing of Synthetic Organic Chemicals
Risk assessment study for the proposed project of Deepak Nitrite Ltd. has been carried
out and the details are elaborated in this chapter. Based on findings and
recommendations of Risk Assesment report, Risk Management Plan for the proposed
project has also been prepared and included.
7.2.1. Objective
The principle objective of this study is to identify major risks in the manufacturing
process and to evaluate on-site & off-site consequences of identified hazard scenarios.
Pointers are then given for effective mitigation of hazards in terms of suggestions for
The following aspects and areas have been covered in this study;
x Identification of major risk areas.
x Hazard identification / Identification of failure cases.
x Consequential analysis of probable risks / failure cases;
o Determination of the probable risk by Releasing of chemical due to leakage of
storage tank and catastrophic failure.
o Risk assessment on the basis of the above evaluation & risk acceptability.
o Minimum preventive & protective measures to be taken to minimize risks to
maximum possible extent.
x Giving pointers for effective disaster management.
x Suggesting measures to further lower the probability of risk.
7.2.2. Methodology
Design data, built in safety systems are studied. Discussions are held with officials.
Safety related individual system is discussed. Hazard identification exercise is
conducted taking into consideration of materials, material handling methods, operating
procedures, built in safety in reactors, operating parameters and safety measures to be
taken in proposed plant. Containment failure scenario related to storage area is
considered for hazard Analysis and consequences of such containment failures are
considered in detail. Thus, this study is mainly oriented towards actual risks rather than
chronic risks.
The unit will handle hazardous materials and will have organized hazard control and
prevention system in place and comly with all the applicable provisions of the following
statutes;
1. The Factories Act, 1948 and Gujarat Factories Rules, 1995
In Quantitative Risk Assessment (QRA), risk has been analyzed using methodology
called Hazard Identification & Risk Assessment (HIRA). Hazard will be identified
considering the following
x The physical and chemical properties of hazardous chemicals
x Storage conditions and modes of storage (Drum storage area, above ground
storage i.e. tank farm area / underground storage etc.)
x Hazard ranking by threshold quantity of toxicity and NFPA code
Hence, all these components are to be thoroughly examined to assess their potential
for an unplanned consequence of events, which can lead to an accident. While
designing the proposed project the detailed hazard identification will be carried out to
ensure plant operation in safely manner. After completion of designing stage or once
the design criteria are well established for proposed project, hazard identification
methods to be used for the proposed project are listed below:
For the proposed project HAZOP study will be conducted at design stage i.e. while
detailed designing of plant and processes are carried out. During HAZOP study, each
pipeline as well as reaction vessel, storage tank, product and raw material storage area
will be evaluated by considering certain limitations and deviations in flow, temperature,
pressure, etc. All possible causes of deviation which gives the idea about severity of
consequence arising from each type of deviation will be identified and accordingly
designing of suitable safety measures for plant, utility and tank farm area will be
incorporated in design.
For the proposed project, FTA will be carried out by considering top events like fire or
toxic hazards, explosion of reactors, boiler, rupture of vessels, loss of pressure in
reactor, over pressurization of reactor and boiler, collapse of major plant machinery,
overheating of boiler or reactors etc.
For the proposed project, ETA will be carried out by considering some initial event
(bottom) like pipeline rupture and pump failure carrying Acids or flammable liquid,
failure of rector stirring, failure of cooling/heating media circulation, stoppage of motor,
mistake of worker/operator. With each ETA mitigation measures will be designed and
adopted to minimize the probability of the undesired event.
For proposed project, HAZAN has been carried out by considering storage details of
raw material to get an idea of necessary safety measures for operation and
environmental risk control. Analysis of mechanism of hazard occurrence for proposed
project and consequence Analysis has been carried out in Section 7.6.3 of this
chapter.
The inventory of hazardous material in the storage area is significantly larger than the
inventory involved in the process, hence storage tanks has been selected for
consequence calculations. The chemical properties of each raw material along with its
hazard identification are listed in Annexure 31.
Many raw materials required for manufacturing of the proposed products fall under the
definition of hazardous material/chemicals as per MSIHC Rules, 2000. None of the
products has been mentioned namely as hazardous in MSIHC rules but may fall under
the definition of hazardous material/ chemicals either due to toxicity or flammability.
Hazardous details of raw materials and products in form of MSDS are enclosed in Part
3 of EIA Report.
Out of the 269 raw materials required for manufacturing of proposed products, 20
chemicals have been selected for consequence analysis as given in Table 7.1.
Hazardous areas identified with view point of their storge within the proposed project
are highlighted in Figure 7.1.
$
Details of Storage Unit Threshold Value of Toxicity, ppm NFPA Code
Type Of
Sr. Hazardous
Press. &
Storage
hazard
Temp.
Storage
Storage
Size of
No. chemicals
Type
Max.
Cap.
*Std. Level 1 Level 2 Level 3 #
IDLH H F R S identified
1. Ammonia (Gas) Tank 90 MT 180 MT Amb. AEGL 30 160 1,100 300 2 0 0 - Toxicity
2. Aniline Drum 200 Lit 20 KL Amb. AEGL 8 12 20 100 3 2 0 - Toxicity, Fire
3. Benzene Tank 272 KL 272 KL Amb. AEGL 52 800 4000 500 2 3 0 - Toxicity, Fire
4. Carbon Disulfide Cylinder 100 kg 20 MT Amb. AEGL 13 160 480 500 3 4 0 - Toxicity, Fire
5. Chlorin Gas Cylinder 900 kg 100 MT Amb. AEGL 0.5 2 20 10 4 0 0 - Toxicity
6. Ethyl Hexanol Tank 305 KL 805 KL Amb. ERPG 0.1 100 200 -- - - - - -
7. Ethylene Dichloride Tank 5 KL 40 KL Amb. ERPG 50 200 300 -- 2 3 0 - Toxicity, Fire
8. Formamide Tank 25 KL 400 KL Amb. PAC 30 110 650 -- 2 1 0 - Toxicity, Fire
Toxicity,
9. Hydrochloric Acid Tank 150 KL 150 KL Amb. AEGL 1.8 22 100 50 3 0 1 -
Corrosivity
458
10. Hydrogen Gas Cylinder 75 MT Amb. PAC 65,000 2,30,000 4,00,000 -- 0 4 0 - Fire
cylinders
11. Iso Propyl Alcohol Tank 20 KL 200 KL Ambient PAC 400 2,000 12,000 2,000 1 3 0 - Toxicity, Fire
12. Methanol Tank 20 KL 200 KL Amb. AEGL 530 2,100 7,200 6,000 1 3 0 - Toxicity, Fire
13. Methylamine Tank 20 KL 200 KL Amb. AEGL 15 64 350 100 3 4 0 - Toxicity, Fire
Methylene
14. Tank 20 KL 200 KL Amb. AEGL 200 560 6900 -- 2 1 0 - Toxicity, Fire
Dichloride
Mono Chloro
15. Tank 5 KL 20 KL Amb. AEGL 10 150 400 1000 2 3 0 - Toxicity, Fire
Benzene
16. Nitric Acid Tank 400 KL 641 KL Amb. ERPG 1 6 78 25 4 0 0 - Toxicity
17. Nitro Toluene Tank 88 KL 310 KL Amb. PAC 6 33 200 200 3 2 0 - Toxicity, Fire
18. SO2 Gas Cylinder 900 kg 6 MT Amb. AEG 0.2 0.75 100 -- 3 0 0 - Toxicity
$
Details of Storage Unit Threshold Value of Toxicity, ppm NFPA Code
Type Of
Sr. Hazardous
Press. &
Storage
hazard
Temp.
Storage
Storage
Size of
No. chemicals
Type
Max.
Cap.
*Std. Level 1 Level 2 Level 3 #
IDLH H F R S identified
19. Toluene Tank 252 KL 456 KL Amb. AEGL 67 560 3,700 500 2 3 0 - Toxicity, Fire
20. Xylene Drum 5 KL 20 KL Amb. PAC 130 920 2500 900 2 3 0 - Toxicity, Fire
*PAC: Protective Actions Criteria for Chemicals, #IDLH: Immediate Danger to Life and Health
$
NFPA: National Fire Protection Association (H- Health, F-Flamability, R-Reactivity, S-Specific hazard)
For the storage of above listed hazardous chemicals a license will be required from
Petroleum & Explosives Safery Organization (PESO) as per the details given in Table
7.2. Unit has obtained licence from PESO for storage of various Gases in cyinder and
various chemicals falling under Petroleum Class A, B & C. Unit will apply for obtaining
licence for additional storage requirement for the proposed expansion project. Copy of
the licences from PESO are enclosed as Annexure 14.
Unit has adopted adequate safety measures for transportation, storage & handling
(spillage and leakage) for various hazardous chemicals in the existing plant. These
measures are listed as follows and will be implemented and followed for the proposed
expansion.
A. General safety measures for transportation, storage & handling (spillage &
leakage)
Layout and location of hazardous chemical storage tank as per natural and
mechanical ventilation.
Storage of hazardous chemicals based on their compatability characteristics.
Provision of display boards on all storage tanks showing name of chemicals, mterial
of construction, calibration of tanks and date of painting.
Installation of level indicators on all storage tanks to know the exact liquid level
inside the tank and to avoid the accidental spillage or overflow.
Provision of On-site detectors for fire based on heat &/or smoke detection with
alarm system as required.
Installation of VOC detectors for implementation of LDAR programme.
Provision of dyke walls and transferring pumps on all the storage area for the
hazardous chemicals which helps to reduce the risk of tank leakages.
Provision of spare barrels/tanks of sufficient quantity for any emergency spillage or
leakage.
Regular inspection of all the drums/tanks of hazardous chemicals and damaged
drums for separation and disposal to avoid the possibility of catastrophic rupture.
Provision of double earthing to all storage tanks to prevent the firing due to static
charges. Regular inspection of earthing pit.
Installation of on-site detectors for fire, based on heat &/or smoke detection, with
alarm system are provided as required.
Periodic calibration and maintenance of all equipments related to hazardous
chemical storage.
Installation of NRV on all pump discharge lines.
Insertion of heavy-duty gaskets to all pipe joints to prevent any leakage.
Thorough examination of piping for transfer of hazardous chemicals on yearly basis for
finding out any defects and rectify the same in due time. Maintain record of such
examination.
Use of drum trolley for the movement of drums of hazardous chemicals to avoid
accident due to manual error.
Display SOP for handling of hazardous chemicals in local language for safe
operating procedure.
Maintain proper inventory of hazardous chemical and keep buffer stock as minimum
as possible.
Implement standard procedure for safe unloading of road tanker.
Provision of static earthing for tanker unloading.
Mount muffler on silencer of tanker during entering in factory premises.
Provision of water showering system (Automated sprinkling system) to the
flammable liquid storage tanks, wherever required to avoid vaporization due to
increase in ambient temperature.
Provision of adequate firefighting system. Details of the same are elaborated in
Section 7.7 I.
Provision of first aid boxes at prominent places in the plant.
Declare entire plant area as “NO SMOKE ZONE.”
x Store cylinders in upright condition, with valve protection cap in place, and firmly
secured to prevent falling or being knocked over.
x Use spark proof tools and explosion proof equipment for containment and cleaning
up of spillage.
x Take utmost care so that cylinder temperature does not exceed 52 °C.
x Provide appropriate respirator in case of inadequate ventilation.
x Use explosion proof electrical equipments for ventilation, lighting and material
handling.
x Strictly prohibit eating, drinking and smoking.
x Open cylinder valve only after connection is made in order to avoid self-ignitaion of
hydrogen.
x Check leakages with leak detection solutions, never with flames.
x Design piping and equipments adequately to withstand pressure to be encounterd.
x Use of check valve and other protective apparatures in any line or piping from the
cylinder to prevent reverse flow.
x Use of only nonsparking tools and equipments.
x Wear an approved respirator, chemical resistant glovesand safety goggles and
other protective clothing while handling Hydrogen.
x Strict prohibition of sources of ignition such as smoking and open flames where
hydrogen is handled.
x Follow safety recommendations and safe operating procedures by persons
handling hydrogen.
x Storage of empty cylinders in separate area from filled cylinders. Fix an ‘EMPTY’
tag on cylinders immediately upon emptying.
x Storage of drums at ground level and take measures to prevent corrosion of the
drum base.
x Availablility of adequate ventilation to ensure that in case of incidental release of
solvent (vapour) the vapour concentration is as low as possible, and in any event
within the regulatory requirements
x Transfer of solvent by mechanical seal pump through fixed pipeline as far as
possible.
x Loading and unloading under nitrogen blanket to exclude moisture. If moisture could
enter into the container via seals or valves, blanket it by slight overpressure of
Nitrogen.
x Pump unloading using secured dry connections and vapour return lines preferred for
larger containers.
x Fitting of atmospheric vent of the tank with air dryer in order to prevent moisture
from entering the storage tank and equip it with flame arrestor.
x Fitting of a pressure-vacuum relief valve of stainless steel, cast iron or brass to
avoid oxidation. It prevents damage to the tank if the vent becomes blocked.
x Construction of dyke walls around storage tanks to keep liquid from flowing out in
case of damage to tank.
x Provision of emergency showers and eyewash fountains in the unloading area in
case of accidental skin or eye contact.
x Availability of safe handling procedure for storage of solvents.
Critical safety measures are the most important aspect of selection of process
technology to ensure safety in production unit. For the safety in production area, some
important critical safety measures must be provided within the process technology/
equipment itself. The details of the general and specific safety measures adopted for
manufacturing process and allied operations are as below.
A. General safety measures and Preventive Maintenance for Process Units and
Allied Operations
x Any reaction upsets to be confined to the reaction vessel itself. Charge defined
quantity of raw materials to the reaction vessel/Day tank by metering pumps/load
cells.
x Define process parameters control as per Standard Operating Procedures.
x Connect all reaction vents to either vapor condensers system or gaseoue scrubber
system.
x Engagement of trained persons for handling of processes and provision of proper
PPEs.
x Examine all the vessels periodically by a recognized competent person.
x Earthing of all the vessels, equipments and drums to protect against static
electricity.
x Disconnect all the motors and pull out fuse before any maintenance work.
x Purging of empty process equipments with Nitrogen and Air before cleaning or
maintenance.
x Installation of temperature indicators on all reactors and distillation systems.
x Display caution note, safety posters, stickers, periodic training and updates in safety
and emergency preparedness plan.
x Availability of all the necessary fire fighting equipments in plant area.
x Availablity of presons to be contacted, in case of emergency, at prominent places of
the unit.
B. Reactor Charging
x Charging of raw materials in a reactor having mechanical seal with powder charging
system and safety devices.
x Check reactor for any leakages before process initiation.
x Proper assessment by using reactivity and reaction data from laboratory
experiments or past experiences and evaluate to prevent accidents due to
exothermic reactions.
x Charging of raw materials through permanent lines for avoiding direct contact.
C. Distillation
At the time of carrying out distillation of crude product there is possibility of organic
vapour release and spillage of crude material from the system.
x Regular monitoring of distillation column pressure and temperature data and
evaluate assessment of properties of solvent to avoid fire/explosion scenarios.
x Loss of cooling media in the condenser system could lead to increase in
vapor/gases of distillate and rise in temperature and pressure could trigger
decomposition of substance in the column. Therefore, continuously monitor cooling
media circulation.
x Loss of vaccum in the Column could increase boiling point of the mixture and could
trigger decomposition in reboiler. Monitor and caliberate vaccum and temperature
gauges at regular intervals to avoid vaccum loss.
D. Centrifugation
Centrigugation during separation of solid liquid phase may lead to mechanical friction
from bearing, vibration, leakage of seals, static electricity and overspeed and may
cause hazard in the plant. Following measures will be taken care to avoid accidents.
x Redundant monitoring of critical components along with reliable maintenance for
mechanical parts.
x Selection of appropriate materials of construction to withstand additional stress put
on the materials from centrifugal forces.
x Flexible connections for process and utility lines will be preferred so that vibration
cannot be transmitted to connected equipment.
x For toxic slurries batch operation of closed centrifuge will be preffered to avoid
frequent toxic exposure to operator.
E. Filtration
At the time of separating catalyst from crude product, there is a possibility of hot vapour
release or spillage of process material from filter or pipinig.
x Availability of trained personnel during separation of process material.
x Availablility of proper collection system in order to avoid dropping of the material on
the floor.
F. Drying
Cool product material and pass in dryer where thermal energy is required to convert
slurry into dry cake formation. Depending on the temperature, the drying takes place
below the boiling point or at the boiling point of liquid to be removed.
x Carry out drying process at particular temperature so as to avoid generation of
excess vapor from the crude product, which may be volatile in nature.
x Monitor and maintain temperature of dyer so as to avoid decomposition of finished
product.
Following are the key safety measure followed and implemented in the existing palant
and will be followed and implemented for the proposed expansion project.
x Provision of all necessary equipment like portable detector, online detectors and
other laboratory equipments as proposed for regular monitoring of workplace air and
other conditions.
x Implementation of safety policy.
x Provision of proximity suits and self- breathing apparatus.
x Provision and compulsory use of necessary PPEs like helmate, safety goggles, face
mask, hand gloves and safety shoes etc. for all workers.
x Provision of ear muffs/ ear plugs to the workers exposed to higher noise level.
x Provision of first-aid boxes (Containing Tincture iodine, Eye Drops, Burnol,
Soframycin (ointment), Sterilized cotton wool, Band-aid, Antiseptic Solution
(Sevlon), Bandage, Rose Water, etc) at various places in the premises.
x Organize training program for information on accident prevention, proper control and
maintenance of equipment, first aid training and safe material handling practices.
Following measures will be followed and implemented for Occupational Health of the
workers.
x Pre medical checkup at the time of employment and regular medical checkup of
employees will be carried out as per details given in Section 7.2.4. Maintain all the
records in Form 33 certifying fitness for employment in hazardous process and
operation as per Factories Act guidelines. Maintain health register of all the
employees in Form 32. Copy of health register / record is enclosed as Annexure
24.
x Monitoring of occupational hazards like noise, ventilation, chemical exposure at
frequent intervals as per details given in Section 7.2.4 and maintain all records as
per Factories Act guidelines.
x Provision of occupational health center (OHC) and part time qualified medical officer
as per factories act guidelines
x Provision of drinking water supply for the employees as per standard of the drinking
water as per WHO guidelines.
x Availability of proper sanitary facilities for the employees so that they do not suffer
from any health ailments.
Sr.
Components Locations Parameters Frequency
No.
Skiagram, Urine,
Complete blood count, etc.
Vision, Audiometry,
Spirometry, Urine, RBS,
Periodical check-
Liver function tests (LFT), Once in a year
up
Complete blood count,
Anemia, etc.
Vision, Audiometry,
Post-employment Spirometry, Chest Once at the time of
check-up Skiagram, Urine, relieving
Complete blood count, etc.
Whole unit Safety Audit Yearly
x At design stage
i.e. while designing
proposed plant &
processes
x At pre-start up
x Utilities stage i.e. when
HAZOP Study construction is
x Manufacturing Operation parameters completed and
plant will be evaluated for operation is to be
deviation from standard started
x Storage tank
operating condition
Farm Area
x At every 5 years of
Risk Assessment
plant operation
5. and Hazard
Management x At the time of plant
&/or process
modification and
upgradation
Event Tree Analysis
and Fault Tree x After completion/
Analysis finalization of plant
x Storage tank Sequence of all unit- design.
Farm Area process/ operation will
x At the time of plant
be evaluated to identify
x Reaction vessels &/or process
all fault and abnormal
modification and
condition leading to
upgradation
abnormal event
factors have greatly increased the risk for major industrial disasters, involving loss of
human lives, plant & property and environmental degradation.
Identification analysis and assessment of hazard and risk are very useful in providing
information to risk management. It provides basis for what should be the type and
capacity of its on-site and off-site emergency plan also what types of safety measures
are required. Risk and consequence analysis are carried out by considering storage
and handling of various hazardous raw materials, intermediates and products as well as
manufacturing process.
START
END
1. Continuous release
2. Instantaneous release
This may be of gas / liquid depending upon type of material stored/released and its
characteristics. More examples, a liquid boiling at ambient conditions, will immediately
be converted to gas upon exposure to atmosphere.
An instantaneous release is any release occurring for a period less than 15 seconds.
Failure mode responsible for instantaneous releases may be catastrophic failure of
road tanker. For an instantaneous gas release, important parameters are release height
& quantity released whereas for instantaneous liquid release, important parameters are
amount spilled, spill area & pool temperature, evaporation rate, vapour mass etc.
Continuous release occurs when the material is released over a period greater than 15
seconds. For a continuous gas release, important parameters include height of leak
above ground, emission rate & total time of release. For continuous liquid release,
important parameters are spill rates, duration, area & pool temperature, evaporation
rate and vapor mass or Gas mass.
The Maximum Credible Loss (MCL) scenarios have been developed for the Facility.
The MCL cases considered, attempt to include the worst “Credible” incidents-what
constitutes a credible incident is always subjective. Nevertheless, guidelines have
evolved over the years and based on basic engineering judgment, the cases have been
The objective of the study is Emergency planning, hence only holistic & conservative
assumptions are used for obvious reasons. Hence, though the outcomes may look
pessimistic, the planning for emergency concept should be borne in mind whilst
interpreting the results.
ALOHA models key hazards like toxicity, flammability, thermal radiation (Heat), and
over pressure (expansion blast force) related to chemical releases that result in toxic
gas dispersion, fire and/or explosion.
Scenario-A: Release of chemical due to leakage and form evaporating puddle (Not
burning)
Scenario-B: Release of chemical due to leakage and form burning puddle (Pool fire)
Scenario-C: Release of chemical due to catastrophic failure (BLEVE)
Atmospheric conditions assumed at the time of accidents are mentioned in Table 7.4.
Particulars Details
Wind 3 m/s
Ground Roughness Urban
Cloud Cover 5 tenths
Air Temperature 32° C
Stability Class C
Relative Humidity 50%
*SCENARIO B *SCENARIO C
SCENARIO A
Sr. Hazardous Thermal Radiation from Thermal Radiation from
Toxic Threat Zone, m
No. Chemicals pool fire / jet fire, m Catastrophic Rupture, m
Red Orange Yellow Red Orange Yellow Red Orange Yellow
18. SO2 Gas 84 564 989 NA NA NA NA NA NA
19. Toluene <10 <10 39 <10 <10 <10 691 978 1,500
20. Xylene <10 -- -- <10 <10 <10 201 285 445
*THERMAL RADIATION INTENSITY
Red: 10 kW/sq.m. (Potentially lethal within 60 sec)
Orange: 5.0 kW/sq. m. (2nd Degree burn within 60 sec)
Yellow: 2.0 kW/sq. m. (Pain within 60 sec)
Figure 7.4, Figure 7.5 and Figure 7.6 shows risk countours plotted on plant layout
which is super imposed on the google map for scenarios of toxic threat zone,
Flammable Threat Zone and thermal radiation threat zone of catastrophic rupture
respectively.
ª Maximum distance of Toxic threat zone is observed at 989 m from leakage of SO2
gas, which is confined within the industrial estate wehre there is no permenant
habitat exist.
ª Maximum distance of thermal radiation from flammable threat is obsered at 144 m
from leakage of Hydrogen gas, which is confined within the project site.
ª Maximum distance of thermal radiation from catastrophic rupture is obsered at 1.6
km from leakage of Benzene.
Consequence / Severity
Risk Rating = Insignificant Minor / Major / Severe /
Probability x Severity Moderate
/ Negligible Marginal Critical Catastrophic
1 2 3 4 5
Highly Unlikely 1 1 2 3 4 5
Likelihood / Probability
Unlikely 2 2 4 6 8 10
Somwhat Likely 3 3 6 9 12 15
Likely 4 4 8 12 16 20
Certain 5 5 10 15 20 25
Based on calculated risk rating, level of an emergency can be defined and in the event
of accident management can take necessary steps as per the standard operating
procedure. Details of level of emergency associated with above risk rating is given in
Table 7.7.
Emergency
Alert Code
Criteria
Risk
Acceptance
Risk Rating
Emergency
Alert Code
Criteria
Risk
Type of Emergency Management
Report.
ª For any case of fire emergency, providion of standard type of Fire fighing equipments
and fire extinguishers in the storage area as well as required places in the plant.
ª Strict prohibition of Smoking inside the factory.
ª Provision of adequate and suitable personnel protective equipments to the operating
workers.
ª Availability of First-Aid facility and First-aid trained person at the time of handling
operation.
H. Emergency Management
Possible emergencies and remedial measures to prevent accident for various scenarios
are elaborated in Table 7.8, Table 7.9 and Table 7.10.
Scenario
Location Hazard Possible Action to be taken Remedial measures to prevent
considered
Consequence Causes recurrence of such incident
Action by
help them in fire fighting. available in Drum storage area.
Ignition x Try to control situation at department x Proper label and identification board
source like level with available respiratory and stickers shall be provided in the
electrical non- respiratory PPEs. storage area.
source, x If it is found uncontrollable condition x Conductive drum pallets shall be
Friction etc. by department level inform Site Main provided.
Controller for onsite emergency x Drum handling trolley / stackers/fork
BLEVE due situation. lift shall be used for drum handling.
to x Declare on site emergency if x Materials shall be stored as per its
overpressure required. Compatibility study and separate
in drum x Remove unburned drums from the area shall be made available for
site if possible without any risk. flammable, corrosive and toxic
x Start fire hydrant system or water chemical drums storage.
hose rill and spray water on x Smoking and other spark, flame
uninvolved drums in fire for cooling generating items shall be banned
purpose. from the entry Gate.
x Use foam fire extinguishers for x NFPA labels shall be provided on
firefighting of solvent fire. drums for hazard identification of the
x Do not enter in fire prone area. chemicals.
x If fire found uncontrollable condition x Exhaust shall be provided at ground
call fire brigade and mutual aider for level in drum storage area.
help. x Drum loading unloading procedures
x In case of BLEVE fire, immediate are prepared and implemented.
evacuate the area up to 50 meters of
the area surrounding.
x All hazardous activates stop at site.
x Inform nearby company to remove
hazardous material or inventory from
the compound wall.
x Ensure search and rescue and
causalities receive attention.
x Administer first aid to the victim.
Quantity, Nos.
Sr.
Type Capacity Proposed
No. Existing
(Additional)
2 kg 30 --
3.2 kg 13 --
4.5 kg 197 --
1 CO2
6.8 kg 8 --
9 kg 7 5
45 kg 2 --
1 kg 19 --
2 ABC 5 kg 82 20
10 kg 97 10
5 kg 72 --
3 Dry Chemical Powder 10 kg 51 --
50 kg 2 --
3 Mechanical Foam 9L 46 --
ª Adequate Fire hydrant system is installed in the existing plant and details of fire
hydrant system are given in Table 7.12.
ª Separate underground fire water tank of 4650 KL is provided with diesel driven
pump and Jockey Pump. Details of Fire water pump is given in Table 7.13.
ª Adequate numbers of smoke detector, flame detector, explosive gas detector and
heat detector with alarm will be provided. Automatic sprinkling system will be
installed at various suitable locations. Details for the same is given in following Table
7.14.
ª D.G. Sets of 2 Nos. x 625 kVA are provided for emergency power supply.
ª Mock drill and training are scheduled and conducted on quarterly basis.
ª Respiratory PPEs like self contanined breathing appartus, bubble hood point with air
compressor, online respirator and non-respiratory PPEs like PVC apron, gum boot,
goggles, rubber hand gloves are provided in case of fire.
ª Nearest fire station is located at a distance of 11 km from project site. Also, nearby
industrial units located within 1 km distance will provide mutual aid for firefighting.
Types of Disaster:
a. Due to Fire and Explosion
b. Due to Vapour Cloud
c. Due to Toxic Gas Release from:
i. Within the Unit
ii. External Sources
d. Hurricane, Flood, Cyclone and other Natural Calamities
x Preserve relevant records and equipment needed as evidence incase of any inquiry.
x Rehabilitate the affected areas.
The primary purpose of the on-site emergency plan is to control and contain the incident
and so as to prevent from spreading to nearby plant. It is not possible to cover every
eventuality in the plant and successful handling of emergency will depend on
appropriate action and decisions being taken on the spot. Following three staged
activities suggested as they are co-related and provide better points for emergency
preparedness, emergency action and subsequent follow up. Hierarchy of the
emergency team is given below in Figure 7.7, which will be implemented for proposed
project. Details of key personnel for emergencies are given in Table 7.15. Details of
personnel for specific possible hazard and emergencies are given in Table 7.16.
Incident Reporter
In charge Person
Sr. Name of the possible Its source and Place of
No. Hazard or emergency reasons effects Name and Telephone
designation Nos.
1 Utility failure Break down Boiler Head Engg. 1302/1280 /
Service. 1428/1456/
1296
2 Power failure Break down of Power In charge 1321/1243/
power plant plant / Electrical 1215/1301/
fault / GEB Panel 1246
supply cut off room
3 Chemical spillage from Road accident Spot Section in 1284
road tanker/ tank / charge/
vessels. material
dept.
4 Tank / vessel burgle Chocking of Spot Concerned 1429/1413/
vent lead to in charge 1438/1287/
vacuum in tank 1244/1317/
1210 /1302
5 Steam leakage Line / gasket Nearest / Head Engg. 1280 /1428/
broken spot area Service. 1456/ 1296
6 Structure Collapse Over loaded / Building Project dept. 1240/
over life 1226/1243
In charge Person
Sr. Name of the possible Its source and Place of
No. Hazard or emergency reasons effects Name and Telephone
designation Nos.
7 Effluent over flow from Plant shut down Land In charge – 1221/1222
tank / trench in house/ ECPL/ /ground Env. / SHE
NECL etc. water /
structure
8 Tank/ vessel or Material fill more Spot In charge Intercom list
System pressurized then limit plant attached
9 Lightening Discontinuity of Factory/ Electrical In 1321/1215/
earthing strip vicinity charge 1243/1246
and grounding.
11 Toxic release Mal operation/ Factory / Plant – in As per
mechanical vicinity charge intercom
failure
12 Fire / Explosion Available Factory Plant head Intercom list
Source of /vicinity attached
ignition / run
away reaction.
A. Training of workers
Training is most important for the effectiveness of an emergency plan. Before
implementing an emergency action plan, a sufficient number of workers are trained for
managing emergency. Details of various training to be given to workers are given
below:
ª Induction and safety training to all workers before engaging for work
ª Safety and fire-fighting training to all employees as well as for contractors’
employees periodically
ª Training on using personnel protective equipment to all workers
ª Training by calling external experts for imparting training on critical subjects
ª Deputing selective employees of EHS department for specialized training being
organized by different professional institution.
Check–list will be prepared to conduct internal safety survey effectively and smoothly
which will cover all the project activities and entire plant area. A template of checklist is
attached as Annexure 33. It will be ensured that the check-list is used by HSE
department as a part of SOP to conduct internal safety survey and will be updated from
time to time for the effective implementation.
G. Mock drills
ª Conduct internal mock drill for training the workers.
ª Conduct periodic drills, once in six months, to check the performance of workers and
equipments.
ª To know the draw backs/defects of the system and its corrective actions.
I. Communication
ª To maintain internal/external communication system in good working condition.
ª To modify the siren sound for emergency.
ª To install wind-socks to indicate wind direction.
J. Emergency Lights
ª To check and maintain the emergency lights in control room and selected areas.
ª To keep sufficient number of torches in supervisor’s cabin/plant and in each
department.
ª Diesel operated power generator set will be maintained in working conditions as a
stand-by in case of failure of normal power supply.
L. Assembly Points
ª To identify the location for assembling the plant emergency staff and co-ordinate in
case of emergency
ª To utilize the services of others to fix assembly points for non-essential workers and
to assemble in case of emergency.
ª Appropriate sign board showing fire exit, assembly points will be provided in the
entire plant.
ª The total quantity of chemical leaked is ascertained and discharge of Air pollutants
through stack is stopped.
ª Other persons in the area will help the injured persons to go out of the place i.e. at
open area and immediately arrange for first aid.
ª Simultaneously by Telephone he will contact the emergency control centre.
ª He will inform the Incident controllers and key personnel depending upon the nature
of emergency.
ª He will also guide the out-side agency emergency aid services till the Incident
Controller/ Site Main Controller reaches to the site of Incident.
ª As soon as Incident controller/Site Main Controller reaches to the site of incident he
will take charge of the situation and guide/advice in tackling the emergency.
ª It is necessary to know that every one on the site should be accounted for and that
the relatives of causalities have been informed. As plant is small there is no problem
of accounting the personnel. It is necessary to have an up dated list of the names of
people at site on Holidays and weekly off days.
ª If the situation is not likely to be controlled by the available sources incident
controller/Site Main controller will assess the situation and declare the emergency as
“OFF SITE EMERGENCY”.
ª The incident controller/Site Main Controller will continue to do the available
resources to control and contain the emergency till the outside authorities and aid
services reaches to the incident site.
ª After District Authority reaches to the site, he will extend all the necessary help,
assistance and give required information/data as when required to control & contain
the emergency.
The Off-site emergency plan will be made based on events, which could affect people
and Environment out side the premises. The off-site plan is largely a matter of ensuring
the co-ordination of proposed services and their readiness as far as possible, for the
specific hazards and problems, which may arise in as incident. Briefly two main
purposes of the plan are as under:
ª To provide the local district authorities, police, fire brigade, doctors etc. the basic
information of risk and environmental impact assessment and to appraise them of
the consequences and the protection / prevention measures and control plans and
to seek their help to communicate with the public in case of major emergency.
ª To assist the district authorities for preparing the off-site emergency plan for the
district or particular area. We have made our key personnel and other fully aware
about this aspect. The function of the off-site plans is as under:
Structure of the off-site emergency plan includes the following. Details of contact in case
of off-site emergency are given in Table 7.17.
ª Organizational set up-Incident controller /Site main controller, Key personnel, etc
ª Communication facilities - List of important telephones
ª Specialized emergency equipment - Fire fighting equipment
ª Specialized Knowledge - Trained people
ª Voluntary Organization - Details of organization
ª Chemical information - MSDS of hazardous substances
ª Meteorological information - Weather condition, Wind velocity etc
ª Humanitarian arrangement - Transport, First aid, Ambulance
Sr.
Name / Designation Telephone numbers (external)
No.
8 Fire Station – GSFC 2232835, 2232451
9 Fire Station – BMC 101, 2426413
10 Bhailal Amin Hospital 2280300, 2281301, 2283055, 2285555
11 SSG Hospital 2423122, 2420602,2424848
12 Narhari Hospital 2794414, 2794415, 2794413
13 Shrijee Hospital 0265-3023827-28
14 Jalaram Blood Bank 2463906,2464130
15 Inspector of Factories 2434464, 2433492
16 ESIC Gen. Hospital, Gotri, Baroda 2336421,22,23
17 GIDC Water Supply 2840262
18 ABS - Bayer 2840285, 2840286, 2840559
19 Bakul (Chemstar) 2840410, 2840210
20 Camphor & Allied 2840851, 2840852
21 GEB Sub Station – NDSR 2840320
22 Police Station - Nandesari 2840440
Role of police
The overall control of an emergency is normally assumed by the police with a senior
officer designated as emergency coordinating officer. Formal duties of the police during
emergency include protection of life and property and controlling traffic movements.
Unit will maintain the records of details of emergency occur, corrective preventive
measures to be taken. Unit will display the details like list of assembly points, name of
the persons involve in the safety team like site controller, incident controller etc.
PROJECT BENEFITS
Deepak Nitrite Ltd., GIDC-Nandesari
Environmental Impact Assessment Report
Proposed Expansion for Manufacturing of Synthetic Organic Chemicals
also identified based on need-based assessment during the EIA study. Based on this
study the village-wise budget allocation is prepared and given in Annexure 34 and
budget allocation for various areas/filed is given in Table 8.1.
Deepak Nitrite Ltd. being a corporate group understands its responsibility towards
society as well as environment protection. As a part of group policy, the group carries
out various CSR activities as per Companies Act for upliftment and betterment of local
people in vicinity of the plant site at various locations. Details of various CSR activates
carried out by the group is given in Annexure 35.
B. Health
The medical facilities in the study area are very limited. Hence, the unit is planning to
help the community through following measures for health benefits:
9 Health awareness campaigns on serious/chronic diseases.
9 Organize free medical check-up camp for the villagers
9 Providing nutritional supplements to lactating mothers, children, adolescent girls
and pregnant women.
9 Providing support for the development and maintenance of the health facilities
9 Offering specialized support services to the physically handicapped and mentally
challenged people.
9 Promote awareness programs against social evils such as addictions, AIDS etc.
and to spread the awareness of legal rights & responsibilities.
D. Infrastructure Development
9 Construction / repair of school buildings, health center, etc. and construction of
separate toilets for boys & girls in school.
9 Promotion and development of water shed & rain water harvesting structure
9 Promotion and development of solar street light and solar system
The various activities narrated above are not the exhaustive but illustrative and fund
allocated for various areas may also be diverted for other social activities depending up
on timely requirements and circumstances.
Project
Probability of
Temporary,
Secondary &
Permanent
Employment
Enhance Commercial
& Economic Status
[[
ENVIRONMENTAL
COST BENEFIT
ANALYSIS
Deepak Nitrite Ltd., GIDC-Nandesari
Environmental Impact Assessment Report
Proposed Expansion for Manufacturing of Synthetic Organic Chemicals
This chapter aims to discuss about the cost benefit analysis aspect with
environmental point of view.
However, it does not necessitate working out the cost benefit analysis as the
proposed expansion project will be setup in the existing plant in industrial estate of
GIDC to manufacture various inorganic and synthetic organic chemical. Moreover,
as SEIAA did not suggest this point during scoping of the project while awarding
Terms of Reference (ToRs), it has not been carried out.
ENVIRONMENTAL
MANAGEMENT PLAN
(EMP)
Deepak Nitrite Ltd., GIDC-Nandesari
Environmental Impact Assessment Report
Proposed Expansion for Manufacturing of Synthetic Organic Chemicals
The long-term objectives of the EMP for all the environmental attributes are as under:
ª To comply with all the regulations / applicable laws stipulated by Central & State
Pollution Control Boards.
ª To create good working conditions (devoid of air & noise pollution) for employees.
ª To rationalize and streamline environmental activities to add value in efficiency and
effectiveness.
ª To encourage and achieve highest performance and response from individual
employees and contractors.
ª To plan out the complete strategy to take care of stakeholder engagement.
ª Perspective budgeting and allocation of funds for environment management
expenditure.
ª To contribute significantly for sustainable development.
To maintain the ecological balance, unit has developed green belt in area of 28,724 m2
which will be expanded up to 36,500 m2 (33% of total plot area) within the project
premises. Layout of greenbelt is given in Figure 10.1. Unit proposes to carryout
plantation of tress during construction phase, which will be completed within a year.
Details of the plant species and budget allocation are given in the Table 10.2 and Table
10.3 respectively. The unit has developed greenbelt outside plant premise at Deepak
Medical Foundation in 500 m2 area and also participated in the greenbelt development
program in 500 m2 area at nearby villages. Photographs of greenbelt developed in
existing plant are given in Table 10.4.
Recurring Expenditure
No. of 100
1. Trees 1,700 1,70,000
Trees
2. Ground Cover & Shrubs m2 11,500 50 5,75,050
The scenario of planting arrangement and size will be based on the optimum use of
available land. Plants suitable to abate the pollution are identified to be local plants.
The general considerations involved while developing the green belt are:
9 Local/native fast-growing trees will be planted.
9 Planting of trees will be undertaken in appropriate encircling rows.
9 Species will be tolerant to air pollutants present in the area mainly dust pollution.
9 It will possess extensive foliar area to provide maximum impinging surface for
continued efficient adsorption of pollutants.
9 It will be tall in peripheral curtain plantation, with large, spreading canopy in the
primary and secondary attenuation zones.
9 It will be able to grow and thrive on soil of areas, be evergreen in habitat having
minimum of leaf fall.
9 It will maintain ecological, land and hydrological balance of the region.
In the proposed project, the unit will implement various techniques of CP in factory
premises and put continuous efforts for developing new techniques. Proposed
implementation of techniques of CP is described below:
ª Unit will maintain the proper inventory of the hazardous chemicals and keeping the
buffer stock as minimum as possible. This will help to reduce the possibilities &
magnitude of environmental hazards.
ª There will be periodic arrangement of environmental training program to create
understanding among plant personnel towards environment.
ª Unit will manufacture products with maximum yield by using high-quality of raw
material and advanced process technology through continuous R&D for the product
range being manufactured.
ª To minimize material wastage, standard SOP will be followed by the unit.
The unit will keep provision for adequate funds aside to meet with regular expenses for
the environmental control measures. Recurring cost for environmental management for
the ultimate phase of the project is given in Table 10.5.
SUMMARY &
CONCLUSION
Deepak Nitrite Ltd., GIDC-Nandesari
Environmental Impact Assessment Report
Proposed Expansion for Manufacturing of Synthetic Organic Chemicals
11.1 INTRODUCTION
M/s. Deepak Nitrite Ltd., a responsible care logo holding company, has an existing unit
located at Plot No. 4/12, Chemical Complex at Nandesari notified industrial estate of
GIDC in Vadodara District of Gujarat State and involved in manufacturing of various
inorganic chemicals @ 17,480 TPM, synthetic organic chemicals @ 8,406 TPM and
Captive Power Plant (Gas based Generator Set) of 4.8 MW capacity. The unit has
obtained Environmental Clearance (EC) from State Level Environment Impact
Assessment Authority (SEIAA), Gujarat for their existing plant on 12/09/2012.
Now, the unit proposes to expand manufacturing of some of the existing inorganic
chemicals up to 45,880 TPM and synthetic organic chemicals up to 22,004 TPM. In
addition to this, unit proposes to manufacture various other synthetic organic chemicals
with production capacity of 510 TPM. Thus, total production capacity of the unit will be
68,394 TPM after proposed expansion. Also, unit proposes to expand Captive Power
Plant (Gas based Generator Set) capacity up to 10 MW. The proposed project is
covered under Category 5(f)-B as per new EIA Notification of Ministry of Environment,
Forest & Climate Change (MoEF&CC), dated 14/09/2006 and subsequent
amendments.
The EIA Study has been carried out by Envisafe Environment Consultants,
Ahmedabad, Gujarat which is based on one season field data collected distance for
other project near to the project site during Nov 2018 to Jan 2019 (Winter Season) and
the same data has been used in assessment of impacts due to the proposed expansion
project.
General Information:
ª Category as per EIA : 5(f)-B
Notification 2006
ª Land availability, sq.m. : 1,10,600 m2
Water Pollution:
Management:
After proposed expansion, total effluent generation
will increase from 1,151 KLD to 2,156 KLD. Effluent
will be segregated into high COD/TDS and low
COD/TDS stream.
Unit proposes install stripper and MEE units for
treatment of high concentrated effluent. High
COD/TDS stream from manufacturing process
@668 KLD will be sent to proposed stripper followed
by MEE. Stripper outlet @668 KLD along with
effluent from DM-Reject @140 KLD and RO Reject
@138 KLD will be sent to MEE. Hence, total
hydraulic load of MEE will be 946 KLD. Condensate
from MEE @896 KLD will be sent to RO. Permeate
from RO @758 KLD will be re-used in cooling tower
makeup.
Low COD/TDS stream from Process, APCE, Boiler,
Cooling and Washing @ 1,321 KLD will be sent to
ETP having primary and tertiary treatment along with
hydrodynamic cavitation treatment units. Treated
effluent from ETP @ 1,321 KLD will be discharged
into VECL as per current practices and hence there
will be no additional discharge to the CETP of VECL.
Air Pollution:
ª Flue gas emission & : Presently, unit has installed Electrostatic Precipitator
control followed by water scrubber to the steam boiler (28
TPH) as an air pollution control measure. The unit
will install new ESP followed by water scrubber for
the proposed steam boiler (40 TPH). Stacks of
adequate height are provided for the existing boilers,
CPP (GG Sets) and DG sets for dispersion of
Gaseous pollutants and the same system will be
implemented for the proposed expansion.
ª Process gas emission & : There are process gas generation from the existing
control plant in the form of NOx, NH3, SO2 and Cl2. Unit has
provided adequate scrubbing system (water/ acid/
alkali scrubbers) to control emission of process gas
into atmosphere. There will be generation of NOx,
NH3, HCl, and H2S from the proposed expansion.
Unit will provide adequate scrubbing system (water/
alkali scrubbers) to control emission of process gas
into atmosphere.
Hazardous Waste : All the hazardous waste will be collected, stored,
Management: handled, transported and disposed as per the
Hazardous & Other Waste (Management and
Transboundary Movement) Rules, 2016.
11.5.2 Seismology
The study area falls in Zone III as per IS 1893 (Part-I):2002, which is referred as
Moderate Damage Risk Zone. The area is liable to earthquakes of Modified Mercalli
Intensity Scale VII.
11.5.3 Micro-Meteorology
The site-specific micrometeorological data has been collected continuously during the
study period by installing automatic weather station at project site. During the study
period, wind was blowing mostly from ENE, NE and WNW direction with average
speed 1.5 m/s and maximum speed of 18 m/s. Average temperature recorded was
24.4 °C with maximum temperature of 40.4°C and minimum of 10.2°C. The average
relative humidity was recorded as 39.4%, whereas minimum as 10% and maximum
as 83%.
x All the parameters of collected water sample from GIDC supply are within the
desirable limit except dissolved solid, total hardness, magnesium and chloride as
highlighted in Table 3.8. However, all the parameters were within the permissible
limit.
x All the parameters of collected ground water and surface water samples were well
within desirable limit except turbidity, dissolved solid, alkalinity, total hardness,
calcium, magnesium and chloride at some of the villages. However, all the
parameters were well within the permissible limit at all the locations.
x All the other Heavy metals measured in samples were below detection limit at all the
locations.
x It is observed from the surface water analysis of the study area and compared with
classes for designated use of fresh Water Standards, that samples of study area are
suitable for “E Class” i.e. Irrigation, industrial cooling & Controlled Waste Disposal.
Impact Assessment:
x As total water supply will be from GIDC only, there will not be any direct impact
envisaged on the ground water resources.
x There may be risk of ground water and surface water contamination due to
wastewater generation and discharge.
x The domestic wastewater (sewage) generation may contribute in surface water
contamination.
Mitigation Measures:
x For effective treatment, safe handling and disposal of effluent, proper stream
segregation is done.
x Unit has installed adequate administrative and infrastructural setup for the
continuous and efficient operation of ETP and will install Stripper followed by MEE &
RO for the treatment of additional effluent generation. Unit will take necessary care
during the handling and discharge of effluent.
x Well-designed storm water network is provided to collect rain water from entire plot
area and to avoid water logging within the premise.
x Wall gate is constructed at final outlet of storm water to prevent any discharge of
contaminated storm water. Contaminated storm water, if any, is diverted to ETP for
further treatment.
x Domestic wastewater will be treated in proposed STP and treated sewage will be re-
used for greenbelt development.
x All the chemicals, raw materials as well as products are stored in dedicated storage
area with impervious flooring to restrict/control leakages and prevent ground water
contamination.
x As a part of CER activity, the unit will explore the possibility to construct rainwater
harvesting and groundwater recharge structures in consultation with local gram
panchayat and village heads in surrounding villages. This may lead to positive
impact on water environment.
Impact Assessment:
x The maximum 24-hourly average ground level concentration for pollutant due to
proposed project calculated using mathematical model (ISCST3) for PM10, SO2,
NO2, NH3, HCl and H2S are 2.452 Pg/m3, 4.481 Pg/m3, 0.810 Pg/m3, 1.045 Pg/m3 ,
0.299 Pg/m3 and 0.274 Pg/m3 respectively which is negligible even for the worst-case
scenario. Moreover, this will occur at a distance of maximum 100 meters from the
source, which falls within the GIDC industrial estate only where there is no existence
of permanent habitat.
x The incremental ground level concentration of all the pollutants at all the ambient air
monitoring locations is very negligible and practically nil and therefore there will not
be any impact on the air quality of surrounding villages due to the proposed
expansion project.
x It is revealed that all the parameters are well within the NAAQS after consideration
of incremental concentration due to proposed expansion project.
Mitigation Measures
x There will be flue gas generation from proposed steam boiler (40 TPH) from the
proposed expansion. ESP followed by water scrubber will be provided as an APCM.
Stack of adequate height will be provided to proposed DG set (625 kVA) and CPP
(GG Set).
x There will be generation of NOx, NH3, HCl, and H2S from the proposed expansion.
Unit will provide adequate scrubbing system (water/ alkali scrubbers) to control
emission of process gas into atmosphere.
x There will be a chance of fugitive emission and odor nuisance during manufacturing
process as well as due to storage & handling of raw materials and products. The unit
will take adequate measures for the control of fugitive emission.
x Unit will install online monitoring system for detection and emission of gaseous
emission from proposed project.
x LDAR program will be implemented and followed for detection and control of fugitive
emission from process.
Impacts Assessment
x In operational phase, there will be chances of soil contamination due to improper
working of machineries or during transportation of raw materials or finished products.
x The impact on soil environment may be due to effluent disposal, chemical and
hazardous waste storage & handling.
x Spillage of chemicals during loading, unloading and transfer, leakage of pumps,
flange leakage in pipelines may create soil contamination.
Mitigation Measures :
x Regular maintenance of plants and machineries are carried out and proper care is
taken while loading, unloading and transfer of materials to avoid any soil
contamination.
x The entire plant area flooring is made up of concrete except open ground cover for
greenbelt development. It prevents any seepage and leakage into sub soil surface.
No spillage is allowed in open ground.
x Proper collection and handling of industrial effluent is done to prevent any seepages
and leakages.
x Entire quantity of domestic wastewater is disposed of in septic tank followed by soak
pit.
x The unit has provided dyke wall around the storage tanks area of hazardous
chemical along with transferring pumps to reduce the risk of proposed tank
leakages.
x Leakages and spillage of chemicals are controlled through regular maintenance of
pumps and flange connections in the pipelines and proper care is taken while
loading, unloading and transfer of materials to avoid any soil/land contamination.
x The unit has provided adequate designated area of 580 m2 for the hazardous waste
storage within premises having impervious floor and roof cover with leachate
collection system. In case of any spillage, it is being collected and treated in ETP.
Thus, there are no chances of contamination of soil due to the storage of chemicals
and hazardous waste.
x The hazardous waste generated is stored and handle as per the Hazardous and
Other Wastes (Management and Transboundary Movement) Rules, 2016.
11.5.7 Noise
Baseline:
The Noise readings were monitored for 24 hours at five different locations within the
study area. Noise levels were compared with the standards prescribed by MoEFCC
which indicates that the noise levels at all the locations were found well within the limit
for day & night time.
Impacts Assessment
x During construction phase the impact on noise environment will be due to
transportation activities (transportation of construction materials), construction
activities etc.
x During operational phase the impact on noise environment will be due to
transportation activities (transportation of raw materials and finished products etc.),
manufacturing activities and utilities.
x Occasional operation of D.G. set in case of power supply failure will contribute to
noise generation.
Mitigation Measures :
In operative phase of the project, there is noise generation within the premises.
However, adequate measures are taken to minimize the noise.
x The unit has installed latest technology based low noise D.G. sets with acoustic
enclosures.
x The noise generation is mitigated by installing noise barriers/absorbers around
stationery noise sources, viz. pumps, compressors and blowers etc.
x Adequate noise control measures such as anti-vibration pad for equipment with high
vibration are provided. Proper and timely oiling, lubrication & preventive
maintenance is done regularly.
x All the vibrating parts are checked periodically and serviced to reduce the noise
generation.
x Noisy equipments are enclosed in sound proofing enclosures to give residual sound
pressure lower than 75 dB (A).
x To minimize the adverse effect on the health, Earmuffs/ earplugs are provided to the
workers working under high noise area.
x Green belt acts as a barrier to the propagation of noise from the factory premises. It
reduces the noise levels appreciably. Hence, there isn’t any adverse impact to the
nearby present human settlement.
x Vehicular movements during operation phase for loading/unloading of raw and
finished materials and other transportation activity may increase noise level. The
Also, there is no protected area notified under the Wild Life (Protection) Act (1972) &
Eco-sensitive area notified under Section 3 of the Environment (Protection) Act-1986
exists within 5 Km radius areas from the Plant Site.
Impacts
Since the proposed project will be established in the industrial estate of GIDC
Nandesari, there will not be any change in land use pattern, forest cover or vegetation in
surrounding area.
literacy rate in the study area is moderate. The overall employment ratio for the villages
in the study area is 41.86%, which shows that employment ratio is low.
Impacts
The proposed project will provide more employment opportunities, which help to
improve the overall socio-economic profile of the study area.
Moreover, unit will carry out CER activities in nearby villages in the field of medical
facilities, public health & welfare and green belt development; this will help to improve
the public health in the region to some extent. Thus, there will be a beneficial impact on
socio-economic environment due to proposed project activities.
Baseline:
The survey was carried out during study period to know the ecological status of the area
with respect to flora and fauna. During the survey, a total of 154 plant species belonging
to139 genera and 70 families were noted in the study area; including 74 tree species,
20 shrubs, 45 herbs, 11 climbers, creepers and lianas, and 4 crop plants. Most of the
species are of common occurrence.
A total of 89 species belonging to 82 genera and 57 families were noted in the study
area; including 55 avifauna species, 6 mammals, 7 reptiles and 21 insects & others.
Most of the species are of common occurrence.
It is observed during site visit that floral and faunal species encountered are quite
common and found everywhere. There is no reserved forest, national park or sanctuary
within the study area.
Impacts
Pollutants of air, water and hazardous waste can interfere with the biotic and abiotic
components of the ecosystem and may include injurious effects when concentrations
exceed permissible limits. All necessary pollution control measures will be provided for
the expansion project. Hence, there will not be any adverse impact of pollution
potentials on the surrounding ecology due to the proposed expansion project.
Also, a green belt area development in and around the premises, helps in inviting small
birds & animals and other creatures to proliferate.
The unit will manufacture synthetic organic chemicals which involves various chemical
reactions. The unit has proposed latest and best technology available so far in the
market for the manufacturing of the products.
Moreover, the unit is very concerned and conscious about the product quality and
equally about the environmental protection and resource conservation; and hence unit
will put continuous efforts for replacing/upgrading plant and machineries from time to
time with the best available technology.
monitoring program. Unit has made necessary tie-up with nearby hospitals for the
medical assistance in case of any emergency. Unit has established a well-organized
Environmental Management Cell (EMC) which performs all the environmental
management activities.
Unit has also formed EHS policy to comply with statutory norm with regards to the
Environment, Health & Safety and strive for the continuous improvement to prevent
pollution, reduce wastages, conserve energy reduces risk & health hazards. Voluntary
reporting of environmental performance with reference to EMP will be undertaken. Head
of EHS department will co-ordinate all monitoring programs at site and data generated
will be submitted regularly to the statutory agencies. Frequency of reporting will be as
per the requirement of GPCB.
Sr.
Activity Management Plan
No.
1. Transportation Structural Measures:
of Raw Vehicular movement only during day time will be ensured.
Materials & Transportation by covered vehicles will be ensured.
Hazardous Regular maintenance and optimum use of the vehicles will be ensured.
Chemicals Driver will be educated about the characteristics of chemicals and
immediate actions in case of any spillage or accident.
Procedural Measures:
All the vehicles will be PUC certified.
Availability of MSDS of all the Hazardous materials to the Off-site
Emergency team will be ensured.
Availability of TREM card with driver during the transportation of
hazardous chemicals will be ensured.
2. Storage & Structural Measures:
handling of Provision of designated storage area with impervious flooring, dyke
hazardous walls and garland drain to restrict / control accidental spillages/leakages
chemicals and to prevent contamination of soil /land.
Provision of adequate ventilation system.
Provision of fixed pipeline and pumps with mechanical seal or seamless
pump for transfer of liquid raw materials.
Provision of Gas detector in process plant and work area.
Provision of breather valve, PRVs, rupture disc etc. on storage tank /
process vent.
Provision of Closed belt conveyance for transfer of coal to coal crusher
and boiler feeder.
Provision of flexi curtains at the entrance of coal storage yard to avoid
spreading of coal dust.
Provision of water sprinklers with high pressure water atomizer nozzle at
coal storage yard, coal crusher and ash disposal point.
Provision of de-dusting system at all loading and unloading points of
coal.
Procedural Measures:
Good housekeeping to maintain clean and orderly working environment
will be ensured.
Storage of all the raw materials & fuel in designated area only to restrict
/ control the seepage and prevent ground water contamination.
Control operating parameters during plant operation.
Handling of all the chemicals in a proper manner with prescribed
procedures to avoid any spillages will be ensured.
Collection and treatment of spillages, if any, with other industrial effluent
Sr.
Activity Management Plan
No.
will be ensured.
LDAR program will be implemented and followed for control and
detection of fugitive emission.
Work zone monitoring will be carried out as per the monitoring program.
Regular training to the persons handling chemicals will be provided
Maintaining minimum stock of hazardous chemicals on-site as far as
possible.
3. Manufacturing Structural Measures
Activities & Installation of flow meter at water intake point and treated effluent
Operations of discharge point.
Utilities Provision of separate energy meter for ETP, MEE / APCM
Obtaining membership of Common Environmental Infrastructure for
effluent disposal.
Installation of flow meters at strategic locations to monitor the effluent
quantity and maintenance of the same.
Construction of wall gate at final outlet of storm water to prevent any
discharge of contaminated storm water.
Overhauling of existing ETP consisting of primary & tertiary treatment
and installation of new MEE & RO for treatment of additional effluent
generated.
Provision of adequate stack height for proposed CPP (GG Set).
Provision of ESP followed by water scrubber for proposed Steam boiler.
Provision of adequate APCM (water / acid / alkali) scrubbers having
design consideration to achieve the emission norms prescribed by
GPCB for process gas stacks.
Provision of stack of adequate height to achieve proper dispersion of
gaseous emission so as to have minimal impact of ground level
concentration
Provision of sampling ports as per guidelines for monitoring of stacks
Ensure close manufacturing systems order to minimize fugitive
emissions.
Connect all reactors to scrubbers and kept under negative pressure as
per the process requirement.
Provision of dedicated measuring tanks for each reactor.
Provision of fume extraction system wherever required.
Provision of designated hazardous waste storage area with proper
roofing and leachate collection.
Acquire membership of common hazardous waste management facility
for disposal of hazardous wastes
Carryout MoUs with authorized end-users for sale of hazardous waste.
Proper foundation, alignment and installation of rubber padding as well
acoustic enclosures for noise and vibration generating equipment and
machineries
Isolation of high noise generating machineries
Adequate green belt development to attenuate the noise levels.
Procedural Measures
Sr.
Activity Management Plan
No.
Handling & management of various stream of the effluent as per the
design and maintaining proper log book
Prepare SOPs for efficient operation of ETP/MEE based on operating
guidelines provide by suppliers and ensure strict implementation.
Supervision of ETP/MEE operation by trained and experienced
personnel.
Continuous and efficient operation of ETP/MEE periodical maintenance
in line with procedures defined and manuals provided by the supplier.
Performance evaluation of installed ETP/MEE as per monitoring
program
Keep wall gate at storm water completely closed other than monsoon to
prevent any discharge of effluent/wash-water in unforeseen situation.
Check storm water for any chemical contamination before discharge, if
found contaminated, re-direct to ETP for further treatment
Ensure proper discharge of sewage to soak pit through septic tank.
Ensure good house-keeping to avoid contamination of storm water.
Prepare SOPs for efficient APCM operation based on operating
guidelines provide by suppliers.
Maintain proper air to fuel ratio is for boilers.
Supervise APCM operation by trained and experienced personnel.
Maintain operational logbook for APCM.
Prepare maintenance schedule for utilities and APCM and ensure its
strict implementation.
Carryout periodical monitoring to evaluate the efficiency of APCM as per
monitoring program.
Ensure regular maintenance of reactors and other process equipment.
Ensure regular usage of proper PPE's by workers in the plant.
Development of green belt for control of air pollution.
Collection, storage, handling, transportation and disposal of all the
hazardous wastes as per the Hazardous and Other Wastes
(Management and Transboundary Movement) Rules, 2016.
Avoid manual handling of hazardous waste.
Ensure disposal of hazardous wastes at approved TSDF/CHWIF with
manifest only.
Explore technology for cleaner production, waste minimization,
treatment / reuse / recycle / co-incineration of wastes.
Preparation and implementation of preventive maintenance schedule for
equipment and machineries
Provision of ear plugs / ear muffs to workers working with high noise
generating areas
“Work permit system” for restricted entry to high noise generating areas
Monitoring of noise levels at prominent locations as per monitoring
program.
4. Green belt Structural Measures
development Selection of species to be done considering the soil type as well as
tolerance to specific air pollutants expected to generate from plant
Sr.
Activity Management Plan
No.
operations.
x Adoption of water sprinklers and drip irrigation system
Procedural Measures:
Allocation of fund for green belt development and maintenance
Survival rate of plant species to be monitored.
Greenbelt will be maintained by regular watering, soil enrichment work
(applying organic manure) weeding and providing proper protection.
5. CER Activities Preference will be given to local people for the recruitment.
Allocation of fund for CER activities
CER activities will be planned after carrying out need based analysis
and in consultation with village heads based on their requirement
Periodical review of fund utilization
11.11 CONCLUSION
It can be concluded on a positive note that after the implementation of the suggested
mitigation measures and environmental management plan outlined, the proposed
project activities during the construction and operation phase would have manageable
impacts on the environment and on balance the project would be beneficial to
surrounding communities and the region.
DISCLOSURE OF
CONSULTANT
Deepak Nitrite Ltd., GIDC-Nandesari
Environmental Impact Assessment Report
Proposed Expansion for Manufacturing of Synthetic Organic Chemicals
The organization has been engaged in carrying out EIA studies and preparation of
EIA/EMP report for the varied range of industries and developmental activity since
2004. Besides the EIA study the organisation is prepared and confident to render the
following services in the field of environmental engineering,
ª Monitoring and analysis of Water, Wastewater, Air Pollution (Stack & Ambient), Solid
Waste and soil
ª Monitoring and analysis of Work Area Environment and filling-up Form-37 as per the
requirements under Factory Act-1948 and Gujarat Factory Rules.
ª Operation and Supervision contracts of ETP.
ª Technical consultation & assistance to ensure & assure complete Environ-Legal
compliance including liaison with statutory bodies in order to get the required
permits, clearances & consents.