03 “TRIBHUVAN UNIVERSITY. INSTITUTE OF ENGINEERING Examination Control Division 2074 Ashwin Engineering Chemistry (811403) "Subject: Y- Candidates are required to give their answers in their own words as far as practicable. Y Attempt All questions. y y ‘The figures in the margin indicate Full Marks, Assume suitable data if necessary. 1. What is meant by Normal Hydrogen Blectrode?, Discuss its use to measure standard electrode potential of eapper electrode, Calculate Ef of the following cell at 20°C. Al(s) / AI?(0.2M) 1/ Cu?(0.1M) /, Cals), Given: Fiza) = +1.66V and E'ay/as=-0.34 V (415125) 2. What is meant by ‘buffer solution’ and buffer action? A litre of solution containing 0.5 mole of CHHsCOOH and 0.5 mole of CHCOONa provides a buffer of pH 4.74. Calenlate the pH of solution after the addition of 0.02 mole NaOH [K,= 1.8x10°] (243) 43, | Define Heterogenous catalysis. What are the general characteristics of a eatalyst? Explain adsorption theory of catalysis. e242) 4, Write short notes on: p5'25) a) Global warming +b) Acid Rain 5. What is soil pollution? Point out major soil pollutants, their effects and possible remedies? 4] 6. a) Why do the transition elements form complexes? 25) 'b) Why do the transition metals exhibit variable valency? {25} 7. a) Whet are transition elements? Which of the d-block elements are not considered as typical elements and why? 12) b) Write the electronic configuration and group of the following elements Cr, Fe, Cu and Zn. (1 8. [Fe(CN)s]* and [FeFq* , both are octahedral complexes. Explain the difference between these two conmplexes on the basis of VBT. (3) 9. a) How do you distinct a double salt from a complex salt? b) Write the IUPAC names of the following co-ordination compounds. @_[Co(H20),(OH)s) i) INKCN). (ii) Ks AK(C200)3) (vi) [Cu(NH5),]8Ox BY] 10. Define the following terms with example. [es] 2) pigment b) thinner c) solid lubricant d) varnishes €) lacquers 11, Write the differences between organic and inorganic polymers. Write the piepayation and applications of polyphosphazines. +3]12. Write the method of preparation and two important uses of Bakelite and polyurethane. [2.5+2.5] 13, Write preparation and two important uses of )-TNT b) TNG 2525] ce. * M4, Hlow do enantiomers differ from diagieromers?, Write all the possible stereoisomers of ‘compound that contain two asymmetric carbon atoins.~ Be 15, What is - elimination reaction? Explain the reaction mechanism for the dehydrohalogenation of pritoary alkyl halide. 4) 16. What are the factors affecting Su! and Sy? reactions, Explain SN? reaction mechanism swith reference to hydrolysis of alkyl halide. (2512510 ‘TRIBHUVAN UNIVERSITY INSTITUTE OF ENGINEERING Examination Control Division 2074 Chaitra Y Candidates are required to give their answers Y Attempt All questions. Y y their own words as far as practicable. The figures in the margin indicate Full Marks. Assume suitable data if necessary. 1. What is an electrochemical series? How does an electrolytic cell differ from a galvanic cell? Calculate the emf ofthe following cell «25°C 114242] ZniZn"*(0.IM)#Cur*(0,05M)/Cu Given, E°Zn™ /Zn=-0.76V.E°Cu* /Cu=034V 2. a) How does an acidic buffér solution eOhaining acetic acid and sodium acetate resist the change im p" inn spite of the addition of the small amount of acid or basc? ‘Explain it. 2) ) Calculate the ptt of resulting solution when 0.01 mole of NaOH is added to 500m! of 0.1M acetic acetic acid (p" for acetic is 4.74) (31 3, What is homogencous catalyst? How does a eatalyst alter the rate of reaction? Explain with example. [14] 4. What is water poliution? Write down the major sources of water pollution and mention the possible measure to control, How docs the oxides nitrogen make the water acidic? [1+3+1] 5. Write short nates on: 2.52.5) i) Ozone layer depletion ii) Global varming due to ai pollution 6. What is condneting polymer? Describe the preparation and uses of polyurethane and Epoxy resin. [242] 7, a) Write down the sinicture of cyelic and cross linked silicones and also give the ‘engineering applications of silicones, tay 'b) What are the general characteristic of inorganic polymer? Write the preparation and uses of polymeric sulphur. 2) 8. Give reasons: 15] 8) Transition elements are mostly paramagnetic ») Transition clements and their compounds show catalytic behavior ©) Feq(SOq)s is more stable then FeSO, d) Compound of Ti” are coloured but those if Ti" are colourless ©) Zn in 3d series is called typical transition clement9. Write the expected and actual electronic configuration of Cr in box notation. Why the actual electronic configuration of Cr is different from expected electronic configuration? [In the 3-d transition series the size of atom decreases from Sc to Cr but the size remains almost similar ftom Cr to Zn. Explain, (414143) 10. How does valence bond theory explain the geometry and magnetic behavior of a complex? Explain with suitable example, 15] LL. a) Explain the formation of [FeF«]* on the basis of VBT and predict its geometry as well as magnetism, B) ) Write 1UPAC names of the given examples. 2] i) EN{CO}q ii) KalFe(CN)e} iii) Na[Ag(CN)2] iv) Ko[Hgh] 12. What primary explosives, low explosives and high explosives? Write the preparation and uses of nitroglycerine. BQ) 13.) What is Iubricant? In what situation grease and'solid lubricant are used? (142) }) What are the characteristics Of good paints? 2 14, Explain enantiomers, raccmie mixture and meso compounds with examples, Draw the structures and specify Zand & configuration of 4-methyl hept 3-ene and 2-chlori pent 2- ene. 32] 15. Describe the bimolecvlar nuélephilie substitution reaction in haloalkane with suitable example, What type of solvent is fayour for this reaction? Write down the differences between Sy, and Sy, reactions? +142) 16, Explain the reaction mechanism of dehyccchalogenation of teriary butyl bromide by alcoholic caustic soda. Mention the factorsigoverning the mechanism of El reaction. [342]oh gemahite’ vp INSTITUTE OF ENGINEERING I _| BE 3 ace Examination Control Division ame 2073 Shrawan Year/Part 1 ‘Subject: - Engineering Chemistry (91403) ‘Candidates are required to give their answers in their own words as far as practicable, Attempt All questions. ‘The figures in the margin indicate Full Marks, Assume suitable data if necessary. SSR ‘What is salt bridge? Write its functions. Write electrode Feaction, net cell reaction, EME. of the cell at 25°C and cell notation of the following electrode couple and also prediet the spontaneity of the cell reaction 04143) E°Fe/Fe"* =044V, E"Ag/Ag* =-0.80V [Fe'*] =0.01M, [Ag"}=0.1M 2. What is buffer capacity? Write the characteristics of buffer sotution. 200 ml of 0.1M CsHs COONa is mixed with 400 ml of 0.2 M C;H,COOHAa at 30°C dilute solution. Calculate the pHT of solution. : (04242) 3. Explain the terms: (a) Acetocatalyst (b) Catalytic poisoining and (¢) Promoters. 243) Explain the mechanism of ozone layer depletion. Write its preventive measures and secondary pollution effects in troposphere. H.541.5] 5. Define soil pollution, Write the major sources of soil pollntion, their negative effects and controt measures. (14242) 6. Write short notes on: 25% i) Polyphosphazine ii) Chaleogenide glasses 7. 2) Give an account for biodegradable and non biodegradable polymer with suitable example, b) What are fibers reinforced plasties? Write down the characteristics and its application (2.5+2.5] 8. What are transition elements? How do they show: (i) catalytic behaviour (ii) coloured ions and (ii) variable oxidation states? [0S+15+1.5+1.5] ‘9. Explain the formation of [NiCl,]~ and [Ni(CN),]” on the basic of VBT of coordination compounds. 2.5") 10.a) Write the formula of the following IUPAC name: R] i) Potassium penta cyano nytrosyl ferate (TIT) ii) Pentaammine chloro cabalt (11) ion iii) Tetracarbonyl cabalt (O) iv) Pentamminenitrito cobalt (III) sulphate b) "[Fe(CN),}* is diamagnetic but [Fe(CN),P” is paramagnetic" justify. [1.5415]11. What are lubricants? What are the characters of good lubricants? What is emuilsm paint? ‘Write its applications? / (28s 12. Define explosive. How it is used for defense purpose? What are the uses ‘of TNT, ING and cellulose nitrate? U+H1e+1] 13. What are geometrical isomers? Geometrical isomer is not possible in the compound (CH)CH = CHL explain. Why are trans isomers more stable than Tis-isomers? [4242] 14 What is a nucleophilic substitution reaction? Differentiate between SN? and SN! reactions, Write the factors affecting SN? and SN! reactions. [1+242) 15. Explain reaction mechanism for dehydrohalogenstion of tertiary butyl bromide, What solvent favours the reaction mechanism? 44] 16. Write ground state electronic configuration of 3d transition series, How do you explain ‘the formation of complexes by 3d transition elements? [243]Sener, || Sh Naess INSTITUTE OF ENGINEERING Led BE [Full Marks | 80 | Examination Control Division | Programme’ BCE, BME, BGE_| Pass Marks 2073 Chaitra Candidates are required to give their answers in thei own words as far as practicable Attempt AU questions. The fleures in the margin indicate Full Marks Assume suitable data if necessary, A688 Define Buffer. Wite the mechanism of acidic buffer. Calculate the pH of the solution formed by adding 0.2 g of sodium acetate in 200 mL 0.1 M acetic acid. pKa fer newtc acid = 4.74, [14242] 2. ‘What is standard hydrogen electrode? How is it used to measure the single electrode potential? Why is salt bridge used in construction of galvanic cell? Calculate the emf of the following cell at 25°C, [1+142) Tess -O.24V and "5, “n= -0.22V). Nis} /AUP*(aq)(4M)//P6 (2c) (202)/20(s) 3+ Explain with an example tho mechani of adsorption theory of catalysis. Write the differences between homogcaous and heterogenous catalysis, [sy ‘4 Define soil polttion. Write the major sources of soil pollution, their negative effects and ‘conto! ineasures, [124] ‘Write the formation, effects aad remedios of SOx and NOx. 25+2.5) & What are biodegradable polymers? Give the preparation and uses’ of Nylon 6.6 and polyurethane, [242 7 Deserbe the preparation and uses of polymeriésulphur(PS), and pelyphasphazines, 2512.5) Give an account for the following 04143] a) Ci Gd))is more stable than Cu® Ga), Justify the statement. b) Why Zinc is cafled non-typical transition elemen:? ©) Explain magnetic properties of transition clemeris 9. Explain with reasons: 2) Transition metals ean form most of the complex compounds ) Zine (I) compounds are white and diamagnetic while copper (II) compounds ere colored and paramagnetic. [2.5+2.5) 10. Explain the formation of [Co(NH)«}" and [CoF¢f” on the basis of Valence Bond Theory and also predict their magnetic property, B24] 1. Write the basic assumptions of Werner's theory of co-ordination compounds, CoCls4NH; gives a Precipitste with AgNOs solution. Explain it on the basis of Wermer’s theory. G42 12. What are plastic explosives? Write the advantages of plastic explosives. Write the preparation of TNT, TNG and nitrocellulose, (4143)13.0) What are lubricants? Skow your familiarity with application of differnt types of lubricants. ») Explain the method of application of paints in galvanized iron. [14243] 14.a) Explain geometrical isomerism with examples, [15] +) Write ail possible stereoisomers of 2,3-dibromopentane. Identify. all possible enantiomers and diastereomers from the stereoisomers, 5 15, What are the differences between ! and E? reactions? Explain the reaction mechanism for the reaction of primary alkyl halide with alcoholic NaOH. Res] 16. Why does SN’ reaction give both retention and inversion isomers but SN? gives only inversion isomer? Write the mechanism for the reaction between bromocthane and ag.NaOH. [283]¢ 03 TRIBHUVANUNIVERSIFY INSTITUTE OF ENGINEERING ~ Candidates are required to give their answers in their own words as far as practicable. Y. Attempt AML questions. v The figures in the margin indicate Full Marks. “ Y Assume suitable data if necessary. 1, Derive the equation required to ealculate the emf of cell at non-standard condition. What are the factors that affect the single electrode potential value? Calculate the oxidation cleetrode potential of given half cell reaction at 20°C. 24142) Fel (.1M)+e— Fe" (0.2M),E° = 40.279 £2. What are the eriterin for buiter system? Caleulate the ebange in pH of buffer system hhaving 200 ¢¢ of 0.1 m.CH;COOH and 0.1 M CH,COONa when 1 milliinole NaOH is added into it. (K, = 1.810") {243} 3. What is autocatalysis? Explein the mechanism of adsorption theory of estalysis with example, [4] 4. What are the major pollutants responsible for water pollution? How do the oxides of sulphur and nitrogen make water acidic? 5 (243) 5. What is meant by ozone depletion? Write its causes nnd consequences. 243) 6. 3) What are chalcogenide glasses? Give afiJaéeount of preparation and uses of chaleogenide glasses in the engincering field. (14242) ») Write down the preparation of cyclic silicones. 7. a) Give an account for the biodegradable and non-biodegradable poiymers with suitable examples, (2.5%2} >) What are fibers-reinforced plastics? Write down its applications. 8. Explain the origin of the adsorption spectra of transition elements with d to d transitions. [5] 9. Mention the main applications of 3d elements and give main causes of variable oxidation states shown by transition elements (32) 10. a) Describe the simple test to distinguish between the following pairs of compounds on the basis of Werner's theory. [Co(NH,),CI]SO, and {Co(NH,),SO,]CL B24) 'b) Name the following complexes by IUPAC system. i) KIA] 4) [Co(en),] Bs, iti) [Cr(H,0), CHIC, iv) [PONH,),Ch IC, ©) State EAN rule.11, Using VBT, predict the possible number of unpaized number in the following complex compounds, K,[Fe(CN),} and [Fe] (2.5125) 12, Write the mechanism for the conversion of Bromomethane into methanol in presence of ‘aqueous alkali. Also explain the stereochemistry of the redetion. (342) 13, What do you mean by Elimination reactions? Explain the reaction mechanism for the and Ey reactions with referance to dchydrohalogenstion of haloalkane and . point out the factors affecting these mechanism. [LS#1.542] 1S. Why does haloalkane favour Sy reaction? Explain why there is only inversion product in 8x2 and both inversion and retention products in Syl path, (14242) Se ee ee 7C w 63 TRIBHUVAN UNIVERSITY x INSTITUTE OF ENGINEERING — [Level BE Full Marks | 80: Examination Control Division | Programme BCE, BME,BGE Pass Marks 32 2071 Shawan art tt ¥ Candidates are required to give their answers in theit own words as fat as practicable, ¥. Attempt All questions. The figures in the margin indicate Full Marks ¥ Assume suitable data if necessary. 1. Whac is buffer solution? Calculate the pH of 500 ce of 0.2 M CHsCOOH solution when. 2g of sodium acetate is added. [K, for CHyCOOH is 1.810] [eq 2. What is Daniell cell? Answer the following question using equation (a) and (b) 14 (Fe! 02M) = FMFe (0.11), €° = 0.770, (6) Cu(O.3M)-2e = Cu, & = -0.24v, (net cell reaction (i) spontaneity of redex reaction (i) cell notation (iv) emf of cell ‘What are catalytic promoter and catalytic poison? Explain their activity on the basis of adsorption theory of eatalyss. PH] 4. a) What are chlorofluorocarbons? Hxplain their photolytic reactions in the upper atmosphere G8) ') Discuss about the air pollution caused by oxide of nonmetals? a 8. What are the major water pollutznts? Point out their adverse efféet and the possible measures to control water pollution (19243) 6. Write the preparation and uses of Teflon and epoxy resin. What are conducting polymers? Point out their applications in engineering field. +141] 7.) Give preparation and uses of the nonmetallic super conductor, G2] b) Write down the main characteristic of inorgenic polymers. 8. Give an account for the followings: i) Transition metals are well known to form complexs. 2) ii). Copper (1) compounds are white and diamegnetic where as copper (If) compounds are colored and paramagnetic. Q iii) Zine is nontypical transtion metal. 0 ._ 8) Explain the variable oxidation states of transition elements. Which divalent meta! has ‘maximum paramagnetic character among the first trénsition metals? (25+141.5] b) A transition metal forms alloys with other transition metals easily. Why? Explain. 10. Explain how the two complexes of Ni, [NI(CN)4” and [NICCO}Y? have different Structures but do not differ in their magnetic behavior (Ni = 28). 15] 11, 3) Write the FUPAC name of the following eompoundsfions pH) 1) Co{NHA).NO3 Ch 2 1 Fe (GOda” 1 [eetent Ch” IN) Nii fer (H.0) (NCS) 1b) What is complex compound? What do you understand by principal and auxiliary valency of the central ion in complex eompound? Illustrate them in [Co (NH5)JC\s aa03 TRIBHUVAN UNIVERSITY Exam, SE ee ae INSTITUTE OF ENGINEERING = [Level BE ‘ull Marks | $0 Examination Control Division Programme (BCE, BME, BGE | Pass Marks 32 2071 Shawan (Yar/Pen 10 =a tre ‘Subject: - Engineering Chemistry (SH403) Y Candidates are required to give their answers in their own words as far as practicable, Y. Attenspt All questions, Y The figures in the margin indicate Pull Marks, Y Assume suitable data if necessary. : 1. What is buffer solution? Calculate the pH of 500 oc of 0.2 M CHsCOOH solution when 2g of sodium acetate is added. [K, for CHsCOOH is 1.810] f+4 (>. whatis Daniell cell? Answer the following question using equation (a) and (b) ty {a Fel (0.204) =F" © (0.211), €°= -0.77¥4{(o) CUIDBMY Eze = Cu", €=-0.34V, (i) net cell reaction (i) spontanetty of redex reaction {i cell notation (iv} emf of cell 3, What are catalytic promoter and catalytic poison? Explain their activity on the basis of adsorption theory of catalysis, 243] 4, a) What are chlorofluococarbons? Explain their photolytic reactions in the upper atmosphere a ) Discuss about the air pollution caused by oxide of nonmetals? a (5. What are the major water pollutancs? Point out their adverse effdet and the possible measures to control water pollution. [13243} 6. Write the preparation nd uses of Teflon and epoxy resin. What are conducting polymers? Point out their applications in enginecring field. BeI+) 7. a) Give preparation and uses of the nonmetallic super conductor. G2 1b). Write down the main characteristic of inorganic polymers, . & Givean account for the followings: i) Transition metals are well known to form complens. @ ii) Copper (1 compounds are white and diamegnetic where es copper (IT compounds are colored end paramagnetic Q iif) Zinc is nontypical wanstion metal. uy 9, a) Explain the variable oxidation states of transition elements. Which divalent metal has maximuin paramagneti¢ character among the frst transition metals? 251415) b) A transition mictal forms alloys with other transition metals easly. Why? Explati 10. Explain how the two complexes of Ni, [Ni(CN)J* and (Ni(CO)|* have different structures but do not differ in their magnetic behavior (Ni = 28). (1 11, 2 Write the TUPAC name of the following compounds/ions (24142), ) {CoAIEISNOH Ch in tFe (Goa tu) fcr fen) ach)” V] NBg [er (HL,0} ANCS) J 8) What is compléx compound? What do you understand by principal and auxiliary valency of the central ion in complex compound? Illustrate thert in [Co (NH3)JCh.12,4) What are lubricating oils? Indicate its application in engineering work +b) Show your familiarity with the types of paint. 13.2) Weite the difference between enantiomers and di examples. 1b) Write Cis, Trans and Z, E not rigisomers giving appropriate forthe possible isomes of but-2-endioe acid. 14. a) Explain the mechanism involved in the renetion betwcen bromomethane end aqueous NaOH. b) How do nucleophile and solvent affect this typ. 15.a) Differentiate between B! and E? reaction 1¢ of reaction? +) Explain the reaction mechanism forthe deby drohalogination of 3 halide 16. What are low explosives? Write the preparation and uses of GTN and TNT. (142 2 (342) Bi e (24) i)3 TRIBHUVANUNIVERSITY INSTITUTE OF ENGINEERING = |L Examination Control Division | Programme ‘BCE, BME, BGE | Pass Marks | 32 2071 Chaitra Year/ a —— [sa ject Enginearng Chemistry 1409) _ 7 Candidates are required to give their answers in theit own words as far as practicable, Attempt all questions. Y y ‘The figures in the margin indicate Full Marks. Assume suitable data if necessary. 1. What is SHE? Calculate the emf of, electrode couple of E*,,y.) =~14Vand O.7TV.. Where the concentration of Sn™,Pe"and Fe" ate 0.2M0.1M and 1M respectively. (243) 2. pin the mechanism of buffer ation with a stable exampic. Calculate the wei cae Of NEWCI required tf prepare buffer solution having pb = 9.35 in 200 ex of 021 ‘ammonia solution. (pb = 4.74) . Be] 44, Whab is heterogeneous eatalysis? How does a ¢atalyst alter the rate of reaction? Give a brief account on the intermediate compound formation theory of-eatalysis. [+3] 4 8) What is ezone depletion?) Write the chemical reactions involved in the statospheri ‘ozame depletion by nitric exise? 11422) 'b) How does carbon dioxide cause atmospheric pollution? . 5, What are the major water pollutants und their hamifil fleet? Mention the possible measures to control water pollution. (23) 6. a) Write the engineering applications of Silicone and give the stauctuze of eycie and cron linked siticons. B21 ). Write the preparation of polyphosphazine and its uses. 7. What are biodegradable polymers? Write down the preparation and uses of Nylon 6.6 and Teflon. (4) 8.) Why do transition metals form complex compound? G2 +) Explain why the 34 transition series having completely filled d-orbital cannot form ‘coloured compounds. 9, What are transition elements? paramagnetic in nature? Explait 10. Name the following complexes by TUPAC system: Q3) i) (Cr (120). (NH),] Brs ii) [CuCh(CHNT)o} fit) NiPICh iv) (Cr (NEB) State and explain EAN rule as applied to metal complexes. 1y does the presence of unpaired electrons make a substance it with magnetic moment measurement. fea) L1Differentiate between inner and outer orbital complexes, Magnetic measurement on K,[Fe(CN),] indicates the presence of one unpaired electron, predict onthe basis of VBT whether the given complex is inner oF outer complex. 23]12, Define explosives. Why are the primary explosives called "detonators"? Write the reaction oftoluene forming an explosive. Mention the important uses of GTN and plastic explosives(1+1+1+2] 13.a) What are solid lubricants? Mention the types and function of lubricants with examples.[1*+2+2] 'b) Explain the method of application of paint in galvanized iron. 14.) What isomerism is shown by tartaie acid and why/? (213) by Define enantiomers with examples. Differentiate between racemie mixture and rmesocompound. 15. Explain the reaction mechanism for the hydrolysis of tertiary alkyl halide by aqueous ‘NaOH, What solvent favours the reaction mechanism? UH 16. What is Saytzeffs rule? Describe the mechanism for the reaction of 3alky! halide in 223]INSTIEL | OF ENGINEERING Level | BE Full Marks | 30 | ‘xamination Control Divis Programme BCE,BME,BGE Pass Marks | 32 2070 Ashad ool Year (Part U/t Time th 10. Me 12. 13. 14, 16. Subject: - Engineering Chemistry (S403) Candidates are required to give their answers in their own words as far as practicable. Altempt All questions. The figures in the margin indicate Full Marks Assume suitable data if necessary. ‘What is buffer and buffer capacity? To 100 ml of 0.1 M acetic acid, 0.1 gm of sodium hydroxide is added. Find the pH of the resulting solution. (pk, for acetic acid is 4.74) (243) How does a galvanic cell differ from an electrolytic cell? Calculate the EMF of the cell; Zelda (0.001M)// Ag” (0.1M) / Ag. The standard potential of Ag/Ag* half cell is 0.080 Vand ZnvZn"™” is - 0.76 V [243] 8) What are promoters? Mention the action of promoters. (141) b) Describe the adsorption theory of catalysis with a suitable example. BI a) Write down the sources and defects of sulphur oxides. BI b) Explain the causes and effects of ozone layer depletion. R) What are the major water pollutants afid their hartiful effect? Mention the possible measures to control water pollution B+2] ‘Write short notes on (i) Sulphur based polymers (ii) Chaleogenide glass, 342] - a) Give preparation and uses of Nylon.6,6 and polyurethane, (4) b) What are engineering applications of conducting polymer? i) a) Write the important characteristics of transition clements, (2.5) b) Explain the magnetic properties ofthe transition elements. (2.5) Explain the following: (2512.5) a) Complexes of transition clements are generally Coloured b) Most of the transition elements are paramagnetic, What are primary and. secondaty.valencies of meial?Gxpiainsthe stmcture of K,[Fe (CN)]s on the basis of Werner's theory. © [243] 8) With the valence bond concept, explain the geometry and magnetic character of the complex [Ni (CO),}. Write down one of the limitations of valence bond theory. 4) ») Write the IUPAC name of the following co-ordination compounds. el ) K Prd ii) Ks [AL(C.04)3} iii) [Co (NH)5804) Br iv) [Pt (NH;)Ch] SOs Explain the reaction mechanism for the hydrolysis of tertiary butyl bromide by aquéous ‘NaOH. Differentiate between SN' and SN* mechanism. [3+2] a) How do enantiomers differs with diasteoisomers? Illustrate with an example, [142] 'b) What isomerism is shown by 2-bromo 1-chloropropene? Mention Z and E notation for the compound. (21 ‘What are secondary explosives? Give preparation and properties and uses of GTN and TNT. [233] What do you mean by Elimination reactions? Explain the reation mechanism for the reaction between primary alkyi halide and alcoholic NaOH R83] a) What are lubricating oils? Indicate their importance. +2) by Show your familiarity with types of paints Qhe0 pila ak os Tapxuvarentvensiry aa INSTITUTE OF ENGINEERING = [Level Examination Control Division programme | © 2070 Chaitra Year/Part /V/1 Subject: - Engineering Chemistry (SH403) Candidates are required to pive their answers in their own words as far as practicable, Attempt All questions. ‘The figures in the margin indicate Full Marks. Assume suitable data if necessary. RRAM Derive Henderson equation for bulfé solution, What is the pH of resulting mixture obtained by mixing of 100 cc of 0,2 N HCL and 50 cc of 0.5M ammonia solution, Ki for ammonia is 1.810. [+4] 2. How can you measure the standard reduction potential of Zn electrode? Hydrogen electrode at 1 atm is connected with Zn electrode in which the emf of the cell is found to be 0.61 V at 25°C. If [Zn] = 1.0M, caleulate I in hydrogen electrode. 243) Giving 2 suitable example, explain the mechanism of ‘any two criteris for choosing 2 catalyst for industrial Purpose. [344] 4, a) What do you mean by CEC? Mention their photolytic reactions in high altitude at stratosphere, 1) Howdo the oxides of sulphur and nitrogen make Water acidic? (11252) 5. Write major sources of water pollutioa, How does CO2 act as pollutant of the atmosphere? Explain: Ie+3) 6. Give an account on chalcogenide glasses and polysulphur nitride. [2542.5] 7. Bxpiain about the biodegradable and non-biodegradable polymers with suitable examples (2.5x2] 8. Explain giving reasons. a) Transition metals and their compounds show paramagnetic behavior. 3) b) Zine (11) Compounds are white and diamagnetic while copper (111} Compounds sre colored and paramagnetic. [2.5] 9. Transition elements formed colored compounds. Explain this on the basis of d to d transition, vg le PEF 10. Compare the magnetic beltivior of the complex entities [F.(CN)s]* and [FeFs]” using ‘volence bond theory. [2,542.5] 11/2), Write the IUPAC name of he following co-ordination compounds... a i) [CNHI i) (PtQNHsyCh} iif) Nas [C, (C20.)s] iv) (CO (NES)«Ch] CI b) What is EAN? How would you. explain the stability and magnetic behavior of ‘‘iiatinaremeiaicnsed bey Tiel ran. e - plee B 2 1 Sea 12-2) Write the characteristics of a good paint and explain the method of application of paint in galvanized iron = — +b) Mention the types and functions of lubricants with examples. ray 13. 8) What isomerism is shown by tie acid? Weite its possible isomers py 1) What do you mean by racemic mixture? Explain chemical resolution of 2 ruemic mixture. 2] 14,8) Desegibe SN! reaction mechanism in haloalkane shown stereochemistry. b) Why does nucleophile attack the substrate molecule from backside in SN? reaction mechanism? (ay 15. Discuss Bt reaction with reference to'the dehydrohalogenation of alkyl halide. How does ) differs from E* reaction. 342) 16. What are plastic explosives” Write down the characteristics of explosives. Give the preparation and uses of explosive obtained from toluene, [12]63 _aRuBHUVAN UNIVERSITY Ti INSTITUTE OF ENGINEERING Level Examination Control Division, [Program | 2069 Ashad Year /Part ingineering Chemistry (St 405) — ¥ Candidates are required to give their answer Y Attempt All questions. % The figures in the margin indicate Full Marks, Y Assume suitable data if necessary, What is meant by buffer capacity? A chemist desires to Prepare one liter of a solution buffered at pH 9.00. How many grams of ammonium chloride have to be added to one liter of 0.20M NEG to make such buffer. pKa value of ammonia is 4.75 +g 2. How does an electrolytic cell differ from a galvanic cell? ‘Calculate the emf of the cell, +3) 2n/Zn""(0.001MY//Ag'(0.IMV/Ag. ‘The standard potential of Ag/Ag’ half coll is +0.80V and Elta is 0.760 >. Expliin the terms: (a) Heterogeneous saalysis (b) Catalytis poisoning and promoters, [243] ‘4 What is meant by ozone depletion? Mention its causes and ‘consequences, (23) Nhat are the major water pollutants and their harmful effects? Mention the possible measures to control water pollution. BR] &. Write short notes on: (a) Polypinosphazines (b) ‘Chaleogenide glasses 2.5x2] 7. a) Give an account for the biodegradable and non-biodegradable. polymers with suitable ‘examples. (2.5x2] 5) What are fiber-einforced plastics? Write down thé applications 8. Whatare transition elements? Point out the applications ofthese elements and their complexes, [5] °- Compare ionisation potential and oxidation state of transition elements with representative jeaments. What is the effect of fantanie contraction in prope tee OF een elements? Explain how colour is originated in transition metal complexes. [i+1+143) '0. Write assumptions of valence’ bond theory of complexes. Explain formation of spin paired ‘complex on the bass ofthis theory. Mention its magnetic behaviour [242+1) {1- What is a Chelate complex? Show Wemer's representation and TUPAC name of the following complexes. (@) (Cu(NH;)\]S0, (b) K[Ptel,(NH,)] [1+242) 12. Give an account of low and high explosives. Write the preparation and uses of TNa, B+] '5- 3) Show your acquaintance wit lubricants? Under what situations ‘Sreases are used? 542] ») What do you understand by paints? Mention the requisites ofa 200d paint. ‘4 8) What isomerism is showm by butenedoie acid and why? (243) ») Define enantiomers with examples. Differentiate betwoon racemic mixture and ‘™meso-compound. . 15. Explain the reaction mechanism for the hydrolysis of 3° alkyl halide by aqueous NaOH, What solvent favours the reaction mechanism? (+1) 16. What do you mean by Elimination reactions? Explain the reaction méchanism for the dehydrohalogenation of tertiary alkyl halide. [243]. 03. TRIBHUVAN UNiveRsiTY Fram INSTITUTE OF ENGINEERING Level BE. Full Marks | 80 ee C 1 Divisi ; BCE, BME, amination Control Division | programme BGE Pass Marks , 32 2069 Chaitra Year/Part [1/1 Time Shi - Subject: - Engineering Chemistry (SH403) _ Y Candidates are required to give their answers in their own words as far as practicable, Y Attempt All questions. “The figures in the margin indicate Full Marks ¥ Assume suitable data if necessary. 1. Define a galvanic cell. What are functions of salt bridge in a galvanic cell? Predict the feasibility of the following reactions, i) Zn+Ao* > Z2nt**+ Ag ii) Zn** +Ag > ZmeRAG* Given, E°zn**/zn= - 0.76V, E%5*/ag = 0.B0V- fa+143) 2. What Is a buffer solution? Discuss the mechanism of buffer action with suitable examples. Z [144] 3. What Is meant by catalysis? Point out its importance. Discuss intermediate compound formation theory of catalysis. (141+3] 4. a) Point out the sources of radioactive substances responsible for environmental Pollution. Give their adverse effectsand protective measures. [2.5] b) Briefly discuss any two sources of arganic and inorganic substances responsible for water pollution. Point out their possible remedies. [2.5] 5.a) How do exhausts of internal combustion engine pollute ait? Give the possible remedies. (3) b) What is the photochemistry behind ozone layer depletion? (21 G. a) What are Chalcogenide glasses? Give their uses, (2.5) b) Give the preparation and applications of silicone rubbers. [2.5] 7.) Give the preparation and applications of polystyrene and polyurethanes. [4] b) What are the advantages of conducting polymers? 1 8. Why do transition elements form complexes? List the Industrial application of 3¢ transition elements in engineering. “(3+2] 9. Explain the following features of transition elements with reference to 3d transition series; ‘ (2.542.5] a)" Variable oxidation state b) Formation of Colored compounds 10. Differentiate between complex salts and double salts. How does Werner's theory explain the bonding In complex salts? [144]1a) Write the LUBAC name of following; i) Ks {fg Md fi) KeLFe(CN)s} ili) {Co (NHL) s ef” iv) LifAlHa) b) How -does-valence bond theory explain its magnetic behaviour, 2 nese 4 12, What are primary explosives, preparation and applications 2,4,6-Trinitroteluene (TNT). 13.4) Show your familiarity with quid, sémi solid and solid lubricants giving examples. b) Discuss any two types of paint works. 14, a) What are geometrical isomers? Give an example b) Show your familiarity withdlastereomeris™- ¢) Draw the structure of 24Chlorobutane speci'ving & and $ configuration. {ts showing their applications in engineering 15, Discuss the unimolecular nucleophilic substitution reaction mechanism in all halide showing the stereochemistry 16, What Is meant by elimination reaction? Biseuss Et and 2 reaction mechanism. gw explosives and plastic explosives? Givé the {2} the formation of (Ni(NH3)6]""? Predict (3t (342) Gl a (2] i2i @ (11 kyl 5] +4]03 —_tmtuvan usivensiry a INSTITUTE OF ENGINEERING | Tevel Examination Control Division | Progr: 2068 Chaitra (Year/ ‘Subject: - Engineering Chemistry (SH 403) Y Candidates are required to give their answers in their own words as far as practicable. Y Attempt All questions Y The figures in the margin indicate Full Marks, ¥ ‘Assume suitable data if necessary. 1. What is meant by normal hydrogen electrode? Calculate the em? of the following cell at 25°C Mg|Mg™(0.1My/Ag' (IM/Ag. Given E°Mg™/Mg = -2.37V, E*Ag/Ag’ =-0.80V. [23] 2. Explain the mechanism of basic buffer, Write the equation for acidic buffer, 0.005gm equivalent of KOH is added 10 400ml of 0.1N acetic acid, calculate the pH of the mixture, (Ka for acetic acid = 1.810"). [15+ 0.5+3] 3. Define heterogenous cat is. Point out some characteristics of catalytic reactions and ‘mention its industrial application, (vay 4, a) Define soil pollution. What are its sources? [143] b). Explain cause and effect of Ozone Jayer depletion. {4} c) Give averse effects of ()) pb (ii) phosphates in water. (2) 5, What are the general churacteristics of inorganic polymer? “What da’ you mean by ctoss - linked? What are the engineering uses of chalcagenide polymer? [2+142] 6. Write short tote on fibre reinforced resin. . (31 7. a) Explain variable oxidation states of transition metals, along with nature of oxides. 4] b) Explain the colour of [Ti(H,0),|* ion. ~ [4] c) Transition metal complex ions with d? or d!®Gonfiguration are colourless. Why?) I 8. a) Explain the formation of [Ni (CO).]* Complex ‘on the basic of VBT. Also predict its geometry and magnetism with reason. (2+y b) Write the formula of the following co-ordination compounds. [0.524] i) Dichloro-tetra-aqua chromium (Ill) cation ii) Dieyano argentate (I) ion—— — iii) Sodium hexa nitrito cobaltate (II) iv) Hexa-cyanoferrate (IIT) ion ©. a) What are primary explosives and plastic explosives? Give the methods of preparation of TNT and uses. 4143] b) Explain lubricating oils with types. 13) ©) What are requisites of good paint? B] 10.) Define: (i) Optical isomers (ii) Racemic mincture (iii) Chirality (iv) Optical activity. 14) b) Get differences in between enantiomers and di-stereomers. Bl ©) How many meso-forms are possible for CH,OH (CHOH); CH;OH? Write their Fischer projection. 1 11. a) Define lubricant and lubrication and explain the main purpose of lubricant. [sy b) What is paint? What are the requisites of a good paint? [142] 12a) Deseribe the mechanism involved in the reaction between a tertiary alkylhalide and aqueaus caustic potash. : [15415] What type af solvent favours the unimolecular nucleophilic’ substitution reaction * »)eee 03 _TeUBkUVAN UNiveRsstY Bam a INSTITUTE OF ENGINEERING Level Ee Examination Control Division | Pr 2 | 2068 Baichakh Tis, Subject: - Engineering Chemistry Candidates are required to give their answers in their own words as far as practicable. Atiompt AU questions. ‘The figures in the niargin indicate Full Marks, Assume suitable data if necessary. KA6K {What's galvanic cell? Write electrode reaction, net cell reaction, EMF of the cell and cell notation of given electrode couple and lso prediet the spontaneity of the cell reaction. [144] \"E? Znfan" =0.76V, E° Ag‘/Ag = 0.80¥ [Zn] =0.01M, [Ag*]=0.1M 2. How does an acidic builer solution reserve its PH value on the addition of strong acid or sirong base? 106ml of 0.2M CH,COONa is mixed with 200ml of 03M CH3COOH, which is 2.1% ionised ia ditetc solution, Find out the PHL of the resulting solution. _[2.542.5] 3. Write the adsorption theory to desctibe the mechanism of heterogencous catalysis with a suitable example, How does 2 promoter enhance the catalytie action? List any two eriteria of catdlysed reactions applicable for the industries GAH) _ & Write short notes on:fany o%0) (2542.5) 2) Green house effect ) Formation and depletion of ozone layer ©) Acid rain 5. List out four major pollutants of air, their acverse eflzets on human health and also write their possible remedies (1242) Write the method of preparation and two important uses of each of polyurethane and nine epoxy resin. [25425] 7. What is biodegradable polymer? Describe the contribution of csrbon fibre reinforced ___ “polymer and chalcogenide glass in engineering 4) 8. 8) What are transition elements? Which of the 34 series elements is not a transition clement and why? (142) b) Explain why compounds of V*S are cdlourless but those of V"? aré colourful, < * Q 9. a), Explain the causé of origin of paramagnetism in transition elements, Bl 'b) Explain why are transition élements good for alloy formation, Q) 10.4), What is meant by effective atomie number of metal ion in the complex sale What 1 information does it convey? (2 b) Explain the formation of (Ni(CO),]* complex on the basis of VBT. Also predict its geometry and magnetism with reason, B) Ll.8) Write the basic assumptions of Wemes’s theory of co-ordination compounds BI gg pee oe Ab) Write the TUPAC names ofthe following co-ordination compounds, 2 i) (CoN) (en) IC, ii), [AMOH) G5:0)5)" iit) KalFe(CN}e} “ivy K[AR(CN)2] 12,.Whatjs.plastic.explosive? Howelo you prepare dynamite and gusrbatton? prey ers 13ea)e Whathis paint, Write characteristics, of good. paint. and. explain the method of application of paint in galvanised iron. (os+i+) b). What is lubricant? Give an example of emulsicin and solid lubricant. Mention their specific functions, fos+141] 14,2) Distinguish between enantiomers and diasteromers, Write all possible stereisomers — ¢~ fof a compound that contain two asymmetric carbon atoms but earinot exist in meso forms. He ) Write the cis and trans isomers of butenedioie ac. oh 15,2) What is resolution? Explain the method of chemiga! resolution of a rasemate: 6) ) Determine B or Z configuration in the following molecules 2 A : ce _ SHAH, y Jen HC CH, HO, ca, ' Ss 7% iy Conc 4 ce \cH,OH 16. What is a nicleophlic substition reaction? Briedly explain SW” and SN* paths of such reaction in haloalkane. Mention the factors governing these paths. (14242}8) TRIBHUVAN UNIVERSITY Examination Control Division | Programme | 8¢ RegulaviBiack ~~ BE Full Mans 1% BME INSTITUTE OF ENGINEERING PassMarks 32 2S, 2087 Ashadh Year Part | (71 Subji Candidates are required to give their ans Attempt All questions. The figures in the margin indicate Full Mi Assume suitable data if necessary. in their own woids as far as practicable How does clecuode poientaf diginale? Define standard electrode potential? Write the cell notation, and cell reaction for Za-Cu cell. [2142) ‘What is busfer solution? Calculate the pit of resulting Solution whien 0.005, mole of KOM is added to 200 mi of 0.LN acetic acid solution, (pK, = 4.74). tea) 2 What is meant by Hiomogcncouss(Gatalysis? D@ieribe the intermediate compound formation theory of catalysis with a suitable example) ist the critevia for choosing a ‘ontalyst for industxial application, fen 4, 8) What are chlorofluorocarbons? “Give their photolytic reaetions in the upper atmosphere. BI b) Why oxides of sulphur and nitrogen are assumed as air pollu 2 Py 2 Pole out four major pollutants of water, their scverse effect on human health ang alse mention theit possible remedies. f2iie2] 3 6. Describe the preparation and 1se8 of polyphosphazines and polymeric sulphur (PS). 5] 7.| What are double and complex salts? Waiteusi@"formulae 0! the following co-ordination compounds. 231 3 8) Dibromotetrsagucclucmium (11)) chloride b) Potassium hexacyanocohaltat (I) ©) Tetrabromocuparate (Il) @) Tetraanminedichlorocabalt (II) ©) Hexacyanoferrate (II) ion ) Sodium trioxalato aluminate (11) 8. a) What are principal and auxiliary valencies of the metal ion in the complex compound? Mlustrate them jn [Co (NH}s] Cs. @ . oS b) Show yout familiarity with electrofi interpretation of complexts. pi 4 2 : y of 0. ak Eee To By Transition elements ace god in forming complexes b) Show your acquaintance with application of 3-4 transition elements, What are transition elements? Explain the following features of transition elements, [14242] 9 }) Variable oxidation state b) Magnetic properties? Give the preparstion, p: initrotoluene (7), ution their functions, different y miliary with types of paint metrical isomers? Draw the siructure of 2-Chloroe S and specify Z and E configuration, OY, , pecity 2 ew © Allustrate enantiomer: with an exemple. M on a typical organic molecule which kN OF exhibits distersuinezin qj 14 Deseribe the mechanism involved in the reaction between a tertiary alkyl halide sa sausows Caustic potash, How does Sy2 reaction differ from Sul i its stereochemistry’ [1-1) 13. F-Write the mecunism of bimolecular elimination reaction rm [2 b) Mention the effect of nucleophile, substrate and solvent on nucleophilic substitmion reaction mechanisms GB HG Wiel ate bio-degradabe-o"d nonbiodegradabt~ Polyies? Menton the uses of epoxy fesin and fibce reinforced potyffien (23) Ln : 4