GD INT NATIONAL APPLICATION PUBL D UNDER THE PATENT COOPERATION TREATY (PCT) World Intellectual Property > era Z AANA International Burau ional Publication Number 2 (10) Interna 01 October 2020 (01.10.2020) WIPO! PCT ean (1) International Patent Classificato ABIK 892 2006.01) A61Q-19/00 (2006.01) AOIK 826 (2006.01) AOIQ.17704 (2006.01) 21) International Application Number: PCT/US20200025091 International ing Date: 27 March 2020 (27.03.2020) (25) Filing Language: English (26) Publicatio Language: English G0) Priority Data: 16/368,082 28 March 2019 2803.2019) US (71) Applicant: ELC MANAGEMENT LLC [US/US]; 155 Pinelawn Road, Suite 345 South, Melville, New York 11747 ws). Inventor: BEKDACH, Carla, Najib’ Abu Sawan Street, Casa Amarilla Building. First Floor, Beirut (LB). (74) Agent: MCKELVEY, Idris N. etal: 155 Pinclawn Road, Suite 345 South, Melville, New York 11747 (US), ™ (81) Designated States (unless otherwise indicated. for every Kind of national protection available): AE, AG, AL, AM, AO, AT, AU, AZ, BA, BB, BG, BH, BN, BR, BW, BY, BZ, CA.CH, CL, CN, CO, CR, CU; CZ, DE, DI, DK, DM, DO, DZ. EC, BE, EG, ES, Fl, GB, GD. GE, GH, GM, GT, HN, HR, HU, ID, IL, IN, IR, 1S, JO, JP, KE, KG, KH, KN, KP. KR, KW, KZ,LA, LC, LK, LR, LS, LU, LY, MA. MD, ME, MG, MK, MN, MW, MX, MY, MZ, NA, NG, NI, NO, NZ, OM, PA, PE, PG, PHL, PL, PT, QA, RO. RS, RU, RW, SA, SC, $D, SE, 8G, SK, SL, ST, SV. SY. TH, TJ, TM, TN, TR, TT, TZ, UA, UG, US, UZ, VC, VN, WS, ZA, 2M, ZW. 6s Designated States (unless otherwise indicated, for every Kind of regional protection available): ARIPO (BW, GH, GM, KE, LR, LS, MW, MZ, NA, RW, SD, SL, ST, SZ,1Z, UG, ZM, ZW), Eurasian (AM, AZ, BY, KG, KZ, RU, TI, ‘TM), Eutopeaa (AL, AT, BE, BG, CH, CY, CZ, DE, DK, EE, ES, Fl, FR. GB, GR. HR, HU, IES, IT, LT, LU. LV. MC, MK, MT, NL, NO, PL, PT, RO, RS, SE, SI. SK, SM, TR), OAPI (BF, BH, CF, CG, Cl, CM, GA. GN, GQ, GW, KM, ML, MR, NE, SN, TD, TG), Ne: ‘wth international search report (Art. 21(3) before the expiration of the time limit for amending the claims and 10 be republished tn the event of receips of ‘amendments (Rule 48.2) 69 Tine: ‘OLOR COSMETIC COMPOSITION CONTAINING WAX BLEND =< 5 + w 6 3 Ss a ludes atleast four dstint waxes, each characterized by having melting temperatures of from about 60°C to about 65°C; from S about 33°C to shout 46°C; from about $8°C to about 96°C; ad from about 74°C to about 99°C, respectively, The compositions further include at least one solvent, and a high pigment load, The compositions have excellent feel and payor characteristic, wo 2WO 2020/198547 PCT/US2020/025001 COLOR COSMETIC COMPOSITION CONTAINING WAX BLEND FIELD OF THE INVENTION The present invention relates to an anhydrous, moldable, cosmetic composition 5 comprising a blend of waxes. BACKGROUND OF THE INVENTION In recent years, there has been a strong trend toward the use of silicone fluids in makeup compositions. A major reason for their popularity is the elegant feel provided by the silicones 10 the product containing them goes onto the skin smoothly, with an excellent slip, and yet does not produce the greasy, heavy feel that non-silicone oils frequently leave. Silicone oils are now ‘common components of virtually all types of makeup compositions, both liquid and powder, for example, foundations, concealers, eyeshadows and eyeliners, lipsticks and lip pencils, and blushes. 15 Another attractive aspect of the silicone oils is their tendency to produce a very shiny appearance cn the skin to which they are applied. This is often desirable for certain types of cosmetics, particularly for those aimed at a younger consumer, to whom a glowing or glossy appearance is very appealing, or for cosmetics intended for evening wear, where subdued lighting permits a greater latitude in the shine produced by the cosmetic. 20 However, for certain types of cosmetic products, and/or for certain types of consumers, a significant amount of shininess is not desired and may even be inappropriate. A more mature user may not be flattered by a very glossy or shiny makeup. The fine lines and wrinkles which characterize a more mature skin are emphasized by a glossy product which ends to directly reflect light. More preferable for the consumer of a certain age is a makeup which will scatter 25 or diffuse light, thereby providing a "soft focus", which blurs lines and hides blemishes. Attempts to achieve this type of masking in the past have largely relied on the use of higher levels of pigment, but this frequently results in a heavy, cakey product which does not flatter a ‘majority of consumers Similarly, it may also simply be desirable to eliminate shininess for products to be used 30 in certain environments, For example, glossy makeup is often perceived as inappropriate in a conservative office environment, and/or may’ be too glaring under the harsh lights of the typical office. In these circumstances, a more matte finish to the cosmetic product may be called for. 110 20 WO 2020/198547 PCT/US2020/025091 Traditionally, this has been achieved by the addition of solid powders, such as mica, silica, tale, and the like, to the formulation, In the case of a silicone oil-based composition, however, counteracting the shine produced tends to be more difficult than with more traditional cosmetic oils, thus requiring addition of even greater amounts of the solid fillers. A larger proportion of solids in a formulation, however, results in a heavy, draggy feel on the skin, thereby canceling out to some extent some of the benefit of the silicone oils. Alternately, a more matte appearance can be achieved by including one or more volatile components, such as water or volatile oils, in the formulation: when the volatile evaporates upon application, this increases the concentration of pigment relative to the composition as a whole, resulting in a more matte look. However, this can also result in a dry, cakey look on the skin. Moreover, the use of volatiles. particularly ‘water, is not appropriate and/or feasible in all products, such as anhydrous lipstick products, and also results in the necessity of finding specialized, and often expensive, airtight packaging to prevent loss of the volatile from the product in the package. results in the necessity of finding specialized, and often expensive, airtight packaging to prevent loss of the volatile from the product in the package. Based on the foregoing, there is an ongoing need for a cosmetic composition which can deliver excellent payoff and aesthetic effects without the drawbacks of the unpleasant feel exhibited by existing formulations when high levels of solids are included. SUMMARY OF THE INVENTION The present invention relates to an anhydrous, moldable, cosmetic composition comprising a blend of waxes. The wax blend includes at least four distinct waxes. each characterized by having melting temperatures of from about 60 °C to about 65 °C: from about 33°C to about 46°C; from about 88°C to about 96°C; and from about 74°C to about 99°C, respectively. The compositions further include at least one solvent, which is preferably a nonvolatile solvent, and at least one pigment. The cosmetic composition may be in the form of an eyeshadow, blush, face powder, lipstick, and the like This, and other aspects of the present invention are described hereinafter.10 20 30 WO 2020/198547 PCT/US2020/025091 DETAILED DESCRIPTION OF THE INVENTION While the specification concludes with claims that particularly point out and distinctly claim the invention, it is believed the present invention will be better understood from the following description All percentages, parts and ratios are based upon the total weight of the compositions of the present invention, unless otherwise specified. All such weights as they pertain to listed ingredients are based on the active level, and therefore they do not include solvents or by- products that may be included in commercially available materials. unless otherwise specified. The term “weight percent” may be denoted as “w.%" herein. All molecular weights, as used herein, are weight average molecular weights expressed as grams/mole, unless otherwise specified, All ratios are weight ratios unless specifically stated otherwise Herein, “anhydrous” means that a composition of ingredients contains litle or no water. Preferably, anhydrous systems, compositions, or materials contain no water. Herein “hot pour” means a cosmetic formulation that must be heated to melt and disperse its constituent ingredients which then solidify upon cooling, Herein, “es” means centistoke. The term, “moldable”, as used herein, means that a material is capable of being molded or shaped, at room temperature, without cracking or breaking. Herein, “molecular weight” is measured in terms of the weight average molecular weight and is measured by gel permeation chromatography (GPC) The term, “nonvolatile solvent”, as used herein means a solvent which does not quickly evaporate at room temperature. Preferably, a nonvolatile solvent will have an evaporation rate of about 0.002 mg/em*/min or less. The evaporation rates herein are expressed in mg of solvent evaporated per unit area (cm) per unit time (minute) The term, “volatile solvent”, as used herein, means a solvent which quickly evaporates at room temperature. Preferably, a volatile solvent will have a rate of about 0.01 mg/em?/min or more. The term, “water-soluble”, as used herein, means that the polymer is soluble in water. In general, the polymer should be soluble at 25°C at a concentration of at least 0.1 w1.% of the water solvent, preferably at least 1 wi.%, more preferably at least 5 w1.%, most preferably at least 15 wi.%.10 20 25 30 WO 2020/198547 PCT/US2020/025091 The term “water-insoluble.” as used herein, means that a compound is not soluble in water, Thus, the compound is not miscible with water. Wax Blend The present compositions include a blend of at least four cosmetically acceptable waxes. Each wax component is characterized by its specified melting temperature range or melting behavior. The waxes may be natural or synthetic. While each of the at least four wax components is different from one another, it may be possible for melting temperature ranges of the waxes to overlap. Itis believed that the blend of waxes, according to the specified melting characteristics, provides a moldable cosmetic composition, with a high pigment load, and desirable payoff and drag characteristics, The total amount of the wax blend which may be present in the compositions may be from about 2 wt.% to about 20 wi.%, more preferably from about 5 w.% to about 15 w1.%, and. ‘most preferably’ from about 8 wt.% to about 12 w1.% of the composition First Wax Component ‘The first wax component is characterized by having a melting temperature of from about 60°C to about 65 °C. Nonlimiting examples of suitable first wax components include, for example, paraffin wax, petrolatum, ceresin wax and the like, Particularly preferred is synthetic beeswax. The first wax component may be present in the compositions herein at a level of from about I w1.% to about 10 wt.%, more preferably from about 3 w1.% to about 8 wi.%, and even more preferably, from about 4 wt.% to about 6.5 w.% of the composition, Second Wax Component ‘The second wax component should generally be capable of melting upon contact with skin, Therefore, the second wax has a melting temperature of from about 33°C to about 46°C. Preferably, the second wax has a melting temperature of less than about 42°C. Exemplary waxes may include laurel wax, jojoba butter, microcrystalline wax such as Paramelt” LMP (available from Paramelt), and natural waxes such as myrica pubescens fruit cera wax. Particularly preferred is steary! dimethicone/octadecene (available under the tradename Dowsil 2503 from Dow Coming). The second wax component may be present in the compositions at allevel of from about 0.5 w1.% to about 5 wt.%, more preferably from about I w1.% to about 4 wt.%, and even more preferably, from about 1 wt.% to about 2 wt.% of the composition.10 20 25 30 WO 2020/198547 PCT/US2020/025091 Third Wax Component The third wax component is characterized by having a melting temperature of from about 88°C to about 96°C. A nonlimiting example of a suitable third wax components includes a microcrystalline wax, such as Microcrystalline Wax SP 88, available from Strahl & Pitsch. The third wax component may be present in the compositions herein at a level of from about | wt. to about 5 wt.%, more preferably from about 2 wt.% to about 4 w1.%, and even more preferably, from about 2.5 wt.% to about 3 wi.% of the composition Fourth Wax Component The fourth wax component is characterized by having a melting temperature of from about 74°C to about 99°C. Nonlimiting examples of suitable second wax components include a microcrystalline wax such as Multiwax. W-835, available from Sonnebom, The fourth wax component may be present in the compositions herein ata level of from about 0.5 wt.% to about 5 wt.%, more preferably from about 1 wt.% to about 4 wt.%, and even more preferably, from about 1 wt.% to about 2 w1.% of the composition. Solvent The compositions include at least one solvent, The solvent may be any lipophilic cosmetically acceptable solvent. Suitable exemplary solvent types may include silicone-based solvents, ester-based solvents, hydrocarbon-based solvents, and mixtures thereof. A silicone solvent can be a dimethicone, cyclomethicone or a single molecule silicone. An ester-based solvent can be defined as an organic compound made by replacing the hydrogen of an acid by an alkyl or other organic group. A hydrocarbon solvent is defined as any Muid consisting of saturated carbons. The solvent may be selected from, for example, nonvolatile hydrocarbon-based oils, where appropriate fluorinated, and/or nonvolatile silicone oils, Nonlimiting examples of suitable nonvolatile hydrocarbon-based oils include hydrocarbon-based oils of either animal or plant origin, Such oils may include, for example, triglycerides consisting of fatty acid esters of glycerol, fatty acids which may have chain lengths varying from Cs to Cai, these chains being linear or branched, and saturated or unsaturated. Exemplary oils may include heptanoic or octanoic aci triglycerides, wheatgerm oil, sunflower oil, grapeseed oil, sesame seed oil, com oil, apricot oil, castor oil, shea oil, avocado cil, olive oil, soybean oil, sweet almond oil, palm oil, rapeseed oil, cottonseed oil, hazelnut oil, macadamia 510 20 30 WO 2020/198547 PCT/US2020/025091 oil, jojoba oil, alfalfa oil. poppy oil. pumpkin oil, marrow oil, blackcurrant oil, evening primrose oil, millet oil, barley oil, quinoa oil, rye oil, safMower oil, candlenut oil, passion-flower oil, musk rose oil and mixtures thereof, Other oils may include shea butter or caprylic/capric acid triglycerides, such as those sold under the names Miglyol 810°, 812° and 818° available from Dynamit Nobel According to one embo ment, the solvent may also comprise synthetic ethers containing from 10 to 40 carbon atoms, other than those corresponding to the definition of dry oils, such as diisocety! ether. In another embodiment, the solvent may comprise linear or branched hydrocarbons of mineral or synthetic origin, such as petroleum jelly, polydecenes, hydrogenated polyisobutene such as Parleam®, squalane and liquid paraffins, and mixtures thereof. According to another embodiment, the nonvolatile solvent may be selected from synthetic esters, other than those corresponding (o the definition of the dry oils, such as oils of formula RiCOOR: in which Ri represents a linear or branched fatty acid residue containing from 1 to 40 carbon atoms and Ro represents an especially branched hy drocarbon-based chain containing from 1 to 40 carbon atoms, on condition that Ri + Ra> 10. Such oils may include, for example, purcellin oil (cetostearyl octanoate), C12 to Cis alkyl benzoates, hexyl laurate, diisopropy! adipate, isononyl isononanoate, 2-ethylhexy! palmitate, isosteary! isostearate, 2- hexyldecy! Jaurate, 2-octyldecy! palmitate, 2-octyldodecy! myristate, alkyl or polyalcohol heptanoates, octanoates, decanoates or ricinoleates such as propylene glycol dioctanoate, and mixtures thereof. Other such oils may include hydroxylated esters such as isostearyl lactate, diisosteary! malate and 2-octyldodecy| lactate, polyol esters, pentaerythritol esters, and mixtures thereof, According to yet another embodiment, the nonvolatile solvent may be selected from fatty alcohols or higher fatty acids, Suitable fatty alcohols include those that are liquid at room temperature, with a branched and/or unsaturated carbon-based chain containing from 12 to 26 carbon atoms. Nonlimiting examples may include octyldodecanol, isostearyl alcohol, oley! alcohol, 2-hexyldecanol, 2-butyloctanol and 2-undecylpentadecanol. Suitable higher fatty acids include, for example, oleic acid, linoleic acid or linolenic acid, and mixtures thereof. The nonvolatile silicone oils that may be used in the present compositions may also be nonvolatile polydimethylsiloxanes (PDMSs), optionally including polydimethylsiloxanes comprising alkyl or alkoxy groups, that are pendent and/or at the end of a silicone chain, the 610 20 30 WO 2020/198547 PCT/US2020/025091 groups each coniaining from 2 to 24 carbon atoms. Such PDMSs may include, for example. phenyl silicones, such as phenyl trimethicones, phenyl dimethicones, phenyltrimethy!- siloxydiphenylsiloxanes, diphenyl dimethicones, diphenyimethyldiphenyltrisiloxanes, and mixtures thereof. According to a preferred embodiment, the solvent is a nonvolatile solvent selected from ethanol, octyldodecanol, isopropanol, and mixtures thereof. Octyldodecanol is particularly preferred ‘The nonvolatile solvent may be present in the composition in an amount ranging from about 0.5 wi.% to 25% wt.%, more preferably from 10 wi.% to 20 wt.%, and most preferably from about 13 wt.% to about 17 w1.% of the composition. In one embodiment, the compositions are free of, or substantially free from, volatile solvents. It has been found that volatile solvents create formulation challenges, resulting in inferior processing conditions and product outcomes. Compositions including material levels of volatile solvents can result in less moldable compositions with inferior feel characteristics, Pigment ‘The compositions comprise a high pigment load. Therefore, the compositions include a pigment level of at least about 35 w.%, more preferably at least about 40 w.%, and most preferably at least about 45 wi.% of the composition. The pigment load should also be less than about 60 wt.%, more preferably less than about 55 wi.%, and most preferably less than about 52 wt % of the composition. Non-limiting examples of pigments useful in the present compositions include tale, mica, silica, synthetic fuorphlogopite, zine oxide, manganese violet, ferric ferrocyanide, ultramarine blue, pear! pigments (bismuth oxychloride, guanine, calcium sodium borosilicate, calcium aluminum borosilicate, alumina, polyethylene terephthalate), iron oxide, titanium oxide, titanated mica, calcium carbonate, tar pigments, and other organic pigments. Pigments which are surface treated with silicones, silanes and its derivatives, metal soaps, fluorine compounds and its derivatives, lecithin and its derivatives, amino acids and its salts, ete. can also be used. The pigments can be dispersed in an oily medium such as those disclosed herein among suitable solvents, Pigments can also be pre-dispersed in an oily medium like castor oil or as dry powders which subsequently are dispersed in a chosen medium,10 15 20 30 WO 2020/198547 PCT/US2020/025091 Preferred pigments and powders include tale, mica, clay, kaolin, zine oxide, nylon powder, ultramarine, pear! pigments (bismuth oxychloride, guanine). iron oxide, titanium oxide, titanated mica, calcium carbonate, tar pigments, and mixtures thereof, Particularly preferred pigments and powders include mica, titanated mica, and/or mica pearls, such as those available from BASF Wetting Agent ‘The compositions may also comprise a wetting agent. Suitable wetting agents may include, for example, surfactants which have an HLB from about 5-7, such as sorbitan trioleate, polyglycerol 3 diisostearate, sorbitan sesquioleate, and mixtures thereof. The wetting agent may be present at a level of from about 0.1 wL% to about 1.5 wt.% of the composition. The wetting agent helps to provide pigment dispersion in compositions with high pigment loads Ultraviolet Absorbing Agent ‘The compositions herein may include one or more known ultraviolet absorbing agents, preferably at least one compound which absorbs in the UV-B region (wavelength 290 to 320 nanometers) and optionally one or more other compounds which absorb in the UV-A region (wavelength 320 to 400 nanometers). The total amount of UV absorbing agents included within the formulation may be from about 2 w1.% to about 15 wt.%, which amount will determine ‘whether itis a sunscreen or sunblock, As the present compositions are anhydrous, the UV agent is preferably lipophilic. Suitable UV-A absorbing agents which may be employed include 2-(2'-hydroxy-5'- methylphenyl)benzo- triazole (Tinuvin Py, 2-(2'-hydroxy (Spectra-Sorb UV S411); 24-dihydroxybenzophenone (Uvinul 400); 2-hydroxy methoxybenzophenone (oxybenzone, Spectra-Sorb. UV9, Uvinul M40); 2,244 4-octylphenyl)benzotriazole tetrahydroxybenzophenone (Uvinul DSO); 2, (Uvinul D49); 2. 2-ethylhexyl-4-phenyl-benzophenone carbonate (Eusolex 3573); 2-hydroxy-4-methoxy-4'- dihydroxy-4.4'-dimethoxybenzophenone hydroxy-4-methoxybenzophenone (dioxybenzone, Spectra-Sorb UV24): methylbenzophenone (mexenone, Uvistat 2211); 2-hydroxy-4-(n-octyloxy)benzophenone (octabenzone, SpectraSorb UVS31): 4-pheny benzophenone (Eusolex 3490); and 2-ethylhexyl- 2-cyano-3,3'-diphenylacry late (Uvinul N539); butyl methoxydibenzoyl methane (Parsol 1789), and benzphthalide (Escalol $47),10 20 30 WO 2020/198547 PCT/US2020/025091 The UV-A absorbing agent or agents may be present in the final product at from about 0 wt.% to about 10 wt.% of the formulation. ‘The amount will vary according to the particular agent selected and whether the formulation is intended to minimize or permit tanning, Where a UV-A absorbing agent is employed, the preferred UV-A absorbing agent is 2-hydroxy ‘methoxybenzophenone alone or in combination with 2,2'-dihydroxy-4-methoxy benzophenone. Suitable UV-B absorbing agents include 4-(dimethylamino)benzoic acid, ethyl ester; 4- (dimethylamino)benzoic acid, 2-ethylhexy1 ester (Escalol 507): 4-(dimethylamino)benzoic acid, pentyl ester (Escalol 506); glyceryl p-amino-benzoate (Excalol 106): isobutyl p-amino- benzoate (Cycloform); and isopropyl p-amino-benzoate; 2-ethylhexyl methoxy cinnamate (Parsol MCX): phenylbenzimidazole sulfonic acid (Eusolex 232); homomenthy! salicylate, and ethyl hexyl salicylate. The UV-B absoring agent or agents may be present in the final product at from about 1 w1.% to about 15 wt.% of the formulation, The amount will vary according to the particular agent selected and degree of protection desired in the final product, The preferred UV-B absorbing agent is 4-(dimethylamino)benzoic acid, 2-ethyl-hexyl ester (Escalol 507), Additional Optional Ingredients ‘The compositions herein may optionally contain one or more additional cosmetically acceptable ingredients. As examples of such additional ingredients, mention may be made of, but not limited to, conventional cosmetic adjuvants selected especially from among fatty substances: organic solvents, ionic or nonionic, hydrophilic or lipophilic thickeners: softeners: humectants pacifiers: stabilizers: preservative; emollients; silicones; anti-foams; fragrances; preservatives: anionic, cationic, nonionic, zwitterionic or amphoteric surfactants; fillets; polymers; propellants; acidifying or basifving agents: pigments; dyes; cosmetic tanning agents, inorganic photoprotective agents and any other ingredients commonly used in a cosmetic or dermatological composition. ‘The fatty substances may be an oil. The term "oil" means a compound that is lipophilic liquid at room temperature. Oils that may be mentioned include mineral oils (paraffin): vegetable oils (sweet almond oil. macadamia oil, grapeseed oil or jojoba ester/oil) : synthetic oils, for instance perhydrosqualene, fatty alcohols, fatty acids or fatty esters (for instance the C12-C15 alkyl benzoate marketed under the name "Finsoly TN" of "Witconol TN" by Witco, octyl palmitate, isonohyl isononanoate, isopropyl lanolate and triglycerides, including 910 20 30 WO 2020/198547 PCT/US2020/025091 capriclcaprylic acid triglycerides), dialkyl carbonate such as dicaprylyl_ carbonate, oxyethylenated or oxypropylenated fatty esters and ethers: silicone oils (cyclomethicones and polydimethylsiloxanes such as dimethicone) or fluoro oils, and polyalkylenes . Oil containing at least one amide structure such as those disclosed in US7,357.920, ean also be used. If desired, one or more lipophilic thickeners may be added to the composition in order to adjust the theological properties of the compositions herein. Lipophilic thickeners that may be mentioned include modified clays such as hectorite and its derivatives, for instance the products marketed under the name "Bentone" As fillers or polymers which may be added to the composition of the present invention, mention may be made of, but not limited to, natural fibers such as silk, cellulose, and wool: synthetic fibers such as polyamide which is also referred to as "Nylon, and rayon; and particles or beads of polymers such as polyamides, polyacrylates, and polymethylsilsesquioxane. Another optional component of the formulation is one or more ¢, The use of a film- former improves the wear of the composition and can confer transfer-resistance to the makeup product, Examples of useful fi forming agents include natural waxes, polymers such as polyethylene polymers and copolymers of PVP, dimethicone gum, and resin, such as shellac, polyterpenes, and various silicone resins. A particularly preferred film-former_ is trimethylsiloxysilicate, used in an amount of from about 01-20%, As described above, an inorganic photoprotective agent may be used together with the lipophilic cosmetic or dermatological active ingredient. An inorganic photoprotective agent used for the present invention may be selected from among pigments and even more preferably nano-pigments (mean size of the primary particles: generally from 5 run to 100 nm and preferably from 10:nm to 50 nm) of treated or untreated metal oxides such as, for example, nano- pigments of titanium oxide (amorphous or crystallized in rutile and/or anatase form), of iron oxide, of zine oxide, of zirconium oxide or of cerium oxide, The treated nano-pigments are pigments that have undergone one or more surface treatments of chemical, electronic, mechanochemical and/or mechanical nature with compounds as described, for example, in Cosmetics & Toiletries, February 1990, Vol. 105, pp. 53-64, such as amino acids, beeswax. falty acids, fatty alcohols, anionic surfactants, lecithins, sodium, potassium, zine, iron or aluminum salts of fatty acids, metal (titanium or aluminum) alkoxides polyethylene, silicones, proteins (collagen or elastin), alkanolamines, silicon oxides, metal oxides, sodium hexametaphosphate, alumina or glycerol 1010 20 WO 2020/198547 PCT/US2020/025091 Many particular pigments and nano-pigments which can be used are disclosed in U.S. Patent No, 7.357.920. NON-LIMITING EXAMPLES ‘The compositions illustrated in the following Examples illustrate specific embodiments of the compositions of the present invention but are not intended to be limiting thereof Other ‘modifications can be undertaken by the skilled artisan without departing from the spirit and scope of this invention, Exemplified embodiments 1-5 provide a moldable, anhydrous, cosmetic, composition with a high pigment load, Examples 6-9 are comparative illustrations of formulas which fail to exhibit acceptable cosmetic performance, as discussed in more detail hereinafter. ‘The compositions according to the following Examples may be prepared according to the following steps: First, mix the synthetic beeswax with each of the microcrystalline waxes and steary! dimethicone/octadecene in a vessel, which is heated to about 95 -C to form a first phase. Next, in a separate beaker, combine all remaining ingredients, except pigments and particles (mica) at about 95 °C to form a second phase. Next, combine the first and second phases to form a single mixture, maintaining a mixing temperature of about 95 °C. Finally, add the pigments and particles to the mixture. Mix until the ingredients form a homogenous composition, then stop mixing and allow the mixture to cool to room temperature. All exemplified amounts are listed as weight percents and exclude minor materials such as diluents, preservatives, color solutions, imagery ingredients, botanicals, and so forth, unless otherwise specified The following are representative of cosmetic compositions of the present invention: TABLET Ingredient Toe 2s ene aloe [ve est) S|: jynthetic Beeswax! 3.24 | 524 [607 [607 [524] - [539 [529 [535 IMicrocry'stalline Wax 284] 2.84 | 1.70 [2.50[284[3.00| - [287 ]2.90 icrocrystalline Wax” 200 | 1.00 | 2.00 |2.30]200/2.11 | 2.06 ]202) - tcaryl Dimethicone/Octadecene’ _| 1.57 | 137 | 1.88 [1.00 [100] 106 [1-03 | - [1.02 tyldodecanol 16.77] 16.77 [16.77 [16.77|15.92| 16.80 [16.36] 16.0816 24 Lecithin 0.13 | 0.15 [0.15 [0.15 | 08 [084 [0.82 [081 [0.82 entacrythrity! TetracthyIhexanoate | 608] 608 | 6.08 |4.08|4.00| 4.22 | 4.11 | 4.04 [4.08 [TrivctyIdodeyl Citrate 3.25 | 325 | 325 [325/325] 343 | 3.85 | 3.28 [3.2 yheny! Trimethicone 126 | 1.29 | 1.26 [1.26.26] 422 | 130 | 127 [1.2910 20 WO 2020/198547 PCT/US2020/025091 [Dipentaerythrity! Hexahydroxystearate/ | 1.37 | 1.37 | 1.37 |1.45]2.02| 2.13 | 2.08 | 2.04 | 2.06 Hexastearate/Hexarosinate jojoba Ester Bis | 3.15 400/315] 332 )3.24 | 318 [3.21 [Butyrospermum Parkii (Shea Butte) | 3.15 | 3.15 $003.15] 332 | 3.24 | 318 [3.21 Tocophery] Acetate 0.10 | 0.10 | 0.10 [0.10 [0.10 0.10 | 0.10 | 0.10 [0.10 ‘aprylyl Glycol O10 | 0.10 | O10 [0.10030] 032 | OST | 030 [0.30 Pentacrythrityl Tetra-Di-T-Butyl 0.15 | O15 | 0.15 [0.15 [0.15] 0.16] 0.15 [0.15 Jos lHydroxydrocinnamate silica 352 | 352 | 352 [352[380] 401 [391 [384 [3.84 [ADITrimehyTo! HexyTlactone Crosspot | 1.98 | 198 | 227 2AT [2.06 | 2.02 [2.04 mer/Polymethyl Methacrylate scorby! Palmitate vos foo | -|- 1-1-1 1-1- Pigment 47.04 | 47.04 [47.08 [47 04f17.04] 51.6 [30.46 |49.50|50.10 Filler as | as [as [as [as [as [as [as [as 1 Synthetic Beeswax #122P, available from Koster Keunen 2 Microcrystalline Wax SP 8, available from Strahl & Pitsch 3 Multiwax W-835, available from Sonnebori 4 Dowsil 2503 Cosmetic Wat, available from Dow Corning, ‘5 The filler may include solvents, fragrances, or other additional optional ingredients disclosed herein, Table 2, below, illustrates comparative cosmetic performance among the examples provided in Table 1. Each exemplary embodiment was observed and evaluated for suitability as a cosmetic composition. First, the compositions were evaluated for processability. It is necessary for the compositions to have good mixing and pourability performance, Second, the product is observed afier the processing step, and it is evaluated for drag, payoff, moldability, and sensorial characteristics, As used herein, the term, rag” means the relative ease with which a product is applied to skin, Sensorially, a product with low drag is perceived to glide onto the skin. In contrast, a product with increased drag will exhibit friction and uneven application to skin, As used herein, the term, “payoff” refers to the color intensity of the cosmetic composition when applied to skin, More intense perceived color intensity correlates with higher relative payoff, and less intense perceived color intensity correlates with less relative payoff TABLE 2 EXAMPLE. OBSERVATIONS 1 Good mixing and pouring performance. ‘The product has some drag but does not crumble upon application to skin. 1210 15 WO 2020/198547 PCT/US2020/025091 2 ‘Acceptable mixing performance, Formula crumbles upon application to skin: 3 Good mixing and pouring performance. Minimal drag, and cooling sensation on skin, 4 ‘Good mixing and pouring performance, Minimal drag, and cooling sensation con skin 5 ‘Good mixing and pouring performance. Excellent glide, payoff, and cooling sensation on skin. 6 Formula is too thick to mix with an impeller. The product is too rigid and brittle to mold. It crumbles when handled. 7 Formula is very viscous and difficult to mix. Tt can be shaped into a ball, but crumbles upon application to skin 8 Mixing and pouring performance are acceptable, but final product drags against skin with uneven payoff. 9 Mixing and pouring performance are acceptable, but final product crumbles ‘upon application to skin. ‘The dimensions and values disclosed herein are not to be understood as being strictly limited to the exact numerical values recited. Instead, unless otherwise specified, each such dimension is intended to mean both the recited value and a functionally equivalent range surrounding that value, For example, a dimension disclosed as “40 mm” is intended to mean “about 40 mm.” Every document cited herein, including any cross referenced or related patent or application, is hereby incorporated herein by reference in its entirety unless expressly excluded or otherwise limited. The citation of any document is not an admission that it is prior art with respect to any invention disclosed or claimed herein or that it alone, or in any combination with any other reference or references, teaches, suggests or discloses any such invention. Further, to the extent that any meaning or definition of a term in this document conflicts with any meaning, or definition of the same term in a document incorporated by reference, the meaning or definition assigned to that term in this document shall gover. While particular embodiments of the present invention have been illustrated and described, it would be obvious to those skilled in the art that various other changes and ‘modifications can be made without departing from the spirit and scope of the invention. Tt is therefore intended to cover in the appended claims all such changes and modifications that are within the scope of this invention.10 15 20 30 WO 2020/198547 PCT/US2020/025091 CLAIMS What is claimed is: 1. An anhydrous, moldable, cosmetic composition comprising: a. ablend of waxes comprising: i. afirst wax having a melting point of between about 60°C to about 65 °C ii, second wax having a melting point of between about 33°C to about 46 °C: iii, a third wax having a melting point of between about 88°C to about 96°C; iv. a fourth wax having a melting point of between about 74°C to about 99 °C, b. atleast one pigment; cc. at least one solvent; and wherein each of said waxes is different from one another. 2. ‘The cosmetic composition according to claim 1, wherein said composition comprises at least about 35 wt.%, of pigments. ‘The cosmetic composition according to claim 1, wherein said blend of waxes comprises: a. from about 1 wt.% to about 10 w1.% of said first wax: b. from about 0.5 wt.% to about 5 wt.% of said second wax: ©. from about 1 wt.% to about 5 wi.% of said third wax; and 4d. from about 0.5 w1.% to about 5 wt.% of said fourth wax. 4. The cosmetic composition according to claim 1, wherein said cosmetic composition comprises said blend of waxes in an amount of from about 2 wt.% to about 20 wt.% 5. The cosmetic composition according to claim 1, wherein said cosmetic composition comprises at least about 30 wt.% of said one or more pigments, 6. The cosmetic composition according to claim 1, wherein said cosmetic composition comprises at least about 40 w1.% of said one or more pigments,10 20 25 30 WO 2020/198547 PCT/US2020/025091 9, 10, 16, The cosmetic composition according to claim 1, further comprising one or more UV absorbing agents, The cosmetic composi mn according to claim 7 wherein said UV absorbing agent is lipophilic. The cosmetic composition according to claim 1, wherein said solvent is nonvolatile. ‘The cosmetic composition according to claim 9, wherein said solvent is selected from the group consisting of silicone-based solvents, ester-based solvents, hy drocarbon-based solvents, and mixtures thereof. ‘The cosmetic composition according to claim 9, wherein said solvent is selected from the group consisting of ethanol, octyldodecanol, isopropanol, and mixtures thereof, ‘The cosmetic composition according to claim 1, where said composition comprises from about 13 wt.% to about 17 wt.% of said solvent. ‘The cosmetic composition according to claim 1, wherein said composition comprises ‘one or more pigments selected from the group consisting of tale, mica, silica, synthetic fluorphlogopite, zinc oxide, manganese violet, ferric ferrocyanide, ultramarine blue, pearl pigments (bismuth oxychloride, guanine, calcium sodium borosilicate, calcium aluminum borosilicate, alumina, polyethylene terephthalate), iron oxide, titanium oxide, titanated mica, calcium carbonate, tar pigments, other organic pigments, and mixtures thereof, The cosmetic composition according to claim1, wherein said pigment comprises mica. The cosmetic composition according to claim 1, wherein said composition further comprises a wetting agent. ‘The cosmetic composition according to claim 1, further comprising a film-forming agent,INTERNATIONAL SEARCH REPORT Incernational application No. PCT/US2020/025091 A. CLASSIFICATION OF SUBJECT MATTER AG1K 8/92(2006.01)i, AGIK 8/26(2006.01)i, A61Q 19/00(2% According to International Patent Classification (PC) of to both nat 2006.01)i, A61Q 17/04(2006.0i ional classification and IPC B.__ FIELDS SEARCHED “Minimum documentation searched (classification system followed b ‘AGIK 8192; AGIK 007/025; AGIK 7/02; AGIK 7H027; AGIK 7/4; 3 classification symbols) ‘AGIK 0d; AGIK BBDI; AGIK 8/26; AGIQ 19/00; AGI 17/4 Korean utility models and applications for utility models Japanese ulility models and applications for uility models Documentation searched oiher than minimum documentalon to the extent that such documents are included tate [elds searched Tectonic data base consulted during the inerational search (name eKOMPASS(KIPO internal) & Keywords wax blend, cosmetic, pig ‘of data base and, where practicable, seater tems used) nent, u-absorbing agent cater aplication or patent bu published ono after the iteration Sing date document which may thow doubs on priority clair) oF which is cited to establish the plication date of anther cietion or ther special reason (as specified) cument refering to an orl dsslosur, use, exhibition or other means documeat published pio to the international ling date but later ‘than the pronty date claimed ©_ DOCUMENTS CONSIDERED TO BE RELEVANT Cacgon'] Citation af document, with indication, where appropiate, ofthe relevant passages Relevant o claim No Y [WO 00-276 AY (OREN SA) TB Way 2000 Tis abstract: example 2: page 5! clains 1-20 v | us 2008-oonz7s4 a1 Casi, K, et af.) 16 danwary 2008 16 abstract: parzgranh [0044]; clains 1-8 A | Us onss050 A (CALELLD, J. F. et al.) 07 March 2000 116 abstract: claims 1-18 A | us 2000-o257060 a1 (SCHLOSSUAN, D, et at.) 15 October 2009 16 aabsteact? clains 1-11 A | us 2016-0924757 A1 (DOW CORNING CORPORATION et a.) 10 Novenber 2016 L6 Farther document ar lsd inthe continsation of Box C. DR) see pate faity anne 7 Spc cnegos of Gal doament “Place docncrpbibed afer etc ling ao poy sa* document defining te ence oft an whichis noconsideed dea ot i cont wth tap bac wean tect pric eve the rine or thay ane te inetion >" documeatciedy he pplcantinthe inten apicion "A cnet af pir eve; claimed vention cao be considered novel of cannot be considered fo involve an inventive step when the docume ti taken aon document of paicular relevance; the lane invention cannot be considered to involve an inveative step when the document is combined with one or more ater sich documents sich combination being obvious to a person skilled in the at document member ofthe same patent fay a Date ofthe actual completion ofthe international search 16 July 2020 (16.07.2020) Date of mailing of the inemnational search repomt 16 July 2020 (16.07.2020) Name and wailing address of the ISAK © Tmerttional Application Division ‘Korean Inellectl Propeny Otic aestmule No, 189 Cheongsiem,Seo-gn, Daejeon 08, Republic of Kor 82-42-48 -8578 Thuthorized officer HEO 100 HYUNG Telephone No,_+82-42-481-8150 Form PCT/ASA/210 (second sheet) (Iuly 2019)INTERNATIONAL SEARCH REPORT “maton application No PCT/US2020/025091 Patent docut Publication Patent family Publication cited in search report, date member(s) date WO 00-27346 AL 18/05/2000 EP 1126814 AL 28/08/2001 EP 1126814 BI 15/07/2009 ES 2329958 13 02/12/2009 JP 2002529384. 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(07/05/2008 EP 1243248 BL 16/11/2005 JP 2002348204 01/12/2002 JP 3909828 B2 25/04/2007 KR 10-0678431 BL (05/02/2007 KR 10-2002-0075254 A 04/10/2002 ‘W 1318574 B 21/12/2009 Us 6740328 B2 25/05/2004 US 6033650 4 07/08/2000 AR 002603 AL 25/08/1998 AR 009222 AL 12/04/2000 CA 2225996 AL 16/01/1997 EP 0835091 AL 15/04/1998 EP 0835091 M4 (04/08/1999 PE 20498 AL 25/04/1998 Us 5849275 A 15/12/1998 US 6143288 A 07/11/2000 WO 97-01321 AL 16/01/1997 ZA 9605426 B 31/01/1997 US 2009-0257966 AL 15/10/2009 EP 2273072 A2 19/01/2011 EP 2273972 BI 03/08/2016 ES 2599029 13 31/01/2017 JP 2011-516575 A 26/05/2011 IP 2015-15478 A 27/08/2015, JP 6162173 B2 12/07/2017 PL 2273972 13 31/01/2017 PL 2273972 T 09/11/2016 US 2014-0235734 AL 21/08/2014 Us 8679464 B2 25/08/2014 TS 9308160 82 12/01/2016 WO 2009-12684 A2 15/10/2009 WO 2009-126854 43 07/01/2010 US 2016-0524757 AL 10/11/2016 CN 106061465 A 26/10/2016 BP 3099286 AL 07/12/2016 JP 2017-50164 A 08/02/2017 US 9801806 B2 31/10/2017 WO 2015-11307 AL 06/08/2015, Form PCT/ISA/210 (patent family annex) (July 2019)