Problema 02.

A
B

H2O(l)
C
a)

Columna d’absorció
Aire X=0,9950

H2O (g) X=0,0050

E

Columna de destil·lació
D H2O (l) X=0,0100

Acetona (C3H6O)
X=0,9900
A Acetona (C3H6O)
X=0,1900 F
1400 kmol/h
H2O (l) X=0,8100
5.00% acetona H2O (l) X=0,9600
(C3H6O) X=0,05
Acetona (C3H60)
2.00% H2O (g)
X=0,0400
X=0,02

93.00% aire
X=0,93

b) TOTAL 0 = ( A + B ) – ( C + D ) + 0
0 = ( 1400 + B ) – ( C + D ) + 0
ACETONA 0 = (A·XA + B·XB) – (C·XC + D·XD) + 0
0 = (1400·0,05 + B·0) – (C·0 + D·0,19) + 0
0 = 70 – D·0,19
70
D= 0,19 = 368,4210526 kmol/h

AIRE 0 = (A·XA + B·XB) – (C·XC + D·XD) + 0

0 = (1400·0,93 + B·0) – (C·0,995 + D·0) + 0
0 = 1302 – C·0,995
1302
C = 0,995 = 1308,542714 kmol/h

AIGUA 0 = (A·XA + B·XB) – (C·XC + D·XD) + 0

0 = (1400·0.02 + B) – (1308,542714·0,005 + 368,4210526·0,81) + 0
0 = 28 + B - 6,54271357 – 298,4210526 + 0
B = 6,54271357 + 298,4210526 – 28 = 276,9637662

B= 276,96 kmol/h
 c) TOTAL 0 = D – ( E + F ) + 0
0 = 368,4210526 – ( E + F ) + 0
ACETONA 0 = D·XD – (E·XE + F·XF) + 0
0 = 368,4210526·0,19 – (E·0,99 + F·0,04) + 0
0 = 70 – E·0,99 – F·0,04 + 0
AIGUA 0 = D·XD – (E·XE + F·XF) + 0
0 = 368,4210526·0,81 – (E·0,01 + F·0.96) + 0
0 = 298,4210526 – E·0,01 – F·0,96 + 0

70−𝐹·0,04
0 = 70 – E·0,99 – F·0,04 + 0 E= 0,99

0 = 298,4210526 – E·0,01 – F·0,96 + 0

70−𝐹·0,04
298,4210526 – ( )·0,01 – F·0,96 = 0
0,99

298,4210526 – 0,707 + F·4,04X10-4 – F·0.96 = 0

297,7140526 – F·0,959596 = 0
297,7140526
F= = 310,2493681
0,959596

70−310,2493681·0,04
E= = 58,1717427
0,99

E = 58,17 kmol/h

Problema 02.B Cabal= 2/3cabal corrent 4

C Etanol pur (C2H6O) 100kg/h
a)
A B F
mesclador

Columna de
destil·lació

D
Etanol (C2H60)
Columna de
destil·lació

20% Massa E
Etanol
H2O (C2H6O)
Etanol (C2H6O) 4% massa
8% molar
H2O
H2O
b) TOTAL 0 = ( A + F ) – ( C + E + F ) + 0
0=A–(C+E)+0
ETANOL 0 = A·WA – (C·WC + E·WE) + 0
0 = A·0,2 – (C·1 + E·0,04) + 0
0 = A·0,2 – 100 – E·0,04 + 0
AIGUA 0 = A·WA – (C·WC + E·WE) + 0
0 = A·0,8 – (C·0 + E·0,96) + 0
0 = A·0,8 – E·0,96 + 0

𝐸·0,96
0 = A·0,2 – 100 – E·0,04 + 0 A= 0,8

0 = A·0,8 – E·0,96 + 0
𝐸·0,96
( )0,2 – 100 – E·0,04 + 0 = 0
0,8

E·0,24 – 100 – E·0,04 = 0

𝟏𝟎𝟎
E= = 500 kg/h
𝟎,𝟐

𝟓𝟎𝟎·𝟎,𝟗𝟔
A= = 600 kg/h
𝟎,𝟖

c) TOTAL 0 = ( A + 2/3 D ) – ( C + D ) + 0
0 = ( 600 + 2/3 D ) – ( 100 + D ) + 0
0 = 600 + 2/3 D – 100 – D + 0
0 = 500 – 1/3 D + 0
D = 500·3 = 1500

D = 1500 kg/h

ETANOL 0 = (A·WA + 2/3Dx) – (C·WC + D·WD) + 0

0 = (600·0,2 + 2/3·1500x) – (100 + 1500·0,368) + 0
0 = 120 + 1000x – 100 – 552
1000x = 100 + 552 – 120
𝟓𝟑𝟐 𝟓,𝟑𝟐𝒌𝒈·𝟏 𝒌𝒎𝒐𝒍
x = 𝟏𝟎𝟎𝟎 = 5,32 kg etanol = = 0,1157 kmol etanol
𝟒𝟔 𝒌𝒈
 AIGUA 0 = (A·WA + 2/3Dy) – (C·WC + D·WD) + 0
0 = (600·0,8 + 2/3·1500y) – (1500·1,657) + 0
0 = 480 + 1000y – 2485,5 + 0
1000y = 2485,5 – 480
𝟐𝟎𝟎𝟓,𝟓 𝟐,𝟎𝟏𝒌𝒈·𝟏 𝒌𝒎𝒐𝒍
y= = 2,01 kg aigua = = 0,1167 kmol aigua
𝟏𝟎𝟎𝟎 𝟏𝟖𝒌𝒈

Problema 02.D
98𝑔 1𝑘𝑔
0,216mol H2SO4 · 1𝑚𝑜𝑙 · 1000𝑔 = 2,1168x10-2kg H2SO4 Cabal 1 = A

18𝑔 1𝑘𝑔 Cabal 2 = B

0,784mol H2O · 1𝑚𝑜𝑙 · 1000𝑔 = 1,4112x10-2kg H2O
Cabal 3 = C
98𝑔 1𝑘𝑔
0,709mol H2SO4 · 1𝑚𝑜𝑙 · 1000𝑔 = 6,9482x10-2kg H2SO4 Cabal 4 = D
18𝑔 1𝑘𝑔 Cabal 5 = E
0,291mol H2O · 1𝑚𝑜𝑙 · 1000𝑔 = 5,238x10-3kg H2O

TOTAL 0 = ( A + E ) – ( B + C + E ) + 0
0=A–B–C+0
ÀCID NÍTRIC 0 = A·WA – (B·WB + C·WC) + 0
0 = A·0,6 – B·0,99 – C·0 + 0
0 = A·0,6 – 100·0,99
A = 99/0,6 = 165 kg/h
AIGUA 0 = A·WA – (B·WB + C·WC) + 0
0 = A·0,4 – B·0,01 – C + 0
0 = 165·0,4 – 100·0,01 – C
C = 66 – 1 = 65 kg/h = C

c) TOTAL 0=(A+E)–(B+D)+0

ÀCID NÍTRIC 0 = (A·WA + E·WE) – (B·WB + D·WD) + 0

0 = 165·0,6 + E·0 – B·0,99 – D·0 + 0

AIGUA 0 = (A·WA + E·WE) – (B·WB + D·WD) + 0

0 = 165·0,4 + E·5,238x10-3 – 100·0,01 – D·1,4412x10-2

0 = 65 + E·5,238x10-3 – D·1,4412x10-2

ÀCID SULFURIC 0 = (A·WA + E·WE) – (B·WB + D·WD) + 0

 0 = 165·0 + E·6,9482x10-2 – 100·0 – D·2,1168x10-2

0 = E·6,9482x10-2 – D·2,1168x10-2

𝐷·2,1168𝑥10−2
0 = 65 + E·5,238x10-3 – D·1,4412x10-2 E= 6,9482𝑥10−2

0 = E·6,9482x10-2 – D·2,1168x10-2
𝐷·2,1168𝑥10−2
65 + ( 6,9482𝑥10−2
)· 5,238x10-3 – D·1,4412x10-2 =0

D = 65/1,28x10-2=5078,125 kg/h
𝟓𝟎𝟕𝟖,𝟏𝟐𝟓·𝟐,𝟏𝟏𝟔𝟖𝒙𝟏𝟎−𝟐
E= = 1547,07 kg/h
𝟔,𝟗𝟒𝟖𝟐𝒙𝟏𝟎−𝟐