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States of Matter

Matter: Anything which has mass and occupies space.

Gaseous Parameters
Temperature, Volume, Pressure

Gaseous Laws
Ideal Gas Equation
PV =nRT

Boyle’s Law
1
P∝
V
( T const )
Charles’ Law
V ∝T
( P const )

Gay Lussac’s Law


P∝T
( V const )

Avogadro’s Law
V ∝n
( P ,T const )
R = 0.0821 or 8/3 L-atm / mol-K
R = 2 cal/mol K
R = 8.314 or 25/3 J/mol K

Density of Ideal Gas


PM
δ gas =
RT
Dalton’s Law of Partial Pressures
For a mixture of gases,
PT =P A + P B + PC
(A, B, C are non-reacting)
P A nA
= =x A
PT nT
Diffusion
Rate of Diffusion
PA
rd ∝
√ MT

KTG (Kinetic Theory of Gases)


3 nRT
K . E=
2
Gaseous Velocities

v mp=
√ 2 RT
M
; v avg=

8 RT
πM √
; v rms=
3 RT
M

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