CPP FIITJEE G.O.

C

1. Among C H3 10, 20, and 30 carbocation, strongest Lewis acid is

(A) 10 (B) 20 (C) 30 (D) C H3

2. The C – H bond length is longest in

(A) C2H2 (B) C2H6 (C) H – C  N (D) C6H6
.. 
3. CH3 - O - C H2 is a very stable carbocation due to
..
(A) – I effect of oxygen (B) + R effect of oxygen
(C) + I effect of – CH3 group (D) none of the above

4. Which of the following is most stable

+
+ + CH2
H2C H3C (C) CH
(A) (B) H3C OH
+ OH (D)
OH CH OH H3C

5. Most stable carbonium ion is

+ +
CH 2 CH 2

(A) (B)

Cl NO 2
+ +
CH2 CH
(C) (D) 2

OCH 3

6. Which of the following amines is least basic in benzene ?

CH3

H 3C N
(A) (B)
NH2 H3C CH3

H3C (D)
(C) None
NH

CH3

7. Which one is most basic?

O O O NH
|| || ||
(A) Me – C – NH2 (B) Me – C – H (C) H2N – C – NH2 (D) H2N – C– NH2

8. Which one is least basic in CCl4 solvent?

(A) Me3N (B) Me2N (C) MeNH2 (D) all are same

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9. OH
OH OH OH

NO 2

NO 2
NO2
(I) (II) (III) (IV)
Arrange the above compounds in the increasing order of their acidic character.
(A) I < II < III < IV (B) I < II < IV < III
(C) I < III < II < IV (D) I < III < IV < II


10. Stability of CH2  CH  CH2 can be explained by:
(A) Inductive effect (B) Electronic effect (C) Resonance (D) Polar effect

11. The order of decreasing stability of the carbanions

(CH3)3C - (I), (CH3)2CH - (II), CH3CH2- (III), C6H5 CH2- (IV) is
(A) (i) > (II) > (III) > (iv) (C) (IV) > (III) > (II) > (I)
(B) (IV) > (I) > (II) > (III) (D) (I) > (II) > (IV) > (III)

12. Dipole moment is shown by

(A) 1, 4 –Dichlorobenzene (B) cis-1,2-Dichloroethene
(C) trans-1,2-Dichloroethene (D) all of them

13. Stability order of the given carbocations will be

+ + +

I II III
(A) I < II < III (B) III < II < I
(C) II < III < I (D) III < I < II

14. Which of the following is the strongest acid ?

(A) CH3 CH2COOH (B) NO2CH2CH2COOH
(C) CH3CHCOOH (D) H3C CH COOH

NO2 CH3

15. Identify the most stable carbocation :

(A) H3C CH CH2 CH2 OCH3

(B) H3C CH CH2 CH2 OCH3

O CH3

(C) H3C CH CH CH3

OCH3

(D) All are equally stable.

16. What is the decreasing order of stability of the ions?

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FIITJEE Ltd., N-W Centre, 31, 32, Central Market, West Avenue Road, Punjabi Bagh, New Delhi - 26, Ph: 011-45634000
   
CH3 – CH – CH3, CH3 – CH – OCH3, CH3 – CH – COCH3
(I) (II) (III)
(A) I > II > III (B) II > III > I
(C) III > I > II (D) II > I > III

17. Which is correct about hybridization of oxygen in given molecules?

O O

I II
(A) in 1st sp2 and in 2nd sp3 (B) in 1st sp3 and in 2nd sp2
(C) in both sp2 (D) in both sp3

18. Among these two resonating structure which is correct regarding their stability
  
RC  O  RC  O
 

I II
(A) I > II (B) I < II
(C) I = II (D) all of these

19. The most stable carbanion among the following is

- -
CH 3 C H 2 CH2

(A) (B)

-
- CH 2
CH2

(C) (D)

NO 2
OCH 3

ANSWERS
1. D 2. B 3. B 4. C
5. C 6. A 7. D 8. C
9. C 10. C 11. B 12. B
13. C 14. C 15. B 16. D
17. A 18. B 19. D

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FIITJEE Ltd., N-W Centre, 31, 32, Central Market, West Avenue Road, Punjabi Bagh, New Delhi - 26, Ph: 011-45634000